SE530028C2 - Method and apparatus for the treatment of exhaust gases and vehicles - Google Patents

Method and apparatus for the treatment of exhaust gases and vehicles

Info

Publication number
SE530028C2
SE530028C2 SE0601418A SE0601418A SE530028C2 SE 530028 C2 SE530028 C2 SE 530028C2 SE 0601418 A SE0601418 A SE 0601418A SE 0601418 A SE0601418 A SE 0601418A SE 530028 C2 SE530028 C2 SE 530028C2
Authority
SE
Sweden
Prior art keywords
catalyst
exhaust gases
reducing agent
content
reducing
Prior art date
Application number
SE0601418A
Other languages
Swedish (sv)
Other versions
SE0601418L (en
Inventor
Vesa Hokkanen
Original Assignee
Scania Cv Abp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Scania Cv Abp filed Critical Scania Cv Abp
Priority to SE0601418A priority Critical patent/SE530028C2/en
Priority to PCT/SE2007/050437 priority patent/WO2008002258A1/en
Priority to DE112007001502.0T priority patent/DE112007001502B4/en
Publication of SE0601418L publication Critical patent/SE0601418L/en
Publication of SE530028C2 publication Critical patent/SE530028C2/en

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion
    • F01N3/206Adding periodically or continuously substances to exhaust gases for promoting purification, e.g. catalytic material in liquid form, NOx reducing agents
    • F01N3/2066Selective catalytic reduction [SCR]
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion
    • F01N3/206Adding periodically or continuously substances to exhaust gases for promoting purification, e.g. catalytic material in liquid form, NOx reducing agents
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features
    • F01N13/009Exhaust or silencing apparatus characterised by constructional features having two or more separate purifying devices arranged in series
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features
    • F01N13/009Exhaust or silencing apparatus characterised by constructional features having two or more separate purifying devices arranged in series
    • F01N13/0093Exhaust or silencing apparatus characterised by constructional features having two or more separate purifying devices arranged in series the purifying devices are of the same type
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2560/00Exhaust systems with means for detecting or measuring exhaust gas components or characteristics
    • F01N2560/02Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being an exhaust gas sensor
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2560/00Exhaust systems with means for detecting or measuring exhaust gas components or characteristics
    • F01N2560/02Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being an exhaust gas sensor
    • F01N2560/021Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being an exhaust gas sensor for measuring or detecting ammonia NH3
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2560/00Exhaust systems with means for detecting or measuring exhaust gas components or characteristics
    • F01N2560/02Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being an exhaust gas sensor
    • F01N2560/026Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being an exhaust gas sensor for measuring or detecting NOx
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2610/00Adding substances to exhaust gases
    • F01N2610/02Adding substances to exhaust gases the substance being ammonia or urea
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2610/00Adding substances to exhaust gases
    • F01N2610/14Arrangements for the supply of substances, e.g. conduits
    • F01N2610/1453Sprayers or atomisers; Arrangement thereof in the exhaust apparatus
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B37/00Engines characterised by provision of pumps driven at least for part of the time by exhaust
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Description

550 028 2 teknik med avgasrecirkulation, sk. EGR (exhaust gas recirculation), varvid de re- cirkulerade avgaserna i de flesta fall dessutom kyls innan den återfórs till motorn. 550 028 2 technology with exhaust gas recirculation, so-called EGR (exhaust gas recirculation), whereby the recirculated exhaust gases in most cases are also cooled before it is returned to the engine.

EGR sänker temperaturen i fórbränningsrummet och genom den lägre temperaturen uppnås lägre NOx-halter i avgaserna, vilka sedan renas genom SCR-teknik. En vä- sentlig nackdel är dock att EGR medför låga temperaturer på avgasema, vilket fór- svårar för SCR-katalysatom att arbeta med tillräckligt höga verkningsgrader efter- som SCR-katalysatorer kräver en viss temperatur fór att fungera tillfredsställande.EGR lowers the temperature in the combustion chamber and the lower temperature achieves lower NOx levels in the exhaust gases, which are then purified by SCR technology. A significant disadvantage, however, is that EGR causes low temperatures on the exhaust gases, which makes it difficult for the SCR catalyst to work with sufficiently high efficiencies, since SCR catalysts require a certain temperature in order to function satisfactorily.

