SE518564C2 - Polymer elektrolyt, battericell innefattande elektrolyten, förfarande för framställning av elektrolyten samt användning av elektrolyten och battericellen - Google Patents
Polymer elektrolyt, battericell innefattande elektrolyten, förfarande för framställning av elektrolyten samt användning av elektrolyten och battericellenInfo
- Publication number
- SE518564C2 SE518564C2 SE9904667A SE9904667A SE518564C2 SE 518564 C2 SE518564 C2 SE 518564C2 SE 9904667 A SE9904667 A SE 9904667A SE 9904667 A SE9904667 A SE 9904667A SE 518564 C2 SE518564 C2 SE 518564C2
- Authority
- SE
- Sweden
- Prior art keywords
- polymer
- electrolyte
- weight
- battery cell
- solvent
- Prior art date
Links
- 239000005518 polymer electrolyte Substances 0.000 title claims abstract description 64
- 238000000034 method Methods 0.000 title claims abstract description 21
- 239000003792 electrolyte Substances 0.000 title claims description 81
- 230000008569 process Effects 0.000 title claims description 11
- 229920000642 polymer Polymers 0.000 claims abstract description 123
- 239000002904 solvent Substances 0.000 claims abstract description 45
- 150000003839 salts Chemical class 0.000 claims abstract description 41
- 239000004014 plasticizer Substances 0.000 claims abstract description 36
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 26
- 229910052751 metal Inorganic materials 0.000 claims abstract description 22
- 239000002184 metal Substances 0.000 claims abstract description 22
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 17
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 13
- 239000011245 gel electrolyte Substances 0.000 claims description 62
- 229920001577 copolymer Polymers 0.000 claims description 34
- 239000007787 solid Substances 0.000 claims description 31
- 239000000203 mixture Substances 0.000 claims description 19
- 229910052744 lithium Inorganic materials 0.000 claims description 14
- 229910003002 lithium salt Inorganic materials 0.000 claims description 12
- 159000000002 lithium salts Chemical group 0.000 claims description 12
- 239000002054 inoculum Substances 0.000 claims description 9
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 8
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 229910012225 LiPFO Inorganic materials 0.000 claims description 4
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- 229910015013 LiAsF Inorganic materials 0.000 claims description 3
- 229910013063 LiBF 4 Inorganic materials 0.000 claims description 3
- 229910013684 LiClO 4 Inorganic materials 0.000 claims description 3
- 229910013131 LiN Inorganic materials 0.000 claims description 3
- 239000003990 capacitor Substances 0.000 claims description 3
- 239000004065 semiconductor Substances 0.000 claims description 3
- 229910013872 LiPF Inorganic materials 0.000 claims description 2
- 101150058243 Lipf gene Proteins 0.000 claims description 2
- 238000010295 mobile communication Methods 0.000 claims description 2
- 229920001477 hydrophilic polymer Polymers 0.000 claims 1
- 229920000578 graft copolymer Polymers 0.000 abstract description 43
- 210000004027 cell Anatomy 0.000 description 25
- -1 salt cation Chemical class 0.000 description 16
- 239000000243 solution Substances 0.000 description 16
- 229940021013 electrolyte solution Drugs 0.000 description 14
- 239000000178 monomer Substances 0.000 description 13
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 12
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 12
- 239000008151 electrolyte solution Substances 0.000 description 12
- 238000002360 preparation method Methods 0.000 description 12
- 150000002500 ions Chemical class 0.000 description 11
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical group [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 10
- 229910001416 lithium ion Inorganic materials 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 9
- 239000011159 matrix material Substances 0.000 description 9
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 8
- 239000010408 film Substances 0.000 description 8
