RU96107237A - TONERS FOR POLYESTERS - Google Patents

TONERS FOR POLYESTERS

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Publication number
RU96107237A
RU96107237A RU96107237/04A RU96107237A RU96107237A RU 96107237 A RU96107237 A RU 96107237A RU 96107237/04 A RU96107237/04 A RU 96107237/04A RU 96107237 A RU96107237 A RU 96107237A RU 96107237 A RU96107237 A RU 96107237A
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Russia
Prior art keywords
alkyl
alkylene
substituted
group
hydrogen
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RU96107237/04A
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Russian (ru)
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RU2142477C1 (en
Inventor
Макс Аллен Уивэр
Вэйн Рэйтон Пруитт
Джерри Фауст Родес
Самуил Давид Хилберт
Уильям Уитфилд Пэрхэм
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Истмэн Кемикал Компани
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Priority claimed from US08/116,419 external-priority patent/US5372864A/en
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Publication of RU96107237A publication Critical patent/RU96107237A/en
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Claims (1)

1. Литой полиэфир или полиэфир в виде фибрилл, сополимеризованный в достаточном для усиления свойственной этому полиэфиру белизны количестве по меньшей мере одного синего соединения 1,4-бис(2,6-диалкиданилино)антрахинона, имеющего формулу I:
###1
в которой R выбирают из группы, содержащей водород, C1 - C6-алкил, галоген, карбокси и C1 - C6
Figure 00000001
R1 и R2 независимо друг от друга представляют собой C1 - C6-алкил; R3 выбирают из группы, содержащей водород, галоген, C1 - C6-алкил, замещенный C1 - C6-алкил, гидрокси, C1 - C6-алкокси, замещенный C1 - C6-алкокси, циано, тиоциано, C1 - C6-алкилтио, замещенный C1 - C6-алкилтио, C1 - C6-алкилсульфонил, замещенный C1 - C6-алкилсульфонил, C1 - C6-алкоксикарбонил, карбокси, арилокси, арилтио, арилсульфонил и SO2N(R4)R5X, если m и/или n = 0; R4 выбирают из группы, содержащей водород, C1 - C6-алкил, замещенный C1 - C6-алкил, C3 - C8-алкенил, C3 - C8-алкинил, C3 - C7-циклоалкил и арил; R5 - связывающая группа, выбранная из группы, содержащей C3 - C8-алкилен, C1 - C6-алкилен-Z-C1 - C6-алкилен, арилен-C1 - C6 - алкилен, арилен-Z-C1 - C6-алкилен, C3 - C7-циклоалкилен, C1 - C6 - алкилен-циклоалкилен-C1 - C6-алкилен, C1 - C6-алкилен-арилен-C1 - C6-алкилен и C1 - C6 - алкилен-Z-арилен-Z-C1 - C6 - алкилен, где Z выбирают из -O-, -S- или SO2; X представляет собой галоген или реактивную полиэфирную группу; и m и n независимо друг от друга представляют собой 0 или 1; при условии, что присутствует по меньшей мере одна полиэфирная реактивная группа; вместе с по крайней мере одним красным соединением антрахинона или антрапиридона, выбранным из группы соединений, имеющих приведенные ниже формулы (II)-(X):
###2
###3
###4
###5
###6
###7
###8
###9
###10
в которых R6 выбирают из группы, содержащей водород, C1 - C6-алкил, замещенный C1 - C6-алкил, C3 - C7-циклоалкил или арил; R7 представляет собой водород или от одной до трех групп, которые выбирают из C1 - C6-алкила, замещенного C1 - C6-алкила, C1 - C6-алканоиламино, галогена, C1 - C6-алкил-C1 - C6-алкокси, C1 - C6-алкилтио; R8 и R9 одинаковые или разные, выбранные из группы, включающей C1 - C6-алкил, замещенный C1 - C6-алкил, C3 - C7-циклоалкил или арил; R10 выбирают из группы, включающей C1 - C6-алкил, замещенный С1 - C6-алкил, C3 - C7-циклоалкил или арил; R11 выбирают из группы, содержащей водород, C1 - C12-алкил, замещенный C1 - C12-алкил, C3 - C7-циклоалкил и арил; R12 представляет собой водород или от одной до трех групп, которые выбирают из C1 - C6-алкила, замещенного C1 - C6-алкила, C1 - C6-алкокси, замещенного C1 - C6-алкокси, C1 - C6-алкилтио, замещенного C1 - -C6-алкилтио, галогена, гидрокси, C1 - C6-алканоиламино, ароиламино, C1 - C6-алкилсульфониламино и арилсульфониламино; R13 и R14 выбирают из водорода, циано или CO2R10; R15 представляет собой определенные ранее R4 или R5X; L представляет собой -CO- или -SO2; X имеет значения, определенные выше; m = 0 или 1; p = 12 или 2, при условии что R13 представляет собой водород, когда m = 0, и что присутствует по меньшей мере одна реактивная полиэфирная группа.1. Molded polyether or polyester in the form of fibrils, copolymerized in sufficient to enhance the amount of at least one blue compound 1,4-bis (2,6-dialkidanilino) anthraquinone, which is of the formula I:
###one
in which R is selected from the group containing hydrogen, C 1 - C 6 -alkyl, halogen, carboxy and C 1 - C 6
Figure 00000001
R 1 and R 2 independently of one another represent C 1 - C 6 -alkyl; R 3 selected from the group containing hydrogen, halogen, C 1 - C 6 -alkyl, substituted C 1 - C 6 -alkyl, hydroxy, C 1 - C 6 -alkoxy, substituted C 1 - C 6 -alkoxy, cyano, thiociano , C 1 -C 6 -alkylthio, substituted C 1 -C 6 -alkylthio, C 1 -C 6 -alkylsulfonyl, substituted C 1 -C 6 -alkylsulfonyl, C 1 -C 6 -alkoxycarbonyl, carboxy, aryloxy, arylthio, arylsulfonyl and SO 2 N (R 4 ) R 5 X, if m and / or n = 0; R 4 is selected from the group containing hydrogen, C 1 -C 6 -alkyl, substituted C 1 -C 6 -alkyl, C 3 -C 8 -alkenyl, C 3 -C 8 -alkynyl, C 3 -C 7 -cycloalkyl and aryl; R 5 is a linking group selected from the group consisting of C 3 - C 8 alkylene, C 1 - C 6 alkylene-ZC 1 - C 6 alkylene, arylene-C 1 - C 6 - alkylene, arylene-ZC 1 - C 6 -alkylene, C 3 - C 7 -cycloalkylene, C 1 - C 6 - alkylene-cycloalkylene-C 1 - C 6 -alkylene, C 1 - C 6 -alkylene-arylene-C 1 - C 6 -alkylene and C 1 - C 6 - alkylene-Z-arylene-ZC 1 - C 6 - alkylene, where Z is selected from -O-, -S- or SO 2 ; X is a halogen or reactive polyether group; and m and n are independently 0 or 1; with the proviso that at least one polyester reactive group is present; together with at least one red anthraquinone or anthrapyridone compound selected from the group of compounds having the formulas (II) - (X) below:
### 2
### 3
###four
###five
### 6
### 7
###eight
###9
###ten
in which R 6 is selected from the group consisting of hydrogen, C 1 -C 6 -alkyl, substituted C 1 -C 6 -alkyl, C 3 -C 7 -cycloalkyl or aryl; R 7 is hydrogen or from one to three groups selected from C 1 -C 6 -alkyl, substituted C 1 -C 6 -alkyl, C 1 -C 6 -alkanoylamino, halogen, C 1 -C 6 -alkyl- C 1 - C 6 alkoxy, C 1 - C 6 alkylthio; R 8 and R 9 are the same or different, selected from the group comprising C 1 -C 6 -alkyl, substituted C 1 -C 6 -alkyl, C 3 -C 7 -cycloalkyl or aryl; R 10 is selected from the group consisting of C 1 -C 6 alkyl, substituted C 1 -C 6 alkyl, C 3 -C 7 cycloalkyl, or aryl; R 11 is selected from the group containing hydrogen, C 1 -C 12 -alkyl, substituted C 1 -C 12 -alkyl, C 3 -C 7 -cycloalkyl and aryl; R 12 represents hydrogen or from one to three groups that are selected from C 1 - C 6 -alkyl, substituted C 1 - C 6 -alkyl, C 1 - C 6 -alkoxy, substituted C 1 - C 6 -alkoxy, C 1 - C 6 -alkylthio, substituted C 1 -C 6 -alkylthio, halogen, hydroxy, C 1 -C 6 -alkanoylamino, aroylamino, C 1 -C 6 -alkylsulfonylamino and arylsulfonylamino; R 13 and R 14 are selected from hydrogen, cyano or CO 2 R 10 ; R 15 is R 4 or R 5 X as previously defined; L represents -CO- or -SO 2 ; X is as defined above; m = 0 or 1; p = 12 or 2, provided that R 13 is hydrogen when m = 0, and that at least one reactive polyester group is present. 