Dessutom sänker känd EGR-teknik motorns verkningsgrad då en del energi går åt till EGR-funktionen.In addition, known EGR technology lowers the engine's efficiency as some energy is used for the EGR function.

Föreliggande uppfinning har till syfte att åstadkomma en effektiv och kostnadsmäs- sigt tilltalande avgasrening fór fórbränningsmotorer, och då i synnerhet för diesel- motorer, vilken dessutom medför bl a lägre hållfasthetsmässiga krav på motorns komponenter såsom cylindrar m.m.The present invention has for its object to achieve an efficient and cost-effective exhaust gas purification for internal combustion engines, and then in particular for diesel engines, which in addition entails, among other things, lower strength requirements for the engine components such as cylinders etc.

Kort beskrivning av uppfinningen Syftet enligt ovan uppnås med en metod, en anordning och ett fordon med särdrag enligt de oberoende patentkraven 1, 6 respektive 12. Ytterligare fördelar uppnås med särdrag enligt respektive beroende patentkrav.Brief description of the invention The object according to the above is achieved with a method, a device and a vehicle with features according to the independent claims 1, 6 and 12, respectively. Further advantages are achieved with features according to the respective dependent claims.

Kort beskrivning av ritningama Nedan beskrivs uppfinningen närmare i anslutning till utfiâringsexempel och bifoga- de ritningar, där Fig. 1 i form av ett blockschema schematiskt visar en första utfóringsform av en anordning enligt uppfinningen. 530 028 Beskrivningsexempel I Fig. 1 visas en fórbränningsmotor exemplifierad av en överladdad dieselmotor 1, vilken enligt det visade utförandet innefattar en laddluftkylare 2 och ett turboaggre- gat 3 av gängse slag. Utföranden utan laddluflkylare 2 kan tänkas och förekommer.Brief description of the drawings The invention is described in more detail below in connection with exemplary embodiments and accompanying drawings, in which Fig. 1 schematically shows a first embodiment of a device according to the invention in the form of a block diagram. 530 028 Description example Fig. 1 shows an internal combustion engine exemplified by a supercharged diesel engine 1, which according to the embodiment shown comprises a charge air cooler 2 and a turbocharger 3 of conventional types. Designs without charger fl cooler 2 are conceivable and occur.

Avgasema från motorn, representerade av en pil 4, leds i avgasledningen till en första SCR- katalysator 5 för selektiv katalysisk reduktion (selektive cathalytic re- duction) under reducerande inverkan av ett reduktionsmedel, företrädesvis urea på i och för sig känt sätt, varvid NOx reduceras till N; och/eller N20. Andra reduk- tionsmedel, exempelvis ammoniak, kan också tänkas användas. Föredraget är urea i form av substansen AdBlue®, vilken är 32,5 %-ig lösning av urea i vatten, vilken substans finns specificerad i DIN standard DIN V 70 070.The exhaust gases from the engine, represented by an arrow 4, are led in the exhaust line to a first SCR catalyst 5 for selective cathalytic reduction under the reducing action of a reducing agent, preferably urea in a manner known per se, wherein NOx reduced to N; and / or N 2 O. Other reducing agents, such as ammonia, may also be used. Preferred is urea in the form of the substance AdBlue®, which is a 32.5% solution of urea in water, which substance is specified in DIN standard DIN V 70 070.

En anordning 6 för dosering och inblandning av urea i avgaserna är anordnad upp- ströms katalysatom 5 i avgasledningen. I den schematiska figuren visas anordningen 6 och katalysatom 5 åtskilda, men altemativa utföringsformer kan tänkas där dessa är sammanbyggda till en enhet.A device 6 for dosing and mixing urea into the exhaust gases is arranged upstream of the catalyst 5 in the exhaust line. In the schematic figure the device 6 and the catalyst 5 are shown separated, but alternative embodiments are conceivable where these are assembled into one unit.

