MY133950A - ANSA GROUP 4 METAL BIS ( µ-SUBSTITUTED ) ALUMINUM COMPLEXES - Google Patents

ANSA GROUP 4 METAL BIS ( µ-SUBSTITUTED ) ALUMINUM COMPLEXES

Info

Publication number
MY133950A
MY133950A MYPI99003260A MYPI9903260A MY133950A MY 133950 A MY133950 A MY 133950A MY PI99003260 A MYPI99003260 A MY PI99003260A MY PI9903260 A MYPI9903260 A MY PI9903260A MY 133950 A MY133950 A MY 133950A
Authority
MY
Malaysia
Prior art keywords
group
metal
aluminum
groups
complex
Prior art date
Application number
MYPI99003260A
Inventor
Eugene Y Chen
William J Kruper Jr
Peter N Nickias
David R Wilson
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of MY133950A publication Critical patent/MY133950A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Dental Preparations (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

ANSA BIS(PERMEABILITY-SUBSTITUTED) GROUP 4 METAL AND ALUMINUM COMPOUNDS COMPRISING A SINGLE GROUP 4 METAL ATOM AND TWO ALUMINUM METAL ATOMS CORRESPONDING TO THE FORMULA: (I)WHEREIN:L'' IS A (PI)-BONDED GROUP,M IS A GROUP 4 METAL,J IS NITROGEN OR PHOSPHORUS;Z IS A DIVALENT BRIDGING GROUP CAUSING THE COMPLEX TO HAVE AN ANSA STRUCTURE, R'' IS AN INERT MONOVELENT LIGAND;R IS ONE OR TWO;X INDEPENDENTLY EACH OCCURRENCE IS A LEWIS BASIC LIGAND GROUP ABLE TO FORM A (PERMEABILITY)-BRIDGING LIGAND GROUP, AND OPTIONALLY THE TWO X GROUPS MAY BE JOINED TOGETHER, AND A INDEPENDENTLY EACH OCCURRENCE IS AN ALUMINUM CONTAINING LEWIS ACID COMPOUND THAT FORMS AN ADDUCT WITH THE METAL COMPLEX BY MEANS OF THE (PERMEABILITY)-BRIDGING GROUPS, AND OPTIONALLY TWO A'' GROUPS MAY BE JOINED TOGETHER THEREBY FORMING A SINGLE DIFUNCTIONAL LEWIS ACID CONTAINING COMPOUND, AND A METHOD OF PREPARATION COMPRISING CONTAINING A CHARGE-NEUTRAL GROUP IV METAL COORDINATION COMPLEX HAVING AT LEAST TWO LEWIS BASIC GROUPS WITH AT LEAST TWO EQUIVALENTS OF CHARGE-NEUTRAL ALUMINUM COORDINATION COMPLEX HAVING LEWIS ACIDIC ALUMINUM ATOMS SUCH THAT AT LEAST TWO OF THE ALUMINUM COORDINATION COMPLEXES BOND TO AT LEAST TWO OF THE LEWIS BASIC GROUPS OF THE GROUP IV COORDINATION COMPLEX.
MYPI99003260A 1998-08-11 1999-07-30 ANSA GROUP 4 METAL BIS ( µ-SUBSTITUTED ) ALUMINUM COMPLEXES MY133950A (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US9608898P 1998-08-11 1998-08-11
US9680098P 1998-08-17 1998-08-17
US10049098P 1998-09-16 1998-09-16
US10422998P 1998-10-14 1998-10-14
US12261599P 1999-03-03 1999-03-03

Publications (1)

Publication Number Publication Date
MY133950A true MY133950A (en) 2007-11-30

Family

ID=27536779

Family Applications (1)

Application Number Title Priority Date Filing Date
MYPI99003260A MY133950A (en) 1998-08-11 1999-07-30 ANSA GROUP 4 METAL BIS ( µ-SUBSTITUTED ) ALUMINUM COMPLEXES

Country Status (9)

