SK279294B6 - Spôsob výroby hydrogenovaných konjugovaných diolef - Google Patents
Spôsob výroby hydrogenovaných konjugovaných diolef Download PDFInfo
- Publication number
- SK279294B6 SK279294B6 SK1397-91A SK139791A SK279294B6 SK 279294 B6 SK279294 B6 SK 279294B6 SK 139791 A SK139791 A SK 139791A SK 279294 B6 SK279294 B6 SK 279294B6
- Authority
- SK
- Slovakia
- Prior art keywords
- polymer
- hydrogenation
- process according
- titanium
- hydrogen
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 145
- 238000000034 method Methods 0.000 title claims abstract description 48
- 150000001993 dienes Chemical class 0.000 title claims abstract description 34
- 229920001577 copolymer Polymers 0.000 title claims description 14
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 72
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 56
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 48
- 239000001257 hydrogen Substances 0.000 claims abstract description 48
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 32
- -1 alkoxy lithium compounds Chemical class 0.000 claims abstract description 18
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 12
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 12
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 12
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 10
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 9
- 239000003999 initiator Substances 0.000 claims abstract description 3
- 239000010936 titanium Substances 0.000 claims description 45
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 41
- 229910052719 titanium Inorganic materials 0.000 claims description 41
- 239000003054 catalyst Substances 0.000 claims description 33
- 230000008569 process Effects 0.000 claims description 30
- 229910000103 lithium hydride Inorganic materials 0.000 claims description 28
- 238000006116 polymerization reaction Methods 0.000 claims description 19
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 14
- WGOPGODQLGJZGL-UHFFFAOYSA-N lithium;butane Chemical compound [Li+].CC[CH-]C WGOPGODQLGJZGL-UHFFFAOYSA-N 0.000 claims description 14
- 239000000178 monomer Substances 0.000 claims description 14
- 229920001400 block copolymer Polymers 0.000 claims description 13
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 12
- 150000001340 alkali metals Chemical class 0.000 claims description 9
- KSFCHHFBQJDGFF-UHFFFAOYSA-L cyclopenta-1,3-diene;dichlorotitanium Chemical compound Cl[Ti]Cl.C1C=CC=C1.C1C=CC=C1 KSFCHHFBQJDGFF-UHFFFAOYSA-L 0.000 claims description 8
- 239000003505 polymerization initiator Substances 0.000 claims description 6
- 238000005507 spraying Methods 0.000 claims description 6
- 238000011065 in-situ storage Methods 0.000 claims description 5
- 230000035484 reaction time Effects 0.000 claims description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 4
- 150000002900 organolithium compounds Chemical class 0.000 claims description 4
- 150000003609 titanium compounds Chemical class 0.000 claims description 4
- 125000003545 alkoxy group Chemical group 0.000 claims description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 3
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 3
- 125000004104 aryloxy group Chemical group 0.000 claims description 3
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 3
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 3
- 125000005843 halogen group Chemical group 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 2
