MXPA04001323A - Substituted dihydro 3-halo-1h-pyrazole-5-carboxylates their preparation and use. - Google Patents

Substituted dihydro 3-halo-1h-pyrazole-5-carboxylates their preparation and use.

Info

Publication number
MXPA04001323A
MXPA04001323A MXPA04001323A MXPA04001323A MXPA04001323A MX PA04001323 A MXPA04001323 A MX PA04001323A MX PA04001323 A MXPA04001323 A MX PA04001323A MX PA04001323 A MXPA04001323 A MX PA04001323A MX PA04001323 A MXPA04001323 A MX PA04001323A
Authority
MX
Mexico
Prior art keywords
preparation
carboxylates
pyrazole
halo
substituted dihydro
Prior art date
Application number
MXPA04001323A
Other languages
Spanish (es)
Inventor
Philip Lahm George
Original Assignee
Du Pont
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27405544&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=MXPA04001323(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Du Pont filed Critical Du Pont
Publication of MXPA04001323A publication Critical patent/MXPA04001323A/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/72Hydrazones
    • C07C251/74Hydrazones having doubly-bound carbon atoms of hydrazone groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C251/76Hydrazones having doubly-bound carbon atoms of hydrazone groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of a saturated carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/72Nitrogen atoms
    • C07D213/76Nitrogen atoms to which a second hetero atom is attached
    • C07D213/77Hydrazine radicals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D231/00Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/06Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D231/00Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/06Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D231/08Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with oxygen or sulfur atoms directly attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D231/00Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D231/00Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/16Halogen atoms or nitro radicals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D401/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D413/00Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/02Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
    • C07D413/04Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D413/00Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/14Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing three or more hetero rings

Abstract

This invention relates to a compound of Formula I, a method for its preparation and its use in the preparation of a compound of Formula II wherein R1, R2, R3, X and n are as defined in the disclosure.This invention also discloses preparation of compounds of Formula III wherein R1, R2, R6, R7, R8 and n are as defined in the disclosure.Also disclosed are certain intermediates of Formula 4 for the preparation of compounds of Formula I wherein X is N and R2, R3 and n are as defined in the disclosure.
MXPA04001323A 2001-08-13 2002-08-13 Substituted dihydro 3-halo-1h-pyrazole-5-carboxylates their preparation and use. MXPA04001323A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US31191901P 2001-08-13 2001-08-13
US34195801P 2001-12-19 2001-12-19
US36966002P 2002-04-02 2002-04-02
PCT/US2002/025614 WO2003016283A1 (en) 2001-08-13 2002-08-13 Substituted dihydro 3-halo-1h-pyrazole-5-carboxylates their preparation and use

Publications (1)

Publication Number Publication Date
MXPA04001323A true MXPA04001323A (en) 2004-05-20

Family

ID=27405544

Family Applications (1)

Application Number Title Priority Date Filing Date
MXPA04001323A MXPA04001323A (en) 2001-08-13 2002-08-13 Substituted dihydro 3-halo-1h-pyrazole-5-carboxylates their preparation and use.

Country Status (19)

Country Link
US (3) US6965032B2 (en)
EP (1) EP1417175B1 (en)
JP (1) JP4564748B2 (en)
KR (1) KR100953251B1 (en)
CN (1) CN1307161C (en)
AU (1) AU2002355952B2 (en)
BR (1) BR0212185B1 (en)
CA (1) CA2454306C (en)
DK (1) DK1417175T3 (en)
ES (1) ES2428888T3 (en)
HU (1) HU230124B1 (en)
IL (1) IL159507A0 (en)
IN (2) IN215218B (en)
MX (1) MXPA04001323A (en)
PL (1) PL214276B1 (en)
PT (1) PT1417175E (en)
TW (3) TWI371450B (en)
WO (1) WO2003016283A1 (en)
ZA (1) ZA200309911B (en)