En andra SCR-katalysator 7 är anordnad i avgasledningen i serie med den fösta SCR-katalysatorn 5 för behandling av de i den första SCR-katalysatom 5 redan be- handlade avgaserna för att ytterligare minska N0x-halten i avgaserna. En anord- ning 8 för dosering och inblandning av urea förefinns anordnad uppströms den andra SCR- katalysatom 7 analogt med vad som är anordnat vid den första katalysa- tom 5. Även i detta fall kan utföringsfonner tänkas där anordningen 8 och katalysa- torn 7 är sammanbyggda till en enhet.A second SCR catalyst 7 is arranged in the exhaust line in series with the first SCR catalyst 5 for treating the exhaust gases already treated in the first SCR catalyst 5 in order to further reduce the NOx content in the exhaust gases. A device 8 for dosing and mixing urea is previously arranged upstream of the second SCR catalyst 7 analogously to that arranged at the first catalyst 5. Also in this case embodiments are conceivable where the device 8 and the catalyst 7 are integrated into one unit.

För respektive katalysator 5, 7 förefinns ett återkopplande styrsystem 9, 10 respekti- ve, anordnat att baserat på utfallet av behandlingen i respektive katalysator styra do- seringen av urea medelst respektive doserings- och inblandningsanordning 6, 8 till 4 respektive katalysator. I detta syfte íörefinns efter respektive katalysator 5, 7 givare i som avkänner halten av representerande parametrar i avgaserna, och vilka givare är förbundna med respektive styrsystem 9, 10 och därvid tillhandahåller information avseende aktuella parametrar. För att givama ska kunna detektera korrekta värden är det viktigt att givama från respektive katalysator är anordnade i positioner där avga- serna är homogent fördelade vad avser de parametar som avkänns. Det är därför en fördel om avgasledningen är utformad med en förhållandevis lång sträcka från kata- lysatom till aktuell givare så att avgasema hinner blandas väl efter utloppen från ka- talysatorn. I vissa fall kan det erfordras att de blandas ytterligare med hjälp av led- skenor , rörkrökar eller andra sätt att blanda avgasema på.For each catalyst 5, 7 there is a feedback control system 9, 10 respectively, arranged to control the dosing of urea by means of the respective dosing and mixing device 6, 8 to 4 and the respective catalyst, based on the outcome of the treatment in each catalyst. For this purpose, according to the respective catalyst 5, 7 there are sensors which sense the content of representative parameters in the exhaust gases, and which sensors are connected to the respective control system 9, 10 and thereby provide information regarding current parameters. In order for the sensors to be able to detect correct values, it is important that the sensors from each catalyst are arranged in positions where the exhaust gases are homogeneously distributed with regard to the parameters that are sensed. It is therefore an advantage if the exhaust line is designed with a relatively long distance from the catalyst to the current sensor so that the exhaust gases have time to mix well after the outlets from the catalyst. In some cases, it may be necessary to mix them further with the help of guide rails, pipe bends or other ways of mixing the exhaust gases.

Enligt föredragna utföringsforrner detekteras utfallet som överskott av reduktions- medel, urea, i avgaserna, varvid respektive återkopplande styrsystem är anordnat att styra doseringen mot en förutbestämd halt av reduktionsmedel, exempelvis urea, i avgaserna, exempelvis en minimering av reduktionsmedelshalten i avgasema.According to preferred embodiments, the outcome is detected as excess reducing agent, urea, in the exhaust gases, the respective feedback control system being arranged to control the dosage towards a predetermined content of reducing agent, for example urea, in the exhaust gases, for example a minimization of the reducing agent content

Utföringsforrner kan också tänkas där utfallet detekteras som halten av NOx i avga- sema, varvid respektive styrsystem är anordnat att styra doseringen mot en förutbe- stämd halt av NOx i avgasema.Embodiments are also conceivable where the outcome is detected as the content of NOx in the exhaust gases, wherein the respective control system is arranged to control the dosage towards a predetermined content of NOx in the exhaust gases.

I båda fallen, reduktionsmedelsöverskott resp. NOx-halt, kan adaptiva styrsystem tänkas där doseringen styrs baserat på erfarenhetsvärden av överskott respektive NOx-halt.In both cases, reduction of excess funds resp. NOx content, adaptive control systems are conceivable where the dosage is controlled based on experience values of excess and NOx content, respectively.

