SE411769B - Enzymgranul innefattade en granulkerna av fast material som ber ett enzym - Google Patents
Enzymgranul innefattade en granulkerna av fast material som ber ett enzymInfo
- Publication number
- SE411769B SE411769B SE7314949A SE7314949A SE411769B SE 411769 B SE411769 B SE 411769B SE 7314949 A SE7314949 A SE 7314949A SE 7314949 A SE7314949 A SE 7314949A SE 411769 B SE411769 B SE 411769B
- Authority
- SE
- Sweden
- Prior art keywords
- granule
- enzyme
- aqueous solution
- resin
- core
- Prior art date
Links
- 239000008187 granular material Substances 0.000 title claims description 76
- 239000011343 solid material Substances 0.000 title claims description 7
- 102000004190 Enzymes Human genes 0.000 claims description 53
- 108090000790 Enzymes Proteins 0.000 claims description 53
- 239000011347 resin Substances 0.000 claims description 45
- 229920005989 resin Polymers 0.000 claims description 45
- 239000003599 detergent Substances 0.000 claims description 43
- 239000007864 aqueous solution Substances 0.000 claims description 32
- 239000000203 mixture Substances 0.000 claims description 31
- 238000000576 coating method Methods 0.000 claims description 27
- 239000011248 coating agent Substances 0.000 claims description 26
- 229920001353 Dextrin Polymers 0.000 claims description 25
- 239000004375 Dextrin Substances 0.000 claims description 25
- 235000019425 dextrin Nutrition 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 150000001875 compounds Chemical class 0.000 claims description 14
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 12
- 239000008103 glucose Substances 0.000 claims description 12
- 239000007787 solid Substances 0.000 claims description 9
- 229920001732 Lignosulfonate Polymers 0.000 claims description 7
- 229910052783 alkali metal Inorganic materials 0.000 claims description 7
- 150000001340 alkali metals Chemical class 0.000 claims description 7
- 239000004202 carbamide Substances 0.000 claims description 6
- 230000007935 neutral effect Effects 0.000 claims description 5
- 229920005552 sodium lignosulfonate Polymers 0.000 claims description 5
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 5
- 238000005507 spraying Methods 0.000 claims description 5
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 4
- 229930006000 Sucrose Natural products 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 239000005720 sucrose Substances 0.000 claims description 4
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 3
- 239000012876 carrier material Substances 0.000 claims description 3
- 229910010272 inorganic material Inorganic materials 0.000 claims description 3
- 239000011147 inorganic material Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000013042 solid detergent Substances 0.000 claims description 2
- 238000009718 spray deposition Methods 0.000 claims 1
- 239000011162 core material Substances 0.000 description 28
- 239000004014 plasticizer Substances 0.000 description 23
- 239000011734 sodium Substances 0.000 description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
- 239000011368 organic material Substances 0.000 description 9
- 229910052708 sodium Inorganic materials 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 8
- 239000002002 slurry Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 235000002639 sodium chloride Nutrition 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 108091005804 Peptidases Proteins 0.000 description 4
- 239000004365 Protease Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 125000003630 glycyl group Chemical group [H]N([H])C([H])([H])C(*)=O 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 244000063299 Bacillus subtilis Species 0.000 description 3
- 235000014469 Bacillus subtilis Nutrition 0.000 description 3
- 102000004157 Hydrolases Human genes 0.000 description 3
- 108090000604 Hydrolases Proteins 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 229920005610 lignin Polymers 0.000 description 3
- 235000012149 noodles Nutrition 0.000 description 3
- 238000007788 roughening Methods 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000003760 tallow Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 102000035195 Peptidases Human genes 0.000 description 2
