PL411282A1 - Method for obtaining composite containing a liquid thickened by means of coagulation - Google Patents

Method for obtaining composite containing a liquid thickened by means of coagulation

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Publication number
PL411282A1
PL411282A1 PL411282A PL41128215A PL411282A1 PL 411282 A1 PL411282 A1 PL 411282A1 PL 411282 A PL411282 A PL 411282A PL 41128215 A PL41128215 A PL 41128215A PL 411282 A1 PL411282 A1 PL 411282A1
Authority
PL
Poland
Prior art keywords
diol
diisocyanate
molecular weight
average molecular
number average
Prior art date
Application number
PL411282A
Other languages
Polish (pl)
Other versions
PL227009B1 (en
Inventor
Marcin Kaczorowski
Gabriel Rokicki
Mikołaj Szafran
Mariusz Brzeziński
Paweł Falkowski
Małgorzata Głuszek
Radosław Żurowski
Ewa Bobryk
Mariusz Tryznowski
Agnieszka Antosik
Marcin Leonowicz
Łukasz Wierzbicki
Original Assignee
Politechnika Warszawska
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Politechnika Warszawska filed Critical Politechnika Warszawska
Priority to PL411282A priority Critical patent/PL227009B1/en
Publication of PL411282A1 publication Critical patent/PL411282A1/en
Publication of PL227009B1 publication Critical patent/PL227009B1/en

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  • Polyurethanes Or Polyureas (AREA)

Abstract

Sposób otrzymywania kompozytu zawierającego ciecz zagęszczaną ścinaniem, polega na tym, że przygotowuje się prepolimer uretanowy na bazie diolu oligowęglanowego o średnim liczbowo ciężarze cząsteczkowym 1000 - 4000 lub diolu oligo(estro - węglanowego) o średnim liczbowo ciężarze cząsteczkowym 1000 - 4000 lub polibutadienu zakończonego grupami hydroksylowymi o średnim liczbowo ciężarze cząsteczkowym 1000 - 3000 jako składnika poliolowego oraz diizocyjanianu izoforonu lub diizocyjanianu heksametylenu lub diizocyjanianu toluilenu lub diizocyjanianu difenylometanu jako składnika diizocyjanianowego, przy stosunku molowym składnika poliolowego do diizocyjanianowego od 20/80 do 33/67, po czym ciecz zagęszczaną ścinaniem wprowadza się w postaci stałych zamrożonych cząstek o wymiarze 1 - 5 mm do formy z elastomeru poliuretanowego i zalewa mieszaniną składającą się z otrzymanego uprzednio prepolimeru uretanowego, przedłużacza łańcucha wybranego spośród: butano-1,4-diolu lub propano-1,2-diolu lub pentano-1,5-diolu oraz katalizatora, w temperaturze od 5 do 20°C, przy czym stosunek molowy przedłużacza łańcucha do ilości obecnych w prepolimerze grup izocyjanianowych wynosi od 33/67 do 30/70, zaś katalizator dodawany jest w ilości od 0,5 do 4%mol w stosunku do ilości obecnych w prepolimerze grup izocyjanianowych, po czym całość pozostawia się do utwardzenia.The method of obtaining a composite containing a shear thickened liquid is that a urethane prepolymer based on oligocarbon diol with a number average molecular weight of 1000 - 4000 or oligo (ester-carbonate) diol with a number average molecular weight of 1000 - 4000 or polybutadiene terminated with hydroxyl groups is prepared with a number average molecular weight of 1000-3000 as a polyol component and isophorone diisocyanate or hexamethylene diisocyanate or toluene diisocyanate or diphenylmethane diisocyanate as a diisocyanate component, at a molar ratio of polyol to diisocyanate from 20/80 to the thickened liquid in the form of solid frozen particles of 1 - 5 mm in size into a polyurethane elastomer mold and is poured with a mixture consisting of the previously obtained urethane prepolymer, a chain extender selected from: butane-1,4-diol or propane-1,2-diol or pentane-1,5-diol and catalyst at a temperature of 5 to 20 ° C, the molar ratio of chain extender to the amount of isocyanate groups present in the prepolymer is from 33/67 to 30/70, and the catalyst is added in an amount of 0.5 to 4 mol% relative to the amount of isocyanate groups present in the prepolymer, after which the whole is allowed to cure.

PL411282A 2015-02-16 2015-02-16 Method for obtaining composite containing a liquid thickened by means of coagulation PL227009B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL411282A PL227009B1 (en) 2015-02-16 2015-02-16 Method for obtaining composite containing a liquid thickened by means of coagulation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL411282A PL227009B1 (en) 2015-02-16 2015-02-16 Method for obtaining composite containing a liquid thickened by means of coagulation

Publications (2)

Publication Number Publication Date
PL411282A1 true PL411282A1 (en) 2016-08-29
PL227009B1 PL227009B1 (en) 2017-10-31

Family

ID=56760122

Family Applications (1)

Application Number Title Priority Date Filing Date
PL411282A PL227009B1 (en) 2015-02-16 2015-02-16 Method for obtaining composite containing a liquid thickened by means of coagulation

Country Status (1)

Country Link
PL (1) PL227009B1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL235452B1 (en) * 2017-11-02 2020-08-10 Politechnika Warszawska Ceramic-polymer composite and method for producing ceramic-polymer composite
PL234638B1 (en) * 2018-01-04 2020-03-31 Politechnika Warszawska Method for producing composite containing a liquid thickened by means of coagulation

Also Published As

Publication number Publication date
PL227009B1 (en) 2017-10-31

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