Enligt en i vissa fall särskilt föredragen utröringsforrn detekteras utfallet genom en kombination av de tidigare beskrivna, dvs. som såväl NOx-halt som reduktionsme- delsöverskott i avgaserna, varvid respektive återkopplande styrsystem är anordnat att styra doseringen mot ett förutbestämt utfall vad avser en eller båda av dessa stor- heter. Härvid kan hänsyn tagas till ofullkomligheter hos en katalysator. Sålunda fö- rekommer det att urea ackumuleras, till och med ackumuleras lokalt, i katalysatorn, 530 0128 varvid ett detekterat nollöverskott av urea i avgaserna ej entydigt betyder att tillförd urea förbrukas.According to an in some cases particularly preferred form of agitation, the outcome is detected by a combination of the previously described, ie. as well as NOx content and excess reducing agent in the exhaust gases, whereby the respective feedback control system is arranged to control the dosage towards a predetermined outcome with regard to one or both of these quantities. In this case, imperfections of a catalyst can be taken into account. Thus, it occurs that urea accumulates, even accumulates locally, in the catalyst, 530 0128, whereby a detected zero excess of urea in the exhaust gases does not unambiguously mean that the supplied urea is consumed.

Härvid kan samtidigt detekterad NOx-halt tillföra information att användas för åstadkommande av en effektivare och mer adekvat styming av doseringen och möj- liggöra hänsynstagande till apparattekniska ofullkomligheter av ovan beskrivet slag.At the same time, detected NOx content can add information to be used to achieve a more efficient and more adequate control of the dosage and enable consideration of device technical imperfections of the type described above.

Tänkbart är att olika utföringsformer av detektering används för olika katalysatorer.It is conceivable that different embodiments of detection are used for different catalysts.

Utföringsformer av anordningen kan tänkas där åtrninstone en ytterligare SCR-kata- lysator kopplas i serie med de två första.Embodiments of the device are conceivable where at least one further SCR catalyst is connected in series with the first two.

Enligt föredragna utföringsforrner är behandlingen av avgaserna avsedd att utföras utan att motorns avgaser recirkuleras till motoms inlopp enligt känd EGR-teknik.According to preferred embodiments, the treatment of the exhaust gases is intended to be carried out without the engine exhaust gases being recycled to the engine inlet according to known EGR technology.

Motorn saknar således returledning som förbinder dess avgassida med dess inlopps- sida. Detta hindrar dock inte att behandlingen av avgaser enligt uppfinningen under vissa betingelser kan kombineras med en motor som dessutom utnyttjar EGR-teknik för reducering av avgasemissionema.The engine thus lacks a return line which connects its exhaust side to its inlet side. However, this does not prevent the treatment of exhaust gases according to the invention under certain conditions from being combined with an engine which also uses EGR technology to reduce exhaust emissions.

Metoden för behandlingen av avgaserna liksom funktionen hos anordningen enligt uppfinningen torde till väsentlig del redan framgått av ovanstående del av beskriv- ningen.The method for the treatment of the exhaust gases as well as the function of the device according to the invention should to a substantial part already have been stated in the above part of the description.

Avgaserna från motorn leds först till den första SCR-katalysator 5 där avgasema i ett första behandlingsteg genom reaktion med den från anordningen 6 insprutade urean reagerar med kväveoxiderna i avgaserna för minskning av halten av dessa.The exhaust gases from the engine are first passed to the first SCR catalyst 5 where the exhaust gases in a first treatment step by reaction with the urea injected from the device 6 react with the nitrogen oxides in the exhaust gases to reduce their content.

Halten av av NOx i avgaserna har visserligen reduceras vid detta steg, men det kvarstår ändock en viss restmängd. De i det första steget behandlade avgasema leds sedan vidare till den andra SCR-katalystaorn 7, som är anordnad i serie med den första katalysatorn, där avgasema i ett andra behandlingssteg genom reaktion med 6 den från anordningen 8 insprutade urean reagerar med kväveoxiderna i avgaserna för ytterligare minskning av halten av NOx .The content of NOx in the exhaust gases has admittedly been reduced at this stage, but a certain amount of residue still remains. The exhaust gases treated in the first stage are then passed on to the second SCR catalyst 7, which is arranged in series with the first catalyst, where the exhaust gases in a second treatment step by reaction with the urea injected from the device 8 react with the nitrogen oxides in the exhaust gases for further reduction of the NOx content.

