SA516380448B1 - أنظمة مدمجة وطرق لفصل واستخلاص الهيدروكربونات العطرية متعددة الأنوية، والمركبات الحلقية غير المتجانسة، والمركبات الفلزية العضوية من خامات تغذية هيدروكربونية - Google Patents
أنظمة مدمجة وطرق لفصل واستخلاص الهيدروكربونات العطرية متعددة الأنوية، والمركبات الحلقية غير المتجانسة، والمركبات الفلزية العضوية من خامات تغذية هيدروكربونية Download PDFInfo
- Publication number
- SA516380448B1 SA516380448B1 SA516380448A SA516380448A SA516380448B1 SA 516380448 B1 SA516380448 B1 SA 516380448B1 SA 516380448 A SA516380448 A SA 516380448A SA 516380448 A SA516380448 A SA 516380448A SA 516380448 B1 SA516380448 B1 SA 516380448B1
- Authority
- SA
- Saudi Arabia
- Prior art keywords
- extraction
- compounds
- solvent
- heteroatom
- stream
- Prior art date
Links
- 238000000605 extraction Methods 0.000 title claims abstract description 429
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 123
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 121
- 238000000034 method Methods 0.000 title claims abstract description 112
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 108
- 229920005547 polycyclic aromatic hydrocarbon Polymers 0.000 title claims abstract description 65
- 150000002391 heterocyclic compounds Chemical class 0.000 title claims abstract description 50
- 238000000926 separation method Methods 0.000 title claims description 39
- 150000002902 organometallic compounds Chemical class 0.000 title abstract description 33
- 150000001875 compounds Chemical class 0.000 claims abstract description 233
- 239000002904 solvent Substances 0.000 claims abstract description 227
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 95
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 47
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 44
- 239000010779 crude oil Substances 0.000 claims abstract description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000002608 ionic liquid Substances 0.000 claims abstract description 22
- 239000000010 aprotic solvent Substances 0.000 claims abstract description 15
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 claims abstract description 13
- 125000005842 heteroatom Chemical group 0.000 claims description 147
- 238000011084 recovery Methods 0.000 claims description 78
- 239000000203 mixture Substances 0.000 claims description 61
- 125000003118 aryl group Chemical group 0.000 claims description 55
- 125000000623 heterocyclic group Chemical group 0.000 claims description 48
- -1 atom compound Chemical class 0.000 claims description 46
- 239000003125 aqueous solvent Substances 0.000 claims description 44
- 125000004429 atom Chemical group 0.000 claims description 33
- 238000005194 fractionation Methods 0.000 claims description 18
- 239000000126 substance Substances 0.000 claims description 17
- 238000009835 boiling Methods 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 14
- 230000015572 biosynthetic process Effects 0.000 claims description 13
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 12
- 238000012546 transfer Methods 0.000 claims description 12
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims description 11
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Substances CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 11
- IYYZUPMFVPLQIF-UHFFFAOYSA-N dibenzothiophene Chemical compound C1=CC=C2C3=CC=CC=C3SC2=C1 IYYZUPMFVPLQIF-UHFFFAOYSA-N 0.000 claims description 10
- 239000000284 extract Substances 0.000 claims description 7
- FCEHBMOGCRZNNI-UHFFFAOYSA-N 1-benzothiophene Chemical compound C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 claims description 6
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 claims description 6
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 6
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 6
- 150000001491 aromatic compounds Chemical class 0.000 claims description 6
- 229930192474 thiophene Natural products 0.000 claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 5
- 235000015076 Shorea robusta Nutrition 0.000 claims description 5