- 150000001768 cations Chemical class 0.000 description 7
- 238000002161 passivation Methods 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 7
- 238000010526 radical polymerization reaction Methods 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- 239000011324 bead Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 230000037427 ion transport Effects 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- 229920002239 polyacrylonitrile Polymers 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- 150000001450 anions Chemical class 0.000 description 4
- 238000010494 dissociation reaction Methods 0.000 description 4
- 230000005593 dissociations Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 4
- 125000001165 hydrophobic group Chemical group 0.000 description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 3
- 238000005481 NMR spectroscopy Methods 0.000 description 3
- 229920000265 Polyparaphenylene Polymers 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 239000007772 electrode material Substances 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 239000007863 gel particle Substances 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 239000011244 liquid electrolyte Substances 0.000 description 3
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
- 239000004926 polymethyl methacrylate Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 230000003248 secreting effect Effects 0.000 description 3
- 239000007784 solid electrolyte Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000032258 transport Effects 0.000 description 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 2
- 229910015645 LiMn Inorganic materials 0.000 description 2
- 229910015643 LiMn 2 O 4 Inorganic materials 0.000 description 2
- 229910013290 LiNiO 2 Inorganic materials 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical group CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001336 alkenes Chemical group 0.000 description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N anhydrous diethylene glycol Natural products OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 239000007774 positive electrode material Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000007614 solvation Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 238000012719 thermal polymerization Methods 0.000 description 2
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- JRRDISHSXWGFRF-UHFFFAOYSA-N 1-[2-(2-ethoxyethoxy)ethoxy]-2-methoxyethane Chemical compound CCOCCOCCOCCOC JRRDISHSXWGFRF-UHFFFAOYSA-N 0.000 description 1
- YZWVMKLQNYGKLJ-UHFFFAOYSA-N 1-[2-[2-(2-ethoxyethoxy)ethoxy]ethoxy]-2-methoxyethane Chemical compound CCOCCOCCOCCOCCOC YZWVMKLQNYGKLJ-UHFFFAOYSA-N 0.000 description 1
- RRQYJINTUHWNHW-UHFFFAOYSA-N 1-ethoxy-2-(2-ethoxyethoxy)ethane Chemical compound CCOCCOCCOCC RRQYJINTUHWNHW-UHFFFAOYSA-N 0.000 description 1
- QENGPZGAWFQWCZ-UHFFFAOYSA-N 3-Methylthiophene Chemical compound CC=1C=CSC=1 QENGPZGAWFQWCZ-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- 229910020261 KBF4 Inorganic materials 0.000 description 1
- 229920006370 Kynar Polymers 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 229910014689 LiMnO Inorganic materials 0.000 description 1
- 229910012767 LiV Inorganic materials 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 229910001128 Sn alloy Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000003708 ampul Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- WLLOZRDOFANZMZ-UHFFFAOYSA-N bis(2,2,2-trifluoroethyl) carbonate Chemical compound FC(F)(F)COC(=O)OCC(F)(F)F WLLOZRDOFANZMZ-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000011329 calcined coke Substances 0.000 description 1
- 150000001722 carbon compounds Chemical class 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910001914 chlorine tetroxide Inorganic materials 0.000 description 1
- KMVZWUQHMJAWSY-UHFFFAOYSA-N chloro-dimethyl-prop-2-enylsilane Chemical compound C[Si](C)(Cl)CC=C KMVZWUQHMJAWSY-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 238000009831 deintercalation Methods 0.000 description 1
