RU97121304A - WATER DRILLING AND COLLECTOR SOLUTION, WAY OF DRILLING A BOREHOLE AND A POLYMER FOR INHIBITING OR SWELLING OF SHALE - Google Patents

WATER DRILLING AND COLLECTOR SOLUTION, WAY OF DRILLING A BOREHOLE AND A POLYMER FOR INHIBITING OR SWELLING OF SHALE

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RU97121304A
RU97121304A RU97121304/03A RU97121304A RU97121304A RU 97121304 A RU97121304 A RU 97121304A RU 97121304/03 A RU97121304/03 A RU 97121304/03A RU 97121304 A RU97121304 A RU 97121304A RU 97121304 A RU97121304 A RU 97121304A
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monomers
polymer
alkyl groups
mol
ethylenically unsaturated
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RU97121304/03A
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RU2160759C2 (en
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Даймонд Брайан
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Эллайд Коллойдс Лимитед П.О.Бокс
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Claims (14)

1. Водный буровой или коллекторный раствор, содержащий в качестве ингибитора для сланца или глины растворенный полимер, образованный из этиленненасыщенного мономера или из смеси мономеров, отличающийся тем, что образован из 50-100 мол.% мономеров формулы (1):
Figure 00000001

где R1 выбран из Н и С14-алкильных групп,
R2 выбран из C14-алкильных групп, -C(CH3)2CH2COCH3, -СН=СН2 и -С(СН3)= СН2,
R3 выбран из Н, C14-алкильных групп, СН2=СН- и СН2=С(СН3)-,
причем, когда R3 представляет Н или С14-алкил, тогда R1 представляет Н, а R2 является -СН=СН2 или -С(СН3)=СН2, и когда R2 является -С(СН3)2СН2СОСН3, тогда R1 представляет Н;
0-50 мол.% других неионных этиленненасыщенных мономеров;
и 0-20 мол. % ионных этиленненасыщенных мономеров; и полимер имеет молекулярную массу менее 1 миллиона.
1. An aqueous drilling fluid or reservoir solution containing, as an inhibitor for shale or clay, a dissolved polymer formed from ethylenically unsaturated monomer or from a mixture of monomers, characterized in that it is formed from 50-100 mol% of monomers of the formula (1):
Figure 00000001

where R 1 selected from H and C 1 -C 4 -alkyl groups,
R 2 is selected from C 1 -C 4 alkyl groups, —C (CH 3 ) 2 CH 2 COCH 3 , —CH = CH 2 and —C (CH 3 ) = CH 2 ,
R 3 selected from H, C 1 -C 4 -alkyl groups, CH 2 = CH - and CH 2 = C (CH 3 ) -,
moreover, when R 3 is H or C 1 -C 4 -alkyl, then R 1 is H and R 2 is —CH═CH 2 or —C (CH 3 ) = CH 2 , and when R 2 is —C ( CH 3 ) 2 CH 2 COCH 3 , then R 1 represents H;
0-50 mol% of other nonionic ethylenically unsaturated monomers;
and 0-20 mol. % ionic ethylenically unsaturated monomers; and the polymer has a molecular weight of less than 1 million.
2. Водный раствор по п. 1, отличающийся тем, что является буровым раствором. 2. An aqueous solution according to claim 1, characterized in that it is a drilling fluid. 3. Водный раствор по п. 1 или 2, отличающийся тем, что количество ионного мономера по существу равно нулю. 3. An aqueous solution according to claim 1 or 2, characterized in that the amount of ionic monomer is essentially zero. 4. Водный раствор по любому из предыдущих пунктов, отличающийся тем, что R1 выбран из H и C13-алкильных групп; R2 выбран из C13-алкильных групп, -С(СH3)22СОСН3, -СН= СН2 и -С(СН3)=СН2; и R3 выбран из Н, C13-алкильных групп, СН2=СН- и СН2=С(СН3)-.4. An aqueous solution according to any one of the preceding paragraphs, characterized in that R 1 selected from H and C 1 -C 3 -alkyl groups; R 2 is selected from C 1 -C 3 alkyl groups, —C (CH 3 ) 2 CH 2 COCH 3 , —CH = CH 2 and —C (CH 3 ) = CH 2 ; and R 3 is selected from H, C 1 -C 3 alkyl groups, CH 2 = CH— and CH 2 = C (CH 3 ) -. 5. Водный раствор по любому из предыдущих пунктов, отличающийся тем, что мономеры формулы (1) выбраны из С13-алкил- и диалкил(мет)акриламидов, N-винилформамида, N-винилацетамида и диацетонакриламида.5. An aqueous solution according to any one of the preceding paragraphs, characterized in that the monomers of formula (1) are selected from C 1 -C 3 -alkyl- and dialkyl (meth) acrylamides, N-vinylformamide, N-vinylacetamide and diacetonone acrylamide. 6. Водный раствор по любому из предыдущих пунктов, отличающийся тем, что мономеры формулы (1) выбраны из N,N-диметилакриламида и N-винилформамида. 6. An aqueous solution according to any one of the preceding paragraphs, characterized in that the monomers of formula (1) are selected from N, N-dimethylacrylamide and N-vinylformamide. 7. Водный раствор по любому из предыдущих пунктов, отличающийся тем, что другие неионные мономеры содержат акриламид. 7. An aqueous solution according to any one of the preceding paragraphs, characterized in that the other non-ionic monomers contain acrylamide. 8. Водный раствор по любому из предыдущих пунктов, отличающийся тем, что смесь мономеров содержит по меньшей мере 70% мономеров формулы (1). 8. An aqueous solution according to any one of the preceding paragraphs, characterized in that the mixture of monomers contains at least 70% of the monomers of the formula (1). 9. Водный раствор по любому из предыдущих пунктов, отличающийся тем, что полимер растворен в количестве до 3% от веса раствора. 9. An aqueous solution according to any one of the preceding paragraphs, characterized in that the polymer is dissolved in an amount up to 3% by weight of the solution. 10. Способ бурения ствола скважины в содержащей сланцы породе, в котором материал удаляют из породы и вымывают водным буровым раствором на поверхность ствола скважины, а водный буровой раствор содержит растворенный полимер, образованный из мономера с этиленовой ненасыщенностью или из смеси мономеров, отличающийся тем, что полимер образован из 50-100 мол.% мономеров формулы (1):
Figure 00000002

