RU2008141367A - Способ получения амина - Google Patents
Способ получения амина Download PDFInfo
- Publication number
- RU2008141367A RU2008141367A RU2008141367/04A RU2008141367A RU2008141367A RU 2008141367 A RU2008141367 A RU 2008141367A RU 2008141367/04 A RU2008141367/04 A RU 2008141367/04A RU 2008141367 A RU2008141367 A RU 2008141367A RU 2008141367 A RU2008141367 A RU 2008141367A
- Authority
- RU
- Russia
- Prior art keywords
- catalyst
- reaction
- group
- metal
- elements
- Prior art date
Links
- 150000001412 amines Chemical class 0.000 title claims abstract 3
- 238000004519 manufacturing process Methods 0.000 title claims abstract 3
- 239000003054 catalyst Substances 0.000 claims abstract 24
- 229910052751 metal Inorganic materials 0.000 claims abstract 14
- 239000002184 metal Substances 0.000 claims abstract 14
- 230000000737 periodic effect Effects 0.000 claims abstract 12
- 150000001299 aldehydes Chemical class 0.000 claims abstract 4
- 150000002576 ketones Chemical class 0.000 claims abstract 4
- 230000035515 penetration Effects 0.000 claims abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000002638 heterogeneous catalyst Substances 0.000 claims abstract 2
- 239000001257 hydrogen Substances 0.000 claims abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract 2
- 150000003141 primary amines Chemical class 0.000 claims abstract 2
- 150000003335 secondary amines Chemical class 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims 25
- 238000000354 decomposition reaction Methods 0.000 claims 15
- 238000006243 chemical reaction Methods 0.000 claims 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 5
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims 4
- 239000007791 liquid phase Substances 0.000 claims 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical group CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 claims 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical group CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims 2
- SXVPOSFURRDKBO-UHFFFAOYSA-N Cyclododecanone Chemical group O=C1CCCCCCCCCCC1 SXVPOSFURRDKBO-UHFFFAOYSA-N 0.000 claims 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 claims 2
- JGFZNNIVVJXRND-UHFFFAOYSA-N N,N-Diisopropylethylamine (DIPEA) Chemical compound CCN(C(C)C)C(C)C JGFZNNIVVJXRND-UHFFFAOYSA-N 0.000 claims 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 2
- 125000002243 cyclohexanonyl group Chemical group *C1(*)C(=O)C(*)(*)C(*)(*)C(*)(*)C1(*)* 0.000 claims 2
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 claims 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexyloxide Natural products O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims 2
- -1 nitrogen-containing compound Chemical class 0.000 claims 2
- RYAUSSKQMZRMAI-ALOPSCKCSA-N (2S,6R)-4-[3-(4-tert-butylphenyl)-2-methylpropyl]-2,6-dimethylmorpholine Chemical compound C=1C=C(C(C)(C)C)C=CC=1CC(C)CN1C[C@H](C)O[C@H](C)C1 RYAUSSKQMZRMAI-ALOPSCKCSA-N 0.000 claims 1
- HNVIQLPOGUDBSU-PHDIDXHHSA-N (2r,6r)-2,6-dimethylmorpholine Chemical compound C[C@@H]1CNC[C@@H](C)O1 HNVIQLPOGUDBSU-PHDIDXHHSA-N 0.000 claims 1
- BZUDVELGTZDOIG-UHFFFAOYSA-N 2-ethyl-n,n-bis(2-ethylhexyl)hexan-1-amine Chemical compound CCCCC(CC)CN(CC(CC)CCCC)CC(CC)CCCC BZUDVELGTZDOIG-UHFFFAOYSA-N 0.000 claims 1
- SAIKULLUBZKPDA-UHFFFAOYSA-N Bis(2-ethylhexyl) amine Chemical compound CCCCC(CC)CNCC(CC)CCCC SAIKULLUBZKPDA-UHFFFAOYSA-N 0.000 claims 1
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical group CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 claims 1
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 claims 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims 1
- 238000001354 calcination Methods 0.000 claims 1
- 150000001728 carbonyl compounds Chemical class 0.000 claims 1
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 claims 1