- 150000001339 alkali metal compounds Chemical class 0.000 claims description 2
- 229910000102 alkali metal hydride Inorganic materials 0.000 claims description 2
- 150000008046 alkali metal hydrides Chemical class 0.000 claims description 2
- 125000002524 organometallic group Chemical group 0.000 claims description 2
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 claims description 2
- 125000002897 diene group Chemical group 0.000 claims 2
- 150000003440 styrenes Chemical class 0.000 claims 2
- 238000007334 copolymerization reaction Methods 0.000 claims 1
- 150000002902 organometallic compounds Chemical class 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 23
- 238000006243 chemical reaction Methods 0.000 description 22
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 22
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 18
- 229920002223 polystyrene Polymers 0.000 description 15
- 239000004793 Polystyrene Substances 0.000 description 14
- 150000001336 alkenes Chemical class 0.000 description 14
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 14
- 238000002474 experimental method Methods 0.000 description 9
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 230000000737 periodic effect Effects 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 239000003638 chemical reducing agent Substances 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 3
- 238000010183 spectrum analysis Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 description 2
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 125000005234 alkyl aluminium group Chemical group 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 229910052805 deuterium Inorganic materials 0.000 description 2
- 150000008282 halocarbons Chemical class 0.000 description 2
- 229920006158 high molecular weight polymer Polymers 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 150000002642 lithium compounds Chemical class 0.000 description 2
- SIAPCJWMELPYOE-UHFFFAOYSA-N lithium hydride Chemical compound [LiH] SIAPCJWMELPYOE-UHFFFAOYSA-N 0.000 description 2
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical group C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- DKCPKDPYUFEZCP-UHFFFAOYSA-N 2,6-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=C1O DKCPKDPYUFEZCP-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical group C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- QTTAWIGVQMSWMV-UHFFFAOYSA-N 3,4-dimethylhexa-1,3-diene Chemical compound CCC(C)=C(C)C=C QTTAWIGVQMSWMV-UHFFFAOYSA-N 0.000 description 1
- KFDVPJUYSDEJTH-UHFFFAOYSA-N 4-ethenylpyridine Chemical group C=CC1=CC=NC=C1 KFDVPJUYSDEJTH-UHFFFAOYSA-N 0.000 description 1
- CJSBUWDGPXGFGA-UHFFFAOYSA-N 4-methylpenta-1,3-diene Chemical compound CC(C)=CC=C CJSBUWDGPXGFGA-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- OEQMCMBXMGAHDM-UHFFFAOYSA-N C1=CC=CC1[Ti](CCCC)(CCCC)C1C=CC=C1 Chemical compound C1=CC=CC1[Ti](CCCC)(CCCC)C1C=CC=C1 OEQMCMBXMGAHDM-UHFFFAOYSA-N 0.000 description 1
- CVDMCCRGHFDEPP-UHFFFAOYSA-N C=1C=CC=CC=1C[Ti](C1C=CC=C1)(C1C=CC=C1)CC1=CC=CC=C1 Chemical compound C=1C=CC=CC=1C[Ti](C1C=CC=C1)(C1C=CC=C1)CC1=CC=CC=C1 CVDMCCRGHFDEPP-UHFFFAOYSA-N 0.000 description 1
- BQBGDPOPPYOXTI-UHFFFAOYSA-N CCCCCC[Ti](CCCCCC)(C1C=CC=C1)C1C=CC=C1 Chemical compound CCCCCC[Ti](CCCCCC)(C1C=CC=C1)C1C=CC=C1 BQBGDPOPPYOXTI-UHFFFAOYSA-N 0.000 description 1