где R1 выбран из H и C14-алкильных групп,
R1 выбран из C13-алкильных групп, -С(СH3)2СН2СОСН3, -CH=CH2 и -С(СН3)= СН2,
R3 выбран из Н, C14-алкильных групп, СН2=СН- и СН2=С(СН3)-, причем, когда R3 представляет Н или C14-алкил, тогда R1 представляет Н, a R2 является -СН=СН2 или -С(СН3)=СН2,
и когда R2 является -С(СН3)2СН2СОСН3, тогда R1 представляет Н;
0-50 мол.% других неионных этиленненасыщенных мономеров;
и 0-20 мол. % ионных этиленненасыщенных мономеров;
и полимер имеет молекулярную массу менее 1 миллиона.
10. A method of drilling a wellbore in a shale-containing rock in which material is removed from the rock and washed with an aqueous drilling fluid to the surface of the wellbore, and the aqueous drilling fluid contains dissolved polymer formed from ethylene unsaturated monomer or from a mixture of monomers, characterized in that the polymer is formed from 50-100 mol.% monomers of the formula (1):
Figure 00000002

where R 1 selected from H and C 1 -C 4 -alkyl groups,
R 1 is selected from C 1 -C 3 alkyl groups, —C (CH 3 ) 2 CH 2 COCH 3 , —CH = CH 2 and —C (CH 3 ) = CH 2 ,
R 3 is selected from H, C 1 -C 4 alkyl groups, CH 2 = CH - and CH 2 = C (CH 3 ) -, and when R 3 is H or C 1 -C 4 alkyl, then R 1 represents H, a R 2 is —CH = CH 2 or —C (CH 3 ) = CH 2 ,
and when R 2 is —C (CH 3 ) 2 CH 2 COCH 3 , then R 1 is H;
0-50 mol% of other nonionic ethylenically unsaturated monomers;
and 0-20 mol. % ionic ethylenically unsaturated monomers;
and the polymer has a molecular weight of less than 1 million.
11. Способ бурения ствола скважины в содержащей сланцы породе, в котором материал удаляют из породы и вымывают водным буровым раствором на поверхность ствола скважины, отличающийся тем, что включает распознавание того, что бурение ствола скважины происходит через содержащую сланцы породу, а буровой раствор включает растворенный полимер, образованный из этиленненасыщенного мономера или из смеси мономеров, где полимер образован из 50-100 мол.% мономеров формулы (1):
Figure 00000003

