NZ744556A - System and method for preparing vanadium battery high-purity electrolyte - Google Patents

System and method for preparing vanadium battery high-purity electrolyte

Info

Publication number
NZ744556A
NZ744556A NZ744556A NZ74455617A NZ744556A NZ 744556 A NZ744556 A NZ 744556A NZ 744556 A NZ744556 A NZ 744556A NZ 74455617 A NZ74455617 A NZ 74455617A NZ 744556 A NZ744556 A NZ 744556A
Authority
NZ
New Zealand
Prior art keywords
vanadium
reduction
electrolyte
fluidised
recovered
Prior art date
Application number
NZ744556A
Inventor
Qingshan Zhu
Chuanlin Fan
Haitao Yang
Wenheng Mu
Jibin Liu
Cunhu Wang
Qixun Ban
Original Assignee
Inst Process Eng Cas
Beijing Zhongkaihongde Tech Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inst Process Eng Cas, Beijing Zhongkaihongde Tech Co Ltd filed Critical Inst Process Eng Cas
Publication of NZ744556A publication Critical patent/NZ744556A/en

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
    • H01M8/184—Regeneration by electrochemical means
    • H01M8/188—Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
    • H01M8/184—Regeneration by electrochemical means
    • H01M8/186—Regeneration by electrochemical means by electrolytic decomposition of the electrolytic solution or the formed water product
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J14/00—Chemical processes in general for reacting liquids with liquids; Apparatus specially adapted therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/0013—Controlling the temperature of the process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/245—Stationary reactors without moving elements inside placed in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/005—Separating solid material from the gas/liquid stream
    • B01J8/0055—Separating solid material from the gas/liquid stream using cyclones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1818—Feeding of the fluidising gas
    • B01J8/1827—Feeding of the fluidising gas the fluidising gas being a reactant
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G31/00—Compounds of vanadium
    • C01G31/02—Oxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0562—Solid materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743—Feeding or discharging of solids
    • B01J2208/00752—Feeding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743—Feeding or discharging of solids
    • B01J2208/00761—Discharging
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0002—Aqueous electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0002—Aqueous electrolytes
    • H01M2300/0005—Acid electrolytes
    • H01M2300/0011—Sulfuric acid-based
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Electrochemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Combustion & Propulsion (AREA)
  • Fuel Cell (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

A system and method for preparing a vanadium battery high-purity electrolyte, using vanadium oxytrichloride as a raw material; preparing low-valence vanadium oxide having an average vanadium valence of 3.5 by means of liquid phase hydrolysis and fluidised reduction, adding clean water and sulphuric acid dissolution, and further using ultraviolet activation to obtain an electrolyte that can be directly used for a new all-vanadium redox flow battery stack; the sensible heat and latent heat of the high-temperature exhaust gas are recovered by means of reduction fluidised bed high temperature exhaust combustion of pre-heated powder vanadium material and the sensible heat of the reduction product is recovered by means of heat transfer of the reduction product and fluidised nitrogen; implementing accurate regulation and control of the state of the reduction product by arranging internal components in a reduction fluidised bed (3) and using ultraviolet to activate the vanadium ions improves electrolyte activity; the present system and method have the advantages of a short procedure, efficiency and cleanliness, and stable product quality, and can be used in large-scale industrial production.
NZ744556A 2016-01-28 2017-01-16 System and method for preparing vanadium battery high-purity electrolyte NZ744556A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201610060029.8A CN106257727B (en) 2016-01-28 2016-01-28 A kind of system and method for preparing the high-purity electrolyte of vanadium cell
PCT/CN2017/071206 WO2017128968A1 (en) 2016-01-28 2017-01-16 System and method for preparing vanadium battery high-purity electrolyte

Publications (1)

Publication Number Publication Date
NZ744556A true NZ744556A (en) 2019-03-29

Family

ID=57713547

Family Applications (1)

Application Number Title Priority Date Filing Date
NZ744556A NZ744556A (en) 2016-01-28 2017-01-16 System and method for preparing vanadium battery high-purity electrolyte

Country Status (10)