- 244000166071 Shorea robusta Species 0.000 claims description 5
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 5
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims description 4
- 230000006835 compression Effects 0.000 claims description 4
- 238000007906 compression Methods 0.000 claims description 4
- 239000006184 cosolvent Substances 0.000 claims description 4
- 238000013461 design Methods 0.000 claims description 4
- 238000003786 synthesis reaction Methods 0.000 claims description 4
- 101100234002 Drosophila melanogaster Shal gene Proteins 0.000 claims description 3
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 claims description 3
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 claims description 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 3
- LISFMEBWQUVKPJ-UHFFFAOYSA-N quinolin-2-ol Chemical compound C1=CC=C2NC(=O)C=CC2=C1 LISFMEBWQUVKPJ-UHFFFAOYSA-N 0.000 claims description 3
- DXBHBZVCASKNBY-UHFFFAOYSA-N 1,2-Benz(a)anthracene Chemical class C1=CC=C2C3=CC4=CC=CC=C4C=C3C=CC2=C1 DXBHBZVCASKNBY-UHFFFAOYSA-N 0.000 claims description 2
- 150000001454 anthracenes Chemical class 0.000 claims description 2
- 230000033228 biological regulation Effects 0.000 claims description 2
- 238000013467 fragmentation Methods 0.000 claims description 2
- 238000006062 fragmentation reaction Methods 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 150000002987 phenanthrenes Chemical class 0.000 claims description 2
- 150000003518 tetracenes Chemical class 0.000 claims description 2
- 240000008042 Zea mays Species 0.000 claims 6
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims 6
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims 6
- 235000005822 corn Nutrition 0.000 claims 6
- 230000002950 deficient Effects 0.000 claims 2
- 239000002994 raw material Substances 0.000 claims 2
- 241001556567 Acanthamoeba polyphaga mimivirus Species 0.000 claims 1
- 101000878595 Arabidopsis thaliana Squalene synthase 1 Proteins 0.000 claims 1
- 101100423891 Caenorhabditis elegans qars-1 gene Proteins 0.000 claims 1
- 235000003385 Diospyros ebenum Nutrition 0.000 claims 1
- 241000792913 Ebenaceae Species 0.000 claims 1
- 241000196324 Embryophyta Species 0.000 claims 1
- 241000989913 Gunnera petaloidea Species 0.000 claims 1
- RNGSTWPRDROEIW-UHFFFAOYSA-N [Ni].N1C(C=C2N=C(C=C3NC(=C4)C=C3)C=C2)=CC=C1C=C1C=CC4=N1 Chemical compound [Ni].N1C(C=C2N=C(C=C3NC(=C4)C=C3)C=C2)=CC=C1C=C1C=CC4=N1 RNGSTWPRDROEIW-UHFFFAOYSA-N 0.000 claims 1
- 230000009977 dual effect Effects 0.000 claims 1
- 230000010354 integration Effects 0.000 claims 1
- 150000003220 pyrenes Chemical class 0.000 claims 1
- 230000007958 sleep Effects 0.000 claims 1
- 239000011800 void material Substances 0.000 claims 1
- 230000002829 reductive effect Effects 0.000 abstract description 4
- 239000012071 phase Substances 0.000 description 63
- 150000002894 organic compounds Chemical class 0.000 description 45
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 24
- 230000008569 process Effects 0.000 description 24
- 229910052717 sulfur Inorganic materials 0.000 description 22
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 19
- 239000011593 sulfur Substances 0.000 description 18
- 238000007670 refining Methods 0.000 description 16
- 239000000047 product Substances 0.000 description 13
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- 230000002441 reversible effect Effects 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 9
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 9
- 238000012545 processing Methods 0.000 description 9
- 238000001179 sorption measurement Methods 0.000 description 9
- 239000000446 fuel Substances 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000003208 petroleum Substances 0.000 description 8
- 230000008929 regeneration Effects 0.000 description 8
- 238000011069 regeneration method Methods 0.000 description 8
- 239000002585 base Substances 0.000 description 7
- 238000006477 desulfuration reaction Methods 0.000 description 7