- FJRNYJKSTZPFNN-UHFFFAOYSA-N C[Si](C)(C)C[Ti](C1C=CC=C1)C1C=CC=C1 Chemical compound C[Si](C)(C)C[Ti](C1C=CC=C1)C1C=CC=C1 FJRNYJKSTZPFNN-UHFFFAOYSA-N 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000002178 anthracenyl group Chemical group C1(=CC=CC2=CC3=CC=CC=C3C=C12)* 0.000 description 1
- 125000002029 aromatic hydrocarbon group Chemical class 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 150000004074 biphenyls Chemical class 0.000 description 1
- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical compound C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 239000012018 catalyst precursor Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229920000547 conjugated polymer Polymers 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- RAABOESOVLLHRU-UHFFFAOYSA-N diazene Chemical compound N=N RAABOESOVLLHRU-UHFFFAOYSA-N 0.000 description 1
- 229910000071 diazene Inorganic materials 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002641 lithium Chemical group 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910052987 metal hydride Inorganic materials 0.000 description 1
- 150000004681 metal hydrides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000002790 naphthalenes Chemical group 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000005506 phthalide group Chemical group 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000005415 substituted alkoxy group Chemical group 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000004260 weight control Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/02—Hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/529,807 US5039755A (en) | 1990-05-29 | 1990-05-29 | Selective hydrogenation of conjugated diolefin polymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SK279294B6 true SK279294B6 (sk) | 1998-09-09 |
Family
ID=24111316
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SK1397-91A SK279294B6 (sk) | 1990-05-29 | 1991-05-13 | Spôsob výroby hydrogenovaných konjugovaných diolef |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US5039755A (cs) |
| EP (1) | EP0460725B1 (cs) |
| JP (1) | JP3162103B2 (cs) |
| KR (1) | KR0185670B1 (cs) |
| CN (1) | CN1036655C (cs) |
| AT (1) | ATE125552T1 (cs) |
| BR (1) | BR9101957A (cs) |
| CA (1) | CA2042438C (cs) |
| CZ (1) | CZ280294B6 (cs) |
| DE (1) | DE69111519T2 (cs) |
| ES (1) | ES2074647T3 (cs) |
| HU (1) | HU211067B (cs) |
| PT (1) | PT97648B (cs) |
| RU (1) | RU2067589C1 (cs) |
| SK (1) | SK279294B6 (cs) |
Families Citing this family (112)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5399626A (en) * | 1991-04-29 | 1995-03-21 | Shell Oil Company | Viscous conjugated diene block copolymers |
| US5229464A (en) * | 1991-04-29 | 1993-07-20 | Shell Oil Company | Epoxidized viscous conjugated diene block copolymers |
| US5206307A (en) * | 1991-09-09 | 1993-04-27 | Shell Oil Company | Process for selective hydrogenation of conjugated diolefin polymers |
| US5166277A (en) * | 1991-10-31 | 1992-11-24 | Shell Oil Company | Hydrogenation of unsaturation in low molecular weight diene polymers |
| US5173537A (en) * | 1991-12-20 | 1992-12-22 | Shell Oil Company | Selective hydrogenation of conjugated diolefin poylmers |
| US5242961A (en) * | 1992-05-28 | 1993-09-07 | Shell Oil Company | Color prevention in titanium catalyzed hydrogenated diene polymers |
| US5242986A (en) * | 1992-08-10 | 1993-09-07 | Shell Oil Company | Selective partial hydrogenation of conjugated diolefin polymers |
| ES2050620B1 (es) * | 1992-11-03 | 1994-12-16 | Repsol Quimica Sa | Procedimiento de hidrogenacion en disolucion de los dobles enlaces de polimeros de dienos conjugados y copolimero bloque hidrogenado producido. |