Country Link
US (1) US10868325B2 (en)
EP (1) EP3401990A4 (en)
JP (1) JP6671486B2 (en)
CN (1) CN106257727B (en)
AU (1) AU2017211613B2 (en)
CA (1) CA3012271A1 (en)
NZ (1) NZ744556A (en)
RU (1) RU2690012C1 (en)
WO (1) WO2017128968A1 (en)
ZA (1) ZA201805716B (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106257727B (en) 2016-01-28 2018-05-22 中国科学院过程工程研究所 A kind of system and method for preparing the high-purity electrolyte of vanadium cell
CN108622935B (en) * 2017-03-17 2020-02-18 中国科学院过程工程研究所 A system and method for preparing high-purity and low-valent vanadium oxide by an efficient and clean chlorination method
CN114883596B (en) * 2020-12-21 2024-04-26 广东三水合肥工业大学研究院 Positive electrode precipitate recovery device for managing all-vanadium redox flow battery
CN113732297B (en) * 2021-09-04 2023-06-23 湖南众鑫新材料科技股份有限公司 High-purity vanadium purification process
CN115235236B (en) * 2022-07-11 2025-06-10 攀钢集团钒钛资源股份有限公司 Rotary kiln gas circuit system for producing battery-grade vanadium oxide
CN117585718B (en) * 2023-12-05 2025-12-26 四川发展兴欣钒能源科技有限公司 A method for recovering vanadium pentoxide from vanadium electrolyte

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WO1989005363A1 (en) 1987-12-10 1989-06-15 Unisearch Limited Vanadium compound dissolution processes
JP2000247643A (en) * 1999-02-24 2000-09-12 Nippon Chem Ind Co Ltd Method for producing vanadium-based electrolyte
RU2175358C1 (en) * 2000-09-04 2001-10-27 Открытое акционерное общество "АВИСМА титано-магниевый комбинат" Method of vanadium middlings processing
CA2447681A1 (en) * 2001-05-18 2002-11-28 Unisearch Limited Vanadium redox battery electrolyte
ATE554799T1 (en) * 2006-08-07 2012-05-15 Procter & Gamble ABSORBENT ARTICLES CONTAINING SUPERABSORBENT POLYMERS AND A RADIATION-INDUCED HYDROPHILIC MATERIAL
RU74634U1 (en) * 2008-01-09 2008-07-10 ООО "Энергострой" PRODUCTION SYSTEM OF TECHNOLOGICAL EQUIPMENT FOR CHLORINE PROCESSING OF TITANIUM-VANADIUM RAW MATERIAL
CN101728560B (en) 2009-04-10 2012-08-29 承德万利通实业集团有限公司 Method for preparing vanadium redox battery negative pole electrolyte
CN101562256B (en) 2009-05-27 2011-06-22 青岛武晓集团有限公司 Preparation method of electrolyte used for all vanadium redox flow batteries
CN101880059B (en) * 2010-06-08 2015-02-18 中国科学院过程工程研究所 Method for producing vanadium trioxide by adopting fluidized bed reactor
CN102468509B (en) 2010-11-16 2015-05-20 中国海洋石油总公司 Method for preparing electrolyte for vanadium battery
WO2013027076A1 (en) 2011-08-23 2013-02-28 Squirrel Holdings Ltd. "in situ" production of electrolyte solution from vanadium pentoxide for use in a flow redox battery storage system
CN102557134B (en) 2011-12-23 2014-07-02 中国科学院过程工程研究所 Fluidized reduction furnace for producing high-purity vanadium trioxide and production method
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CN106257727B (en) * 2016-01-28 2018-05-22 中国科学院过程工程研究所 A kind of system and method for preparing the high-purity electrolyte of vanadium cell

Also Published As

Publication number Publication date
AU2017211613A1 (en) 2018-08-09
WO2017128968A1 (en) 2017-08-03
US10868325B2 (en) 2020-12-15
EP3401990A4 (en) 2019-01-09
US20190044171A1 (en) 2019-02-07
JP6671486B2 (en) 2020-03-25
CN106257727A (en) 2016-12-28
CN106257727B (en) 2018-05-22
ZA201805716B (en) 2019-11-27
CA3012271A1 (en) 2017-08-03
RU2690012C1 (en) 2019-05-30
AU2017211613B2 (en) 2019-05-16
JP2019510338A (en) 2019-04-11
EP3401990A1 (en) 2018-11-14

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Free format text: THE OWNER HAS BEEN CORRECTED TO 3576253, INSTITUTE OF PROCESS ENGINEERING, CHINESE ACADEMY OF SCIENCES, BEI ER TIAO NO.1, ZHONG GUAN CUN, HAIDIAN DISTRICTBEIJING 100190, CN; 3633051, BEIJING ZHONGKAIHONGDE TECHNOLOGY CO., LTD, ROOM 202, HOPSON FORTUNE PLAZA BUILDING 1, BLOCK 13, DESHENGMENWAI STREET, XICHENG DISTRICT, BEIJING 100088, CN

Effective date: 20180911

PSEA Patent sealed
LAPS Patent lapsed