Dosering av urea i respektive steg styrs medelst de återkopplande styrsystemen 9, 10 i respektive steg baserat på utfallet i respektive steg, där utfallet kan detekteras som NOx-halt och/eller reduktionsmedelsöverskott i avgasema efter respektive steg.Dosage of urea in each step is controlled by means of the feedback control systems 9, 10 in each step based on the outcome in each step, where the outcome can be detected as NOx content and / or excess reducing agent in the exhaust gases after each step.

Uppfinningen erbjuder fördelar i form av effektiv avgasbehandling.The invention offers advantages in the form of efficient exhaust gas treatment.

Eliminering av behovet av EGR erbjuder fördelar i form av acceptans för höga av- gastemperaturer, vilket medför effektivare katalysatorfunktion. Vidare minskar håll- fasthetskraven på motorn pga. minskat behov av tålighet för höga cylindertryck.Elimination of the need for EGR offers advantages in the form of acceptance of high exhaust gas temperatures, which leads to more efficient catalyst function. Furthermore, the strength requirements of the motor decrease due to reduced need for durability for high cylinder pressures.

Eliminerad EGR eliminerar naturligtvis erforderligt EGR-system och medför också att fordonets befintliga kylkapacitet räcker till för att tillåta uttag av högre effekter 111' ITIOÉOYIL Det ligger också ett tekniskt egenvärde i att en enhetlig och motom ej påverkande behandlingsteknik används, vilket blir fallet vid seriell användning av SCR- katalysatorer.Eliminated EGR naturally eliminates the required EGR system and also means that the vehicle's considerable cooling capacity is sufficient to allow extraction of higher effects. of SCR catalysts.

Ovan har uppfmningen beskrivits i anslutning till föredragna utföringsformer och utföringsexempel.The invention has been described above in connection with preferred embodiments and embodiments.

Naturligtvis kan fler utföringsfonner liksom mindre förändringar och komplette- ringar tänkas utan att den grundläggande uppfinningstanken frångås.Of course, more embodiments as well as minor changes and additions are conceivable without departing from the basic idea of invention.

Sålunda kan två eller flera SCR-katalysatorer inklusive doserings- och inbland- ningsanordningar byggas samman till en enhet.Thus, two or more SCR catalysts, including dosing and mixing devices, can be assembled into one unit.

UW (N CD CD P» 3 G3 7 I beskrivningen ovan har urea i vissa stycken använts som exempel på reduktions- medel. För det fall reduktionsmedlet skulle vara ett annat än urea är beskrivningen tillämplig även för detta, exempelvis vad avser doserings- och inblandningsanord- ningarna etc.UW (N CD CD P »3 G3 7 In the description above, urea has been used as an example of a reducing agent in some cases. - ningarna etc.

Utföringsformer kan tänkas där ej samma reduktionsmedel används i samtliga SCR- katalysatorer.Embodiments are conceivable where the same reducing agent is not used in all SCR catalysts.

Vidare kan de återkopplande styrsystemen ingå som en integrerad del av fordonets övergripande styr- och kontrollsystem. Tänkas kan också att ett gemensamt styrsy- stem finns for båda/alla katalysatorema.Furthermore, the feedback control systems can be included as an integral part of the vehicle's overall control and monitoring system. It is also conceivable that a common control system exists for both / all the catalysts.

Det har här förutsätts att SCR-katalysatorer och doserings- och inblandningsanord- ningar är för fackmannen kända komponenter med känd funktion. Detsamma gäller teknik för att mäta NOx-halter och reduktionsmedelshalter i avgaserna.It has been assumed here that SCR catalysts and dosing and mixing devices are components known to those skilled in the art with known function. The same applies to technology for measuring NOx levels and reducing agent levels in the exhaust gases.

Uppfinningen skall således ej anses begränsad till ovan angivna utfóringsfonner utan kan varieras inom sin av bifogade patentkrav angivna ram.The invention should thus not be considered limited to the above-mentioned embodiments but can be varied within the scope specified by the appended claims.