- 210000001787 dendrite Anatomy 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 239000002001 electrolyte material Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 125000003010 ionic group Chemical group 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- GCICAPWZNUIIDV-UHFFFAOYSA-N lithium magnesium Chemical compound [Li].[Mg] GCICAPWZNUIIDV-UHFFFAOYSA-N 0.000 description 1
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 1
- 229910001486 lithium perchlorate Inorganic materials 0.000 description 1
- 229910001496 lithium tetrafluoroborate Inorganic materials 0.000 description 1
- UIDWHMKSOZZDAV-UHFFFAOYSA-N lithium tin Chemical compound [Li].[Sn] UIDWHMKSOZZDAV-UHFFFAOYSA-N 0.000 description 1
- ACFSQHQYDZIPRL-UHFFFAOYSA-N lithium;bis(1,1,2,2,2-pentafluoroethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)C(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)C(F)(F)F ACFSQHQYDZIPRL-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- GBPVMEKUJUKTBA-UHFFFAOYSA-N methyl 2,2,2-trifluoroethyl carbonate Chemical compound COC(=O)OCC(F)(F)F GBPVMEKUJUKTBA-UHFFFAOYSA-N 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 239000007773 negative electrode material Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000006259 organic additive Substances 0.000 description 1
- 239000005486 organic electrolyte Substances 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000003791 organic solvent mixture Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Chemical compound [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920006112 polar polymer Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 229910001495 sodium tetrafluoroborate Inorganic materials 0.000 description 1
- VGTPCRGMBIAPIM-UHFFFAOYSA-M sodium thiocyanate Chemical compound [Na+].[S-]C#N VGTPCRGMBIAPIM-UHFFFAOYSA-M 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
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- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Dispersion Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Secondary Cells (AREA)
- Conductive Materials (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Primary Cells (AREA)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE9904667A SE518564C2 (sv) | 1999-12-20 | 1999-12-20 | Polymer elektrolyt, battericell innefattande elektrolyten, förfarande för framställning av elektrolyten samt användning av elektrolyten och battericellen |
| CN00817429A CN1411475A (zh) | 1999-12-20 | 2000-12-20 | 聚合物电解质、包含该电解质的电池组电池和生产该电解质的方法 |
| JP2001547187A JP4741140B2 (ja) | 1999-12-20 | 2000-12-20 | ポリマー電解質、ポリマー電解質を含むバッテリーセル、およびポリマー電解質の製造方法 |
| PCT/SE2000/002599 WO2001046280A1 (en) | 1999-12-20 | 2000-12-20 | A polymer electrolyte, a battery cell comprising the electrolyte and a method of producing the electrolyte |
| EP00989109A EP1272538B1 (de) | 1999-12-20 | 2000-12-20 | Ein polymerelektrolyt, eine batteriezelle enthaltend den elektrolyten und verfahren zur herstellung des elektrolyten |
| AU25655/01A AU2565501A (en) | 1999-12-20 | 2000-12-20 | A polymer electrolyte, a battery cell comprising the electrolyte and a method ofproducing the electrolyte |
| AT00989109T ATE297422T1 (de) | 1999-12-20 | 2000-12-20 | Ein polymerelektrolyt, eine batteriezelle enthaltend den elektrolyten und verfahren zur herstellung des elektrolyten |
| US09/745,137 US6596440B2 (en) | 1999-12-20 | 2000-12-20 | Polymer electrolyte, a battery cell comprising the electrolyte and method of producing the electrolyte |
| DE60020745T DE60020745D1 (de) | 1999-12-20 | 2000-12-20 | Ein polymerelektrolyt, eine batteriezelle enthaltend den elektrolyten und verfahren zur herstellung des elektrolyten |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE9904667A SE518564C2 (sv) | 1999-12-20 | 1999-12-20 | Polymer elektrolyt, battericell innefattande elektrolyten, förfarande för framställning av elektrolyten samt användning av elektrolyten och battericellen |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| SE9904667D0 SE9904667D0 (sv) | 1999-12-20 |