Country Link
US (1) US6140521A (en)
EP (1) EP1104429B1 (en)
JP (1) JP2002522551A (en)
AT (1) ATE217318T1 (en)
AU (1) AU4440499A (en)
CA (1) CA2337024A1 (en)
DE (1) DE69901451T2 (en)
MY (1) MY133950A (en)
WO (1) WO2000009523A1 (en)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI104826B (en) * 1996-01-30 2000-04-14 Borealis As Heteroatom-substituted metallose compounds for catalytic systems in olefin polymerization and process for their preparation
US6214760B1 (en) * 1998-08-11 2001-04-10 The Dow Chemical Company Catalyst activator composition
WO2005090425A1 (en) 2004-03-17 2005-09-29 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for ethylene copolymer formation
EP2792690B1 (en) 2004-03-17 2019-05-15 Dow Global Technologies LLC Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
NZ549262A (en) 2004-03-17 2010-08-27 Dow Global Technologies Inc Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
CN102321201B (en) 2004-06-16 2013-06-26 陶氏环球技术有限责任公司 Method for selecting polymerization modifiers
US20080051537A1 (en) * 2004-08-09 2008-02-28 Carnahan Edmund M Supported Bis(Hydroxylarylaryloxy) Catalysts For Manufacture Of Polymers
EP2894176B1 (en) * 2005-03-17 2022-06-01 Dow Global Technologies LLC Catalyst composition comprising shuttling agent for regio-irregular multi-block copolymer formation
US9410009B2 (en) 2005-03-17 2016-08-09 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
CA2600140A1 (en) 2005-03-17 2006-09-28 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
KR20080055838A (en) 2005-09-15 2008-06-19 다우 글로벌 테크놀로지스 인크. Control of Polymer Composition and Molecular Weight Distribution with Multi-core Shuttles
AR058449A1 (en) 2005-09-15 2008-02-06 Dow Global Technologies Inc CATALYTIC OLEFINE BLOCK COPOLYMERS VIA A POLYMERIZABLE TRANSFER AGENT
US8153243B2 (en) 2005-12-09 2012-04-10 Dow Global Technologies Llc Interpolymers suitable for multilayer films
BRPI0711029A2 (en) * 2006-05-17 2011-05-31 Dow Global Technologies Inc process for polymerization of ethylene and one or more c3-30 α-olefins or diolefins
ITMI20070877A1 (en) 2007-05-02 2008-11-03 Dow Global Technologies Inc PROCESS FOR THE PRODUCTION OF MULTI-BLOCKED COPOLYMERS WITH THE USE OF POLAR SOLVENTS
ITMI20070878A1 (en) 2007-05-02 2008-11-03 Dow Global Technologies Inc PROCESS FOR POLYMERIZZAINE OF TACTICAL POLYMERS USING CHIRAL CATALYSTS
ES2435568T3 (en) * 2007-11-19 2013-12-20 Dow Global Technologies Llc Propylene-alpha-olefin copolymers with long chain branching
US8592615B2 (en) 2009-03-06 2013-11-26 Dow Global Technologies, Llc Catalysts, processes for making catalysts, processes for making polyolefin compositions, and polyolefin compositions
WO2011016992A2 (en) 2009-07-29 2011-02-10 Dow Global Technologies Inc. Polymeric chain transfer/shuttling agents
BR112012001948B1 (en) 2009-07-29 2019-08-20 Dow Global Technologies Llc Chain transfer agent, process for polymerizing at least one addition polymerizable monomer, multi-block copolymer and catalyst composition
CN108026115B (en) 2015-09-30 2021-11-09 陶氏环球技术有限责任公司 Multi-head or double-head composition capable of being used for chain shuttling and preparation method thereof
WO2018064553A1 (en) 2016-09-30 2018-04-05 Dow Global Technologies Llc Multi- or dual-headed compositions useful for chain shuttling and process to prepare the same
EP3519474B1 (en) 2016-09-30 2024-09-25 Dow Global Technologies LLC Process for preparing multi- or dual-headed compositions useful for chain shuttling
JP7029448B2 (en) 2016-09-30 2022-03-03 ダウ グローバル テクノロジーズ エルエルシー A sealed multi- or dual-head composition useful for chain shuttling, and the process of preparing it.
ES3040148T3 (en) 2018-12-28 2025-10-28 Dow Global Technologies Llc Organometallic chain transfer agents
US20220073540A1 (en) 2018-12-28 2022-03-10 Dow Global Technologies Llc Curable compositions comprising unsaturated polyolefins
US12590174B2 (en) 2018-12-28 2026-03-31 Dow Global Technologies Llc Curable compositions comprising telechelic polyolefins
CN113454091A (en) 2018-12-28 2021-09-28 陶氏环球技术有限责任公司 Curable compositions comprising unsaturated polyolefins
SG11202107051UA (en) 2018-12-28 2021-07-29 Dow Global Technologies Llc Telechelic polyolefins and processes for preparing the same

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5763549A (en) * 1989-10-10 1998-06-09 Fina Technology, Inc. Cationic metallocene catalysts based on organoaluminum anions
US5721185A (en) * 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
JPH05230134A (en) * 1992-02-24 1993-09-07 Mitsui Toatsu Chem Inc Method for producing polyolefin having a wide molecular weight distribution
KR100292158B1 (en) * 1992-08-04 2001-06-01 가지와라 야스시 Olefin polymerization catalyst and polymerization method of olefin

Also Published As

Publication number Publication date
JP2002522551A (en) 2002-07-23
DE69901451T2 (en) 2002-12-12
ATE217318T1 (en) 2002-05-15
WO2000009523A1 (en) 2000-02-24
AU4440499A (en) 2000-03-06
CA2337024A1 (en) 2000-02-24
EP1104429A1 (en) 2001-06-06
DE69901451D1 (en) 2002-06-13
EP1104429B1 (en) 2002-05-08
US6140521A (en) 2000-10-31

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