| US5244980A (en) * | 1992-12-07 | 1993-09-14 | Shell Oil Company | Selective hydrogenation of conjugated diolefin polymers with Tebbe's reagent |
| US5336726A (en) * | 1993-03-11 | 1994-08-09 | Shell Oil Company | Butadiene polymers having terminal silyl groups |
| US5536772A (en) * | 1993-06-18 | 1996-07-16 | Shell Oil Company | Radiation cured conjugated diene block copolymer compositions |
| USH1517H (en) * | 1993-07-12 | 1996-02-06 | Shell Oil Company | Radiation curable printing ink composition |
| FI97141C (fi) * | 1994-03-14 | 1996-10-25 | Neste Oy | Menetelmä tyydyttämättömien polymeerien selektiiviseksi hydrogenoimiseksi |
| US5447995A (en) | 1994-05-27 | 1995-09-05 | Shell Oil Company | Method for producing asymmetric radial polymers |
| US5550196A (en) | 1994-11-09 | 1996-08-27 | Shell Oil Company | Low viscosity adhesive compositions containing asymmetric radial polymers |
| WO1996018655A1 (en) * | 1994-12-12 | 1996-06-20 | The Dow Chemical Company | Hydrogenation of unsaturated polymers using monocyclopentadienyl group iv metal catalysts |
| KR100201228B1 (ko) * | 1995-10-17 | 1999-06-15 | 박찬구 | 리빙중합체의 수첨방법 |
| CN1130383C (zh) * | 1996-03-15 | 2003-12-10 | 国际壳牌研究有限公司 | 共轭二烯聚合物的氢化方法及其适用的催化剂组合物 |
| US5863646A (en) * | 1996-03-25 | 1999-01-26 | Ppg Industries, Inc. | Coating composition for plastic substrates and coated plastic articles |
| US6001469A (en) * | 1996-03-28 | 1999-12-14 | Ppg Industries Ohio, Inc. | Thermosettable primer and topcoat for plastics, a method for applying and coated plastic articles |
| US5814709A (en) * | 1996-04-12 | 1998-09-29 | Shell Oil Company | Process for hydrogenation on conjugataed diene polymers and catalyst composition suitable for use therein |
| KR0182835B1 (ko) * | 1996-04-26 | 1999-05-15 | 김흥기 | 올레핀성 이중결합을 갖는 리빙중합체의 선택적 수소화 방법 |
| US5705571A (en) * | 1996-05-17 | 1998-01-06 | Taiwan Synthetic Rubber Corporation | Process for selective hydrogenation of conjugated diene polymer |
| JPH1053614A (ja) * | 1996-05-29 | 1998-02-24 | Shell Internatl Res Maatschappij Bv | 共役ジエンポリマーの水素化のためのプロセスとこのプロセスで使用するのに適した触媒組成物 |
| IT1284105B1 (it) * | 1996-07-04 | 1998-05-08 | Enichem Elastomers | Procedimento per la preparazione di un catalizzatore utile per la idrogenazione di copolimeri stirene-butadiene |
| JPH10101727A (ja) * | 1996-09-24 | 1998-04-21 | Shell Internatl Res Maatschappij Bv | オレフィン又はポリマーを水素化するための触媒及び方法 |
| US5710192A (en) * | 1996-10-02 | 1998-01-20 | Shell Oil Company | Polydiene diols in resilient polyurethane foams |
| US5849806A (en) * | 1997-05-23 | 1998-12-15 | Shell Oil Company | Resilient polyurethane foams of polydiene diols and tackifying resin |
| RU2149877C1 (ru) * | 1997-06-20 | 2000-05-27 | Репсол Кимика С.А. | Способ получения гидрированного каучука |
| KR100219260B1 (ko) * | 1997-07-24 | 1999-09-01 | 박찬구 | 리빙 중합체 수첨용 신규 촉매 및 촉매를 이용한 수첨방법 |
| US6187873B1 (en) * | 1997-08-07 | 2001-02-13 | Shell Oil Company | Increased throughput in the manufacture of block copolymers by reduction in polymer cement viscosity through the addition of polar solvents |
| ES2172941T3 (es) | 1997-10-31 | 2002-10-01 | Kraton Polymers Res Bv | Composicion de espuma que contiene aceite, elastomero termoplastico y particulas expandibles. |
| IT1296066B1 (it) * | 1997-11-06 | 1999-06-09 | Enichem Spa | Procedimento per la idrogenazione di (co) polimeri dienici |
| US6203913B1 (en) | 1997-12-19 | 2001-03-20 | Ppg Industries Ohio, Inc. | Coating composition for plastic substrates |