| SE9904667L SE9904667L (sv) | 2001-06-21 |
| SE518564C2 true SE518564C2 (sv) | 2002-10-22 |
Family
ID=20418203
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE9904667A SE518564C2 (sv) | 1999-12-20 | 1999-12-20 | Polymer elektrolyt, battericell innefattande elektrolyten, förfarande för framställning av elektrolyten samt användning av elektrolyten och battericellen |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6596440B2 (de) |
| EP (1) | EP1272538B1 (de) |
| JP (1) | JP4741140B2 (de) |
| CN (1) | CN1411475A (de) |
| AT (1) | ATE297422T1 (de) |
| AU (1) | AU2565501A (de) |
| DE (1) | DE60020745D1 (de) |
| SE (1) | SE518564C2 (de) |
| WO (1) | WO2001046280A1 (de) |
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| KR100413800B1 (ko) * | 2001-10-17 | 2004-01-03 | 삼성에스디아이 주식회사 | 불소계 코폴리머, 이를 포함한 폴리머 전해질 및 이폴리머 전해질을 채용한 리튬 전지 |
| CN1617701A (zh) * | 2001-12-05 | 2005-05-18 | 宝丽化学工业有限公司 | 用于皮肤的外部制剂以及被用于其中的共聚物 |
| EP1553117B1 (de) | 2002-07-23 | 2007-01-17 | Nippon Soda Co., Ltd. | Polymerfestelektrolyt |
| CA2418257A1 (fr) * | 2003-01-30 | 2004-07-30 | Hydro-Quebec | Composition electrolytique et electrolyte, generateurs les contenant et operant sans formation de dendrite lors du cyclage |
| US20040253520A1 (en) * | 2003-05-13 | 2004-12-16 | Wensley C. Glen | Polyimide matrix electrolyte and improved batteries therefrom |
| US20040229127A1 (en) | 2003-05-13 | 2004-11-18 | Wensley C. Glen | Polyimide matrix electrolyte |
| US6936377B2 (en) * | 2003-05-13 | 2005-08-30 | C. Glen Wensley | Card with embedded IC and electrochemical cell |
| GB2401608B (en) * | 2003-05-13 | 2005-07-20 | Univ Sheffield | Polymer electrolyte |
| US20070009805A1 (en) * | 2003-05-13 | 2007-01-11 | Wright Peter V | Polymer electrolyte |
| US7390336B2 (en) * | 2003-07-29 | 2008-06-24 | Solicore, Inc. | Polyimide-based lithium metal battery |
| JP4562364B2 (ja) * | 2003-09-12 | 2010-10-13 | 日本曹達株式会社 | ブロック・グラフト共重合体及びそれらを用いた高分子固体電解質 |
| PL2290738T3 (pl) * | 2003-09-23 | 2020-01-31 | Innolith Assets Ag | Elektrochemiczne ogniwo akumulatorowe |
| EP1787344B1 (de) | 2004-07-22 | 2017-02-22 | BrightVolt, Inc. | Verbesserter batterielaschen- und kapselungsentwurf |
| US7435496B2 (en) * | 2005-01-12 | 2008-10-14 | Toyota Motor Engineering & Manufacturing North America, Inc. | Anhydrous proton conductor based on heterocycle attached to a polymer backbone |
| CN100483798C (zh) * | 2005-03-31 | 2009-04-29 | 鸿富锦精密工业（深圳）有限公司 | 负极、其制备方法和使用该负极的锂二次电池 |
| AU2006235061A1 (en) * | 2005-04-07 | 2006-10-19 | The Regents Of The University Of California | Highly efficient polymer solar cell by polymer self-organization |
| CN101288199B (zh) * | 2005-10-12 | 2011-06-15 | 三井化学株式会社 | 非水电解液以及使用其的锂二次电池 |
| JP5306815B2 (ja) * | 2006-09-07 | 2013-10-02 | 国立大学法人豊橋技術科学大学 | 共重合体およびその製造方法 |
| KR100796989B1 (ko) | 2006-09-20 | 2008-01-22 | 연세대학교 산학협력단 | 수소이온 전도성 가교형 불소계 공중합체 전해질막 |
| KR100796990B1 (ko) | 2006-09-20 | 2008-01-22 | 연세대학교 산학협력단 | 친수성 및 술폰화 그룹이 도입된 가지형 불소계 공중합체전해질막 |
| WO2008081520A1 (ja) * | 2006-12-27 | 2008-07-10 | Mitsubishi Electric Corporation | 放電表面処理用電極およびその製造方法 |
| JP4427629B2 (ja) * | 2008-04-11 | 2010-03-10 | パナソニック株式会社 | エネルギー蓄積デバイス、その製造方法及びそれを搭載した装置 |
| US20110076572A1 (en) * | 2009-09-25 | 2011-03-31 | Khalil Amine | Non-aqueous electrolytes for electrochemical cells |
| WO2011146670A1 (en) * | 2010-05-19 | 2011-11-24 | Seeo, Inc | High temperature lithium cells with solid polymer electrolytes |
| US9093722B2 (en) | 2010-09-30 | 2015-07-28 | Uchicago Argonne, Llc | Functionalized ionic liquid electrolytes for lithium ion batteries |
| CN104465099B (zh) * | 2014-12-18 | 2017-12-15 | 中山大学 | 一种金属有机凝胶电解质的制备方法 |
| KR101750472B1 (ko) | 2014-12-22 | 2017-06-26 | 주식회사 엘지화학 | 아조단량체 및 상기 아조단량체의 중합에 의해 제조되는 아조중합체 |
| CN104698717B (zh) * | 2015-03-12 | 2017-12-05 | 浙江工业大学 | 凝胶状的聚合物电解质以及基于导电聚合物的固态电致变色器件的制备方法 |
| EP3353844B1 (de) | 2015-03-27 | 2022-05-11 | Mason K. Harrup | Vollständig anorganische lösungsmittel für elektrolyte |
| US10211462B2 (en) * | 2016-02-12 | 2019-02-19 | Sanyo Chemical Industries, Ltd. | Lithium ion cell |
