NO772391L - PESTICIDE COMPOSITIONS. - Google Patents
PESTICIDE COMPOSITIONS.Info
- Publication number
- NO772391L NO772391L NO772391A NO772391A NO772391L NO 772391 L NO772391 L NO 772391L NO 772391 A NO772391 A NO 772391A NO 772391 A NO772391 A NO 772391A NO 772391 L NO772391 L NO 772391L
- Authority
- NO
- Norway
- Prior art keywords
- oil
- agent according
- pepper
- amount
- pepper oil
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 17
- 239000000575 pesticide Substances 0.000 title abstract description 17
- 239000003921 oil Substances 0.000 claims description 54
- 241000722363 Piper Species 0.000 claims description 46
- 235000008184 Piper nigrum Nutrition 0.000 claims description 46
- 235000002566 Capsicum Nutrition 0.000 claims description 45
- 239000006002 Pepper Substances 0.000 claims description 45
- 235000016761 Piper aduncum Nutrition 0.000 claims description 45
- 235000017804 Piper guineense Nutrition 0.000 claims description 45
- 239000003795 chemical substances by application Substances 0.000 claims description 42
- 240000004460 Tanacetum coccineum Species 0.000 claims description 13
- ROVGZAWFACYCSP-MQBLHHJJSA-N [2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(C\C=C/C=C)C(=O)C1 ROVGZAWFACYCSP-MQBLHHJJSA-N 0.000 claims description 13
- 229940015367 pyrethrum Drugs 0.000 claims description 13
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 claims description 12
- 239000010642 eucalyptus oil Substances 0.000 claims description 12
- 239000002728 pyrethroid Substances 0.000 claims description 12
- 229940044949 eucalyptus oil Drugs 0.000 claims description 11
- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 claims description 10
- 230000002195 synergetic effect Effects 0.000 claims description 8
- 241000607479 Yersinia pestis Species 0.000 claims description 7
- 230000000361 pesticidal effect Effects 0.000 claims description 7
- 239000005792 Geraniol Substances 0.000 claims description 6
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 claims description 6
- 206010035148 Plague Diseases 0.000 claims description 6
- 229940113087 geraniol Drugs 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 244000166124 Eucalyptus globulus Species 0.000 claims description 5
- 239000003380 propellant Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 2
- 229940060184 oil ingredients Drugs 0.000 claims 1
- 235000019198 oils Nutrition 0.000 description 40
- 239000000443 aerosol Substances 0.000 description 14
- 230000000749 insecticidal effect Effects 0.000 description 11
- 241000255925 Diptera Species 0.000 description 10
- 238000003197 gene knockdown Methods 0.000 description 10
- 239000000126 substance Substances 0.000 description 9
- 239000008601 oleoresin Substances 0.000 description 8
- 239000000470 constituent Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000004615 ingredient Substances 0.000 description 7
- 239000002917 insecticide Substances 0.000 description 6
- 240000003085 Quassia amara Species 0.000 description 5
- 235000009694 Quassia amara Nutrition 0.000 description 5
- 238000001256 steam distillation Methods 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000002147 killing effect Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- WEEGYLXZBRQIMU-UHFFFAOYSA-N Eucalyptol Chemical compound C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 description 3
- 241000238631 Hexapoda Species 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 241000257226 Muscidae Species 0.000 description 3
- 206010033799 Paralysis Diseases 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229940013788 quassia Drugs 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 description 2
- FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
- 231100000674 Phytotoxicity Toxicity 0.000 description 2
- 239000012675 alcoholic extract Substances 0.000 description 2
- 229940024113 allethrin Drugs 0.000 description 2
- 229950002373 bioresmethrin Drugs 0.000 description 2
- 229960005233 cineole Drugs 0.000 description 2
- -1 compound piperonyl butoxide Chemical class 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 229960003536 phenothrin Drugs 0.000 description 2
- MXXWOMGUGJBKIW-YPCIICBESA-N piperine Chemical compound C=1C=C2OCOC2=CC=1/C=C/C=C/C(=O)N1CCCCC1 MXXWOMGUGJBKIW-YPCIICBESA-N 0.000 description 2
- 229940075559 piperine Drugs 0.000 description 2
- WVWHRXVVAYXKDE-UHFFFAOYSA-N piperine Natural products O=C(C=CC=Cc1ccc2OCOc2c1)C3CCCCN3 WVWHRXVVAYXKDE-UHFFFAOYSA-N 0.000 description 2
- 235000019100 piperine Nutrition 0.000 description 2
- 229960005235 piperonyl butoxide Drugs 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- CXBMCYHAMVGWJQ-CABCVRRESA-N (1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-CABCVRRESA-N 0.000 description 1
- SBNFWQZLDJGRLK-RTWAWAEBSA-N (1R)-trans-phenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-RTWAWAEBSA-N 0.000 description 1
- 241000256118 Aedes aegypti Species 0.000 description 1
- 241000228245 Aspergillus niger Species 0.000 description 1
- 241001674044 Blattodea Species 0.000 description 1
- 241000238678 Boophilus Species 0.000 description 1
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000256135 Chironomus thummi Species 0.000 description 1
- 241000256057 Culex quinquefasciatus Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- WEEGYLXZBRQIMU-WAAGHKOSSA-N Eucalyptol Chemical compound C1C[C@H]2CC[C@]1(C)OC2(C)C WEEGYLXZBRQIMU-WAAGHKOSSA-N 0.000 description 1
- 241000006111 Eucalyptus dives Species 0.000 description 1
- 235000004692 Eucalyptus globulus Nutrition 0.000 description 1
- 240000004476 Eucalyptus polybractea Species 0.000 description 1
- 235000009683 Eucalyptus polybractea Nutrition 0.000 description 1
- 206010015548 Euthanasia Diseases 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241000282313 Hyaenidae Species 0.000 description 1
- 235000019501 Lemon oil Nutrition 0.000 description 1
- 241000258915 Leptinotarsa Species 0.000 description 1
- 241000258916 Leptinotarsa decemlineata Species 0.000 description 1
- 241000736227 Lucilia sericata Species 0.000 description 1