- JMXKCYUTURMERF-UHFFFAOYSA-N dodemorph Chemical compound C1C(C)OC(C)CN1C1CCCCCCCCCCC1 JMXKCYUTURMERF-UHFFFAOYSA-N 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- DZFLMRWVSCEAAK-UHFFFAOYSA-N ethene;hexanal Chemical group C=C.CCCCCC=O DZFLMRWVSCEAAK-UHFFFAOYSA-N 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 238000005984 hydrogenation reaction Methods 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- VMOWKUTXPNPTEN-UHFFFAOYSA-N n,n-dimethylpropan-2-amine Chemical compound CC(C)N(C)C VMOWKUTXPNPTEN-UHFFFAOYSA-N 0.000 claims 1
- QHCCDDQKNUYGNC-UHFFFAOYSA-N n-ethylbutan-1-amine Chemical compound CCCCNCC QHCCDDQKNUYGNC-UHFFFAOYSA-N 0.000 claims 1
- 150000002823 nitrates Chemical class 0.000 claims 1
- 229910017604 nitric acid Inorganic materials 0.000 claims 1
- 150000002826 nitrites Chemical class 0.000 claims 1
- 230000020477 pH reduction Effects 0.000 claims 1
- 229910052763 palladium Inorganic materials 0.000 claims 1
- 239000012071 phase Substances 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 239000004332 silver Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
- 229910017464 nitrogen compound Inorganic materials 0.000 abstract 1
- 150000002830 nitrogen compounds Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/24—Preparation of compounds containing amino groups bound to a carbon skeleton by reductive alkylation of ammonia, amines or compounds having groups reducible to amino groups, with carbonyl compounds
- C07C209/26—Preparation of compounds containing amino groups bound to a carbon skeleton by reductive alkylation of ammonia, amines or compounds having groups reducible to amino groups, with carbonyl compounds by reduction with hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
- C07D295/023—Preparation; Separation; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06111505 | 2006-03-21 | ||
| EP06111505.1 | 2006-03-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2008141367A true RU2008141367A (ru) | 2010-04-27 |
Family
ID=38134730
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2008141367/04A RU2008141367A (ru) | 2006-03-21 | 2007-03-13 | Способ получения амина |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US8017808B2 (https=) |
| EP (1) | EP1999099B1 (https=) |
| JP (1) | JP5222278B2 (https=) |
| CN (1) | CN101405254B (https=) |
| AT (1) | ATE545626T1 (https=) |
| BR (1) | BRPI0710025A2 (https=) |
| IL (1) | IL193542A0 (https=) |
| MX (1) | MX2008011260A (https=) |
| RU (1) | RU2008141367A (https=) |
| WO (1) | WO2007107477A1 (https=) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2388682T3 (es) | 2006-05-31 | 2012-10-17 | Basf Se | Método para la producción de una amina |
| JP2017511797A (ja) * | 2014-02-18 | 2017-04-27 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | Ｎ−エチルジイソプロピルアミンの製造方法 |
| EP3169689B1 (de) * | 2014-07-18 | 2018-09-05 | Rheinisch-Westfälische Technische Hochschule (RWTH) Aachen | Verfahren zur herstellung primärer isohexid-amine |
| JP7345495B2 (ja) | 2018-04-06 | 2023-09-15 | ビーエーエスエフ ソシエタス・ヨーロピア | アミンを合成する方法 |
| EP3725768A1 (en) | 2019-04-17 | 2020-10-21 | Newron Pharmaceuticals S.p.A. | Process for the production of substituted 2-[2-(phenyl) ethylamino]alkaneamide derivatives |
| CN110713469A (zh) * | 2019-09-26 | 2020-01-21 | 宿州亿帆药业有限公司 | 一种十三吗啉的合成工艺 |
| EP4069418A1 (de) | 2019-12-03 | 2022-10-12 | Basf Se | Verfahren zur herstellung von aminen an einem kupferhaltigen katalysator |
| EP4463435A1 (en) | 2022-01-14 | 2024-11-20 | Basf Se | Method for the manufacture or conversion of alkanolamines |
| CN115814820B (zh) * | 2022-12-19 | 2024-03-22 | 山东中科新材料研究院有限公司 | 一种加氢催化剂及其制备方法和一种n,n-二甲基环己胺的制备方法 |
| CN117209443A (zh) * | 2023-07-31 | 2023-12-12 | 合肥远志医药科技开发有限公司 | 一种4-环十二烷基-2,6-二甲基吗啉的制备方法 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1179947B (de) | 1961-08-22 | 1964-10-22 | Basf Ag | Verfahren zur Herstellung N-alkylierter aromatischer Amine |
| NL137371C (https=) * | 1963-08-02 | |||