| US6593423B1 (en) * | 2000-05-03 | 2003-07-15 | Ppg Industries Ohio, Inc. | Adhesion promoting agent and coating compositions for polymeric substrates |
| KR100250230B1 (ko) * | 1998-03-04 | 2000-04-01 | 박찬구 | 공역디엔 중합체의 수소화 방법 |
| TW583027B (en) * | 1998-10-30 | 2004-04-11 | Shell Int Research | A method for preparing a hydrogenation catalyst system |
| US6303550B1 (en) | 1998-11-06 | 2001-10-16 | Infineum Usa L.P. | Lubricating oil composition |
| DE60019439T2 (de) * | 1999-07-02 | 2005-09-01 | Kraton Polymers Research B.V. | Schmelzverarbeitbare, gegen bleichmittel resistente, dauerhafte fasern mit hoher elastischer rückgewinnung und niedriger druckentspannung aus polyurethan-elastomeren |
| KR100348761B1 (ko) | 1999-11-26 | 2002-08-13 | 금호석유화학 주식회사 | 공액디엔을 포함하는 중합체의 선택적 수소화 방법 |
| US7877949B1 (en) * | 2000-02-29 | 2011-02-01 | Owens Corning Intellectual Capital, Llc | Shingle for optically simulating a slate roof |
| DE60116917T2 (de) | 2000-04-21 | 2006-09-07 | Jsr Corp. | Thermoplastische Harzzusammensetzung |
| EP1311561B1 (en) * | 2000-07-28 | 2005-06-08 | KRATON Polymers Research B.V. | Process for preparing partially hydrogenated butadiene polymers |
| KR100411861B1 (ko) | 2000-11-28 | 2003-12-18 | 금호석유화학 주식회사 | 유기티타늄 화합물로 선택적으로 수소화된 중합체로부터금속 촉매를 제거하는 방법 |
| KR100833720B1 (ko) * | 2000-12-01 | 2008-05-29 | 크레이튼 폴리머즈 리서치 비.브이. | 겔화 성향이 감소된 역청질 조성물 |
| ES2185467B2 (es) * | 2000-12-20 | 2004-10-01 | Chi Mei Corporation | Composicion catalizadora para hidrogenacion de cauchos sinteticos a base de dieno conjugado. |
| ES2307678T3 (es) | 2001-03-26 | 2008-12-01 | Jsr Corporation | Polimero modificado hidrogenado, procedimiento para producir el mismo y composicion que contiene el mismo. |
| WO2003064528A2 (en) * | 2002-01-31 | 2003-08-07 | Kraton Polymers Research B.V. | Block copolymer compositions, having improved mechanical properties and processability |
| JP4179990B2 (ja) * | 2002-01-31 | 2008-11-12 | クレイトン・ポリマーズ・リサーチ・ベー・ベー | 機械的特性と加工性が改善されたブロック共重合体組成物およびそれに用いるスチレン系ブロック共重合体 |
| US6777026B2 (en) * | 2002-10-07 | 2004-08-17 | Lord Corporation | Flexible emissive coatings for elastomer substrates |
| US6844412B2 (en) * | 2002-07-25 | 2005-01-18 | Lord Corporation | Ambient cured coatings and coated rubber products therefrom |
| EP1431348A1 (en) * | 2002-12-16 | 2004-06-23 | KRATON Polymers Research B.V. | Block copolymer modified bitumen felts |
| KR100515452B1 (ko) * | 2003-01-04 | 2005-09-20 | 금호석유화학 주식회사 | 고속분사 노즐 장착 반응기로부터 제조된 리튬하이드라이드를 사용하여 선택적으로 수소화된 공역디엔 중합체를 제조하는 방법 |
| US7144933B2 (en) * | 2003-11-12 | 2006-12-05 | Eastman Chemical Company | Modified asphalt compositions |
| US7202290B2 (en) * | 2003-11-12 | 2007-04-10 | Eastman Chemical Company | Modified asphalt compositions |
| US20050215724A1 (en) * | 2004-03-25 | 2005-09-29 | Kraton Polymers U.S. Llc | Thermoplastic gel compositions that can be converted into thermoset gel compositions by exposure to radiation |
| DE602005009514D1 (de) * | 2004-03-25 | 2008-10-16 | Kraton Polymers Res Bv | Thermoplastische gelzusammensetzungen, die durch bestrahlung in duroplastische gelzusammensetzungen umgewandelt werden können |
| DE602004012618T2 (de) * | 2004-03-29 | 2009-05-14 | Pirelli & C. S.P.A. | Thermoplastisches elastomer enthaltend in verteilter form vulkanisierten kautschuk |
| EP1582576A1 (en) * | 2004-04-02 | 2005-10-05 | KRATON Polymers Research B.V. | Process for the prevention or restriction of oil spiLls |