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- -1 amylase Chemical class 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 235000014633 carbohydrates Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229960004106 citric acid Drugs 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 239000007850 fluorescent dye Substances 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 2
- QHZLMUACJMDIAE-SFHVURJKSA-N 1-Monopalmitin Natural products CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)CO QHZLMUACJMDIAE-SFHVURJKSA-N 0.000 description 1
- QHZLMUACJMDIAE-UHFFFAOYSA-N 1-monopalmitoylglycerol Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(O)CO QHZLMUACJMDIAE-UHFFFAOYSA-N 0.000 description 1
- IZHVBANLECCAGF-UHFFFAOYSA-N 2-hydroxy-3-(octadecanoyloxy)propyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)COC(=O)CCCCCCCCCCCCCCCCC IZHVBANLECCAGF-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 108090000371 Esterases Proteins 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 102000004195 Isomerases Human genes 0.000 description 1
- 108090000769 Isomerases Proteins 0.000 description 1
- 102000004317 Lyases Human genes 0.000 description 1
- 108090000856 Lyases Proteins 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 241000234479 Narcissus Species 0.000 description 1
- 101710163270 Nuclease Proteins 0.000 description 1
- 102000004316 Oxidoreductases Human genes 0.000 description 1
- 108090000854 Oxidoreductases Proteins 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 241000287219 Serinus canaria Species 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 239000003568 Sodium, potassium and calcium salts of fatty acids Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 108090000787 Subtilisin Proteins 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 102000004357 Transferases Human genes 0.000 description 1
- 108090000992 Transferases Proteins 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 229960004543 anhydrous citric acid Drugs 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000001175 calcium sulphate Substances 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002303 glucose derivatives Chemical class 0.000 description 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 210000000440 neutrophil Anatomy 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 150000007523 nucleic acids Chemical class 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 235000020030 perry Nutrition 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002265 redox agent Substances 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 235000013875 sodium salts of fatty acid Nutrition 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38672—Granulated or coated enzymes
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
- C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
- C12N9/98—Preparation of granular or free-flowing enzyme compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Zoology (AREA)
- Genetics & Genomics (AREA)
- Microbiology (AREA)
- Biotechnology (AREA)
- Biochemistry (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Molecular Biology (AREA)
- Medicinal Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB5068172A GB1435905A (en) | 1972-11-03 | 1972-11-03 | Enzyme granules |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SE7314949L SE7314949L (fr) | 1974-05-06 |
| SE411769B true SE411769B (sv) | 1980-02-04 |
Family
ID=10456925
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE7314949A SE411769B (sv) | 1972-11-03 | 1973-11-02 | Enzymgranul innefattade en granulkerna av fast material som ber ett enzym |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4009076A (fr) |
| AT (1) | AT336529B (fr) |
| BE (1) | BE806856A (fr) |
| CA (1) | CA994266A (fr) |
| CH (1) | CH584234A5 (fr) |
| DE (1) | DE2354791C2 (fr) |
| DK (1) | DK139156B (fr) |
| ES (1) | ES420218A1 (fr) |
| FR (1) | FR2205532B1 (fr) |
| GB (1) | GB1435905A (fr) |
| IT (1) | IT1004634B (fr) |
| NL (1) | NL7315113A (fr) |
| SE (1) | SE411769B (fr) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4115292A (en) * | 1977-04-20 | 1978-09-19 | The Procter & Gamble Company | Enzyme-containing detergent articles |
| US4176079A (en) * | 1977-04-20 | 1979-11-27 | The Procter & Gamble Company | Water-soluble enzyme-containing article |
| MX4829E (es) * | 1977-07-20 | 1982-10-21 | Gist Brocades Nv | Proceso para preparar particulas conteniendo enzimas |
| GB1603640A (en) * | 1977-07-20 | 1981-11-25 | Gist Brocades Nv | Enzyme particles |