Claims (12)

10 15 20 25 30 (fl (JJ CD CD iQ! PATENTKRAV10 15 20 25 30 (fl (JJ CD CD iQ! PATENTKRAV 1. Metod för behandling av avgaser från en förbränningsmotor innefattande ett för- sta steg för att reducera halten av kväveoxider, NOx, i avgaserna genom behandling i en första katalysator under reducerande inverkan av reduktionsmedel, och ett andra steg för att ytterligare reducera halten av kväveoxider, NOx, i avgaserna ge- nom behandling av de i den första katalysatom (5) sålunda behandlade avgaserna i åtminstone ytterligare en katalysator (7) ansluten i serie med den första katalysatorn (5) under reducerande inverkan av reduktionsmedel kännetecknat av stegen att dosera tillförseln av reduktionsmedel för respektive katalysator (5, 7) baserat på ut- fallet av behandlingen i respektive katalysator medelst återkopplande styrsystem (9, 10), vilka styrsystem härför är förbundna med givare anordnade efter respektive ka- talysator (5, 7) och som avkänner halten av i avgaserna representerande parametrar och därvid tillhandahåller information .avseende aktuella parametrar.A method of treating exhaust gases from an internal combustion engine comprising a first step of reducing the content of nitrogen oxides, NOx, in the exhaust gases by treatment in a first catalyst under the reducing action of reducing agent, and a second step of further reducing the content of nitrogen oxides. , NOx, in the exhaust gases by treating the exhaust gases thus treated in the first catalyst (5) in at least one further catalyst (7) connected in series with the first catalyst (5) under the reducing action of reducing agent characterized by the steps of metering the feed of reducing agents for each catalyst (5, 7) based on the outcome of the treatment in each catalyst by means of feedback control systems (9, 10), which control systems are for this purpose connected to sensors arranged after the respective catalyst (5, 7) and which sense the content of parameters representing in the exhaust gases and thereby provide information regarding current parameters. 2. Metod enligt krav 1, kännetecknat av steget att bestämma utfallet som NOx-halt och/eller reduktionsmedelsöverskott i avgaserna.Method according to claim 1, characterized by the step of determining the outcome as NOx content and / or excess reducing agent in the exhaust gases. 3. Metod enligt krav 1 eller 2, kännetecknat av att som reduktionsmedel utnyttja urea, företrädesvis i form av AdBlue®.Method according to Claim 1 or 2, characterized in that urea is used as reducing agent, preferably in the form of AdBlue®. 4. Metod enligt krav 1, 2, eller 3, kännetecknat av steget att tillhandahålla inforrna- tion rörande NOx-halten i avgaserna efter åtminstone den ena katalysatom (5, 7) som underlag för dosering av reduktionsmedel för den katalysatorn (5, 7) samt ste- get att dosera reduktionsmedel för katalysatorn (5, 7) mot en förutbestämd halt av NOX i avgaserna.Method according to claim 1, 2, or 3, characterized by the step of providing information regarding the NOx content in the exhaust gases after at least one catalyst (5, 7) as a basis for dosing reducing agents for that catalyst (5, 7). and the step of dosing a reducing agent for the catalyst (5, 7) against a predetermined content of NOX in the exhaust gases. 5. Metod enligt krav 1, 2, eller 3, kännetecknat av steget att tillhandahålla informa- tion rörande reduktionsmedelsöverskottet i avgaserna efter åtminstone den ena kata- lysatom (5, 7) som underlag för dosering av reduktionsmedel för den katalysatorn 10 15 20 25 5250 Üilšš 9 (5, 7) samt steget att dosera reduktionsmedel för katalysatom (5, 7) så att reduk- tionsmedelsöverskottet minimeras.Method according to claim 1, 2, or 3, characterized by the step of providing information concerning the excess reducing agent in the exhaust gases after at least one catalyst (5, 7) as a basis for dosing reducing agent for that catalyst. Üilšš 9 (5, 7) and the step of dosing a reducing agent for the catalyst (5, 7) so that the excess of reducing agent is minimized. 