где R1 выбран из Н и C1-C4-алкильных групп,
R2 выбран из C1-C4-алкильных групп, -С(СН3)2СН2СОСН3, -СН=СН2 и -С(СН3)= СН2,
R3 выбран из Н, C1-C4-алкильных групп, СН2=СН- и СН2=С(СН3)-, причем когда R3 представляет Н или C1-C4-алкил, тогда представляет Н, a R2 является -СН=СН2 или -С(СН3)=СН2,
и когда R2 является -C(CH3)2CH2COCH3, тогда R1 представляет Н;
0-50 мол.% других неионных этиленненасыщенных мономеров;
и 0-20 мол.% ионных этиленненасыщенных мономеров;
и полимер имеет молекулярную массу менее 1 миллиона.
11. A method of drilling a wellbore in a shale-containing rock in which material is removed from the rock and washed with an aqueous drilling fluid onto the surface of the wellbore, characterized in that it recognizes that the wellbore is being drilled through the shale-containing rock and the drilling fluid includes dissolved a polymer formed from ethylenically unsaturated monomer or from a mixture of monomers, where the polymer is formed from 50-100 mol.% monomers of the formula (1):
Figure 00000003

where R 1 selected from H and C 1 -C 4 -alkyl groups,
R 2 is selected from C 1 -C 4 alkyl groups, —C (CH 3 ) 2 CH 2 COCH 3 , —CH = CH 2 and —C (CH 3 ) = CH 2 ,
R 3 selected from H, C 1 -C 4 -alkyl groups, CH 2 = CH - and CH 2 = C (CH 3 ) -, and when R 3 represents H or C 1 -C 4 -alkyl, then represents H, a R 2 is —CH = CH 2 or —C (CH 3 ) = CH 2 ,
and when R 2 is —C (CH 3 ) 2 CH 2 COCH 3 , then R 1 is H;
0-50 mol% of other nonionic ethylenically unsaturated monomers;
and 0-20 mol.% ionic ethylenically unsaturated monomers;
and the polymer has a molecular weight of less than 1 million.
12. Способ по п. 10 или 11, отличающийся тем, что водный буровой раствор имеет любые характеристики, указанные в пп. 3-9. 12. The method according to p. 10 or 11, characterized in that the aqueous drilling fluid has any of the characteristics specified in paragraphs. 3-9. 13. Полимер для ингибирования гидратации и дробления стенок ствола скважины в содержащей сланцы породе и удаляемого из него материала, растворенный в водном буровом растворе, образованный из этиленненасыщенного мономера или из смеси мономеров, отличающийся тем, что полимер образован из 50-100 мол.% мономеров формулы (1):
Figure 00000004

где R1 выбран из Н и C1-C4-алкильных групп,
R2 выбран из C1-C4-алкильных групп, -С(СН3)2СН2СОСН3, -СН=СН2 и -С(СН3)= СН2,
R3 выбран из Н, C1-C4-алкильных групп, СН2=СН- и СН2=С(СН3)-, причем, когда R3 представляет Н или C1-C3-алкил, тогда R1 представляет Н, a R2 является -СН=СН2 или -С(СН3)=СН2.
13. A polymer for inhibiting the hydration and crushing of the walls of a borehole in a rock containing shale and material removed from it, dissolved in an aqueous drilling fluid, formed from an ethylenically unsaturated monomer or from a mixture of monomers, characterized in that the polymer is formed from 50-100 mol% of monomers formulas (1):
Figure 00000004

where R 1 selected from H and C 1 -C 4 -alkyl groups,
R 2 is selected from C 1 -C 4 alkyl groups, —C (CH 3 ) 2 CH 2 COCH 3 , —CH = CH 2 and —C (CH 3 ) = CH 2 ,
R 3 is selected from H, C 1 -C 4 -alkyl groups, CH 2 = CH - and CH 2 = C (CH 3 ) -, and when R 3 is H or C 1 -C 3 -alkyl, then R 1 represents H, and R 2 is —CH = CH 2 or —C (CH 3 ) = CH 2 .
и когда R2 является -C(CH3)2CH2COCH3, тогда R1 представляет Н;
0-50 мол.% других этиленненасыщенных мономеров;
и 0-20 мол.% ионных этиленненасыщенных мономеров;
и полимер имеет молекулярную массу менее 1 миллиона.
and when R 2 is —C (CH 3 ) 2 CH 2 COCH 3 , then R 1 is H;
0-50 mol% of other ethylenically unsaturated monomers;
and 0-20 mol.% ionic ethylenically unsaturated monomers;
and the polymer has a molecular weight of less than 1 million.
14. Полимер по п. 13, отличающийся тем, что водный буровой раствор имеет характеристики, определенные в пп. 3oC9.14. The polymer according to claim 13, wherein the aqueous drilling fluid has the characteristics defined in paragraphs. 3 o C9.
RU97121304/03A 1995-05-23 1996-05-22 Aqueous drilling or collecting mud and method of drilling shaft of borehole (variants) RU2160759C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB9510396.6A GB9510396D0 (en) 1995-05-23 1995-05-23 Polymers for drilling and reservoir fluids and their use
GB9510396.6 1995-05-23

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AR (1) AR002085A1 (en)
AU (1) AU5773896A (en)
CA (1) CA2219808A1 (en)
GB (2) GB9510396D0 (en)
MX (1) MX9709046A (en)
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