NL7317192A - Terephthalic acid continuous esterification process - from solid terephthalic acid, methanol and recycled mixture, and no catalyst in first reactor - Google Patents

Terephthalic acid continuous esterification process - from solid terephthalic acid, methanol and recycled mixture, and no catalyst in first reactor

Info

Publication number
NL7317192A
NL7317192A NL7317192A NL7317192A NL7317192A NL 7317192 A NL7317192 A NL 7317192A NL 7317192 A NL7317192 A NL 7317192A NL 7317192 A NL7317192 A NL 7317192A NL 7317192 A NL7317192 A NL 7317192A
Authority
NL
Netherlands
Prior art keywords
terephthalic acid
catalyst
reactor
methanol
continuous esterification
Prior art date
Application number
NL7317192A
Other languages
English (en)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19722261333 external-priority patent/DE2261333C3/de
Application filed filed Critical
Publication of NL7317192A publication Critical patent/NL7317192A/xx

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18Stationary reactors having moving elements inside
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/28Moving reactors, e.g. rotary drums
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0446Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
    • B01J8/0449Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
    • B01J8/0457Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds the beds being placed in separate reactors
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/08Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00168Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212Plates; Jackets; Cylinders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00168Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00247Reflux columns
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00168Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00256Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles in a heat exchanger for the heat exchange medium separate from the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00265Part of all of the reactants being heated or cooled outside the reactor while recycling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00548Flow
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18Details relating to the spatial orientation of the reactor
    • B01J2219/182Details relating to the spatial orientation of the reactor horizontal
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
NL7317192A 1972-12-15 1973-12-14 Terephthalic acid continuous esterification process - from solid terephthalic acid, methanol and recycled mixture, and no catalyst in first reactor NL7317192A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19722261333 DE2261333C3 (de) 1972-12-15 Verfahren zur Veresterung von Terephthalsäure

Publications (1)

Publication Number Publication Date
NL7317192A true NL7317192A (en) 1974-06-18

Family

ID=5864457

Family Applications (1)

Application Number Title Priority Date Filing Date
NL7317192A NL7317192A (en) 1972-12-15 1973-12-14 Terephthalic acid continuous esterification process - from solid terephthalic acid, methanol and recycled mixture, and no catalyst in first reactor

Country Status (10)

Country Link
US (1) US3972912A (https=)
JP (1) JPS4987641A (https=)
BE (1) BE808657R (https=)
ES (1) ES419510A1 (https=)
FR (1) FR2210602B2 (https=)
GB (1) GB1449474A (https=)
IT (1) IT1051565B (https=)
NL (1) NL7317192A (https=)
RO (1) RO64011A2 (https=)
SU (1) SU695554A3 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114984888A (zh) * 2022-04-28 2022-09-02 华东理工大学 一种生产增塑剂的连续酯化的循环反应器系统

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1115446A (en) * 1977-12-16 1981-12-29 Lawrence E. Shelley Process
US4365078A (en) * 1977-12-16 1982-12-21 The Goodyear Tire & Rubber Company Process for charging dry terephthalic acid into a reactor
WO2001027062A2 (en) 1999-10-13 2001-04-19 Sulzer Chemtech Ag Process and device for hydrolytically obtaining a carboxylic acid and alcohol from the corresponding carboxylate

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1088474B (de) * 1958-11-17 1960-09-08 Bergwerksverband Gmbh Verfahren zur Veresterung von Terephthalsaeure
NL282032A (https=) * 1961-08-17
DE1212063B (de) * 1964-04-20 1966-03-10 Basf Ag Verfahren zur kontinuierlichen Herstellung von Dimethylterephthalat
FR1496079A (fr) * 1965-03-11 1967-09-29 Mobil Oil Corp Procédé perfectionné d'estérification
US3377376A (en) * 1966-02-07 1968-04-09 Mobil Oil Corp Vapor phase esterification of terephthalic acid in the presence of alkali metal impregnated catalyst
US3617226A (en) * 1968-04-26 1971-11-02 Huels Chemische Werke Ag Apparatus for the continuous preparation of esters
US3676485A (en) * 1968-08-12 1972-07-11 Eastman Kodak Co Method for use in a continuous flow reaction for producing a monomer and or a protopolymer