| FR2481942B1 (fr) * | 1980-05-12 | 1988-04-22 | Unilever Nv | Granules antimousse, leur procede de fabrication et leur utilisation dans les compositions detergentes |
| US4801544A (en) * | 1984-09-12 | 1989-01-31 | The Clorox Company | Method of improving the storage life of liquid compositions containing enzymes |
| US4689297A (en) * | 1985-03-05 | 1987-08-25 | Miles Laboratories, Inc. | Dust free particulate enzyme formulation |
| US4707287A (en) * | 1985-06-28 | 1987-11-17 | The Procter & Gamble Company | Dry bleach stable enzyme composition |
| JPS624730A (ja) * | 1985-06-29 | 1987-01-10 | Ihara Chem Ind Co Ltd | コ−テイング粒状芳香族ジアミン |
| US4711739A (en) * | 1986-12-18 | 1987-12-08 | S. C. Johnson & Son, Inc. | Enzyme prespotter composition stabilized with water insoluble polyester or polyether polyol |
| US5436004A (en) * | 1988-07-21 | 1995-07-25 | Iowa State University Research Foundation, Inc. | Administration of cholesterol reductase to humans |
| US4921710A (en) * | 1988-07-21 | 1990-05-01 | Iowa State University Research Foundation, Inc. | Method of converting cholesterol in food to coprostanol |
| US5972685A (en) * | 1988-07-21 | 1999-10-26 | Iowa State University Research Foundation, Inc. | Oral administration of coprostanol producing microorganisms to humans to decrease plasma cholesterol concentration |
| US5468622A (en) * | 1990-04-03 | 1995-11-21 | Immunomatrix, Inc. | Salt stabilization of antibody-enzyme conjugates heat-dried into paper |
| US6451586B1 (en) * | 1990-11-10 | 2002-09-17 | Roehm Gmbh & Co Kg | Enzyme preparation containing protease |
| HUT67007A (en) * | 1991-07-24 | 1995-01-30 | Enzacor Pty Ltd | Preparations containing biologically activ agent wich are absorbed in the superior intestinal tract of animals |
| US5879920A (en) * | 1991-10-07 | 1999-03-09 | Genencor International, Inc. | Coated enzyme-containing granule |
| US5324649A (en) * | 1991-10-07 | 1994-06-28 | Genencor International, Inc. | Enzyme-containing granules coated with hydrolyzed polyvinyl alcohol or copolymer thereof |
| GB2267911A (en) * | 1992-04-30 | 1993-12-22 | Unilever Plc | Solid granulate detergent additives |
| DE4344215A1 (de) * | 1993-12-23 | 1995-06-29 | Cognis Bio Umwelt | Silberkorrosionsschutzmittelhaltige Enzymzubereitung |
| US5674488A (en) * | 1994-10-07 | 1997-10-07 | Reich; John J. | Method for prevention and treatment of hyperchlolesterolemia by in vivo hydrogenation of cholesterol |
| US5876791A (en) * | 1995-02-01 | 1999-03-02 | Cal-West Equipment Co., Inc. | Protective coating compositions and methods of use thereof |
| US5603992A (en) * | 1995-04-18 | 1997-02-18 | Cal West Equipment Company, Inc. | Compositions and methods for the temporary protection of activated surfaces |
| BR9608984A (pt) * | 1995-06-22 | 1999-06-29 | Unilever Nv | Composição enzimática e processos para preparara mesma e para misturar um composto de lignina com uma preparação enzimática ou um tensoativo não áquoso |
| US5858952A (en) * | 1995-12-22 | 1999-01-12 | Kao Corporation | Enzyme-containing granulated product method of preparation and compositions containing the granulated product |
| ES2176814T3 (es) * | 1997-01-10 | 2002-12-01 | Genencor Int | Recuperacion de proteinas mediante precipitacion usando lignosulfonatos. |
| US6017864A (en) * | 1997-12-30 | 2000-01-25 | Ecolab Inc. | Alkaline solid block composition |
| EP0943242A1 (fr) * | 1998-02-26 | 1999-09-22 | Puratos N.V. | Compositions granulées d'amélioration du pain et leur utilisation pour la fabrication de produits de boulangerie |
| DE19859385A1 (de) * | 1998-12-22 | 2000-06-29 | Basf Ag | Verfahren zur Herstellung von enzymhaltigen Granulaten |
| AU4358300A (en) * | 1999-04-19 | 2000-11-02 | Procter & Gamble Company, The | Bleach-free automatic dishwashing detergent composition having enzyme particles with acid barrier coating |
| ES2243255T3 (es) * | 1999-04-19 | 2005-12-01 | THE PROCTER & GAMBLE COMPANY | Particulas compuestas de enzima que contienen una barrera acida y un revestimiento de barrera fisica. |
| KR100485090B1 (ko) * | 2002-01-14 | 2005-04-22 | 주식회사 포스코 | 이온성 액체로 코팅된 효소 |
| DE602004026032D1 (de) * | 2003-01-27 | 2010-04-29 | Novozymes As | Enzymstabilisierung |
| MXPA05012879A (es) * | 2003-06-11 | 2006-06-23 | Glatt Ingtech Gmbh | Metodo para la produccion de granulados de enzima y el granulado de enzima que se obtiene. |
| DE102004062326A1 (de) * | 2004-12-20 | 2006-07-06 | Henkel Kgaa | Verfahren zur Herstellung von Enzymgranulaten mit verbesserter Abriebfestigkeit |