| WO2006024329A1 (en) * | 2004-09-03 | 2006-03-09 | Kraton Polymers Research B.V. | Foamable polymeric compositions and articles containing foamed compositions |
| EP1674530A1 (en) * | 2004-12-24 | 2006-06-28 | Kraton Polymers Research B.V. | High melt strength thermoplastic elastomer composition |
| CA2600852A1 (en) * | 2005-03-01 | 2006-09-08 | Firestone Polymers, Llc | Oxygen scavenging polyesters with reduced recycle color |
| JP4716756B2 (ja) * | 2005-03-03 | 2011-07-06 | 旭化成ケミカルズ株式会社 | ランダム共重合体の製造方法 |
| CN101429305B (zh) | 2005-09-12 | 2012-09-26 | 陶氏环球技术有限责任公司 | 乙烯/α-烯烃组合物制备的汽车部件 |
| JP2009509727A (ja) * | 2005-09-22 | 2009-03-12 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 樹脂基材上に付着コーティングを生成する方法 |
| JP2009510194A (ja) * | 2005-09-22 | 2009-03-12 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 樹脂基材用の付着コーティング組成物 |
| US7645507B2 (en) * | 2005-10-24 | 2010-01-12 | Kraton Polymers U.S. Llc | Protective films and pressure sensitive adhesives |
| KR20080080569A (ko) | 2005-12-05 | 2008-09-04 | 제이에스알 가부시끼가이샤 | 열가소성 엘라스토머 조성물, 발포체 및 그의 제조 방법 |
| EP1980589B1 (en) | 2006-02-02 | 2017-12-20 | JSR Corporation | Hydrogenated diene polymer composition and rubber molded article |
| EP1847557A1 (en) * | 2006-04-21 | 2007-10-24 | Kraton Polymers Research B.V. | High molecular weight coupled block copolymer compositions |
| BRPI0716296B1 (pt) | 2006-11-01 | 2019-01-15 | Dow Global Technologies Inc | composição, artigo, estrutura laminada, dispersão, artigo moldado por injeção, artigo moldado, artigo para calçados e peça automotiva |
| US8227038B2 (en) * | 2007-01-12 | 2012-07-24 | E I Du Pont De Nemours And Company | Adhesion promoting cleaner solution |
| WO2008117868A1 (ja) | 2007-03-28 | 2008-10-02 | Jsr Corporation | 変性水添ジエン系重合体組成物 |
| KR100910255B1 (ko) | 2007-10-08 | 2009-07-31 | 금호석유화학 주식회사 | 수소화된 공역디엔계 중합체의 제조방법 |
| CA2913375A1 (en) | 2007-10-19 | 2009-04-30 | Lord Corporation | Suspension system for aircraft auxiliary power unit with elastomeric member |
| US9017791B2 (en) | 2008-05-13 | 2015-04-28 | Owens Corning Intellectual Capital, Llc | Shingle blank having formation of individual hip and ridge roofing shingles |
| US9151055B2 (en) * | 2009-02-25 | 2015-10-06 | Owens Corning Intellectual Capital, Llc | Hip and ridge roofing material |
| US11313127B2 (en) | 2009-02-25 | 2022-04-26 | Owens Corning Intellectual Capital, Llc | Hip and ridge roofing material |
| US9574350B2 (en) | 2009-03-20 | 2017-02-21 | Owens Corning Intellectual Capital, Llc | Sealant composition for releasable shingle |
| DK2272588T3 (da) | 2009-06-22 | 2013-08-05 | Dynasol Elastomeros Sa | Katalysator til hydrogenering af umættede forbindelser |
| EP2289947A1 (en) * | 2009-08-26 | 2011-03-02 | University Of Waterloo | Nano-sized hydrogenated diene-based latex particles |
| US20110171119A1 (en) * | 2009-12-14 | 2011-07-14 | Rachid Yazami | Hydrogen storage and/or generation |
| KR101739161B1 (ko) | 2009-12-25 | 2017-05-23 | 제이에스알 가부시끼가이샤 | 축열재용 조성물 및 축열재 |
| US9097020B2 (en) | 2010-03-04 | 2015-08-04 | Owens Corning Intellectual Capital, Llc | Hip and ridge roofing shingle |
| IT1400743B1 (it) | 2010-06-30 | 2013-07-02 | Dow Global Technologies Inc | Composizioni polimeriche |
| JP5120522B2 (ja) | 2010-11-29 | 2013-01-16 | Ｊｓｒ株式会社 | 電池用バインダー組成物、電池電極用スラリー、固体電解質組成物、電極及び全固体型電池 |
| US20150368387A1 (en) | 2013-02-14 | 2015-12-24 | Jsr Corporation | Method for producing hydrogenated conjugated diene polymer |