- 240000007794 Melaleuca viridiflora Species 0.000 description 1
- 241000283973 Oryctolagus cuniculus Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 244000203593 Piper nigrum Species 0.000 description 1
- ATTZFSUZZUNHBP-UHFFFAOYSA-N Piperonyl sulfoxide Chemical compound CCCCCCCCS(=O)C(C)CC1=CC=C2OCOC2=C1 ATTZFSUZZUNHBP-UHFFFAOYSA-N 0.000 description 1
- 241000333689 Tineola Species 0.000 description 1
- VXSIXFKKSNGRRO-MXOVTSAMSA-N [(1s)-2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate;[(1s)-2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-3-[(e)-3-methoxy-2-methyl-3-oxoprop-1-enyl Chemical class CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1.CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VXSIXFKKSNGRRO-MXOVTSAMSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- MKHVZQXYWACUQC-UHFFFAOYSA-N bis(2-hydroxyethyl)azanium;dodecyl sulfate Chemical compound OCCNCCO.CCCCCCCCCCCCOS(O)(=O)=O MKHVZQXYWACUQC-UHFFFAOYSA-N 0.000 description 1
- 235000013614 black pepper Nutrition 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229930007050 cineol Natural products 0.000 description 1
- RFFOTVCVTJUTAD-UHFFFAOYSA-N cineole Natural products C1CC2(C)CCC1(C(C)C)O2 RFFOTVCVTJUTAD-UHFFFAOYSA-N 0.000 description 1
- 239000010632 citronella oil Substances 0.000 description 1
- 239000010636 coriander oil Substances 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000010501 lemon oil Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- 231100001184 nonphytotoxic Toxicity 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 1
- 229940070846 pyrethrins Drugs 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 239000012747 synergistic agent Substances 0.000 description 1
- 229960005199 tetramethrin Drugs 0.000 description 1
- 239000010678 thyme oil Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Pest Control & Pesticides (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
PESTICIDKOMPOSISJONERPESTICIDE COMPOSITIONS
Description
Foreliggende oppfinnelse vedrører forbedringer i eller i forbindelse med pestiside midler. The present invention relates to improvements in or in connection with pesticides.
Mange brukte pestisider er basert på syntetiske organiske kjemikalier. Skjønt disse forbindelsene ofte er av relativ enkel struktur og ofte kan fremstilles fra forholdsvis billige utgangsmaterialer, lider de av forskjellige ulemper Dette gjelder særlig klorerte organiske insektisider som, til tross for god virkning som insektisider, nå faller i økende unåde fordi de ikke er tilstrekkelig biologisk nedbrytbare. Ikke-klorerte organiske insektisider, for eksempel organo-fosfater, idet riktignok ikke av disse ulempene, men forskjellige insektarter utvikler ofte resistens overfor dem og bruken av dem begrenses. Videre besitter forskjellige syntetiske insektisider varmblodstoksisitet og/eller fytotoksisitet utover det som normalt ville være ønskelig. Det betår derfor behov for nye pestisider som enten er fri for disse ulemper eller lider av dem i mer begrenset grad. Særlig er det et behov for nye pestisider som fullstendig eller delvis er av naturlig opprinnelse. Many used pesticides are based on synthetic organic chemicals. Although these compounds are often of relatively simple structure and can often be produced from relatively cheap starting materials, they suffer from various disadvantages. This applies in particular to chlorinated organic insecticides which, despite their good effect as insecticides, are now falling out of favor because they are not sufficiently biological degradable. Non-chlorinated organic insecticides, for example organo-phosphates, although not of these disadvantages, but different insect species often develop resistance to them and their use is limited. Furthermore, various synthetic insecticides possess warmblood toxicity and/or phytotoxicity beyond what would normally be desirable. There is therefore a need for new pesticides which are either free of these disadvantages or suffer from them to a more limited extent. In particular, there is a need for new pesticides that are completely or partially of natural origin.
Insektisider som har funnet stor utbredelse er sådanne som er basert på naturlige og syntetiske pyretroider. Naturlig pyretroider kalles her i det følgende "pyretrum". Insecticides that have found widespread use are those based on natural and synthetic pyrethroids. Natural pyrethroids are hereafter called "pyrethrum".
Hittil har pyretrum blitt anvendt nesten utelukkende i formuleringer som spesielt er tilpasset husholdningsbruk for kontroll av flygende insekter f. eks. fluer og mygg. De har i alminne-lighet vært hydrokarbonoljer-dispersjoner som middels til høyt raffinerte kerosenolje-formuleringer. Until now, pyrethrum has been used almost exclusively in formulations that are specially adapted for household use for the control of flying insects, e.g. flies and mosquitoes. They have generally been hydrocarbon oil dispersions such as medium to highly refined kerosene oil formulations.
Pyretrum er et insektisid av "knock-down" typen. Anvendt alene i den derfor paralyse ved kontakt. Brukt i meget høye konsentra- jgir den derfor paralyse ved kontakt. Brukt i meget høye konsentira-! sjoner kan den bevirke 90% eller bedre "knock-down" målt i et Pear Grady-kammer innen få minutter. Således er dets øye-blikkelige virkning utmerket. Imidlertid er dets evne til å opprettholde "knock-down" kontroll, dvs. frembringe paralyse og død hos insektene som skal kontrolleres over et langt tids-rom ikke imponerende. Pyrethrum is an insecticide of the "knock-down" type. Used alone in the therefore paralysis by contact. Used in very high concentrations, it therefore causes paralysis on contact. Used in very high concentrations! tions, it can effect 90% or better knock-down as measured in a Pear Grady chamber within minutes. Thus, its immediate effect is excellent. However, its ability to maintain "knock-down" control, i.e. produce paralysis and death in the insects to be controlled over a long period of time is not impressive.