| GB201106409D0 (en) | 2011-04-15 | 2011-06-01 | Revolymer Ltd | Novel composite |
| GB201106408D0 (en) | 2011-04-15 | 2011-06-01 | Revolymer Ltd | Novel composite |
| GB201106391D0 (en) | 2011-04-15 | 2011-06-01 | Reckitt & Colman Overseas | Novel composite |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3519570A (en) * | 1966-04-25 | 1970-07-07 | Procter & Gamble | Enzyme - containing detergent compositions and a process for conglutination of enzymes and detergent compositions |
| GB1237144A (en) * | 1968-07-26 | 1971-06-30 | Pfizer Ltd | Coating method |
| IT915806A (fr) * | 1970-12-22 |
-
1972
- 1972-11-03 GB GB5068172A patent/GB1435905A/en not_active Expired
-
1973
- 1973-10-31 FR FR7338957A patent/FR2205532B1/fr not_active Expired
- 1973-10-31 BE BE137363A patent/BE806856A/fr not_active IP Right Cessation
- 1973-10-31 CA CA184,758A patent/CA994266A/en not_active Expired
- 1973-11-02 AT AT923273A patent/AT336529B/de not_active IP Right Cessation
- 1973-11-02 ES ES420218A patent/ES420218A1/es not_active Expired
- 1973-11-02 DK DK595873AA patent/DK139156B/da not_active IP Right Cessation
- 1973-11-02 DE DE2354791A patent/DE2354791C2/de not_active Expired
- 1973-11-02 SE SE7314949A patent/SE411769B/sv unknown
- 1973-11-02 CH CH1546773A patent/CH584234A5/xx not_active IP Right Cessation
- 1973-11-02 US US05/412,394 patent/US4009076A/en not_active Expired - Lifetime
- 1973-11-05 IT IT70244/73A patent/IT1004634B/it active
- 1973-11-05 NL NL7315113A patent/NL7315113A/xx not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| GB1435905A (en) | 1976-05-19 |
| CA994266A (en) | 1976-08-03 |
| AT336529B (de) | 1977-05-10 |
| SE7314949L (fr) | 1974-05-06 |
| BE806856A (fr) | 1974-04-30 |
| ATA923273A (de) | 1976-09-15 |
| CH584234A5 (fr) | 1977-01-31 |
| NL7315113A (fr) | 1974-05-07 |
| US4009076A (en) | 1977-02-22 |
| DE2354791C2 (de) | 1982-09-23 |
| FR2205532A1 (fr) | 1974-05-31 |
| DK139156B (da) | 1979-01-02 |
| FR2205532B1 (fr) | 1977-09-16 |
| IT1004634B (it) | 1976-07-20 |
| DE2354791A1 (de) | 1974-05-09 |
| DK139156C (fr) | 1979-06-05 |
| ES420218A1 (es) | 1976-03-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| SE411769B (sv) | Enzymgranul innefattade en granulkerna av fast material som ber ett enzym | |
| US4826632A (en) | Detergent compositions manufacturing process by spraying anionic/nonionic surfactant mix | |
| US4820441A (en) | Process for the preparation of a granular detergent composition | |
| EP0040091B1 (fr) | Granulés supprimant la mousse à utiliser dans des compositions détergentes | |
| EP0451894B2 (fr) | Compositions détergentes granulaires à haute densité apparente et leur procédé de préparation | |
| US4260651A (en) | Phosphate-free concentrated particulate heavy duty laundry detergent | |
| US5591707A (en) | Process for producing free-flowing granules with superheated steam | |
| EP2138564B1 (fr) | Procédé de préparation d'une lessive en poudre | |
| CA1096740A (fr) | Detergent a lessive concentre | |
| EP2123743B2 (fr) | Composition de détergent solide pour lessive comprenant du sel de silicate à faible densité | |
| KR950002354B1 (ko) | 세제조성물 및 그 제조방법 | |
| US4006110A (en) | Manufacture of free-flowing particulate heavy duty synthetic detergent composition | |
| CA1105347A (fr) | Agglomerats d'agents desintegrables ameliorant la detergence | |
| US5663136A (en) | Process for making compact detergent compositions | |
| JPH0832917B2 (ja) | 自由流動性粉末洗剤の製造方法 | |
| CA2595487A1 (fr) | Detergent lessiviel particulaire comprenant un tensioactif detersif, du carbonate et un polymere cellulosique | |
| DK163364B (da) | Smudsloesnende vaskemiddel samt en fremgangsmaade under anvendelse deraf | |
| CA2083332C (fr) | Compositions pour detergent et procede de preparation | |
| US4310431A (en) | Free flowing builder beads and detergents | |
| JPS591439B2 (ja) | 粒状洗剤の改質法 | |
| US4111853A (en) | Particulate composition of sodium alpha olefin sulfonate and sodium silicate | |
| US4663194A (en) | Phosphate-free concentrated particulate heavy duty laundry detergent | |
| US20110257059A1 (en) | Process for Making a Detergent | |
| US4186114A (en) | Free-flowing granular detergent compositions containing olefin sulfonates | |
| CA1042306A (fr) | Fabrication de produits ameliores d'iminoacetate d'hydroxyalkyle de metal silicate-alcali et de metal alcalin aqueux |