2. Полиэфир согласно п. 1, отличающийся тем, что синее соединение(я) антрахинона соответствуют приведенной выше структуре (I), в которой R представляет собой водород; R1 и R2 независимо друг от друга выбирают из метила и этила; R3 представляет собой водород, метил или бром; R4 представляет собой водород, C1 - C4-алкил или арил; R5 выбирают из группы, содержащей C1 - C6-алкилен, C1 - C4-алкилен-O-C1 - C4-алкилен, -CH2C6H10CH2-, арилен или -CH2-арилен-, а красный компонент соответствует формуле (V), в которой R7 представляет собой C1 - C6-алкокси, а R4 и R5 имеют значения, определенные в пункте 1 патентной формулы.2. The polyester according to claim 1, characterized in that the blue compound (s) of anthraquinone correspond to the above structure (I), in which R is hydrogen; R 1 and R 2 are independently selected from methyl and ethyl; R 3 is hydrogen, methyl or bromo; R 4 represents hydrogen, C 1 - C 4 -alkyl or aryl; R 5 is selected from the group containing C 1 - C 6 alkylene, C 1 - C 4 alkylene-OC 1 - C 4 alkylene, -CH 2 C 6 H 10 CH 2 -, arylene or -CH 2 -arylene and the red component corresponds to the formula (V) in which R 7 represents C 1 - C 6 -alkoxy, and R 4 and R 5 have the meanings defined in paragraph 1 of the patent formula. 3. Полиэфир по п.1 или 2, отличающийся тем, что концентрации синего и красного соединений, взятые вместе, составляют от ~ 0.5 ppm до ~ 10 ppm. 3. The polyester according to claim 1 or 2, characterized in that the concentrations of the blue and red compounds, taken together, range from ~ 0.5 ppm to ~ 10 ppm. 4. Полиэфир по п.1 или 2, отличающийся тем, что суммарная концентрация синего и красного соединений составляет от 1 до 7 ppm, а концентрация красного соединения(ий) составляет от 0,5 до 3 ppm. 4. The polyester according to claim 1 or 2, characterized in that the total concentration of blue and red compounds is from 1 to 7 ppm, and the concentration of the red compound (s) is from 0.5 to 3 ppm. 5. Полиэфир согласно пп.1, 2, 3 или 4, отличающийся тем, что соединение формулы (I) представляет собой:
###11
###12
6. Полиэфир согласно любого из пунктов с 1 по 5, отличающийся тем, что красное соединение формулы (V) представляет собой:
###13
###14
7. Полиэфир согласно любого из пунктов с 1 по 6, отличающийся тем, что синее соединение формулы (I) представляет собой
###15
и тем, что красное соединение формулы (V) представляет собой
###16
8. Метод сообщения белизны обычно воспринимаемому желтым полиэфиру, причем для улучшения видимой белизны этого полиэфира указанный метод включает сополимеризацию или смешивание указанного полиэфира с достаточным для отмеченной цели количеством по крайней мере одного синего 1,4-бис(2,6-диалкиланилино)антрахинона формулы (I)
###17
в которой: R выбирают из группы, содержащей водород, C1 - C6, галоген, карбокси и
Figure 00000002