| DE102013204991A1 (de) | 2013-03-21 | 2014-09-25 | Evonik Industries Ag | Herstellung von Polyurethanschäumen, die Polyole auf Polyolefinbasis enthalten |
| TWI586693B (zh) | 2013-07-23 | 2017-06-11 | 財團法人工業技術研究院 | 選擇性氫化共聚物的方法 |
| US9758970B2 (en) | 2014-02-25 | 2017-09-12 | Owens Corning Intellectual Capital, Llc | Laminated hip and ridge shingle |
| USD755997S1 (en) | 2014-02-27 | 2016-05-10 | Owens Corning Intellectual Capital, Llc | Shingle |
| HUE044702T2 (hu) | 2015-03-12 | 2019-11-28 | Huntsman Adv Mat Licensing Switzerland Gmbh | Poliol összetevõ pur-habok elõállításához |
| TW201714952A (zh) | 2015-09-02 | 2017-05-01 | Jsr Corp | 組成物及成形體 |
| JP6716942B2 (ja) | 2016-02-18 | 2020-07-01 | 住友ゴム工業株式会社 | 空気入りタイヤ及び空気入りタイヤの製造方法 |
| JP6805502B2 (ja) | 2016-02-18 | 2020-12-23 | 住友ゴム工業株式会社 | 空気入りタイヤ |
| JP6862787B2 (ja) | 2016-11-22 | 2021-04-21 | 住友ゴム工業株式会社 | 空気入りタイヤ |
| EP3378877B1 (en) * | 2017-02-28 | 2019-06-19 | Evonik Oil Additives GmbH | Hydrogenated polybutadienes useful as lubricant additives |
| JP6953841B2 (ja) | 2017-07-05 | 2021-10-27 | 住友ゴム工業株式会社 | 空気入りタイヤ |
| JP6417064B1 (ja) | 2018-04-09 | 2018-10-31 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物及びタイヤ |
| JP7400717B2 (ja) | 2018-07-24 | 2023-12-19 | 日本ゼオン株式会社 | ブロック共重合体及びその製造方法、ブロック共重合体水素化物、重合体組成物、並びに、成形体 |
| EP3747943B1 (en) | 2018-08-06 | 2024-06-26 | Sumitomo Rubber Industries, Ltd. | Pneumatic tire |
| JP2020079336A (ja) | 2018-11-12 | 2020-05-28 | 住友ゴム工業株式会社 | ゴム組成物及び空気入りタイヤ |
| JP7224149B2 (ja) | 2018-11-12 | 2023-02-17 | 住友ゴム工業株式会社 | ゴム組成物及び空気入りタイヤ |
| JP7159799B2 (ja) | 2018-11-12 | 2022-10-25 | 住友ゴム工業株式会社 | 空気入りタイヤ |
| JP7224150B2 (ja) | 2018-11-12 | 2023-02-17 | 住友ゴム工業株式会社 | ゴム組成物及び空気入りタイヤ |
| JP7253897B2 (ja) | 2018-11-12 | 2023-04-07 | 住友ゴム工業株式会社 | ゴム組成物及び空気入りタイヤ |
| WO2020162304A1 (ja) | 2019-02-05 | 2020-08-13 | 住友ゴム工業株式会社 | ゴム組成物及びタイヤ |
| WO2020261618A1 (ja) | 2019-06-26 | 2020-12-30 | 住友ゴム工業株式会社 | 空気入りタイヤ |
| JP7585053B2 (ja) | 2020-02-05 | 2024-11-18 | 株式会社Ｅｎｅｏｓマテリアル | 重合体組成物、架橋重合体、及びタイヤ |
| WO2023006474A1 (en) | 2021-07-26 | 2023-02-02 | Basf Coatings Gmbh | Peelable coating system and methods for forming the peelable coating system |
| JP2024074035A (ja) | 2022-11-18 | 2024-05-30 | 住友ゴム工業株式会社 | タイヤ |
| WO2025133963A1 (en) * | 2023-12-21 | 2025-06-26 | Versalis S.P.A. | Viscosity index improver additives of lubricating oils and process for their preparation |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB363810A (en) * | 1930-12-11 | 1931-12-31 | Ig Farbenindustrie Ag | Improvements in the polymerisation of diolefines |
| US2449949A (en) * | 1944-09-04 | 1948-09-21 | Shell Dev | Hydrogenated linear polymers and copolymers of branch-chain hexadienes |
| US3113986A (en) * | 1962-01-08 | 1963-12-10 | Hercules Powder Co Ltd | Hydrogenation of unsaturated hydrocarbons |
| US3475399A (en) * | 1966-04-26 | 1969-10-28 | Standard Oil Co | Saturation of polyalkylenes |
| US3580897A (en) * | 1967-11-27 | 1971-05-25 | Bridgestone Tire Co Ltd | Process for producing hydrogenated hydrocarbon polymers |
| US3525729A (en) * | 1967-12-04 | 1970-08-25 | Phillips Petroleum Co | Process for production of polymers with controlled saturation |
| US3472829A (en) * | 1968-06-10 | 1969-10-14 | Exxon Research Engineering Co | Process for broadening the molecular weight distribution in polymers |
| US3541064A (en) * | 1968-07-11 | 1970-11-17 | Bridgestone Tire Co Ltd | Hydrogenation catalysts and a process for hydrogenating polymers by the use of them |