- 230000023556 desulfurization Effects 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000008346 aqueous phase Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 238000001914 filtration Methods 0.000 description 6
- 239000012535 impurity Substances 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 239000003849 aromatic solvent Substances 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 238000012864 cross contamination Methods 0.000 description 4
- 230000006837 decompression Effects 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 239000003502 gasoline Substances 0.000 description 4
- 230000007246 mechanism Effects 0.000 description 4
- 229910017464 nitrogen compound Inorganic materials 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 150000002898 organic sulfur compounds Chemical class 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 239000010426 asphalt Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 239000003344 environmental pollutant Substances 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 238000004508 fractional distillation Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 150000002897 organic nitrogen compounds Chemical class 0.000 description 3
- 231100000719 pollutant Toxicity 0.000 description 3
- 125000004434 sulfur atom Chemical group 0.000 description 3
- YNHJECZULSZAQK-UHFFFAOYSA-N tetraphenylporphyrin Chemical compound C1=CC(C(=C2C=CC(N2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3N2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 YNHJECZULSZAQK-UHFFFAOYSA-N 0.000 description 3
- 125000005287 vanadyl group Chemical group 0.000 description 3
- AOSZTAHDEDLTLQ-AZKQZHLXSA-N (1S,2S,4R,8S,9S,11S,12R,13S,19S)-6-[(3-chlorophenyl)methyl]-12,19-difluoro-11-hydroxy-8-(2-hydroxyacetyl)-9,13-dimethyl-6-azapentacyclo[10.8.0.02,9.04,8.013,18]icosa-14,17-dien-16-one Chemical compound C([C@@H]1C[C@H]2[C@H]3[C@]([C@]4(C=CC(=O)C=C4[C@@H](F)C3)C)(F)[C@@H](O)C[C@@]2([C@@]1(C1)C(=O)CO)C)N1CC1=CC=CC(Cl)=C1 AOSZTAHDEDLTLQ-AZKQZHLXSA-N 0.000 description 2
- 229940126657 Compound 17 Drugs 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- 101150107869 Sarg gene Proteins 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012847 fine chemical Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- HDVPIMZXLWNIIP-UHFFFAOYSA-N nickel 5,10,15,20-tetraphenyl-21,23-dihydroporphyrin Chemical compound [Ni].c1cc2nc1c(-c1ccccc1)c1ccc([nH]1)c(-c1ccccc1)c1ccc(n1)c(-c1ccccc1)c1ccc([nH]1)c2-c1ccccc1 HDVPIMZXLWNIIP-UHFFFAOYSA-N 0.000 description 2
- 150000002830 nitrogen compounds Chemical class 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 230000002085 persistent effect Effects 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 2
- 150000004032 porphyrins Chemical class 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 238000000638 solvent extraction Methods 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- AVJPROTYKYNVCI-UHFFFAOYSA-N 1-benzothiophene;thiophene Chemical compound C=1C=CSC=1.C1=CC=C2SC=CC2=C1 AVJPROTYKYNVCI-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- 235000016936 Dendrocalamus strictus Nutrition 0.000 description 1
- 101100289061 Drosophila melanogaster lili gene Proteins 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- QCWPXJXDPFRUGF-UHFFFAOYSA-N N1C=2C=C(N=3)C=CC=3C=C(N3)C=CC3=CC(=N3)C=CC3=CC1=CC=2C1=CC=CC=C1 Chemical compound N1C=2C=C(N=3)C=CC=3C=C(N3)C=CC3=CC(=N3)C=CC3=CC1=CC=2C1=CC=CC=C1 QCWPXJXDPFRUGF-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 108010067035 Pancrelipase Proteins 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 238000005267 amalgamation Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000002146 bilateral effect Effects 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 125000005586 carbonic acid group Chemical group 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- XTEGARKTQYYJKE-UHFFFAOYSA-N chloric acid Chemical compound OCl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-N 0.000 description 1
