SG11201808175UA - Metal complexes - Google Patents

Metal complexes

Info

Publication number
SG11201808175UA
SG11201808175UA SG11201808175UA SG11201808175UA SG11201808175UA SG 11201808175U A SG11201808175U A SG 11201808175UA SG 11201808175U A SG11201808175U A SG 11201808175UA SG 11201808175U A SG11201808175U A SG 11201808175UA SG 11201808175U A SG11201808175U A SG 11201808175UA
Authority
SG
Singapore
Prior art keywords
international
independently
texas
het
st
Prior art date
Application number
SG11201808175UA
Inventor
Mahsa Heydari
Roger Kuhlman
C Harlan
Original Assignee
Univation Tech Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US201662314480P priority Critical
Application filed by Univation Tech Llc filed Critical Univation Tech Llc
Priority to PCT/US2017/022008 priority patent/WO2017172332A1/en
Publication of SG11201808175UA publication Critical patent/SG11201808175UA/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/003Compounds containing elements of Groups 4 or 14 of the Periodic System without C-Metal linkages
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/28Titanium compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12Olefin polymerisation or copolymerisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46Titanium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48Zirconium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/49Hafnium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Abstract

INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property -, Organization MD IIIII0110111 11111 010111110111010111111111111111111011111111111110111111 International Bureau .. .... ..Yejd ..... .....!;,,, (10) International Publication Number (43) International Publication Date WO 2017/172332 Al 5 October 2017 (05.10.2017) W I PO I P CT (51) International Patent Classification: (81) Designated States (unless otherwise indicated, for every C07F 7/00 (2006.01) CO8F 4/76 (2006.01) kind of national protection available): AE, AG, AL, AM, C07F 7/28 (2006.01) AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, (21) International Application Number: DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, PCT/US2017/022008 HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KH, KN, (22) International Filing Date: KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, 13 March 2017 (13.03.2017) MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, (25) Filing Language: English RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, (26) Publication Language: English TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (30) Priority Data: 62/314,480 29 March 2016 (29.03.2016) US (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, (71) Applicant: UNIVATION TECHNOLOGIES, LLC GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, [US/US]; 5555 San Felipe, Suite 1950, Houston, Texas TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, 77056 (US). TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, (72) Inventors: HEYDARI, Mahsa; 4806 Chenevert St., Hous- LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, ton, Texas 77004 (US). KUHLMAN, Roger, L.; 2301 SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, North Brazosport Boulevard, B-1811, Freeport, Texas — 77541 (US). HARLAN, C., Jeff; 15810 Dunmoor Dr., GW, KM, ML, MR, NE, SN, TD, TG). — Houston, Texas 77059 (US). Published: _ with international search report (Art. 21(3)) (74) Agent: HAGEN, Robert, J.; Brooks, Cameron & — _ = Huebsch, PLLC, 1201 Marquette Avenue South, Suite 400, Minneapolis, Minnesota 55403 (US). = = = = = = = = = = = = — (54) Title: METAL COMPLEXES = L., Het / X 1/X 1-1 / I I Y ( )11 i (I) N Het L M (R 1 )n M ei IN ,-1 ----. (57) : Embodiments of the present disclosure are directed towards metal complexes that can be utilized to form polymers. IN As an example, the present disclosure provides a metal complex of Formula (I) wherein M is Zr, Hf, or Ti; each Het is independently C a heterocyclic; each L is independently a bridging group; each X is independently Cl, Br, I, or alkyl; each R is independently selec- 1 ei ted from the group including hydrogen, alkyls, alkenyls, alkynyls, cycloalkyls, aryls, acyls, aroyls, alkoxys, acyloxys, alkylthiols, 0 dialkylamines, alkylamidos, alkoxycarbonyls, aryloxycarbonyls, carbomoyls, alkyl- and dialkyl-carbamoyls, acyloxys, acylaminos, aroylaminos, aromatic rings, fused aromatic rings, and combinations thereof; and each n is independently an integer having a value 5 of one to five.
SG11201808175UA 2016-03-29 2017-03-13 Metal complexes SG11201808175UA (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US201662314480P true 2016-03-29 2016-03-29
PCT/US2017/022008 WO2017172332A1 (en) 2016-03-29 2017-03-13 Metal complexes