R1 и R2 независимо друг от друга представляют собой C1 - C6-алкил; R3 выбирают из группы, содержащей водород, галоген, C1 - C6-алкил, замещенный C1 - C6-алкил, гидрокси, C1 - C6-алкокси, замещенный C1 - C6-алкокси, циано, тиоциано, C1 - C6-алкилтио, замещенный C1 - C6-алкилтио, C1 - C6-алкилсульфонил, замещенный C1 - C6-алкилсульфонил, C1 - C6-алкоксикарбонил, карбокси, арилокси, арилтио, арилсульфонил и SO2N(R4)R5X, если m и/или n = 0; R4 выбирают из группы, содержащей водород, C1 - C6-алкил, замещенный C1 - C6-алкил, C3 - C8-алкенил, C3 - C8-алкинил, C3 - C7-циклоалкил и арил; R5 - связывающая группа, выбранная из группы, содержащей C1 - C8-алкилен, C1 - C6-алкилен-Z-C1 - C6-алкилен, арилен-C1 - C6-алкилен, арилен-Z-C1 - C6-алкилен, C3 - C7-циклоалкилен, C1 - C6-алкилен-циклоалкилен-C1 - C6-алкилен, C1 - C6-алкилен-арилен-C1 - C6-алкилен и C1 - C6-алкилен-Z-арилен-Z-C1 - C6-алкилен, где Z выбирают из -O-, -S- или SO2; X представляет собой галоген или реактивную полиэфирную группу; и m и n независимо друг от друга представляют собой 0 или 1; при условии, что присутствует по меньшей мере одна полиэфирная реактивная группа; вместе с по крайней мере одним красным соединением антрахинона или антрапиридона, имеющих приведенные ниже формулы (II)-(X):
###18
###19
###20
###21
###22
###23
###24
###25
###26
в которых R6 выбирают из группы, содержащей водород, C1 - C6-алкил, замещенный C1 - C6-алкил, C3 - C7-циклоалкил или арил; R7 представляет собой водород или от одной до трех групп, которые выбирают из C1 - C6-алкила, замещенного C1 - C6-алкила, C1 - C6-алканоиламино, галогена, C1 - C6-алкил-C1 - C6-алкокси, C1 - C6-алкилтио; R8 и R9 одинаковые или разные, выбранные из группы, включающей C1 - C6-алкил, замещенный C1 - C6-алкил, C3 - C7-циклоалкил или арил; R10 выбирают из группы, включающей C1 - C6-алкил, C3 - C7-циклоалкил или арил; R11 выбирают из группы, содержащей водород, C1 - C12-алкил, замещенный C1 - C12-алкил, C3 - C7-циклоалкил и арил; R12 представляет собой водород или от одной до трех групп, которые выбирают из C1 - C6-алкила, замещенного C1 - C6-алкила, C1 - C6-алкокси, замещенного C1 - C6-алкокси, C1 - C6-алкилтио, замещенного C1 - C6-алкилтио, C1 - C6-алканоиламино, галогена, ароиламино, C1 - C6-алкилсульфониламино и арилсульфониламино; R13 и R14 выбирают из водорода, циано или CO2R10; R15 представляет собой определенные ранее R4 или R5X; L представляет собой -CO- или -SO2-; X имеет значения, определенные выше; m = 0 или 1; p = 1 или 2, при условии что R13 представляет собой водород, когда m = 0, и что при сополимеризации соединений формул (II)-(X) присутствует по меньшей мере одна реактивная полиэфирная группа.5. Polyester according to claims 1, 2, 3 or 4, characterized in that the compound of formula (I) is:
###eleven
###12
6. The polyester according to any one of paragraphs 1 to 5, characterized in that the red compound of formula (V) is:
###13
###14
7. The polyester according to any one of paragraphs 1 to 6, characterized in that the blue compound of formula (I) is
###15
and in that the red compound of formula (V) is
###sixteen
8. The method of reporting whiteness is usually perceived yellow polyester, and to improve the visible whiteness of this polyester, this method involves copolymerizing or mixing the specified polyester with a sufficient amount for the marked purpose of at least one blue 1,4-bis (2,6-dialkylanilino) anthraquinone of the formula (I)
### 17
in which: R is selected from the group consisting of hydrogen, C 1 - C 6 , halogen, carboxy and
Figure 00000002