| US10587005B2 (en) * | 2016-03-30 | 2020-03-10 | Wildcat Discovery Technologies, Inc. | Solid electrolyte compositions |
| CN107437600B (zh) * | 2016-06-15 | 2023-09-19 | 许昌学院 | 骨架及凝胶基质一体化的锂离子电池活性隔膜及制备方法 |
| US10707531B1 (en) | 2016-09-27 | 2020-07-07 | New Dominion Enterprises Inc. | All-inorganic solvents for electrolytes |
| US10741874B2 (en) * | 2017-01-12 | 2020-08-11 | Lg Chem, Ltd. | Composition for gel polymer electrolyte and lithium secondary battery including the same |
| WO2019054622A1 (ko) * | 2017-09-14 | 2019-03-21 | 주식회사 엘지화학 | 이차전지용 고체 전해질 조성물 및 이로부터 제조된 고체 전해질 |
| KR102183663B1 (ko) | 2017-09-14 | 2020-11-26 | 주식회사 엘지화학 | 이차전지용 고체 전해질 조성물 및 이로부터 제조된 고체 전해질 |
| CN109037771B (zh) * | 2018-07-25 | 2020-07-28 | 江苏合志锂硫电池技术有限公司 | 聚合物锂离子电池及其制备方法 |
| US11955595B2 (en) | 2019-04-22 | 2024-04-09 | Bioenno Tech LLC | High-ionic conductivity ceramic-polymer nanocomposite solid state electrolyte |
| US11223088B2 (en) | 2019-10-07 | 2022-01-11 | Bioenno Tech LLC | Low-temperature ceramic-polymer nanocomposite solid state electrolyte |
| US11588176B2 (en) | 2021-01-04 | 2023-02-21 | Bioenno Tech LLC | All solid-state lithium-ion battery incorporating electrolyte-infiltrated composite electrodes |
| US12463245B2 (en) | 2021-01-04 | 2025-11-04 | Solid Energies Inc. | High voltage electrolyte for 5V solid state lithium-ion battery cell |
| CN115312853B (zh) * | 2022-07-26 | 2025-09-26 | 广州巨湾技研有限公司 | 一种半凝胶电解质及其制备方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2544016B2 (ja) * | 1990-10-11 | 1996-10-16 | 信越化学工業株式会社 | リチウム電池 |
| DE59206145D1 (de) | 1991-02-09 | 1996-06-05 | Dornier Gmbh | Polymerer Festelektrolyt |
| AT395438B (de) * | 1991-02-12 | 1992-12-28 | Vianova Kunstharz Ag | Verfahren zur herstellung von organozinn-zubereitungen und deren verwendung |
| US5275750A (en) | 1991-07-18 | 1994-01-04 | Matsushita Electric Industrial Co., Ltd. | Method of manufacturing a solid polymer electrolyte |
| JP2978290B2 (ja) * | 1991-07-18 | 1999-11-15 | 松下電器産業株式会社 | 高分子固体電解質 |
| JPH05221701A (ja) * | 1992-02-14 | 1993-08-31 | Kajima Corp | 地下連続壁用コンクリート混和剤、それを用いたコンクリートおよび該コンクリートを用いて地下連続壁を施工する方法 |
| US5496656A (en) * | 1992-06-30 | 1996-03-05 | Yuasa Corporation | Battery |
| JPH06267593A (ja) * | 1993-03-15 | 1994-09-22 | Yuasa Corp | 電 池 |
| US5538655A (en) * | 1994-06-29 | 1996-07-23 | Arthur D. Little, Inc. | Molecular complexes for use as electrolyte components |
| US5609974A (en) | 1995-08-04 | 1997-03-11 | Battery Engineering, Inc. | Rechargeable battery polymeric electrolyte |
| JP2936097B2 (ja) * | 1997-04-22 | 1999-08-23 | 錦湖石油化學 株式會▲社▼ | 複合電極およびそれから得られる二次電池 |
| JPH1135765A (ja) | 1997-07-24 | 1999-02-09 | Sharp Corp | 高分子固体電解質とその製造方法 |
| US6294289B1 (en) * | 1998-08-25 | 2001-09-25 | 3M Innovative Properties Company | Cyano-substituted methide and amide salts |
-
1999
- 1999-12-20 SE SE9904667A patent/SE518564C2/sv not_active IP Right Cessation
-
2000
- 2000-12-20 WO PCT/SE2000/002599 patent/WO2001046280A1/en not_active Ceased
- 2000-12-20 EP EP00989109A patent/EP1272538B1/de not_active Expired - Lifetime
- 2000-12-20 CN CN00817429A patent/CN1411475A/zh active Pending
- 2000-12-20 US US09/745,137 patent/US6596440B2/en not_active Expired - Lifetime
- 2000-12-20 DE DE60020745T patent/DE60020745D1/de not_active Expired - Lifetime
- 2000-12-20 AT AT00989109T patent/ATE297422T1/de not_active IP Right Cessation
- 2000-12-20 JP JP2001547187A patent/JP4741140B2/ja not_active Expired - Fee Related
- 2000-12-20 AU AU25655/01A patent/AU2565501A/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| CN1411475A (zh) | 2003-04-16 |
| EP1272538A1 (de) | 2003-01-08 |
| AU2565501A (en) | 2001-07-03 |
| WO2001046280A1 (en) | 2001-06-28 |
| JP4741140B2 (ja) | 2011-08-03 |
| SE9904667D0 (sv) | 1999-12-20 |
| SE9904667L (sv) | 2001-06-21 |
| DE60020745D1 (de) | 2005-07-14 |
| US6596440B2 (en) | 2003-07-22 |
| US20010033974A1 (en) | 2001-10-25 |
| JP2003518172A (ja) | 2003-06-03 |
| ATE297422T1 (de) | 2005-06-15 |
| EP1272538B1 (de) | 2005-06-08 |
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