Utstrakt forskningsarbeide har blitt utført på forskjellige steder for å øke virkningen av pyretrum for å gjøre den mer utstrakt brukbar. Således har synergistisk virkning funnet å fremkomme ved å bruke pyretrum i blanding med forskjellige substanser, særlig i utstrakt kommersiell skala sammen med en syntetiske forbindelsen piperonyl butoksyd. Extensive research work has been carried out in various places to increase the effectiveness of pyrethrum to make it more widely usable. Thus, synergistic effects have been found to occur by using pyrethrum in mixture with various substances, particularly on an extensive commercial scale together with a synthetic compound piperonyl butoxide.
Det er tidligere blitt oppgitt av Matsubara og Tanimura i Bochu Kagaku 31(4) 162-7 (1966) at de synergistiske virkningene av piperin, kavisin og oleoresin, alle bestanddeler i pepper, It has previously been stated by Matsubara and Tanimura in Bochu Kagaku 31(4) 162-7 (1966) that the synergistic effects of piperine, cavisine and oleoresin, all constituents of pepper,
på virkningen av pyretrum og alletrin (et syntetisk pyretriod) var lavere enn for piperonyl butoksyd mot voksne husfluer av hunnkjønn. I søkerens undersøkelser har de erholdte resultatene med disse pepperbestanddelene vært usikre, skjønt det var åpenbart at en bestenddel av pepper bidro til merkbar insektisid. aktivitet. Karvisin og piperin i den utstrekning de bidrar til aktivitet eksisterer i variable konsentrasjoner i peppereksetrater. Oleoresin på den annen side er ikke en tilfredstillende forbindelse for bruk ved insektiside pre-parater fordi den forårsaker blo.kkering av sprayåpningen samtidig med å gi utilfremstillende grad av insektidi aktivitet. on the effect of pyrethrum and allethrin (a synthetic pyrethriode) was lower than that of piperonyl butoxide against adult female houseflies. In the applicant's investigations, the results obtained with these pepper constituents have been uncertain, although it was obvious that a constituent of pepper contributed to noticeable insecticidal activity. Activity. Carvisine and piperine to the extent that they contribute to activity exist in variable concentrations in pepper extracts. Oleoresin, on the other hand, is not a satisfactory compound for use in insecticidal preparations because it causes blockage of the spray orifice while providing unsatisfactory levels of insecticidal activity.
Utstrakt forskning er også utført med syntetiske pyretroider f.eks. alletrin, bioresmetrin og fenotrin. Disse.substansene besitter mange av pyretrums fordeler, f. eks. biologisk ned-brytbarhet>men har også andre fordeler omfattende tilstrekkelig øket "knock-down" og drepende effekt. Extensive research has also been carried out with synthetic pyrethroids, e.g. allethrin, bioresmethrin and phenothrin. These substances possess many of pyrethrum's advantages, e.g. biodegradability>but also has other advantages including sufficiently increased "knock-down" and killing effect.
Det er nå funnet at den insektiside aktiviteten til naturligeIt has now been found that the insecticidal activity of natural
og syntetiske pyretroider kan forbedres i synergistiske hyen-seende hvis de brukes i forbindelse med pepperolje. Denne and synthetic pyrethroids can be enhanced in synergistic hyena sightings if used in conjunction with pepper oil. This
I IN
1 oppdagelsen kan benyttes for å fremstille pestiside midler med en sterk insektisid aktivitet. 1 the discovery can be used to produce pesticides with a strong insecticidal activity.
Ulike bestanddeler fra pepper som refereres til i teknikkens stand, pepperolje, brukt i forbindelse med et naturlig eller syntetisk pyretroid, gir tilstrekkelig insektisid aktivitet, Various constituents from pepper referred to in the prior art, pepper oil, used in conjunction with a natural or synthetic pyrethroid, provide sufficient insecticidal activity,
og lider heller ikke av de hovedsaklig ulemper hos andre pepperbestanddeler. Skjønt den normalt erholdes og avnendes and also does not suffer from the main disadvantages of other pepper components. Although it is normally obtained and disposed of
som en fler-bestanddelsolje, kan denne lett fremstilles ved dampdestillasjon ved pepperekstrakter med en hovedsaklig jevn spesifikasjon. as a multi-constituent oil, this can easily be prepared by steam distillation of pepper extracts with a substantially uniform specification.
Ifølge et aspekt ved foreliggende oppfinnelse frembringes et pestisid middel som består av et naturlig eller syntetisk pyretroid i blanding med pepperolje der disse to bestanddelene brukes i slike relativeproposjoner at en synergistisk virkning frembringes. According to one aspect of the present invention, a pesticide is produced which consists of a natural or synthetic pyrethroid mixed with pepper oil where these two components are used in such relative proportions that a synergistic effect is produced.
Pepperolje fremstilles normalt fra oleoresin fra pepper, et produkt som oppstår ved å ekstrahere pepper med alkohol fulgt av fjerning av løsningsmiddelet under redusert trykk. Oleoresin er et bi-produkt fra krydderfremstilling-industrien og dets industrielle anvendelse er et spørsmål av en viss betydning. Pepper oil is normally made from pepper oleoresin, a product obtained by extracting pepper with alcohol followed by removal of the solvent under reduced pressure. Oleoresin is a by-product of the spice manufacturing industry and its industrial application is a matter of some importance.