R 1 and R 2 independently of one another represent C 1 - C 6 -alkyl; R 3 selected from the group containing hydrogen, halogen, C 1 - C 6 -alkyl, substituted C 1 - C 6 -alkyl, hydroxy, C 1 - C 6 -alkoxy, substituted C 1 - C 6 -alkoxy, cyano, thiociano , C 1 -C 6 -alkylthio, substituted C 1 -C 6 -alkylthio, C 1 -C 6 -alkylsulfonyl, substituted C 1 -C 6 -alkylsulfonyl, C 1 -C 6 -alkoxycarbonyl, carboxy, aryloxy, arylthio, arylsulfonyl and SO 2 N (R 4 ) R 5 X, if m and / or n = 0; R 4 is selected from the group containing hydrogen, C 1 -C 6 -alkyl, substituted C 1 -C 6 -alkyl, C 3 -C 8 -alkenyl, C 3 -C 8 -alkynyl, C 3 -C 7 -cycloalkyl and aryl; R 5 is a linking group selected from the group consisting of C 1 - C 8 alkylene, C 1 - C 6 alkylene-ZC 1 - C 6 alkylene, arylene-C 1 - C 6 alkylene, arylene-ZC 1 - C 6 -alkylene, C 3 -C 7 -cycloalkylene, C 1 -C 6 -alkylene-cycloalkylene-C 1 -C 6 -alkylene, C 1 -C 6 -alkylene-arylene-C 1 -C 6 -alkylene and C 1 - C 6 -alkylene-Z-arylene-ZC 1 - C 6 -alkylene, where Z is selected from -O-, -S- or SO 2 ; X is a halogen or reactive polyether group; and m and n are independently 0 or 1; with the proviso that at least one polyester reactive group is present; together with at least one red compound of anthraquinone or anthrapyridone, having the formulas (II) - (X) below:
###18
###nineteen
###20
### 21
### 22
### 23
### 24
### 25
### 26
in which R 6 is selected from the group consisting of hydrogen, C 1 -C 6 -alkyl, substituted C 1 -C 6 -alkyl, C 3 -C 7 -cycloalkyl or aryl; R 7 is hydrogen or from one to three groups selected from C 1 -C 6 -alkyl, substituted C 1 -C 6 -alkyl, C 1 -C 6 -alkanoylamino, halogen, C 1 -C 6 -alkyl- C 1 - C 6 alkoxy, C 1 - C 6 alkylthio; R 8 and R 9 are the same or different, selected from the group comprising C 1 -C 6 -alkyl, substituted C 1 -C 6 -alkyl, C 3 -C 7 -cycloalkyl or aryl; R 10 is selected from the group consisting of C 1 -C 6 alkyl, C 3 -C 7 cycloalkyl, or aryl; R 11 is selected from the group containing hydrogen, C 1 -C 12 -alkyl, substituted C 1 -C 12 -alkyl, C 3 -C 7 -cycloalkyl and aryl; R 12 represents hydrogen or from one to three groups that are selected from C 1 - C 6 -alkyl, substituted C 1 - C 6 -alkyl, C 1 - C 6 -alkoxy, substituted C 1 - C 6 -alkoxy, C 1 - C 6 -alkylthio, substituted C 1 -C 6 -alkylthio, C 1 -C 6 -alkanoylamino, halogen, aroylamino, C 1 -C 6 -alkylsulfonylamino and arylsulfonylamino; R 13 and R 14 are selected from hydrogen, cyano or CO 2 R 10 ; R 15 is R 4 or R 5 X as previously defined; L represents -CO- or -SO 2 -; X is as defined above; m = 0 or 1; p = 1 or 2, provided that R 13 is hydrogen, when m = 0, and that at least one reactive polyether group is present when copolymerizing compounds of formulas (II) to (X). 9. Метод по п.8, в котором синее соединение антрахинона соответствует приведенной выше структуре (I), в которой R1 и R2 независимо друг от друга выбирают из метила и этила; R3 представляет собой водород, метил или бром; R4 представляет собой водород, C1 - C4-алкил или арил; R5 выбирают из группы, содержащей C1 - C6-алкилен, C1 - C4-алкилен-O-C1 - C4-алкилен, -CH2C6H10CH2-, арилен или -CH2-арилен-, а красный компонент соответствует формуле (V), в которой R7 представляет собой C1 - C6-алкокси, и отличающийся тем, что суммарная концентрация синего и красного компонентов составляет от ~ 0.5 до ~ 10 ppm.9. The method of claim 8, in which the blue anthraquinone compound corresponds to the above structure (I), in which R 1 and R 2 are independently