MY165000A - Aqueous vinylidene fluoride polymer latex - Google Patents
Aqueous vinylidene fluoride polymer latexInfo
- Publication number
- MY165000A MY165000A MYPI2014000119A MYPI2014000119A MY165000A MY 165000 A MY165000 A MY 165000A MY PI2014000119 A MYPI2014000119 A MY PI2014000119A MY PI2014000119 A MYPI2014000119 A MY PI2014000119A MY 165000 A MY165000 A MY 165000A
- Authority
- MY
- Malaysia
- Prior art keywords
- aqueous
- vinylidene fluoride
- electrode
- aqueous composition
- polymer
- Prior art date
Links
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 title abstract 5
- 229920000642 polymer Polymers 0.000 title abstract 4
- 239000004816 latex Substances 0.000 title abstract 3
- 229920000126 latex Polymers 0.000 title 1
- 239000000203 mixture Substances 0.000 abstract 4
- YZCKVEUIGOORGS-UHFFFAOYSA-N Hydrogen atom Chemical compound [H] YZCKVEUIGOORGS-UHFFFAOYSA-N 0.000 abstract 2
- 150000002430 hydrocarbons Chemical group 0.000 abstract 2
- 238000004519 manufacturing process Methods 0.000 abstract 2
- 239000011164 primary particle Substances 0.000 abstract 2
- -1 HYDROXYL GROUP Chemical group 0.000 abstract 1
- 239000007772 electrode material Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/621—Binders
- H01M4/622—Binders being polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/16—Homopolymers or copolymers or vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C09D127/16—Homopolymers or copolymers of vinylidene fluoride
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0404—Methods of deposition of the material by coating on electrode collectors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1393—Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/621—Binders
- H01M4/622—Binders being polymers
- H01M4/623—Binders being polymers fluorinated polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
Abstract
THE PRESENT INVENTION PERTAINS TO AN AQUEOUS COMPOSITION COMPRISING: (A) AN AQUEOUS LATEX COMPRISING AT LEAST ONE VINYLIDENE FLUORIDE (VDF) POLYMER [POLYMER (F)] COMPRISING RECURRING UNITS DERIVED FROM VINYLIDENE FLUORIDE (VDF) AND AT LEAST ONE (METH)ACRYLIC MONOMER (MA) HAVING FORMULA (I) HERE BELOW: WHEREIN: - R1, R2 AND R3, EQUAL TO OR DIFFERENT FROM EACH OTHER, ARE INDEPENDENTLY SELECTED FROM A HYDROGEN ATOM AND A C1-C3 HYDROCARBON GROUP, AND - ROH IS A HYDROGEN ATOM OR A C1-C5 HYDROCARBON MOIETY COMPRISING AT LEAST ONE HYDROXYL GROUP, (B) AT LEAST ONE POWDERY ELECTRODE MATERIAL, AND (C) OPTIONALLY, LESS THAN 10% BY WEIGHT, BASED ON THE TOTAL WEIGHT OF THE AQUEOUS COMPOSITION, OF AT LEAST ONE ORGANIC SOLVENT (S), WHEREIN THE POLYMER (F) IN THE AQUEOUS LATEX IS UNDER THE FORM OF PRIMARY PARTICLES HAVING AN AVERAGE PRIMARY PARTICLE SIZE OF LESS THAN 1 µM, AS MEASURED ACCORDING TO ISO 13321. THE PRESENT INVENTION ALSO PERTAINS TO A PROCESS FOR MANUFACTURING AN ELECTRODE USING SAID AQUEOUS COMPOSITION, TO AN ELECTRODE COMPRISING A METAL SUBSTRATE COATED ON AT LEAST ONE SURFACE WITH SAID AQUEOUS COMPOSITION AND TO USE OF SAID ELECTRODE FOR MANUFACTURING A NON-AQUEOUS-TYPE ELECTROCHEMICAL DEVICE.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161508245P | 2011-07-15 | 2011-07-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MY165000A true MY165000A (en) | 2018-02-28 |