6. Anordning för behandling av avgaser från en lörbränningsmotor, innefattande anordningar för att minska halten av kväveoxider, NOx, i avgaserna genom behand- ling i en första katalysator under reducerande inverkan av reduktionsmedel, och åtminstone ytterligare en katalysator (7) för behandling under reducerande in- verkan av reduktionsmedel av den sålunda i den första katalysatorn (5) behandlade avgasema, vilken ytterligare katalysator (7) är ansluten i serie med den första kataly- satom (5), kännetecknad av anordningar (6, 8) för att dOSCIa ICÖUKÜOHSIHCÖCI för tillförsel för respektive katalysator (5, 7) baserat på utfallet av behandlingen i respektive katalysator (5,7) medelst återkopplande styrsystem (9, 10), vilka styrsy- stem (9, 10) härför är förbundna med givare anordnade efter respektive katalysator (5, 7) och som avkänner halten av i avgaserna representerande parametrar och där- vid tillhandahåller information avseende aktuella parametrar.Apparatus for treating exhaust gases from an internal combustion engine, comprising means for reducing the content of nitrogen oxides, NOx, in the exhaust gases by treatment in a first catalyst under the reducing action of reducing agent, and at least one further catalyst (7) for treatment under reducing action of reducing agent of the exhaust gases thus treated in the first catalyst (5), which further catalyst (7) is connected in series with the first catalyst (5), characterized by devices (6, 8) for dOSCIa ICÖUKÜOHSIHCÖCI for supply for each catalyst (5, 7) based on the outcome of the treatment in each catalyst (5,7) by means of feedback control systems (9, 10), which control systems (9, 10) are for this purpose connected to sensors arranged after each catalyst (5, 7) and which senses the content of parameters representing in the exhaust gases and thereby provides information regarding current parameters. 7. Anordning enligt krav 6, kännetecknad av anordningar för att bestämma utfallet som NOx-halt och/eller reduktionsmedelsöverskott i avgaserna efier respektive ka- talysator (5, 7).Device according to Claim 6, characterized by devices for determining the outcome as NOx content and / or excess of reducing agent in the exhaust gases or catalyst (5, 7), respectively. 8. Anordning enligt krav 6 eller 7, kännetecknad av att sagda reduktionsmedel är urea, företrädesvis i fonn av AdBlue®.Device according to claim 6 or 7, characterized in that said reducing agent is urea, preferably in the form of AdBlue®. 9. Anordning enligt krav 6, 7 eller 8, kännetecknad av anordningar för att tillhan- dahâlla infonnation rörande NOx-halten i avgaserna som underlag för dosering av reduktionsmedel till åtminstone den ena katalysatom (5, 7) samt att styrsystemet (9, 10) är anordnat att dosera reduktionsmedel för aktuell katalysator (5, 7) mot en för- utbestämd halt av NOx i avgasema. 10 *CO 550 02 10Device according to claim 6, 7 or 8, characterized by devices for providing information regarding the NOx content in the exhaust gases as a basis for dosing reducing agents to at least one catalyst (5, 7) and for the control system (9, 10) is arranged to dose reducing agent for the catalyst in question (5, 7) against a predetermined content of NOx in the exhaust gases. 10 * CO 550 02 10 10. Anordning enligt krav 6, 7 eller 8, kännetecknad av anordningar för att tillhan- dahålla information rörande halten reduktionsmedel i avgaserna som underlag för dosering av reduktionsmedel till åtminstone den ena katalysatom (5, 7) samt att styr- systemet (9, 10) är anordnat att dosera reduktionsmedel för aktuell katalysator (5, 7) så att reduktionsmedelsöverskott minimeras.Device according to claim 6, 7 or 8, characterized by devices for providing information concerning the content of reducing agent in the exhaust gases as a basis for dosing reducing agent to at least one catalyst (5, 7) and for the control system (9, 10 ) is arranged to dose reducing agent for the catalyst in question (5, 7) so that excess reducing agent is minimized. 11. Anordning enligt krav 7, 8, 9e11er 10, kännetecknad av att åtminstone två kata- lysatorer (5, 7) är anordnade som en enhet for seriell behandling av avgaserna.Device according to Claim 7, 8, 9e11er 10, characterized in that at least two catalysts (5, 7) are arranged as a unit for serial treatment of the exhaust gases. 12. Fordon, kännetecknat av att det innefattar anordningar enligt något av patent- kraven 6-11.Vehicle, characterized in that it comprises devices according to any one of claims 6-11.
SE0601418A 2006-06-28 2006-06-28 Method and apparatus for the treatment of exhaust gases and vehicles SE530028C2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
SE0601418A SE530028C2 (en) 2006-06-28 2006-06-28 Method and apparatus for the treatment of exhaust gases and vehicles
PCT/SE2007/050437 WO2008002258A1 (en) 2006-06-28 2007-06-20 Method and device for treatment of exhaust gases, and vehicle
DE112007001502.0T DE112007001502B4 (en) 2006-06-28 2007-06-20 Method and device for the treatment of exhaust gases, as well as vehicle

