NL7900425A - Werkwijze voor de bereiding van polypyrrolidon. - Google Patents
Werkwijze voor de bereiding van polypyrrolidon. Download PDFInfo
- Publication number
- NL7900425A NL7900425A NL7900425A NL7900425A NL7900425A NL 7900425 A NL7900425 A NL 7900425A NL 7900425 A NL7900425 A NL 7900425A NL 7900425 A NL7900425 A NL 7900425A NL 7900425 A NL7900425 A NL 7900425A
- Authority
- NL
- Netherlands
- Prior art keywords
- polymerization
- conversion
- pyrrolidone
- polymer
- dispersant
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 18
- 229920001007 Nylon 4 Polymers 0.000 title claims description 5
- 238000002360 preparation method Methods 0.000 title claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 51
- 238000006116 polymerization reaction Methods 0.000 claims description 38
- 229920000642 polymer Polymers 0.000 claims description 22
- 239000002270 dispersing agent Substances 0.000 claims description 20
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 13
- 150000003951 lactams Chemical class 0.000 claims description 3
- 239000011541 reaction mixture Substances 0.000 claims description 3
- 239000011952 anionic catalyst Substances 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 description 16
- 238000012662 bulk polymerization Methods 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 239000000725 suspension Substances 0.000 description 7
- 238000010557 suspension polymerization reaction Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- -1 fatty acid salts Chemical class 0.000 description 4
- UXQAEOWCSOPBLF-UHFFFAOYSA-N 2,2,3,3-tetramethyloctane Chemical compound CCCCCC(C)(C)C(C)(C)C UXQAEOWCSOPBLF-UHFFFAOYSA-N 0.000 description 3
- PWXIKGAMKWRXHD-UHFFFAOYSA-N 3-butylaziridin-2-one Chemical compound CCCCC1NC1=O PWXIKGAMKWRXHD-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- MEXQWQLMJYIYPG-UHFFFAOYSA-M potassium;2-oxopyrrolidine-1-carboxylate Chemical compound [K+].[O-]C(=O)N1CCCC1=O MEXQWQLMJYIYPG-UHFFFAOYSA-M 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910003480 inorganic solid Inorganic materials 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical class [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
- C08G69/24—Pyrrolidones or piperidones
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL7900425A NL7900425A (nl) | 1979-01-19 | 1979-01-19 | Werkwijze voor de bereiding van polypyrrolidon. |
| JP199380A JPS5599921A (en) | 1979-01-19 | 1980-01-11 | Manufacture of polypyrrolidone |
| US06/113,286 US4309530A (en) | 1979-01-19 | 1980-01-18 | Two stage procedure for the preparation of polypyrrolidone |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL7900425 | 1979-01-19 | ||
| NL7900425A NL7900425A (nl) | 1979-01-19 | 1979-01-19 | Werkwijze voor de bereiding van polypyrrolidon. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NL7900425A true NL7900425A (nl) | 1980-07-22 |
Family
ID=19832489
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL7900425A NL7900425A (nl) | 1979-01-19 | 1979-01-19 | Werkwijze voor de bereiding van polypyrrolidon. |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US4309530A (https=) |
| JP (1) | JPS5599921A (https=) |
| NL (1) | NL7900425A (https=) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1213482B (it) * | 1986-08-14 | 1989-12-20 | Canalini Giovanni | Processo perfezionato per la polimerizzazione anionica del caprolattame e sua copolimerizzazione con altri lattami. |
| WO2013058019A1 (ja) * | 2011-10-21 | 2013-04-25 | 独立行政法人産業技術総合研究所 | 生分解性が制御された生分解性ポリマー |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4017465A (en) * | 1975-01-23 | 1977-04-12 | Chevron Research Company | Process for polymerization of 2-pyrrolidone |
-
1979
- 1979-01-19 NL NL7900425A patent/NL7900425A/nl not_active Application Discontinuation
-
1980
- 1980-01-11 JP JP199380A patent/JPS5599921A/ja active Granted
- 1980-01-18 US US06/113,286 patent/US4309530A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6261054B2 (https=) | 1987-12-19 |
| US4309530A (en) | 1982-01-05 |
| JPS5599921A (en) | 1980-07-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3278506A (en) | Water-soluble polymers and copolymers | |
| US4694063A (en) | Anhydrous process for the manufacture of polyamide powder from lactam in the presence of N,N'-alkylene bis amide | |
| EP1118626B1 (fr) | Procédé de fabrication d'une composition de polymères d'oléfines | |
| JPS63270706A (ja) | オレフインの重合方法 | |
| IE841196L (en) | Butadiene polymerisation process | |
| JP2003513119A (ja) | 高反応性ポリイソブテンの製法 | |
| NL7900425A (nl) | Werkwijze voor de bereiding van polypyrrolidon. | |
| US4605714A (en) | Catalyst, production and use | |
| US3293227A (en) | Recovery of polymers from slurries | |
| JPH0841135A (ja) | スチレン−アクリロニトリルコポリマーを製造するための方法 | |
| US4017465A (en) | Process for polymerization of 2-pyrrolidone | |
| CN113214417B (zh) | 一种使用茂金属催化剂制备聚丙烯的方法 | |
| US3418292A (en) | Polymerization process | |
| EP0033019B1 (en) | Procedure for the preparation of polypyrrolidone | |
| BE549466A (https=) | ||
| Stampa | The anionic dispersion polymerization of α‐methylstyrene | |
| US3484426A (en) | Suspensoid composition | |
| US5530071A (en) | Preparation of imide-modified methyl methacrylate (MMA) polymer/copolymers | |
| CN116640251B (zh) | 一种由混合气体合成烯烃功能聚合物的方法 | |
| US2698320A (en) | Method for polymerizing with powedered alcl3 | |
| JP2004503617A (ja) | 無水マレイン酸及びｃ１‐４アルキルビニルエーテルの共重合体を製造する連続的無溶媒方法 | |
| US3624008A (en) | Catalyst and method for the polymerization of ethylene oxide | |
| CN1076357C (zh) | 烯烃共聚物多段聚合方法 | |
| US3629224A (en) | Aqueous phase polymerization of ethylene | |
| JPH0362174B2 (https=) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A1B | A search report has been drawn up | ||
| BV | The patent application has lapsed |