Ved å underkaste oleoresin en dampdestillasjonsbehandlingBy subjecting the oleoresin to a steam distillation treatment
eller tilsvarende kan den ønskede pepperoljen erholdes. Dampdestillasjon er en relativ enkel industriell prosess og kan brukes for å fremstille den ønskede pepperoljen nær produksjons-stedet for oleoresin. Pepperoljen kan alternativt erholdes or equivalently, the desired pepper oil can be obtained. Steam distillation is a relatively simple industrial process and can be used to produce the desired pepper oil close to the oleoresin production site. The pepper oil can alternatively be obtained
ved dampdestillasjon av knuste pepperkorn. Oljen kan oppdelesby steam distillation of crushed peppercorns. The oil can be divided
i forskjellige adskilte fraksjoner, og det er funnet at den første fraksjonen, dvs. den lavest kokende fraksjonen, i særdeleshet er den sterkest insektiside aktive. I praksis er det imidlertid ofte enklest å bruke hele oljen med mindre in various separate fractions, and it has been found that the first fraction, i.e. the lowest boiling fraction, in particular is the most strongly insecticidally active. In practice, however, it is often easiest to use the whole oil with less
man tar sikte på spesielt høy insektisid effektivitet, da man ville bruke den første fraksjonen eller en blanding av den one aims at particularly high insecticidal efficiency, as one would use the first fraction or a mixture thereof
første og andre fraksjonen.first and second fraction.
Det er klart at pepperolje inneholder forskjellige bestanddeler.It is clear that pepper oil contains different constituents.
I IN
En kombinasjon av to eller flere av disse bidrar sannsynligvis<1>til middelets insektiside virkning ifølge oppfinnelsen. A combination of two or more of these probably contributes <1> to the agent's insecticidal effect according to the invention.
Den anvendte pepperet geografiske kilde synes å være av betydning. Mengden pepperolje som er til stede i pepperet samt oljens karakteristika (f.eks. dens spesifike vekt og brytningsindeks) kan variere fra kilde til kilde og kan også være avhengig av alderen og den fysiske tilstanden til de anvendte pepperkornene. Pepper dyrkes utelukkende i det indiske underkontinent samt i syd-øst Asia og i deler av Afrika. Skjønt man befatter seg med en enkel art Piper The peppered geographical source used seems to be of importance. The amount of pepper oil present in the pepper as well as the characteristics of the oil (eg its specific gravity and refractive index) may vary from source to source and may also depend on the age and physical condition of the peppercorns used. Pepper is grown exclusively in the Indian subcontinent as well as in south-east Asia and parts of Africa. Although one is dealing with a simple species Piper
nigrum, eksisterer forskjellige underarter som bidrar til variasjon av mengde og kvalitet av oljen. Disse variasjonene antas ikke å være av betydning for formålet med oppfinnelsen. nigrum, there are different subspecies that contribute to variation in the amount and quality of the oil. These variations are not believed to be of importance for the purpose of the invention.
Pyretrum kan brukes om et kommersielt alkoholisk konsentrat. Konsentrater av denne typen inneholder hyppig rundt 50 vekt-% faste pyretriner. Pyrethrum can be used for a commercial alcoholic concentrate. Concentrates of this type often contain around 50% by weight of solid pyrethrins.
Uttrykket "syntetiske pyretroid" brukes her for å betegne The term "synthetic pyrethroid" is used here to denote
•insektisid aktive syntetiske pyretroidforbindelser. Syntetiske pyretroider som kan brukes i midlene ifølge oppfinnelsen omfatter bioallertrin, bioresmetrin, d-fenotrin og tetrametrin. Mengden av fast pyretrum som anvendes kan variere fra 5 til 50 vekt-% av pepperoljen. Det vil generelt være hensikts-messig å bruke fra 20 til 45 vekt-% faste pyretrum beregnet på pepperoljens vekt. •insecticidally active synthetic pyrethroid compounds. Synthetic pyrethroids that can be used in the agents according to the invention include bioallerthrin, bioresmethrin, d-phenothrin and tetramethrin. The amount of solid pyrethrum used can vary from 5 to 50% by weight of the pepper oil. It will generally be appropriate to use from 20 to 45% by weight of solid pyrethrum calculated on the weight of the pepper oil.
Ved bruk av syntetiske pyretroider vil den angitte mengden variere avhengig av det spesielle syntetiske pyretroidet som anvendes, men vil generelt variere fra 50 til 950 vekt-% av pepperoljen. When using synthetic pyrethroids, the stated amount will vary depending on the particular synthetic pyrethroid used, but will generally vary from 50 to 950% by weight of the pepper oil.
En videre bestanddel som med fordel er tilstede i middeletA further component which is advantageously present in the remedy
er eukalyptusolje.is eucalyptus oil.
Som kjent erholdes eukalyptus oljer fra forskjellige eukalyptus-arter på den nordlige og sydlige halvkule og de resulterende As is known, eucalyptus oils are obtained from different eucalyptus species in the northern and southern hemisphere and the resulting
: i ' t : i ' t
i in
oljer har ikke en enhetlig analyse. Det antas imidlertid at egenskapene til middelet ifølge oppfinnelsen ikke er avhengig av en spesiell eukalyptusolje-kilde og man kan bruke oljer fra eukalyptus globulus eller eukalyptus dives. Det er imidlertid foretrukket å anvende olje som fåes fra de Australske arter oils do not have a uniform analysis. It is believed, however, that the properties of the agent according to the invention do not depend on a particular source of eucalyptus oil and you can use oils from eucalyptus globulus or eucalyptus dives. However, it is preferred to use oil obtained from the Australian species
som er ålment kjent som Blue Mallee, dvs. eukalyptus poly-bractea, særlig på grunne av denne oljens virksomhet og delvis på grunn av den letthet hvormed Blue Mallee kan dyrkes. En sl olje er rik på cineol (1,8-epoksy-p-mentan). Det er i all-minnelighet fortrukket å anvende en olje fra eukalyptus som inneholder minst 50 vekt-% cineol. which is commonly known as the Blue Mallee, i.e. Eucalyptus poly-bractea, chiefly on account of the action of this oil, and partly on account of the ease with which the Blue Mallee may be cultivated. One tablespoon of oil is rich in cineol (1,8-epoxy-p-menthane). It is generally preferred to use an oil from eucalyptus which contains at least 50% by weight of cineole.