- 229940005991 chloric acid Drugs 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 230000009918 complex formation Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229940092125 creon Drugs 0.000 description 1
- 150000001923 cyclic compounds Chemical class 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000009795 derivation Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000012776 electronic material Substances 0.000 description 1
- 229940096118 ella Drugs 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 210000003127 knee Anatomy 0.000 description 1
- 210000002414 leg Anatomy 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 230000005693 optoelectronics Effects 0.000 description 1
- 125000001477 organic nitrogen group Chemical group 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000001741 organic sulfur group Chemical group 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 150000003233 pyrroles Chemical class 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000000246 remedial effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Chemical group 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- OOLLAFOLCSJHRE-ZHAKMVSLSA-N ulipristal acetate Chemical compound C1=CC(N(C)C)=CC=C1[C@@H]1C2=C3CCC(=O)C=C3CC[C@H]2[C@H](CC[C@]2(OC(C)=O)C(C)=O)[C@]2(C)C1 OOLLAFOLCSJHRE-ZHAKMVSLSA-N 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G53/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes
- C10G53/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only
- C10G53/04—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one extraction step
- C10G53/06—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one extraction step including only extraction steps, e.g. deasphalting by solvent treatment followed by extraction of aromatics
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
- C10G21/06—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents characterised by the solvent used
- C10G21/08—Inorganic compounds only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
- C10G21/06—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents characterised by the solvent used
- C10G21/12—Organic compounds only
- C10G21/16—Oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
- C10G21/06—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents characterised by the solvent used
- C10G21/12—Organic compounds only
- C10G21/20—Nitrogen-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14/300,709 US9688923B2 (en) | 2014-06-10 | 2014-06-10 | Integrated methods for separation and extraction of polynuclear aromatic hydrocarbons, heterocyclic compounds, and organometallic compounds from hydrocarbon feedstocks |
| PCT/US2015/031327 WO2015191244A1 (en) | 2014-06-10 | 2015-05-18 | Integrated systems and methods for separation and extraction of polynuclear aromatic hydrocarbons, heterocyclic compounds, and organometallic compounds from hydrocarbon feedstocks |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SA516380448B1 true SA516380448B1 (ar) | 2021-04-11 |
Family
ID=53268934
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SA516380448A SA516380448B1 (ar) | 2014-06-10 | 2016-12-07 | أنظمة مدمجة وطرق لفصل واستخلاص الهيدروكربونات العطرية متعددة الأنوية، والمركبات الحلقية غير المتجانسة، والمركبات الفلزية العضوية من خامات تغذية هيدروكربونية |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9688923B2 (https=) |
| EP (1) | EP3155071B1 (https=) |
| JP (1) | JP6261779B2 (https=) |
| KR (1) | KR101995703B1 (https=) |
| CN (1) | CN106459774A (https=) |
| SA (1) | SA516380448B1 (https=) |
| SG (1) | SG11201609787VA (https=) |
| WO (1) | WO2015191244A1 (https=) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6867494B2 (ja) * | 2017-01-04 | 2021-04-28 | サウジ アラビアン オイル カンパニーSaudi Arabian Oil Company | リサイクルからイオン性液体及び固体吸着剤により重質多核芳香族を分離することを含む水素化分解方法及びシステム |
| KR102283633B1 (ko) * | 2017-01-04 | 2021-08-03 | 사우디 아라비안 오일 컴퍼니 | 탄화수소 공급 원료로부터 복소환형 화합물 및 다핵 방향족 탄화수소의 분리 및 추출을 위한 시스템 및 방법 |
| CN106833719A (zh) * | 2017-03-08 | 2017-06-13 | 中国石油大学(北京) | 一种萃取分离原油的方法 |