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SE0601418A SE530028C2 (en) 2006-06-28 2006-06-28 Method and apparatus for the treatment of exhaust gases and vehicles

Publications (2)

Publication Number Publication Date
SE0601418L SE0601418L (en) 2007-12-29
SE530028C2 true SE530028C2 (en) 2008-02-12

Family

ID=38845902

Family Applications (1)

Application Number Title Priority Date Filing Date
SE0601418A SE530028C2 (en) 2006-06-28 2006-06-28 Method and apparatus for the treatment of exhaust gases and vehicles

Country Status (3)

Country Link
DE (1) DE112007001502B4 (en)
SE (1) SE530028C2 (en)
WO (1) WO2008002258A1 (en)

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19859003A1 (en) 1998-12-21 2000-06-29 Bosch Gmbh Robert Exhaust gas purification to reduce nitrogen oxides from oxygen-containing exhaust gases from an internal combustion engine
US6182443B1 (en) * 1999-02-09 2001-02-06 Ford Global Technologies, Inc. Method for converting exhaust gases from a diesel engine using nitrogen oxide absorbent
JP3518398B2 (en) * 1999-03-11 2004-04-12 トヨタ自動車株式会社 Exhaust gas purification device for internal combustion engine
DE10038741A1 (en) 2000-08-09 2002-02-21 Porsche Ag Method and device for feeding a reducing agent into a catalyst device
DE10300555B4 (en) 2002-01-10 2009-03-19 Toyota Jidosha Kabushiki Kaisha, Toyota-shi A deterioration determination device for an engine exhaust gas control device and deterioration determination method
AT412845B (en) * 2003-07-14 2005-08-25 Alpps Fuel Cell Systems Gmbh EXHAUST GAS TREATMENT SYSTEM FOR REDUCING NOX EMISSIONS FROM HEATING POWER MACHINES USING FUEL PRODUCED REDUCTIVE MEANS
JP4020054B2 (en) * 2003-09-24 2007-12-12 トヨタ自動車株式会社 Exhaust gas purification system for internal combustion engine

Also Published As

Publication number Publication date
WO2008002258A1 (en) 2008-01-03
DE112007001502B4 (en) 2025-03-27
SE0601418L (en) 2007-12-29
DE112007001502T5 (en) 2009-05-07

Similar Documents

Publication Publication Date Title
EP2141331B1 (en) Exhaust purification device for internal combustion engine
US20110146235A1 (en) Abnormality detection system and abnormality detection method for internal combustion engine
US8677736B2 (en) Exhaust gas purification apparatus of an internal combustion engine
EP2133524B1 (en) Apparatus for purifying exhaust gas in internal combustion engine
WO2009031030A2 (en) Exhaust emission control system of internal combustion engine and exhaust emission control method
US9228466B2 (en) Method for operating a dosing valve, and corresponding internal combustion engine
US10138849B2 (en) Exhaust gas recirculation apparatus and control method therefor
US8857161B2 (en) Exhaust gas purification apparatus and exhaust gas purification method for an internal combustion engine
SE1050854A1 (en) Arrangement for injecting a reducing agent into an exhaust line of an internal combustion engine
CN106194359B (en) Method and system for controlling exhaust flow in an engine system
WO2008105996A1 (en) Engine exhaust treatment system
EP1767754A1 (en) Exhaust gas purification apparatus
US10823040B2 (en) Exhaust gas control system for internal combustion engine
US9140164B2 (en) Exhaust gas purification device for internal combustion engine
US8919102B2 (en) Exhaust purifying device for internal combustion engines
SE530582C2 (en) Arrangement and method of a supercharged internal combustion engine
CN102062003A (en) Method for operating a diesel engine system
US20190308886A1 (en) System For Neutralizing The PH Of Exhaust Condensate
EP2264291B1 (en) Exhaust gas purification system for internal combustion engine
JP6319561B2 (en) Exhaust purification system
US20110093185A1 (en) Method for operating an internal combustion engine system
SE530028C2 (en) Method and apparatus for the treatment of exhaust gases and vehicles
EP2957737B1 (en) Engine exhaust-gas purification device
JP4919056B2 (en) Control device for internal combustion engine
JP7420044B2 (en) Internal combustion engine cooling system