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114984888A (zh) * 2022-04-28 2022-09-02 华东理工大学 一种生产增塑剂的连续酯化的循环反应器系统
CN114984888B (zh) * 2022-04-28 2023-10-03 华东理工大学 一种生产增塑剂的连续酯化的循环反应器系统

Also Published As

Publication number Publication date
GB1449474A (en) 1976-09-15
SU695554A3 (ru) 1979-10-30
BE808657R (fr) 1974-03-29
ES419510A1 (es) 1976-04-16
FR2210602A2 (https=) 1974-07-12
JPS4987641A (https=) 1974-08-22
US3972912A (en) 1976-08-03
DE2261333A1 (de) 1974-07-04
FR2210602B2 (https=) 1977-06-10
IT1051565B (it) 1981-05-20
RO64011A2 (ro) 1978-03-31
DE2261333B2 (de) 1975-08-21

Similar Documents

Publication Publication Date Title
CH609321A5 (en) Process for the preparation of carboxylic acid anhydrides
GB1004895A (en) Process for the production of isophthalic and terephthalic acids
ES451830A1 (es) Procedimiento para la preparacion de productos oxigenados selectos.
NL7317192A (en) Terephthalic acid continuous esterification process - from solid terephthalic acid, methanol and recycled mixture, and no catalyst in first reactor
ATE816T1 (de) Gebrauch von mikrowellenenergie bei der herstellung von weichmacherestern.
GB1007353A (en) Process and catalysts for the production of unsaturated aliphatic carboxylic acids
BE747357A (fr) Procede de preparation de catalyseurs promouvant les reactions d'oxydo-reduction et nouveau catalyseur de conversion de l'oxyde de carbone avec la vapeur d'eau.
ES448524A1 (es) Un proceso para la produccion de acido m-benzoil-hidratropi-co.
ES301028A1 (es) Procedimiento para la obtencion de un poliester.
US2004521A (en) Catalytic dehydration
ES409540A3 (es) Un procedimiento para la preparacion de esteres dialcohili-cos del acido tereftalico.
GB1147482A (en) Improvements in or relating to addition products of ethylene oxide to carboxylic acids
ES300280A1 (es) Procedimiento de preparación de de una resina poliesférica insaturada
FR2059345A5 (en) Acetic acid by oxidation of 4-carbon - hydrocarbons
ES395784A1 (es) Un procedimiento para la obtencion de anhidrido maleico pu-ro.
ES402121A1 (es) Procedimiento para la purificacion de esteres de alto pun-to de abullicion.
SU768811A1 (ru) Состав дл жировани кож и способ его производства
GB1074265A (en) Preparation or aldehydes and ketones
ES389870A3 (es) Procedimiento continuo para la produccion de esteres del a-cido o-ftalico.
ES390312A1 (es) Procedimiento mejorado para la produccion de esteres meti- licos del acido tereftalico.
ES382935A1 (es) Procedimiento para la obtencion de derivados balsamicos de teofilina.
GB1139218A (en) Process and apparatus for continuously producing compounds capable of being polymerized
GB1205180A (en) Process for the catalytic preparation of epoxyalkyl esters
FR2303596A1 (fr) Procede de preparation d'anhydride maleique a partir d'hydrocarbures non aromatiques et compositions catalytiques a base de phosphore, de vanadium et d'oxygene utilisees dans ce procede
GB740595A (en) Improvements in or relating to the production of thermoplastic materials and benzyl hydrocarbons

Legal Events

Date Code Title Description
BV The patent application has lapsed