RU2003102895A - CATALYST AND METHOD FOR PRODUCING HYDROCARBONS - Google Patents

CATALYST AND METHOD FOR PRODUCING HYDROCARBONS

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Publication number
RU2003102895A
RU2003102895A RU2003102895/15A RU2003102895A RU2003102895A RU 2003102895 A RU2003102895 A RU 2003102895A RU 2003102895/15 A RU2003102895/15 A RU 2003102895/15A RU 2003102895 A RU2003102895 A RU 2003102895A RU 2003102895 A RU2003102895 A RU 2003102895A
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RU
Russia
Prior art keywords
catalyst
total weight
rhenium
catalytic composition
composition
Prior art date
Application number
RU2003102895/15A
Other languages
Russian (ru)
Other versions
RU2259988C2 (en
Inventor
Якобюс Йоханнес Корнелис ГЕРЛИНГС
Ханс Мишель ХЕЙСМАН
Original Assignee
Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Шелл Интернэшнл Рисерч Маатсхаппий Б.В. filed Critical Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Publication of RU2003102895A publication Critical patent/RU2003102895A/en
Application granted granted Critical
Publication of RU2259988C2 publication Critical patent/RU2259988C2/en

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Claims (10)

1. Способ получения преимущественно С5+ углеводородов, включающий контактирование монооксида углерода с водородом при температуре 180-270°С и повышенном давлении в присутствии каталитической композиции, содержащей кобальт, марганец и, по крайней мере, рений и/или рутений на носителе из диоксида титана.1. A method of producing predominantly C 5+ hydrocarbons, comprising contacting carbon monoxide with hydrogen at a temperature of 180-270 ° C and elevated pressure in the presence of a catalytic composition containing cobalt, manganese and at least rhenium and / or ruthenium on a dioxide carrier titanium. 2. Способ по п.1, где катализатор содержит от 5 до 30 мас.% Со, и от 0,01 до 5 мас.% Mn в расчете на общую массу каталитической композиции.2. The method according to claim 1, where the catalyst contains from 5 to 30 wt.% Co, and from 0.01 to 5 wt.% Mn based on the total weight of the catalyst composition. 3. Способ по п.1 или 2, где катализатор содержит рений и/или рутений, содержание каждого из которых составляет от 0,01 до 5 мас.% в расчете на общую массу каталитической композиции.3. The method according to claim 1 or 2, where the catalyst contains rhenium and / or ruthenium, the content of each of which is from 0.01 to 5 wt.% Based on the total weight of the catalyst composition. 4. Способ по любому из пп.1-3, где температура находится в интервале 200-250°С.4. The method according to any one of claims 1 to 3, where the temperature is in the range of 200-250 ° C. 5. Способ по любому из пп.1-4, который осуществляют с использованием неподвижного слоя катализатора.5. The method according to any one of claims 1 to 4, which is carried out using a fixed catalyst bed. 6. Каталитическая композиция, содержащая кобальт, марганец и рений на носителе из диоксида титана.6. A catalytic composition containing cobalt, manganese and rhenium on a carrier of titanium dioxide. 7. Каталитическая композиция по п.6, содержащая от 5 до 30 мас.% Со и от 0,01 до 5 мас.% Re в расчете на общую массу каталитической композиции.7. The catalytic composition according to claim 6, containing from 5 to 30 wt.% Co and from 0.01 to 5 wt.% Re, based on the total weight of the catalytic composition. 8. Каталитическая композиция по п.6 или 7, содержащая от 0,01 до 5 мас.% Mn в расчете на общую массеу каталитической композиции.8. The catalytic composition according to claim 6 or 7, containing from 0.01 to 5 wt.% Mn calculated on the total weight of the catalyst composition. 9. Активированный катализатор для синтеза углеводородов, полученный путем восстановления водородом при повышенной температуре катализатора по любому из пп.6-8.9. An activated catalyst for the synthesis of hydrocarbons obtained by reduction with hydrogen at an elevated temperature of the catalyst according to any one of claims 6 to 8. 10. Способ получения каталитической композиции по любому из пп.6-9, включающий экструзию носителя из диоксида титана с соединениями кобальта и марганца, с последующим высушиванием и, необязательно, прокаливанием и последующей пропиткой раствором соли рения.10. A method of producing a catalyst composition according to any one of claims 6 to 9, comprising extruding a titanium dioxide support with cobalt and manganese compounds, followed by drying and, optionally, calcining and subsequent impregnation with a rhenium salt solution.
RU2003102895/15A 2000-07-03 2001-06-29 Catalyst and method for preparing hydrocarbons RU2259988C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP00305613.2 2000-07-03
EP00305613 2000-07-03

Publications (2)

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RU2003102895A true RU2003102895A (en) 2004-06-27
RU2259988C2 RU2259988C2 (en) 2005-09-10

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Country Status (16)

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US (2) US6759440B2 (en)
EP (1) EP1296914B1 (en)
AR (1) AR029551A1 (en)
AT (1) ATE274485T1 (en)
AU (2) AU8192001A (en)
CA (1) CA2414710A1 (en)
DE (1) DE60105162T2 (en)
DZ (1) DZ3373A1 (en)
ES (1) ES2227249T3 (en)
MX (1) MXPA02012731A (en)
MY (1) MY122994A (en)
NO (1) NO20030002L (en)
NZ (1) NZ523269A (en)
RU (1) RU2259988C2 (en)
WO (1) WO2002002489A1 (en)
ZA (1) ZA200300068B (en)

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