RU2609779C2 - Газофазная и жидкофазная каталитическая перегруппировка бекмана оксимов с получением лактамов - Google Patents

Газофазная и жидкофазная каталитическая перегруппировка бекмана оксимов с получением лактамов Download PDF

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RU2609779C2
RU2609779C2 RU2014121157A RU2014121157A RU2609779C2 RU 2609779 C2 RU2609779 C2 RU 2609779C2 RU 2014121157 A RU2014121157 A RU 2014121157A RU 2014121157 A RU2014121157 A RU 2014121157A RU 2609779 C2 RU2609779 C2 RU 2609779C2
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catalyst
sapo
silicon
oxime
reaction
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RU2014121157A
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RU2014121157A (ru
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Алан Б. ЛЕВИ
Роберт РАДЖА
Мэтью И. ПОТТЕР
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Ханивелл Интернешнл Инк.
Юниверсити Оф Саутгемптон
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
    • C01B37/08—Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/54—Phosphates, e.g. APO or SAPO compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
    • C07D201/02—Preparation of lactams
    • C07D201/04—Preparation of lactams from or via oximes by Beckmann rearrangement
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D223/00—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
    • C07D223/02—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D223/06—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D223/08—Oxygen atoms
    • C07D223/10—Oxygen atoms attached in position 2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D225/00—Heterocyclic compounds containing rings of more than seven members having one nitrogen atom as the only ring hetero atom
    • C07D225/02—Heterocyclic compounds containing rings of more than seven members having one nitrogen atom as the only ring hetero atom not condensed with other rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/05—Nuclear magnetic resonance [NMR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/10—Infrared [IR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Other In-Based Heterocyclic Compounds (AREA)
RU2014121157A 2011-10-28 2012-10-25 Газофазная и жидкофазная каталитическая перегруппировка бекмана оксимов с получением лактамов RU2609779C2 (ru)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201161628419P 2011-10-28 2011-10-28
US61/628,419 2011-10-28
US13/658,495 US8772476B2 (en) 2011-10-28 2012-10-23 Gas and liquid phase catalytic Beckmann rearrangement of oximes to produce lactams
US13/658,495 2012-10-23
PCT/US2012/061876 WO2013063244A1 (en) 2011-10-28 2012-10-25 Gas and liquid phase catalytic beckmann rearrangement of oximes to produce lactams

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RU2014121157A RU2014121157A (ru) 2015-12-10
RU2609779C2 true RU2609779C2 (ru) 2017-02-03

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US (3) US8772476B2 (https=)
EP (1) EP2771317B1 (https=)
JP (2) JP6243340B2 (https=)
KR (1) KR102002197B1 (https=)
CN (1) CN104039760B (https=)
CO (1) CO6950487A2 (https=)
ES (1) ES2856699T3 (https=)
IN (1) IN2014DN03074A (https=)
MX (1) MX354802B (https=)
RU (1) RU2609779C2 (https=)
WO (1) WO2013063244A1 (https=)

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RU2672912C1 (ru) * 2014-12-16 2018-11-21 Эдвансикс Ресинс Энд Кемикалс Ллк Иерархические алюмофосфаты в качестве катализаторов для перегруппировки бекмана

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US8772476B2 (en) * 2011-10-28 2014-07-08 Honeywell International Inc. Gas and liquid phase catalytic Beckmann rearrangement of oximes to produce lactams

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2672912C1 (ru) * 2014-12-16 2018-11-21 Эдвансикс Ресинс Энд Кемикалс Ллк Иерархические алюмофосфаты в качестве катализаторов для перегруппировки бекмана
US10537884B2 (en) 2014-12-16 2020-01-21 Advansix Resins & Chemicals Llc Hierarchical aluminophosphates as catalysts for the Beckmann rearrangement

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IN2014DN03074A (https=) 2015-05-15
WO2013063244A1 (en) 2013-05-02
US20150126732A1 (en) 2015-05-07
EP2771317B1 (en) 2020-12-09
BR112014010194A2 (pt) 2017-06-13
JP6243340B2 (ja) 2017-12-06
CN104039760B (zh) 2018-03-09
EP2771317A1 (en) 2014-09-03
US20150306586A1 (en) 2015-10-29
US20160279622A9 (en) 2016-09-29
US9221762B2 (en) 2015-12-29
CN104039760A (zh) 2014-09-10
JP2017200906A (ja) 2017-11-09
KR102002197B1 (ko) 2019-07-19
US8772476B2 (en) 2014-07-08
ES2856699T3 (es) 2021-09-28
MX354802B (es) 2018-03-22
JP2015501321A (ja) 2015-01-15
EP2771317A4 (en) 2015-10-07
MX2014005018A (es) 2014-07-09
US20130109851A1 (en) 2013-05-02
KR20150000863A (ko) 2015-01-05
RU2014121157A (ru) 2015-12-10
CO6950487A2 (es) 2014-05-20
US9662643B2 (en) 2017-05-30
BR112014010194A8 (pt) 2017-06-20

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