Publications (1)

Publication Number Publication Date
SG11201808175UA true SG11201808175UA (en) 2018-10-30

Family

ID=58410477

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201808175UA SG11201808175UA (en) 2016-03-29 2017-03-13 Metal complexes

Country Status (9)

Country Link
US (1) US20190144570A1 (en)
EP (1) EP3436464A1 (en)
JP (1) JP2019513130A (en)
KR (1) KR20180128927A (en)
CN (1) CN108779130A (en)
BR (1) BR112018068845A2 (en)
CA (1) CA3019327A1 (en)
SG (1) SG11201808175UA (en)
WO (1) WO2017172332A1 (en)

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3248179A (en) 1962-02-26 1966-04-26 Phillips Petroleum Co Method and apparatus for the production of solid polymers of olefins
US4271060A (en) 1979-09-17 1981-06-02 Phillips Petroleum Company Solution polymerization process
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
US4588790A (en) 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
US4613484A (en) 1984-11-30 1986-09-23 Phillips Petroleum Company Loop reactor settling leg system for separation of solid polymers and liquid diluent
US5001205A (en) 1988-06-16 1991-03-19 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst
FR2634212B1 (en) 1988-07-15 1991-04-19 Bp Chimie Sa Apparatus and process for polymerizing olefins in gas phase in a fluidized bed reactor
US5236998A (en) 1991-03-07 1993-08-17 Occidental Chemical Corporation Process for the manufacture of linear polyethylene containing α-alkene commonomers
US5589555A (en) 1991-10-03 1996-12-31 Novacor Chemicals (International) S.A. Control of a solution process for polymerization of ethylene
US5352749A (en) 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
US5436304A (en) 1992-03-19 1995-07-25 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
US5462999A (en) 1993-04-26 1995-10-31 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
US5317036A (en) 1992-10-16 1994-05-31 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization reactions utilizing soluble unsupported catalysts
RU2120947C1 (en) 1993-04-26 1998-10-27 Эксон Кемикэл Пейтентс Инк. Method of gas-phase polymerization in fluidized layer
ZA9403399B (en) 1993-05-20 1995-11-17 Bp Chem Int Ltd Polymerisation process
US5453471B1 (en) 1994-08-02 1999-02-09 Carbide Chemicals & Plastics T Gas phase polymerization process
US5616661A (en) 1995-03-31 1997-04-01 Union Carbide Chemicals & Plastics Technology Corporation Process for controlling particle growth during production of sticky polymers
US5677375A (en) 1995-07-21 1997-10-14 Union Carbide Chemicals & Plastics Technology Corporation Process for producing an in situ polyethylene blend
US5665818A (en) 1996-03-05 1997-09-09 Union Carbide Chemicals & Plastics Technology Corporation High activity staged reactor process
US5627242A (en) 1996-03-28 1997-05-06 Union Carbide Chemicals & Plastics Technology Corporation Process for controlling gas phase fluidized bed polymerization reactor
DE60228632D1 (en) * 2001-03-12 2008-10-09 Tosoh Corp A transition metal compound-based catalyst for olefin polymerization and use of the catalyst for olefin polymerization

Also Published As

Publication number Publication date
CN108779130A (en) 2018-11-09
CA3019327A1 (en) 2017-10-05
JP2019513130A (en) 2019-05-23
US20190144570A1 (en) 2019-05-16
KR20180128927A (en) 2018-12-04
WO2017172332A1 (en) 2017-10-05
BR112018068845A2 (en) 2019-01-22
EP3436464A1 (en) 2019-02-06

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