Mengden eukalyptusolje som brukes kan variere innen vide grenser f.eks. 2 til 30 ganger vekten pepperolje. Generelt vil det være praktisk å anvende olje fra eukalyptus i en mengde på 4 til 40 ganger vekten av pepperoljen. The amount of eucalyptus oil used can vary within wide limits, e.g. 2 to 30 times its weight of pepper oil. In general, it will be practical to use oil of eucalyptus in an amount of 4 to 40 times the weight of the pepper oil.
Det er også noen indikasjoner på at den insektiside aktivitete til middelet ifølge oppfinnelsen økes ved tilsetting av geraniol (trans-3, 7-dimetyl-2, 6-oktadien-l-ol). Denne kan brukes i en mengde på opp til 5 ganger vekten av pepperolje f.eks. 2 til 4 ganger. Oppfinnelsen omfatter også de forskjellige nye synergistiske midler som her er beskrevet for bruk sammen med naturlige og syntetiske pyretroider. There are also some indications that the insecticidal activity of the agent according to the invention is increased by the addition of geraniol (trans-3,7-dimethyl-2,6-octadien-l-ol). This can be used in an amount of up to 5 times the weight of pepper oil, e.g. 2 to 4 times. The invention also includes the various new synergistic agents described herein for use with natural and synthetic pyrethroids.
Den kombinerte bruken med sesamolje er også fordelaktig for å forhindre nedbrytning, av pyretrum og for å forbedre den insektidise virkning. Denne kan brukes i en mengde på 1 til 5 ganger vekten av pepperoljen. The combined use with sesame oil is also beneficial to prevent the breakdown of pyrethrum and to improve the insecticidal effect. This can be used in an amount of 1 to 5 times the weight of the pepper oil.
Videre fordelaktige resultater kan oppnås ved å tilsette middelet ifølge oppfinnelsen den bitre substansen som er kjent som kvassia. Sistnevnte kan anvendes som Jamaica-kvassia eller Surinam-kvassia. Kvassiaen kan brukes i en mengde på 5 til 100% gjerne 10 til 50 vekt-% av pepperoljen. Kvassiaen brukes gjerne som alkoholisk ekstrakt. Further advantageous results can be obtained by adding to the agent according to the invention the bitter substance known as quassia. The latter can be used as Jamaica quassia or Surinam quassia. The quassia can be used in an amount of 5 to 100% preferably 10 to 50% by weight of the pepper oil. Quassia is often used as an alcoholic extract.
Videre substanser som kan brukes omfatter andre essensielleFurther substances that can be used include other essentials
I oljer (og deres bestanddeler) dvs. sitronelleoljer, kori- andreolje, kajeputolje, lemonolje og tymenianolje. Slike substanser kan også gi middelet en behagelig lukt og/eller forbedre dets pestiside virkning. Slike substanser kan brukes i mengder opp til 5 ganger vekten av pepperoljen. In oils (and their constituents) i.e. citronella oils, coriander oil, kajeput oil, lemon oil and thyme oil. Such substances can also give the product a pleasant smell and/or improve its pesticide effect. Such substances can be used in amounts up to 5 times the weight of the pepper oil.
Andre substanser som kan brukes omfatter poylhydroalkoholer, f.eks propylen-glykol og trietylen-glykol. Other substances that can be used include polyhydric alcohols, eg propylene glycol and triethylene glycol.
For å lette applikasjonen av midlene ifølge oppfinnelsen kan disse inneholde et didavere alkyl) sulfoksyd, f.eks. dimetyl sulfoksyd, gjerne i en mengde på 50 til 150 vekt-% av pepperoljen. Sulfoksydet synes å øke kontakten mellom pesten og pestisidet og/eller også å lette fremstillingen av homogene løsninger av de aktive substansene. In order to facilitate the application of the agents according to the invention, these can contain an additional alkyl) sulphoxide, e.g. dimethyl sulfoxide, preferably in an amount of 50 to 150% by weight of the pepper oil. The sulfoxide seems to increase the contact between the pest and the pesticide and/or also to facilitate the preparation of homogeneous solutions of the active substances.
Middelet ifølge oppfinnelsen kan brukes i forbindelse medThe agent according to the invention can be used in connection with
et fast eller flytende fortynningsmiddel som er egnet til å lette applikasjonen av pestisidet til applikasjonsstedet. a solid or liquid diluent suitable for facilitating the application of the pesticide to the site of application.
Der hvor applikasjonsstedet omfatter planteliv bør bære-middelet være hovedsaklig ikke-fytotoksiske midler Where the application site includes plant life, the carrier should mainly be non-phytotoxic agents
■ifølge forbindelsen har generelt lav fytotoksisitet.■according to the compound generally has low phytotoxicity.
