SU7509A1 - Chargeable galvanic cell - Google Patents
Chargeable galvanic cellInfo
- Publication number
- SU7509A1 SU7509A1 SU10860A SU10860A SU7509A1 SU 7509 A1 SU7509 A1 SU 7509A1 SU 10860 A SU10860 A SU 10860A SU 10860 A SU10860 A SU 10860A SU 7509 A1 SU7509 A1 SU 7509A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- chargeable
- galvanic cell
- iron
- solution
- oxide
- Prior art date
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 229910052742 iron Inorganic materials 0.000 description 7
- NUJOXMJBOLGQSY-UHFFFAOYSA-N Manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 6
- 229910000468 manganese oxide Inorganic materials 0.000 description 5
- AMWRITDGCCNYAT-UHFFFAOYSA-L manganese(II,III) oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 5
- 210000004027 cells Anatomy 0.000 description 4
- 229910002804 graphite Inorganic materials 0.000 description 4
- 239000010439 graphite Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N Iron(III) oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L Zinc chloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 229910000460 iron oxide Inorganic materials 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- QDHHCQZDFGDHMP-UHFFFAOYSA-N monochloramine Chemical compound ClN QDHHCQZDFGDHMP-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004328 sodium tetraborate Substances 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- 235000005074 zinc chloride Nutrition 0.000 description 2
- 239000011592 zinc chloride Substances 0.000 description 2
- 210000002421 Cell Wall Anatomy 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L Iron(II) sulfate Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Description
Предлагаемый способный к зар дке гальванический элемент комбинируетс из положительных пластин , угольных, и отрицательных- железных. При этом угсЯЛьные пластины обкладываютс бурой окисью марганца, смешанной, дл лучшей электропроводности, с графитом.The proposed chargeable galvanic cell is combined from positive plates, carbon, and negative iron. At the same time, the contaminated plates are lined with brown manganese oxide, mixed with graphite for better conductivity.
Бура окись марганца получаетс прокаливанием перекиси марганца Мп On на воздухе. Вместо того, чтобы массу МпзО и графит пр мо накладывать на уголь, можно приготовл ть тонкие брикеты прессованием и их уже пускать в дело, при чем рецепт дл брикетов по весу следующий:Borax manganese oxide is obtained by calcining manganese peroxide Mn On in air. Instead of putting a mass of MpZO and graphite directly on coal, you can prepare thin briquettes by pressing and have them put into action, and the recipe for briquettes by weight is as follows:
Бурой окиси марганца . 75 частейBrown manganese oxide. 75 pieces
Графита .21 „Graphite .21 „
Лака ,........ 4 „Varnish, ........ 4 „
Бура окись марганца вл етс положительно действующим веществом на угольной пластине. Железные пластины вл ютс в .комбинированном аккумул торе отрицательными полюсами.Borax manganese oxide is a positively active substance on the coal plate. The iron plates are in the combined battery the negative poles.
Перед употреблением железные пластины никелируютс или жеIron plates are nickel plated before use.
могут быть амальгамированы ртутью (что было сделано автором при опыте, а именно: железна пластина покрывалась медью и на последнюю наносилась ртуть тонким слоем). Форма пластины решетчата , с очень тонкими стенками чеек решетки.can be amalgamated by mercury (what was done by the author during the experiment, namely: the iron plate was covered with copper and mercury was applied to the latter in a thin layer). The plate form is lattice, with very thin lattice cell walls.
Посредством прессовани в чейки железных решеток вдавливаетс бура водна окись железа, котора есть отрицательно действующее активное вещество в аккумул торе.By pressing the cells into iron gratings, a drill is pressed into aqueous ferric oxide, which is the negative active ingredient in the accumulator.
Бура водна окись железа получалась автором следующим образом: к раствору железного купороса в воде прибавл лс раствор едкого натра, отчего в растворе по вл лись сначала белые, а затем зеленые хлопь , которые отжимались, промывались и высушивались, при чем их цвет из зеленого при сушке переходил в бурый.The author obtained the water oxide iron oxide in the following way: a solution of caustic soda was added to the solution of ferrous sulfate in water, causing the solution to appear first white and then green flakes, which were squeezed, washed and dried, and their color from green when dried turned into brown.
Электролитом гальванического элемента служит раствор, получаемый следующим способом: К 10% раствора хлористого цинка (ZnCy прибавл етс до насыщени хлористый аммоний ().The electrolyte of the galvanic cell is the solution obtained by the following method: To a 10% solution of zinc chloride (ZnCy is added to saturation ammonium chloride ().
Раствор покрывает пластины до конца брикетов.The solution covers the plates to the end of the briquettes.
Электродвижуща сила предлагаемого элемента равна 1,5-2,3 вольт (по приближенным измерени м, произведенным автором).The electromotive force of the proposed element is 1.5-2.3 volts (according to approximate measurements made by the author).
Предмет патента.The subject of the patent.
Способный к зар дке гальванический элемент, характеризующийс A chargeable galvanic cell characterized by
приме1 ением положительного электрода из брикетированной смеси бурой окиси марганца и графита и отрицательного электрода в виде железной решетки, в отверсти которой запрессована водна окись железа, а в качестве электролита- раствора хлористого аммони с хлористым цинком.by applying a positive electrode from a briquetted mixture of brown manganese oxide and graphite and a negative electrode in the form of an iron lattice, in the hole of which water oxide of iron is pressed, and the electrolyte is a solution of ammonium chloride with zinc chloride.
Publications (1)
Publication Number | Publication Date |
---|---|
SU7509A1 true SU7509A1 (en) | 1929-01-31 |
Family
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