| NL169595C (nl) | 1970-05-21 | 1982-08-02 | Shell Int Research | Werkwijze voor de bereiding van aminen en van smeerolien en vloeibare motorbrandstoffen die deze bevatten. |
| BE790119A (fr) | 1971-04-15 | 1973-04-13 | Basf Ag | Procede de preparation d'amines aliphatiques et cycloaliphatiques secondaires ou tertiaires. |
| DE2830999A1 (de) | 1978-07-14 | 1980-01-31 | Basf Ag | Verfahren zur herstellung von stereoisomeren n-aralkyl-2,6-dimethylmorpholinen |
| US4404124A (en) * | 1981-05-06 | 1983-09-13 | Phillips Petroleum Company | Selective hydrogenation catalyst |
| US4521624A (en) * | 1984-04-16 | 1985-06-04 | Ethyl Corporation | Process for making cyclic amines |
| DE3611230A1 (de) * | 1986-04-04 | 1987-10-08 | Basf Ag | Polybutyl- und polyisobutylamine, verfahren zu deren herstellung und diese enthaltende kraft- und schmierstoffzusammensetzungen |
| EP0485371B1 (en) | 1987-10-16 | 1995-06-14 | Kao Corporation | Process for preparing N-substituted amine |
| CA2115025A1 (en) | 1993-02-08 | 1994-08-09 | Atsushi Furutani | Process for producing amines |
| FR2742679B1 (fr) * | 1995-12-22 | 1998-01-16 | Inst Francais Du Petrole | Catalyseur d'hydrogenation selective et procede utilisant ce catalyseur |
| DE19734975A1 (de) | 1997-08-13 | 1999-03-11 | Hoechst Ag | Schalenkatalysator, Verfahren zu dessen Herstellung sowie Verwendung, insbesondere zur Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat |
| DE19839459A1 (de) * | 1998-08-29 | 2000-03-02 | Basf Ag | Katalysator und Verfahren zur Selektivhydrierung ungesättigter Verbindungen in Kohlenwasserstoffströmen |
| DE19840373A1 (de) * | 1998-09-04 | 2000-03-09 | Basf Ag | Katalysator und Verfahren zur Selektivhydrierung ungesättigter Verbindungen in Kohlenwasserstoffströmen |
| AR033004A1 (es) * | 2001-03-16 | 2003-12-03 | Basf Ag | Procedimiento para elaborar 2,6-dialquilmorfolinas n-sustituidas |
| DE10153410A1 (de) | 2001-10-30 | 2003-05-15 | Basf Ag | Verfahren zur Auftrennung von wasserhaltigen Rohamingemischen aus der Aminsynthese |
| DE10153411A1 (de) * | 2001-10-30 | 2003-05-15 | Basf Ag | Verfahren zur Auftrennung von wasserhaltigen Rohamingemischen aus der Aminsynthese |
| DE102004059282A1 (de) | 2004-10-13 | 2006-04-27 | Basf Ag | Selektivhydrierkatalysator |
| DE102005019540A1 (de) | 2005-04-27 | 2006-11-09 | Basf Ag | Verfahren zur Herstellung eines Amins |
| WO2008006754A1 (de) * | 2006-07-14 | 2008-01-17 | Basf Se | Verfahren zur herstellung eines amins |
-
2007
- 2007-03-13 MX MX2008011260A patent/MX2008011260A/es not_active Application Discontinuation
- 2007-03-13 WO PCT/EP2007/052332 patent/WO2007107477A1/de not_active Ceased
- 2007-03-13 JP JP2009500819A patent/JP5222278B2/ja not_active Expired - Fee Related
- 2007-03-13 RU RU2008141367/04A patent/RU2008141367A/ru not_active Application Discontinuation
- 2007-03-13 AT AT07726838T patent/ATE545626T1/de active
- 2007-03-13 EP EP07726838A patent/EP1999099B1/de not_active Revoked
- 2007-03-13 US US12/293,609 patent/US8017808B2/en active Active
- 2007-03-13 CN CN2007800098506A patent/CN101405254B/zh not_active Expired - Fee Related
- 2007-03-13 BR BRPI0710025-6A patent/BRPI0710025A2/pt not_active Application Discontinuation
-
2008
- 2008-08-19 IL IL193542A patent/IL193542A0/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP1999099B1 (de) | 2012-02-15 |
| WO2007107477A1 (de) | 2007-09-27 |
| US8017808B2 (en) | 2011-09-13 |
| JP5222278B2 (ja) | 2013-06-26 |
| BRPI0710025A2 (pt) | 2011-08-02 |
| ATE545626T1 (de) | 2012-03-15 |
| MX2008011260A (es) | 2008-09-10 |
| IL193542A0 (en) | 2009-02-11 |
| EP1999099A1 (de) | 2008-12-10 |
| CN101405254A (zh) | 2009-04-08 |
| US20090082562A1 (en) | 2009-03-26 |
| CN101405254B (zh) | 2012-02-15 |
| JP2009530344A (ja) | 2009-08-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA93 | Acknowledgement of application withdrawn (no request for examination) |
Effective date: 20110216 |