Midlene ifølge oppfinnelsen som inneholder konvensjonelle hjelpestoffer som fuktemidler, emulgeringsmidler, pyro-r tekniske midler, uklarhetsmidler etc. De er gjerne formulert for sprayapplikasjon, f.eks. som aeroeoler, men de kan også appliseres på alle brukbare måter. The agents according to the invention which contain conventional auxiliaries such as wetting agents, emulsifiers, pyrotechnical agents, clouding agents etc. They are often formulated for spray application, e.g. such as aeroeoles, but they can also be applied in all useful ways.
Middelet kan emulgeres i en vandig fase ved hjelp av et emulsjons-, fukte- eller dispersjonsmiddel, f.eks. dietanol-amin lauryl sulfat, og fortrinnsvis av en biologisk nedbrytbar natur. The agent can be emulsified in an aqueous phase using an emulsifying, wetting or dispersing agent, e.g. diethanolamine lauryl sulfate, and preferably of a biodegradable nature.
Komposisjonen kan fremstilles som et konsentrat f.eks. i en alkfatisk alkohol f.eks. etylalkohol eller isopropylalkohol og/eller i et alifatisk hydrokarbon for fortynning til den nødvendige mengde. The composition can be prepared as a concentrate, e.g. in an alkphatic alcohol e.g. ethyl alcohol or isopropyl alcohol and/or in an aliphatic hydrocarbon for dilution to the required amount.
Når komposisjonen ifølge oppfinnelsen brukes i en aerosol When the composition according to the invention is used in an aerosol
i in
! formulering består drivmiddelet gjerne av en liten mengde av gass som ikke er i flytende fase, men som kan være i løsning i aerosolbeholderen, f.eks. nitrogenoksyd, sammen med en hoved mengde konvensjonelt flourkarbon-drivmiddel, f.eks. 11 og/12. ! formulation, the propellant usually consists of a small amount of gas which is not in liquid phase, but which can be in solution in the aerosol container, e.g. nitrous oxide, together with a major amount of conventional fluorocarbon propellant, e.g. 11 and/12.
Oppfinnelsen omfatter en metode for å kontrollere pester som består av å applisere på et sted der pester forekommer eller som kan angripes av pester en virksom mengde an en komposisjon ifølge oppfinnelsen. The invention includes a method for controlling plagues which consists of applying to a place where plagues occur or which can be attacked by plagues an effective amount of a composition according to the invention.
Komposisjonene ifølge oppfinnelsen kan brukes, inter alia, ved kontroll av husfluer ( Musea domestica) av forskjellige stammer, "sheep blow fly" larver ( Lucilla cuprina), kakkelakk ( Båtella germanica), Colorado-billelarve ( Leptinotarsa decemlineara),femiddlarve(Boophilus microphus), gulfebermyggl ( Åedes aegypti) og andre mygger ( Culex fatigans) og larver av klesmøll ( Tineola pittoralis), inklusive stammer som er resistente mot konvensjonelle pestisider. The compositions according to the invention can be used, inter alia, in the control of house flies (Musea domestica) of various strains, "sheep blow fly" larvae (Lucilla cuprina), cockroaches (Båtella germanica), Colorado beetle larvae (Leptinotarsa decemlineara), female midge larvae (Boophilus microphus) ), yellow fever mosquitoes ( Åedes aegypti ) and other mosquitoes ( Culex fatigans ) and larvae of the clothes moth ( Tineola pittoralis ), including strains that are resistant to conventional pesticides.
Fremstilling av pepperoljeProduction of pepper oil
100 g renset oleoresin, et alkoholisk ekstrakt fremstilt av sort pepper av Techno Chemical Industries Ltd of Calicut, India ble gjort til gjenstand fro dampdestillasjon og destillatet (vann pluss olje) ble oppsamlet i 100 ml porsjoner. Oljen ble deretter avskilt fra det vandige destillatet og veiet. På denne måten erholdtes 6 fraksjoner olje. 100 g of purified oleoresin, an alcoholic extract prepared from black pepper by Techno Chemical Industries Ltd of Calicut, India was subjected to steam distillation and the distillate (water plus oil) was collected in 100 ml portions. The oil was then separated from the aqueous distillate and weighed. In this way, 6 fractions of oil were obtained.
Totalt utbytte av olje 17.45 g (16.6% ved vekt av oleoresin, Total yield of oil 17.45 g (16.6% by weight of oleoresin,
brytningsindeks ved 20 1.4786, spesifikt vekt0.8603, refractive index at 20 1.4786, specific gravity 0.8603,
25° 25°
'EKSEMPEL 1 EXAMPLE 1
A. Et pestisidmiddel ble fremstilt ved å blande følgende bestanddeler: - A. A pesticide was prepared by mixing the following ingredients:-
B. Dette middelet (A) ble så pakket i aerosolbeholdere på følgende basis: - B. This agent (A) was then packaged in aerosol containers on the following basis:-
xx xx
En blanding av like deler drivmiddel 11 og drivmiddel 12. A mixture of equal parts propellant 11 and propellant 12.
To sammenlikningsmidler A' og A'' ble fremstilt som følger: Two comparators A' and A'' were prepared as follows:
Middel A' og A'<1>ble pakket i aerosolbeholdere på samme måte som A. Alle 3 midlene ble undersøkt med hensyn til insektisid aktivitet i et<p>eat Grady-kammer mot Kingsford (Australia) husfluer ( Musea domestica). Den angitte vekten for aerosol-middelet ble sprøytet inn i kammeret som inneholdt ca. 100 fluer med en antitte alder og prosentdelen "knock-down" ble beregnet i hvert tilfelle ved 2 forsøk. Resultatene ble som følger: Agents A' and A'<1> were packaged in aerosol containers in the same manner as A. All 3 agents were tested for insecticidal activity in an<p>eat Grady chamber against Kingsford (Australia) houseflies ( Musea domestica). The stated weight of the aerosol agent was injected into the chamber containing approx. 100 flies of an antitite age and the percentage "knock-down" was calculated in each case by 2 trials. The results were as follows:
Disse resultatene viser at middelet A virker på en synergistisk måte. These results show that agent A acts in a synergistic manner.