| WO2019123237A1 (en) * | 2017-12-18 | 2019-06-27 | Reliance Industries Limited | Process for reducing content of asphaltene and unsubstituted polynuclear aromatics of heavy hydrocarbons |
| CN110835571A (zh) * | 2019-11-21 | 2020-02-25 | 山西焦煤集团有限责任公司 | 基于离子液体-非极性超临界流体体系的原煤脱硫方法 |
Family Cites Families (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2541458A (en) | 1945-07-09 | 1951-02-13 | Union Oil Co | Recovery of nitrogen bases |
| DE1493190C3 (de) | 1963-04-16 | 1980-10-16 | Studiengesellschaft Kohle Mbh, 4330 Muelheim | Verfahren zur Trennung von Stoffgemischen |
| US3231487A (en) | 1963-12-23 | 1966-01-25 | Pan American Petroleum Corp | Demulsification |
| US3649500A (en) | 1968-03-29 | 1972-03-14 | Petrolite Corp | Electric treatment of conductive dispersions |
| US3546098A (en) * | 1968-07-24 | 1970-12-08 | Chevron Res | Making a lube oil by hydrocracking and solvent extraction |
| CA949910A (en) | 1973-03-06 | 1974-06-25 | George J. Stastny | Separation of water - minerals - hydrocarbons emulsions using carbon dioxide gas |
| CA1023677A (en) | 1974-04-18 | 1978-01-03 | Dagmar M. Votypkova | Separation of water - minerals - hydrocarbons emulsions using carbon dioxide gas |
| GB1567310A (en) | 1975-12-29 | 1980-05-14 | Ici Ltd | Demulsification of water-in-oil emulsions |
| US4746420A (en) | 1986-02-24 | 1988-05-24 | Rei Technologies, Inc. | Process for upgrading diesel oils |
| US4778591A (en) | 1986-08-28 | 1988-10-18 | Chevron Research Company | Demetalation of hydrocarbonaceous feedstocks using carbonic acid and salts thereof |
| CN1007239B (zh) | 1986-08-28 | 1990-03-21 | 切夫尔昂研究公司 | 用螯合剂对烃类进料脱金属方法 |
| US4964995A (en) | 1989-06-16 | 1990-10-23 | Midwest Research Institute | Supercritical separation process for complex organic mixtures |
| US5143594A (en) | 1989-11-08 | 1992-09-01 | Nalco Chemical Company | Refinery anti-foulant - asphaltene dispersant |
| US5120900A (en) | 1990-12-05 | 1992-06-09 | Exxon Research And Engineering Company | Integrated solvent extraction/membrane extraction with retentate recycle for improved raffinate yield |
| FR2697020B1 (fr) | 1992-10-15 | 1994-12-09 | Oreal | Procédé de désodorisation d'un mercaptoacide par extraction des composés malodorants et produit désodorisé ainsi obtenu. |
| US6187175B1 (en) | 1996-10-04 | 2001-02-13 | Exxonmobil Research And Engineering Company | Co2 treatment to remove organically bound metal ions from crude |
| US5911869A (en) | 1997-12-09 | 1999-06-15 | Exxon Research And Engineering Co. | Method for demetallating petroleum streams (LAW639) |
| TW426775B (en) | 1998-03-16 | 2001-03-21 | Ind Tech Res Inst | Method of fibers scouring |
| US6320090B1 (en) | 1999-03-10 | 2001-11-20 | Miami University | Method of removing contaminants from petroleum distillates |
| US6248797B1 (en) | 1999-05-17 | 2001-06-19 | Shelton A. Dias | Supercritical carbon dioxide extraction of contaminants from ion exchange resins |
| DE19926577A1 (de) | 1999-06-11 | 2000-12-14 | Messer Griesheim Gmbh | Verfahren und Vorrichtung zur Emulsionsspaltung |
| US6566410B1 (en) | 2000-06-21 | 2003-05-20 | North Carolina State University | Methods of demulsifying emulsions using carbon dioxide |
| US7622035B2 (en) | 2000-09-14 | 2009-11-24 | North Carolina State University | Methods of deresinating crude oils using carbon dioxide |
| CA2436625A1 (en) | 2001-02-01 | 2002-08-22 | Lobo Liquids, Llc. | Cleaning of hydrocarbon-containing materials with critical and supercritical solvents |
| NO314389B1 (no) | 2001-02-23 | 2003-03-17 | Statoil Asa | Fremgangsmate for separering av olje, vann og gass i en separator ved bryting av vann-i-olje emulsjoner |
| JP2008274175A (ja) * | 2007-05-02 | 2008-11-13 | National Institute Of Advanced Industrial & Technology | 炭化水素類の精製法 |
| US20120279902A1 (en) | 2007-06-11 | 2012-11-08 | Mcgrady Gerard Sean | Carbonaceous material upgrading using supercritical fluids |
| WO2008154576A1 (en) | 2007-06-11 | 2008-12-18 | Hsm Systems, Inc. | Bitumen upgrading using supercritical fluids |