Family
ID=46514359
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MYPI2014000119A MY165000A (en) | 2011-07-15 | 2012-07-13 | Aqueous vinylidene fluoride polymer latex |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US10079388B2 (en) |
| EP (1) | EP2731990B1 (en) |
| JP (2) | JP6359450B2 (en) |
| KR (1) | KR101963637B1 (en) |
| CA (1) | CA2839389C (en) |
| MY (1) | MY165000A (en) |
| WO (1) | WO2013010936A1 (en) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012084578A1 (en) * | 2010-12-22 | 2012-06-28 | Solvay Specialty Polymers Italy S.P.A. | Vinylidene fluoride copolymers |
| US10079388B2 (en) * | 2011-07-15 | 2018-09-18 | Solvay Specialty Polymers Italy S.P.A. | Aqueous vinylidene fluoride-(meth)acrylic co-polymer latex, electrode and lithium ion secondary battery using the same |
| TWI521777B (en) * | 2013-09-12 | 2016-02-11 | 烏明克公司 | Water-based cathode slurry for a lithium ion battery |
| CN105723547A (en) * | 2013-10-23 | 2016-06-29 | 索尔维公司 | Positive electrodes for lithium-sulphur batteries |
| JP6165036B2 (en) * | 2013-11-27 | 2017-07-19 | 株式会社クレハ | Vinylidene fluoride polymer aqueous composition and use thereof |
| US9385374B2 (en) | 2014-04-01 | 2016-07-05 | Ppg Industries Ohio, Inc. | Electrode binder composition for lithium ion electrical storage devices |
| US20150280239A1 (en) | 2014-04-01 | 2015-10-01 | Ppg Industries Ohio, Inc. | Aqueous binder composition for lithium ion electrical storage devices |
| EP3168900A1 (en) | 2015-11-11 | 2017-05-17 | Solvay Specialty Polymers Italy S.p.A. | Electrode and separator assembly for an electrochemical cell |
| CN109715684B (en) * | 2016-07-15 | 2022-01-11 | 索尔维特殊聚合物意大利有限公司 | Fluorinated surfactant-free aqueous dispersions of vinylidene fluoride copolymers containing hydroxyl groups |
| TWI846664B (en) * | 2016-10-20 | 2024-07-01 | 義大利商首威專業聚合物義大利公司 | Pvdf for metal/metal ion batteries |
| WO2018077669A1 (en) * | 2016-10-28 | 2018-05-03 | Solvay Specialty Polymers Italy S.P.A. | Coating composition |
| KR102576131B1 (en) | 2017-08-11 | 2023-09-08 | 솔베이 스페셜티 폴리머스 이태리 에스.피.에이. | Methods for Stabilizing Aqueous Dispersions of Fluorinated Polymers |
| JP7447022B2 (en) * | 2018-05-17 | 2024-03-11 | ソルベイ スペシャルティ ポリマーズ イタリー エス.ピー.エー. | Electrode forming composition |
| EP3830886A1 (en) | 2018-08-02 | 2021-06-09 | Solvay Specialty Polymers Italy S.p.A. | Battery separator coating |
| JP7460599B2 (en) | 2018-08-09 | 2024-04-02 | ソルベイ スペシャルティ ポリマーズ イタリー エス.ピー.エー. | Crosslinkable blends of VDF copolymers |
| CN112601768B (en) | 2018-08-09 | 2023-01-13 | 索尔维特殊聚合物意大利有限公司 | Self-crosslinking PVDF |
| CN114008846A (en) | 2019-07-01 | 2022-02-01 | 索尔维特殊聚合物意大利有限公司 | Battery separator coating |
| EP3767710A1 (en) * | 2019-07-15 | 2021-01-20 | Arkema France | Waterbased pvdf slurry formulation for silicon graphite anodes |
| US20240186522A1 (en) * | 2021-03-22 | 2024-06-06 | Solvay Specialty Polymers Italy S.P.A. | Composition for electrodes |