EKSEMPEL 2EXAMPLE 2
Dette eksempelet viser bruken av flerkomponentmiddel.This example shows the use of multi-component agent.
A. Et middel ble fremstilt ved å danne følgende bestanddeler: - j B. Middel A ble så pakket i aerosolbeholdere på føgende j basis: A. An agent was prepared by forming the following components: - j B. Agent A was then packaged in aerosol containers on the following j basis:
De resulterende aerosolbeholderne ble så brukt i en serie forsøk i et teraperaturkontrollert Peat Grådy forsøks- The resulting aerosol containers were then used in a series of experiments in a temperature-controlled Peat Grådy experiment.
kaniner ved bruk av Kingsford-fluer som i eksempel 1. Utmerket "knock-sown" og avlivingsresultater ble erholdt rabbits using Kingsford flies as in Example 1. Excellent knock-sown and kill results were obtained
med et middelshøyt nivå av aerosolspray.with a medium-high level of aerosol spray.
Middelet ble også funnet å ha betraktelig fungesiv virknings-grad mot forskjellige saprofytiske sopper som Aspergillus niger. The agent was also found to have considerable fungative activity against various saprophytic fungi such as Aspergillus niger.
EKSEMPEL 3EXAMPLE 3
Dette eksempel illustrer variasjoner på formulgeringen i eksempel 2. This example illustrates variations on the wording in example 2.
A. Forskjellige midler ble fremstilt ved å blande følgende bestanddeler: - A. Various remedies were prepared by mixing the following ingredients:-
B. Midlene i A ble så pakket i aerosolbeholdere på følgende basis: - B. The agents in A were then packaged in aerosol containers on the following basis:-
og produktene ble prøvet i et Peak Grady-kammer som forut med | and the products were tested in a Peak Grady chamber as before with |
I IN
i in
<:>utmerkede resultater av "knock-down" og avlivning.<:>excellent knock-down and kill results.
EKSEMPEL 4EXAMPLE 4
A. Et pestisid middel ble fremstilt ved å blande de følgende bestandelene: - A. A pesticide was prepared by mixing the following ingredients:-
B. Middel A ble så pakket i aerosolbeholdere på følgende basis: - B. Agent A was then packaged in aerosol containers on the following basis:-
De resulterende beholderne ble så prøvet mot Kingsfor -fluer ,som i ekempel 1. Utmerket "knock-down"- og avlivnings-resulta ble erholdt. The resulting containers were then tested against Kingsfor flies, as in Example 1. Excellent knock-down and kill results were obtained.
EKSEMPEL 5EXAMPLE 5
A. Et pestisid middel ble fremstilt ved å blande følgende bestanddeler: - A. A pesticide was prepared by mixing the following ingredients:-
Middel A ble så pakket i aerosolbeholdere på samme basis som i eksempel 4 for prøving mot Kingsford-fluer og utmerket "knock-sown" og avlivning ble så oppnådd. Agent A was then packaged in aerosol containers on the same basis as in Example 4 for testing against Kingsford flies and excellent knock-sown and killing was then achieved.
! I-EKSEMPEL 6 I ! I-EXAMPLE 6 I
A. En pestisid middel ble fremstilt ved å blande følgende bestanddeler: - A. A pesticide was prepared by mixing the following ingredients:-
Middel A ble så pakket i aerosolbeholdere som basis i eksempel 4 for prøving mot Kingsford-fluer og utmerket "knock-down" Agent A was then packaged in aerosol containers as the basis of Example 4 for testing against Kingsford flies and excellent knock-down
og avlivning ble så oppnådd.and euthanasia was then achieved.
EKSEMPEL 7EXAMPLE 7
A. Et pestisid middel ble fremstilt ved å blande følgende bestanddeler: A. A pesticide was prepared by mixing the following ingredients:
Middel A ble så pakket i aerosolbeholdere på samme basis som i eksempel 4 for prøving mot Kingsford-fluer og utmerket "knock-down" og avlivning ble også oppnådd. Agent A was then packaged in aerosol containers on the same basis as in Example 4 for testing against Kingsford flies and excellent knock-down and killing was also achieved.
EKSEMPEL 8EXAMPLE 8
A. Et pestisid middel ble fremstilt ved å blande følgende bestanddeler: - A. A pesticide was prepared by mixing the following ingredients:-
Middel A ble så pakket i aerosolbeholdere på samme basis som i eksempel 4 for prøving mot Kingsford-fluer og utmerket "knock-down" og avliving ble så oppnådd. Agent A was then packaged in aerosol containers on the same basis as in Example 4 for testing against Kingsford flies and excellent knock-down and killing was then achieved.