| DE102007059389A1 (de) | 2007-07-21 | 2009-06-10 | Universität Dortmund | Verfahren zur Aufarbeitung von koaleszenzgehemmten Emulsionen aus Ganzzell-Biotransformationen mit komprimierten oder überkritischen Gasen |
| CO6030027A1 (es) | 2007-10-18 | 2009-04-30 | Ecopetrol Sa | Procesos para el tratamiento de crudos pesados y extrapesados a boca de pozo para mejorar sus condiciones de transporte |
| DE102007060651B3 (de) | 2007-12-15 | 2009-06-25 | Clariant International Limited | Asphalten-Dispergatoren auf Basis von Phosphonsäuren |
| WO2010148204A2 (en) | 2009-06-17 | 2010-12-23 | University Of Massachusetts | Particle stabilized emulsions for extraction of hydrocarbons from oil sands and oil shale |
| EP2338955A1 (en) | 2009-12-03 | 2011-06-29 | BP Oil International Limited | Selective removal of aromatics |
| KR101605053B1 (ko) | 2009-12-30 | 2016-03-21 | 아이알피씨 퍼블릭 컴퍼니 리미티드 | 낮은 폴리아로마틱 탄화수소 함량을 갖는 프로세스 오일의 제조방법 |
| EP2542651A4 (en) | 2010-03-01 | 2017-08-23 | Envirollea Inc. | Solvent extraction process to stabilize, desulphurize and dry wide range diesels, stabilized wide range diesels obtained and their uses |
| JP5750508B2 (ja) | 2010-05-17 | 2015-07-22 | ピーティー プルタミナ (ぺルセロ) | 多環芳香族炭化水素含有量が低いプロセスオイルを製造するためのプロセス |
| CN102146297B (zh) * | 2011-03-04 | 2014-08-13 | 苏州久泰集团公司 | 一种环保芳烃油的生产方法 |
| US8574426B2 (en) | 2011-12-15 | 2013-11-05 | Uop Llc | Extraction of polycyclic aromatic compounds from petroleum feedstocks using ionic liquids |
| CN103214332B (zh) | 2012-01-18 | 2015-03-18 | 中国石油化工股份有限公司 | 由催化裂化柴油生产轻质芳烃和高品质油品的方法 |
| GB201202704D0 (en) | 2012-02-16 | 2012-04-04 | Univ Belfast | Ionic liquid separations |
| US8961780B1 (en) * | 2013-12-16 | 2015-02-24 | Saudi Arabian Oil Company | Methods for recovering organic heteroatom compounds from hydrocarbon feedstocks |
-
2014
- 2014-06-10 US US14/300,709 patent/US9688923B2/en active Active
-
2015
- 2015-05-18 WO PCT/US2015/031327 patent/WO2015191244A1/en not_active Ceased
- 2015-05-18 EP EP15725210.7A patent/EP3155071B1/en active Active
- 2015-05-18 JP JP2016572468A patent/JP6261779B2/ja active Active
- 2015-05-18 SG SG11201609787VA patent/SG11201609787VA/en unknown
- 2015-05-18 CN CN201580029240.7A patent/CN106459774A/zh active Pending
- 2015-05-18 KR KR1020167034014A patent/KR101995703B1/ko active Active
-
2016
- 2016-12-07 SA SA516380448A patent/SA516380448B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US9688923B2 (en) | 2017-06-27 |
| KR101995703B1 (ko) | 2019-07-03 |
| SG11201609787VA (en) | 2016-12-29 |
| JP6261779B2 (ja) | 2018-01-17 |
| WO2015191244A1 (en) | 2015-12-17 |
| KR20170018824A (ko) | 2017-02-20 |
| US20150353847A1 (en) | 2015-12-10 |
| JP2017523265A (ja) | 2017-08-17 |
| EP3155071A1 (en) | 2017-04-19 |
| CN106459774A (zh) | 2017-02-22 |
| EP3155071B1 (en) | 2018-11-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP2225349B1 (en) | Process and apparatus for upgrading whole crude oil to remove nitrogen and sulfur compounds | |
| KR101895091B1 (ko) | 피드/버텀 처리를 갖는 수소화 분해 공정 | |
| SA516380448B1 (ar) | أنظمة مدمجة وطرق لفصل واستخلاص الهيدروكربونات العطرية متعددة الأنوية، والمركبات الحلقية غير المتجانسة، والمركبات الفلزية العضوية من خامات تغذية هيدروكربونية | |
| US10808186B2 (en) | Systems and methods for separation and extraction of heterocyclic compounds and polynuclear aromatic hydrocarbons from a hydrocarbon feedstock | |
| SA516371316B1 (ar) | عملية لمعالجة تلقيمة هيدروكربون لها محتوى كبريت | |
| KR102271509B1 (ko) | 탄화수소 공급원료로부터 유기 헤테로원자 화합물의 회수방법 | |
| CN105296000A (zh) | 一种催化裂化汽油脱硫的耦合方法 | |
| CN102851068B (zh) | 一种汽油脱硫的方法 | |
| JP2020514459A5 (https=) | ||
| CN105238441B (zh) | 一种对汽油进行深度脱硫的方法 | |
| CN103555359A (zh) | 一种催化裂化汽油的深度脱硫方法 | |
| JP2004323544A (ja) | 油に含まれる硫黄化合物の分離方法、油に含まれる硫黄化合物および芳香族炭化水素の分離方法、高オクタン価の脱硫ガソリン基材の製造方法ならびに高オクタン価の脱硫および脱芳香族ガソリン基材の製造方法 | |
| CN102533319B (zh) | 一种脱除油品中碱性氮化物的方法 | |
| CN105154132A (zh) | 一种汽油脱硫方法 | |
| Savastano | The solvent extraction approach to petroleum demetallation | |
| CN105255516B (zh) | 一种汽油脱硫的组合方法 | |
| KR20210121723A (ko) | 초임계 추출을 이용한 중질유의 탈황 방법 | |
| CN108359493A (zh) | 对催化裂化汽油进行改质的方法 |