| KR20230014947A (en) * | 2021-07-22 | 2023-01-31 | 한국화학연구원 | Preparation method of polyvinylidene fluoride and polyvinylidene fluoride prepared by the method |
| US11643486B1 (en) | 2022-06-08 | 2023-05-09 | Arkema Inc. | Non-linear vinylidene fluoride copolymers |
| CN118307705A (en) * | 2023-01-06 | 2024-07-09 | 宁德时代新能源科技股份有限公司 | Fluoropolymer, preparation method and application thereof, insulating slurry, insulating coating, secondary battery and electric device |
| CN118307709A (en) * | 2023-01-09 | 2024-07-09 | 宁德时代新能源科技股份有限公司 | Fluoropolymer, aqueous primer slurry, secondary battery, and electric device |
| CN119039506A (en) * | 2023-05-29 | 2024-11-29 | 宁德时代新能源科技股份有限公司 | Fluorine-containing polymer, preparation method, negative electrode slurry, negative electrode plate, secondary battery and electricity utilization device |
| CN116854841B (en) * | 2023-07-31 | 2026-02-17 | 河南省氟基新材料科技有限公司 | A method for preparing lithium-ion battery-grade polyvinylidene fluoride adhesive |
| FR3159391A1 (en) * | 2024-02-16 | 2025-08-22 | Arkema France | Composition based on poly(vinylidene fluoride) |
| WO2025205948A1 (en) * | 2024-03-29 | 2025-10-02 | 株式会社クレハ | Electrode binder, electrode mixture, electrode, and battery |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA786877A (en) | 1968-06-04 | Pasetti Adolfo | Fluorinated oxygen-containing products and process for their preparation | |
| US3242218A (en) | 1961-03-29 | 1966-03-22 | Du Pont | Process for preparing fluorocarbon polyethers |
| US3715378A (en) | 1967-02-09 | 1973-02-06 | Montedison Spa | Fluorinated peroxy polyether copolymers and method for preparing them from tetrafluoroethylene |
| GB1226566A (en) | 1967-04-04 | 1971-03-31 | ||
| US3665041A (en) | 1967-04-04 | 1972-05-23 | Montedison Spa | Perfluorinated polyethers and process for their preparation |
| US4523039A (en) | 1980-04-11 | 1985-06-11 | The University Of Texas | Method for forming perfluorocarbon ethers |
| US4379869A (en) | 1981-01-15 | 1983-04-12 | W. R. Grace & Co. | Cationic latices and their electrodeposition |
| DE3486428T2 (en) | 1983-12-26 | 1996-10-10 | Daikin Ind Ltd | Halogen containing polyether |
| US4675452A (en) | 1985-07-18 | 1987-06-23 | Lagow Richard J | Perfluorinated polyether fluids |
| IL82308A (en) | 1986-06-26 | 1990-11-29 | Ausimont Spa | Microemulsions containing perfluoropolyethers |
| FR2644466B1 (en) | 1989-03-15 | 1992-08-14 | Solvay | PROCESS FOR THE MANUFACTURE OF VINYLIDENE FLUORIDE POLYMERS AND USE OF VINYLIDENE FLUORIDE POLYMERS FOR THE FORMULATION OF PAINTS |
| IT1265067B1 (en) | 1993-05-18 | 1996-10-30 | Ausimont Spa | PROCESS OF (CO) POLYMERIZATION IN WATER EMULSION OF FLUORINATED OLEFINIC MONOMERS |
| IT1276072B1 (en) | 1995-10-31 | 1997-10-24 | Ausimont Spa | PROCESS OF (CO) POLYMERIZATION OF FLUORINATED MONOMERS TO OBTAIN HYDROGEN CONTAINING POLYMERS |
| IT1295535B1 (en) | 1996-07-01 | 1999-05-12 | Ausimont Spa | VINYLIDENFLUORIDE (VDF) POLYMERIZATION PROCESS |
| JP3601250B2 (en) | 1997-04-25 | 2004-12-15 | Jsr株式会社 | Binder for non-aqueous battery electrode |