selected from methyl and ethyl; R 3 is hydrogen, methyl or bromo; R 4 represents hydrogen, C 1 - C 4 -alkyl or aryl; R 5 is selected from the group containing C 1 - C 6 alkylene, C 1 - C 4 alkylene-OC 1 - C 4 alkylene, -CH 2 C 6 H 10 CH 2 -, arylene or -CH 2 -arylene and the red component corresponds to the formula (V), in which R 7 represents C 1 - C 6 alkoxy, and characterized in that the total concentration of the blue and red components is from ~ 0.5 to ~ 10 ppm. 10. Метод по п. 8 или 9, в котором синее соединение I представляет собой:
###27
а красное соединение формулы (V) представляет собой
###28
11. Тонирующий состав премикса, содержащий смесь по меньшей мере одного синего соединения 1,4-бис(2,6-диалкиланилино)антрахинона, имеющего формулу (I):
###29
в которой R выбирают из группы, содержащей водород, C1 - C6-алкил, галоген, карбокси и C1 - C6
Figure 00000003
R1 и R2 независимо друг от друга представляют собой C1 - C6-алкил; R3 выбирают из группы, содержащей водород, галоген, C1 - C6-алкил, замещенный C1 - C6-алкил, гидрокси, C1 - C6-алкокси, замещенный C1 - C6-алкокси, циано, тиоциано, C1 - C6-алкилтио, замещенный C1 - C6-алкилтио, C1 - C6-алкилсульфонил, замещенный C1 - C6-алкилсульфонил, C1 - C6-алкоксикарбонил, карбокси, арилоси, арилтио, арилсульфонил и SO2N(R4)R5X, если m и/или n = 0; R4 выбирают из группы, содержащей водород, C1 - C6-алкил, замещенный C1 - C6-алкил, C3 - C8-алкенил, C3 - C8-алкинил, C3 - C7-циклоалкил и арил; R5 - связывающая группа, выбранная из группы, содержащей C1 - C8-алкилен, C1 - C6-алкилен-Z-C1 - C6-алкилен, арилен-C1 - C6-алкилен, арилен-Z-C1 - C6-алкилен, C3 - C7-циклоалкилен, C1 - C6-алкилен-циклоалкилен-C1 - C6-алкилен, C1 - C6-алкилен-арилен-C1 - C6-алкилен и C1 - C6-алкилен-Z-арилен-Z-C1 - C6-алкилен, где Z выбирают из -O-, -S- или SO2; X представляет собой галоген или реактивную полиэфирную группу; и m и n независимо друг от друга представляют собой 0 или 1; при условии, что присутствует по меньшей мере одна полиэфирная реактивная группа; вместе с по крайней мере одним красным соединением антрахинона или антрапиридона, выбранным из группы соединений, имеющих приведенные ниже формулы (II)-(X):
###30
###31
###32
###33
###34
###35
###36
###37
###38
в которых R6 выбирают из группы, содержащей водород, C1 - C6-алкил, замещенный C1 - C6-алкил, C3 - C7-циклоалкил или арил; R7 представляет собой водород или от одной до трех групп, которые выбирают из C1 - C6-алкила, замещенного C1 - C6-алкила, C1 - C6-алканоиламино, галогена, гидрокси, C1 - C6-алкил-C1 - C6-алкокси, C1 - C6-алкилтио; R8 и R9 одинаковые или разные, выбранные из группы, включающей C1 - C6-алкил, замещенный C1 - C6-алкил, C3 - C7-циклоалкил или арил; R10 выбирают из группы, включающей C1 - C6-алкил, замещенный C1 - C6-алкил, C3 - C7-циклоалкил или арил; R11 выбирают из группы, содержащей водород, C1 - C12-алкил, замещенный C1 - C12-алкил, C3 - C7-циклоалкил и арил; R12 представляет собой водород или от одной до трех групп, которые выбирают из C1 - C6-алкила, замещенного C1 - C6-алкила, C1 - C6-алкокси, замещенного C1 - C6-алкокси, C1 - C6-алкилтио, замещенного C1 - C6-алкилтио, C1 - C6-алканоиламино, галогена, гидрокси, ароиламино, C1 - C6-алкилсульфониламино и арилсульфониламино; R13 и R14 выбирают из водорода, циано или CO2R10; R15 представляет собой определенные ранее R4 или R5X; L представляет собой -CO- или -SO2; X имеет значения, определенные выше; m = 0 или 1; p = 1 или 2, при условии, что R13 представляет собой водород, когда m = 0.10. The method according to claim 8 or 9, in which the blue compound I is:
### 27
and the red compound of formula (V) is
### 28
11. The toning composition of the premix containing a mixture of at least one blue compound 1,4-bis (2,6-dialkylanilino) anthraquinone, having the formula (I):
### 29
in which R is selected from the group containing hydrogen, C 1 - C 6 -alkyl, halogen, carboxy and C 1 - C 6
Figure 00000003
R 1 and R 2 independently of one another represent C 1 - C 6 -alkyl; R 3 selected from the group containing hydrogen, halogen, C 1 - C 6 -alkyl, substituted C 1 - C 6 -alkyl, hydroxy, C 1 - C 6 -alkoxy, substituted C 1 - C 6 -alkoxy, cyano, thiociano C 1 -C 6 alkylthio, substituted C 1 -C 6 alkylthio, C 1 -C 6 alkylsulfonyl, substituted C 1 -C 6 alkylsulfonyl, C 1 -C 6 alkoxycarbonyl, carboxy, arylsi, arylthio, arylsulfonyl and SO 2 N (R 4 ) R 5 X, if m and / or n = 0; R 4 is selected from the group containing hydrogen, C 1 -C 6 -alkyl, substituted C 1 -C 6 -alkyl, C 3 -C 8 -alkenyl, C 3 -C 8 -alkynyl, C 3 -C 7 -cycloalkyl and aryl; R 5 is a linking group selected from the group consisting of C 1 - C 8 alkylene, C 1 - C 6 alkylene-ZC 1 - C 6 alkylene, arylene-C 1 - C 6 alkylene, arylene-ZC 1 - C 6 -alkylene, C 3 -C 7 -cycloalkylene, C 1 -C 6 -alkylene-cycloalkylene-C 1 -C 6 -alkylene, C 1 -C 6 -alkylene-arylene-C 1 -C 6 -alkylene and C 1 - C 6 -alkylene-Z-arylene-ZC 1 - C 6 -alkylene, where Z is selected from -O-, -S- or SO 2 ; X is a halogen or reactive polyether group; and m and n are independently 0 or 1; with the proviso that at least one polyester reactive group is present; together with at least one red anthraquinone or anthrapyridone compound selected from the group of compounds having the formulas (II) - (X) below:
###thirty
### 31
### 32
### 33
### 34
### 35
### 36
### 37
### 38
in which R 6 is selected from the group consisting of hydrogen, C 1 -C 6 -alkyl, substituted C 1 -C 6 -alkyl, C 3 -C 7 -cycloalkyl or aryl; R 7 is hydrogen or from one to three groups selected from C 1 - C 6 alkyl, substituted C 1 - C 6 alkyl, C 1 - C 6 alkanoylamino, halogen, hydroxy, C 1 - C 6 - alkyl-C 1 -C 6 -alkoxy, C 1 -C 6 -alkylthio; R 8 and R 9 are the same or different, selected from the group comprising C 1 -C 6 -alkyl, substituted C 1 -C 6 -alkyl, C 3 -C 7 -cycloalkyl or aryl; R 10 is selected from the group consisting of C 1 -C 6 alkyl, substituted C 1 -C 6 alkyl, C 3 -C 7 cycloalkyl or aryl; R 11 is selected from the group containing hydrogen, C 1 -C 12 -alkyl, substituted C 1 -C 12 -alkyl, C 3 -C 7 -cycloalkyl and aryl; R 12 represents hydrogen or from one to three groups that are selected from C 1 - C 6 -alkyl, substituted C 1 - C 6 -alkyl, C 1 - C 6 -alkoxy, substituted C 1 - C 6 -alkoxy, C 1 - C 6 -alkylthio, substituted C 1 -C 6 -alkylthio, C 1 -C 6 -alkanoylamino, halogen, hydroxy, aroylamino, C 1 -C 6 -alkylsulfonylamino and arylsulfonylamino; R 13 and R 14 are selected from hydrogen, cyano or CO 2 R 10 ; R 15 is R 4 or R 5 X as previously defined; L represents -CO- or -SO 2 ; X is as defined above; m = 0 or 1; p = 1 or 2, provided that R 13 is hydrogen when m = 0. 12. Формованное или профилированное изделие, содержащее полиэфир согласно любому из пунктов патентной формулы с 1 по 7. 12. A molded or shaped product containing a polyester according to any one of claims 1 to 7.
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