SU411066A1 - - Google Patents

Info

Publication number

SU411066A1

SU411066A1 SU1709781A SU1709781A SU411066A1 SU 411066 A1 SU411066 A1 SU 411066A1 SU 1709781 A SU1709781 A SU 1709781A SU 1709781 A SU1709781 A SU 1709781A SU 411066 A1 SU411066 A1 SU 411066A1

Authority

SU

USSR - Soviet Union

Prior art keywords

catalyst

oxide

propylene

bismuth

yield

Prior art date

1971-10-26

Links

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• 239000003054 catalyst Substances 0.000 claims description 26
• 238000000034 method Methods 0.000 claims description 13
• QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 7
• 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 7
• 230000001590 oxidative effect Effects 0.000 claims description 3
• KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 2
• 229910001948 sodium oxide Inorganic materials 0.000 claims description 2
• JKUMLNOQXADSAD-UHFFFAOYSA-N [Bi].[P] Chemical compound [Bi].[P] JKUMLNOQXADSAD-UHFFFAOYSA-N 0.000 claims 1
• 229910000416 bismuth oxide Inorganic materials 0.000 claims 1
• TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 claims 1
• 229910052698 phosphorus Inorganic materials 0.000 claims 1
• 239000011574 phosphorus Substances 0.000 claims 1
• 150000003839 salts Chemical group 0.000 description 8
• PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 4
• PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 4
• 239000000203 mixture Substances 0.000 description 4
• 238000006243 chemical reaction Methods 0.000 description 3
• 239000007789 gas Substances 0.000 description 3
• 239000000047 product Substances 0.000 description 3
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
• PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
• 229910052797 bismuth Inorganic materials 0.000 description 2
• JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
• 238000001035 drying Methods 0.000 description 2
• 238000001030 gas--liquid chromatography Methods 0.000 description 2
• 238000004519 manufacturing process Methods 0.000 description 2
• 230000003647 oxidation Effects 0.000 description 2
• 238000007254 oxidation reaction Methods 0.000 description 2
• 239000001301 oxygen Substances 0.000 description 2
• 229910052760 oxygen Inorganic materials 0.000 description 2
• 238000001556 precipitation Methods 0.000 description 2
• 238000002360 preparation method Methods 0.000 description 2
• PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
• 239000000126 substance Substances 0.000 description 2
• 238000005979 thermal decomposition reaction Methods 0.000 description 2
• 238000004566 IR spectroscopy Methods 0.000 description 1
• 239000002202 Polyethylene glycol Substances 0.000 description 1
• JANBFCARANRIKJ-UHFFFAOYSA-N bis(3-methylbutyl) benzene-1,2-dicarboxylate Chemical compound CC(C)CCOC(=O)C1=CC=CC=C1C(=O)OCCC(C)C JANBFCARANRIKJ-UHFFFAOYSA-N 0.000 description 1
• KGYVPEZNLFNUKA-UHFFFAOYSA-N bismuth palladium Chemical compound [Pd].[Bi] KGYVPEZNLFNUKA-UHFFFAOYSA-N 0.000 description 1
• 239000007795 chemical reaction product Substances 0.000 description 1
• 230000000052 comparative effect Effects 0.000 description 1
• 238000004821 distillation Methods 0.000 description 1
• 230000000694 effects Effects 0.000 description 1
• 238000002474 experimental method Methods 0.000 description 1
• 239000011521 glass Substances 0.000 description 1
• 238000010438 heat treatment Methods 0.000 description 1
• 229910052748 manganese Inorganic materials 0.000 description 1
• 239000011572 manganese Substances 0.000 description 1
• AMWRITDGCCNYAT-UHFFFAOYSA-L manganese oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 1
• 229910044991 metal oxide Inorganic materials 0.000 description 1
• 150000004706 metal oxides Chemical class 0.000 description 1
• JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
• 229910052757 nitrogen Inorganic materials 0.000 description 1
• 230000000737 periodic effect Effects 0.000 description 1
• IBIRZFNPWYRWOG-UHFFFAOYSA-N phosphane;phosphoric acid Chemical compound P.OP(O)(O)=O IBIRZFNPWYRWOG-UHFFFAOYSA-N 0.000 description 1
• 229920001223 polyethylene glycol Polymers 0.000 description 1
• 239000002861 polymer material Substances 0.000 description 1
• 229910052573 porcelain Inorganic materials 0.000 description 1
• 239000002244 precipitate Substances 0.000 description 1
• 239000004576 sand Substances 0.000 description 1
• 239000013049 sediment Substances 0.000 description 1
• 229940032094 squalane Drugs 0.000 description 1
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1