| JPH11126633A (en) | 1997-08-30 | 1999-05-11 | Samsung Display Devices Co Ltd | Electrolyte for Li-ion battery and Li-ion battery employing the same |
| US6203944B1 (en) | 1998-03-26 | 2001-03-20 | 3M Innovative Properties Company | Electrode for a lithium battery |
| US6255017B1 (en) | 1998-07-10 | 2001-07-03 | 3M Innovative Properties Co. | Electrode material and compositions including same |
| FR2822296A1 (en) | 2001-03-19 | 2002-09-20 | Atofina | Separators and electroactive layers for lithium batteries, produced by shaping a microcomposite powder comprising a filler and a finely divided fluoropolymer |
| EP1392744B1 (en) | 2001-05-02 | 2008-07-09 | 3M Innovative Properties Company | Emulsifier free aqueous emulsion polymerization process for making fluoropolymers |
| JP4135074B2 (en) | 2002-10-25 | 2008-08-20 | ソニー株式会社 | Negative electrode manufacturing method and battery manufacturing method |
| JP2006504844A (en) | 2002-10-31 | 2006-02-09 | スリーエム イノベイティブ プロパティズ カンパニー | Emulsifier-free aqueous emulsion polymerization to produce copolymers of fluorinated olefins and hydrocarbon olefins |
| GB2430437A (en) | 2005-09-27 | 2007-03-28 | 3M Innovative Properties Co | Method of making a fluoropolymer |
| WO2008019155A1 (en) | 2006-08-11 | 2008-02-14 | The University Of North Carolina At Chapel Hill | Process of fluoromonomer polymerization |
| TWI437009B (en) | 2007-04-24 | 2014-05-11 | Solvay Solexis Spa | Vinylidene fluoride copolymers |
| JP5133111B2 (en) * | 2008-03-31 | 2013-01-30 | Jsr株式会社 | Lithium ion capacitor |
| JP5177040B2 (en) * | 2008-03-31 | 2013-04-03 | Jsr株式会社 | Composition for capacitor electrode binder, slurry for capacitor electrode, and capacitor electrode |
| WO2009135030A1 (en) | 2008-04-30 | 2009-11-05 | Battelle Memorial Institute | Metal-air battery |
| AU2010254037B2 (en) | 2009-05-29 | 2014-05-01 | Arkema Inc. | Aqueous polyvinylidene fluoride composition |
| US10079388B2 (en) * | 2011-07-15 | 2018-09-18 | Solvay Specialty Polymers Italy S.P.A. | Aqueous vinylidene fluoride-(meth)acrylic co-polymer latex, electrode and lithium ion secondary battery using the same |
-
2012
- 2012-07-13 US US14/232,894 patent/US10079388B2/en active Active
- 2012-07-13 CA CA2839389A patent/CA2839389C/en active Active
- 2012-07-13 KR KR1020147003640A patent/KR101963637B1/en active Active
- 2012-07-13 JP JP2014520618A patent/JP6359450B2/en active Active
- 2012-07-13 EP EP12735527.9A patent/EP2731990B1/en active Active
- 2012-07-13 MY MYPI2014000119A patent/MY165000A/en unknown
- 2012-07-13 WO PCT/EP2012/063778 patent/WO2013010936A1/en not_active Ceased
-
2017
- 2017-05-17 JP JP2017098558A patent/JP2017197747A/en not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| EP2731990A1 (en) | 2014-05-21 |
| CA2839389A1 (en) | 2013-01-24 |
| JP6359450B2 (en) | 2018-07-18 |
| US10079388B2 (en) | 2018-09-18 |
| JP2014527097A (en) | 2014-10-09 |
| WO2013010936A1 (en) | 2013-01-24 |
| JP2017197747A (en) | 2017-11-02 |
| KR101963637B1 (en) | 2019-04-01 |
| KR20140051945A (en) | 2014-05-02 |
| US20140154573A1 (en) | 2014-06-05 |
| CA2839389C (en) | 2020-09-01 |
| EP2731990B1 (en) | 2016-12-28 |
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