| US3720654A (en) * | 1971-05-21 | 1973-03-13 | Cities Service Co | Molecular sizing process for preparing low molecular isobutylene-conjugated polyene copolymers |
| GB1419012A (en) * | 1973-03-29 | 1975-12-24 | Ici Ltd | Production of polyethylene |
| US3937759A (en) * | 1974-05-01 | 1976-02-10 | Shell Oil Company | Hydrogenation process |
| US4156673A (en) * | 1976-02-10 | 1979-05-29 | Shell Oil Company | Hydrogenated star-shaped polymer |
| FR2480289A1 (fr) * | 1980-04-09 | 1981-10-16 | Michelin & Cie | Procede de preparation de polymeres de dienes conjugues ou de copolymeres de dienes conjugues soit entre eux, soit avec un compose |
| GB2134909B (en) * | 1983-01-20 | 1986-08-20 | Asahi Chemical Ind | Catalytic hydrogenation of conjugated diene polymer |
| US4547555A (en) * | 1983-09-01 | 1985-10-15 | Mobil Oil Corporation | Method for rapid kill gas injection to gas phase polymerization reactors during power failures |
| JPS60220147A (ja) * | 1984-04-18 | 1985-11-02 | Asahi Chem Ind Co Ltd | オレフイン水添触媒および該触媒を用いた重合体の水添方法 |
| US4629767A (en) * | 1985-07-12 | 1986-12-16 | Phillips Petroleum Co. | Hydrogenation process and catalyst |
| JPS62209102A (ja) * | 1986-03-10 | 1987-09-14 | Asahi Chem Ind Co Ltd | ポリマ−の水添法 |
| JPS62209103A (ja) * | 1986-03-10 | 1987-09-14 | Asahi Chem Ind Co Ltd | ポリマ−の水添方法 |
| JP2718059B2 (ja) * | 1988-04-28 | 1998-02-25 | 日本合成ゴム株式会社 | 重合体の水素添加方法および触媒 |
| US4988421A (en) * | 1989-01-12 | 1991-01-29 | Ford Motor Company | Method of toughening diamond coated tools |
-
1990
- 1990-05-29 US US07/529,807 patent/US5039755A/en not_active Expired - Lifetime
-
1991
- 1991-05-13 CN CN91103051A patent/CN1036655C/zh not_active Expired - Fee Related
- 1991-05-13 SK SK1397-91A patent/SK279294B6/sk unknown
- 1991-05-13 AT AT91201154T patent/ATE125552T1/de not_active IP Right Cessation
- 1991-05-13 JP JP13728291A patent/JP3162103B2/ja not_active Expired - Fee Related
- 1991-05-13 KR KR1019910007695A patent/KR0185670B1/ko not_active Expired - Fee Related
- 1991-05-13 CZ CS911397A patent/CZ280294B6/cs not_active IP Right Cessation
- 1991-05-13 BR BR919101957A patent/BR9101957A/pt not_active IP Right Cessation
- 1991-05-13 HU HU911594A patent/HU211067B/hu not_active IP Right Cessation
- 1991-05-13 CA CA002042438A patent/CA2042438C/en not_active Expired - Fee Related
- 1991-05-13 DE DE69111519T patent/DE69111519T2/de not_active Expired - Fee Related
- 1991-05-13 EP EP91201154A patent/EP0460725B1/en not_active Expired - Lifetime
- 1991-05-13 ES ES91201154T patent/ES2074647T3/es not_active Expired - Lifetime
- 1991-05-13 RU SU914895493A patent/RU2067589C1/ru active
- 1991-05-14 PT PT97648A patent/PT97648B/pt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| ES2074647T3 (es) | 1995-09-16 |
| PT97648A (pt) | 1992-02-28 |
| CA2042438A1 (en) | 1991-11-30 |
| ATE125552T1 (de) | 1995-08-15 |
| EP0460725B1 (en) | 1995-07-26 |
| CN1063693A (zh) | 1992-08-19 |
| US5039755A (en) | 1991-08-13 |
| DE69111519D1 (de) | 1995-08-31 |
| DE69111519T2 (de) | 1996-01-04 |
| CA2042438C (en) | 2002-07-09 |
| RU2067589C1 (ru) | 1996-10-10 |
| HU911594D0 (en) | 1991-11-28 |
| JPH0790017A (ja) | 1995-04-04 |
| KR0185670B1 (ko) | 1999-05-15 |
| CZ280294B6 (cs) | 1995-12-13 |
| BR9101957A (pt) | 1991-12-24 |
| JP3162103B2 (ja) | 2001-04-25 |
| KR910020044A (ko) | 1991-12-19 |
| HU211067B (en) | 1995-10-30 |
| CN1036655C (zh) | 1997-12-10 |
| EP0460725A1 (en) | 1991-12-11 |
| HUT62019A (en) | 1993-03-29 |
| CS139791A3 (en) | 1992-02-19 |
| PT97648B (pt) | 1998-08-31 |
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