Claims (21)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB28118/76A GB1574609A (en) | 1976-07-06 | 1976-07-06 | Pesticidal compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO772391L true NO772391L (en) | 1978-01-09 |
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ID=10270563
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| Application Number | Title | Priority Date | Filing Date |
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| NO772391A NO772391L (en) | 1976-07-06 | 1977-07-05 | PESTICIDE COMPOSITIONS. |
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| AT (1) | AT356460B (en) |
| AU (1) | AU2674177A (en) |
| BE (1) | BE856487A (en) |
| CA (1) | CA1092020A (en) |
| DD (1) | DD133389A1 (en) |
| DE (1) | DE2730340A1 (en) |
| DK (1) | DK300877A (en) |
| FI (1) | FI772101A (en) |
| FR (1) | FR2357177A1 (en) |
| GB (1) | GB1574609A (en) |
| GR (1) | GR63751B (en) |
| IE (1) | IE45739B1 (en) |
| IT (1) | IT1105103B (en) |
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| NL (1) | NL7707450A (en) |
| NO (1) | NO772391L (en) |
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| PT (1) | PT66764B (en) |
| SE (1) | SE7707846L (en) |
| ZA (1) | ZA774036B (en) |
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| DE2947648A1 (en) * | 1979-11-27 | 1981-08-06 | C.F. Spiess & Sohn GmbH & Co, 6719 Kleinkarlbach | USE OF TERTIARY HETEROCYCLIC AMINES AS A POTENCING AGENT FOR INSECTICIDES |
| HU182802B (en) * | 1980-02-26 | 1984-03-28 | Biogal Gyogyszergyar | Fotostabil delousing (insecticide) composition containing synthetic piretroides |
| DE3436859A1 (en) * | 1984-10-08 | 1986-04-10 | Henkel KGaA, 4000 Düsseldorf | METHOD FOR OBTAINING A PEPPER EXTRACT WITH INSECTICIDAL EFFECT, AND MEANS CONTAINING THIS FOR INSECT CONTROLLING |
| AU602144B2 (en) * | 1986-05-08 | 1990-10-04 | R & C Products Pty Limited | Animal repellant composition and method |
| US6451605B1 (en) * | 1996-03-29 | 2002-09-17 | Ornaquin Ltd. | Pharmaceutical or veterinary composition |
| AU5237999A (en) * | 1998-07-28 | 2000-02-21 | Ecosmart Technologies, Inc. | Synergistic and residual pesticidal compositions containing plant essential oils |
| US6849614B1 (en) | 1998-07-28 | 2005-02-01 | Ecosmart Technologies, Inc. | Synergistic and residual pesticidal compositions containing plant essential oils |
| EP1634500A3 (en) * | 1998-07-28 | 2006-08-09 | Ecosmart Technologies Inc. | Synergistic and residual pesticidal compositions containing plant essentials oils |
| CA2769005A1 (en) * | 2009-07-28 | 2011-02-03 | The Energy And Resources Institute (Teri) | Novel biopesticide compositions and method for isolation and characterization of same |
| WO2022223967A1 (en) * | 2021-04-20 | 2022-10-27 | Reckitt & Colman (Overseas) Hygiene Home Limited | Insect control composition |
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| US2425530A (en) * | 1942-12-26 | 1947-08-12 | Thompson Boyce Plant Res | Insecticide |
| US3186903A (en) * | 1964-05-06 | 1965-06-01 | William T Soltes | Synergistic pyrethrum insecticide |
| PH10400A (en) * | 1972-12-08 | 1977-03-07 | Inchoape Chemco Ltd | Pesticidal compositions containing oil of eucalyptus |
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1976
- 1976-07-06 GB GB28118/76A patent/GB1574609A/en not_active Expired
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1977
- 1977-07-05 PT PT66764A patent/PT66764B/en unknown
- 1977-07-05 FR FR7720626A patent/FR2357177A1/en active Granted
- 1977-07-05 AU AU26741/77A patent/AU2674177A/en active Pending
- 1977-07-05 DK DK300877A patent/DK300877A/en unknown
- 1977-07-05 LU LU77690A patent/LU77690A1/en unknown
- 1977-07-05 NO NO772391A patent/NO772391L/en unknown
- 1977-07-05 DE DE19772730340 patent/DE2730340A1/en not_active Withdrawn
- 1977-07-05 GR GR53889A patent/GR63751B/en unknown
- 1977-07-05 DD DD77199892A patent/DD133389A1/en unknown
- 1977-07-05 SE SE7707846A patent/SE7707846L/en not_active Application Discontinuation
- 1977-07-05 AT AT478577A patent/AT356460B/en not_active IP Right Cessation
- 1977-07-05 BE BE179089A patent/BE856487A/en unknown
- 1977-07-05 FI FI772101A patent/FI772101A/fi not_active Application Discontinuation
- 1977-07-05 NZ NZ184567A patent/NZ184567A/en unknown
- 1977-07-05 ZA ZA00774036A patent/ZA774036B/en unknown
- 1977-07-05 IT IT50122/77A patent/IT1105103B/en active
- 1977-07-05 IE IE1394/77A patent/IE45739B1/en unknown
- 1977-07-05 CA CA282,045A patent/CA1092020A/en not_active Expired
- 1977-07-05 NL NL7707450A patent/NL7707450A/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| FR2357177B1 (en) | 1980-06-13 |
| ATA478577A (en) | 1979-09-15 |
| LU77690A1 (en) | 1979-03-26 |
| AU2674177A (en) | 1979-01-11 |
| CA1092020A (en) | 1980-12-23 |
| BE856487A (en) | 1978-01-05 |
| FR2357177A1 (en) | 1978-02-03 |
| IE45739B1 (en) | 1982-11-17 |
| NZ184567A (en) | 1980-03-05 |
| IE45739L (en) | 1978-01-06 |
| DK300877A (en) | 1978-01-07 |
| GR63751B (en) | 1979-12-07 |
| SE7707846L (en) | 1978-01-07 |
| AT356460B (en) | 1980-04-25 |
| NL7707450A (en) | 1978-01-10 |
| PT66764B (en) | 1979-07-07 |
| PT66764A (en) | 1977-08-01 |
| IT1105103B (en) | 1985-10-28 |
| ZA774036B (en) | 1978-05-30 |
| FI772101A (en) | 1978-01-07 |
| DD133389A1 (en) | 1979-01-03 |
| DE2730340A1 (en) | 1978-02-02 |
| GB1574609A (en) | 1980-09-10 |
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