Families Citing this family (90)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2454298A1 (en) 2001-08-13 2003-02-27 Gary David Annis Substituted 1h-dihydropyrazoles, their preparation and use
MY142967A (en) * 2001-08-13 2011-01-31 Du Pont Method for controlling particular insect pests by applying anthranilamide compounds
AR036872A1 (en) 2001-08-13 2004-10-13 Du Pont ANTRANILAMIDE COMPOSITE, COMPOSITION THAT INCLUDES IT AND METHOD FOR CONTROLLING AN INVERTEBRATE PEST
BR0212189A (en) * 2001-08-15 2004-07-13 Du Pont Compound, method for invertebrate pest control and composition for invertebrate pest control
PT1417176E (en) * 2001-08-16 2009-02-26 Du Pont Substituted anthranilamides for controlling invertebrate pests
TW200724033A (en) 2001-09-21 2007-07-01 Du Pont Anthranilamide arthropodicide treatment
US20040110777A1 (en) * 2001-12-03 2004-06-10 Annis Gary David Quinazolinones and pyridinylpyrimidinones for controlling invertebrate pests
WO2003062226A1 (en) * 2002-01-22 2003-07-31 E. I. Du Pont De Nemours And Company Quinazoline(di) ones for invertebrate pest control
WO2003106427A2 (en) * 2002-06-13 2003-12-24 E.I. Du Pont De Nemours And Company Pyrazolecarboxamide insecticides
TWI326283B (en) * 2002-07-31 2010-06-21 Du Pont Method for preparing fused oxazinones
TWI343376B (en) * 2002-07-31 2011-06-11 Du Pont Method for preparing 3-halo-4, 5-dihydro-1h-pyrazoles
ES2342595T3 (en) 2002-11-15 2010-07-09 E.I. Du Pont De Nemours And Company NEW INSECTICIDES OF ANTRANILAMIDE.
PT1599463E (en) * 2003-01-28 2013-09-03 Du Pont Cyano anthranilamide insecticides
TWI367882B (en) * 2003-03-26 2012-07-11 Du Pont Preparation and use of 2-substituted-5-oxo-3-pyrazolidinecarboxylates
BRPI0411195A (en) * 2003-06-12 2006-07-25 Du Pont Method for the preparation of a fused oxazinone and Method for the preparation of a compound
DE10353281A1 (en) 2003-11-14 2005-06-16 Bayer Cropscience Ag Combination of active ingredients with insecticidal and acaricidal properties
DE102004021564A1 (en) 2003-11-14 2005-07-07 Bayer Cropscience Ag Composition for controlling animal pests comprises a synergistic combination of a pyrethroid and an anthranilic acid derivative
DE102004006075A1 (en) 2003-11-14 2005-06-16 Bayer Cropscience Ag Composition for controlling animal pests comprises a synergistic combination of a nicotinergic acetylcholine receptor agonist or antagonist and an anthranilamide derivative
WO2005053406A1 (en) 2003-12-04 2005-06-16 Bayer Cropscience Aktiengesellschaft Active substance combinations having insecticidal properties
DE10356550A1 (en) 2003-12-04 2005-07-07 Bayer Cropscience Ag Drug combinations with insecticidal properties
AR048669A1 (en) * 2004-03-03 2006-05-17 Syngenta Ltd BISAMIDE BICYCLE DERIVATIVES
RU2006139953A (en) * 2004-04-13 2008-05-20 Е.И. Дюпон Де Немур Энд Компани (Us) ANTRANILAMIDE INSECTICIDES
DE102004031100A1 (en) * 2004-06-28 2006-01-12 Bayer Cropscience Ag anthranilamides
GT200500179A (en) * 2004-07-01 2006-02-23 SYNERGIST MIXTURES OF ANTRANILAMIDE AGENTS FOR THE CONTROL OF INVERTEBRATE PESTS
DE102004035134A1 (en) 2004-07-20 2006-02-16 Bayer Cropscience Ag Selective insecticides based on Halogenalkylnicotinsäurederivaten, Anthranilsäureamiden or phthalic diamides and safeners
MY140912A (en) * 2004-07-26 2010-01-29 Du Pont Mixtures of anthranilamide invertebrate pest control agents
UA93869C2 (en) 2005-03-18 2011-03-25 Э.И. Дю Пон Де Немур Энд Компани Method for preparing pyrazoles
BRPI0617046A2 (en) * 2005-08-24 2011-07-12 Du Pont compound, invertebrate pest control composition, bait composition for invertebrate pest control, spray composition for invertebrate pest control, invertebrate pest control methods, cockroach, ant or termite control method and mosquito, fly control method black, stable flies, deer flies, horse flies, wasps, hornets, hornets, ticks, spiders, ants or mosquitoes
DE102005044108A1 (en) 2005-09-15 2007-03-29 Bayer Cropscience Ag Dioxazine- and oxdiazine-substituted arylamides
DE102006032168A1 (en) 2006-06-13 2007-12-20 Bayer Cropscience Ag Anthranilic acid diamide derivatives with heteroaromatic substituents
JP2009001541A (en) * 2006-12-15 2009-01-08 Ishihara Sangyo Kaisha Ltd Method for producing anthranilamide compound using new pyrazole compound as intermediate
JP5507045B2 (en) * 2006-12-15 2014-05-28 石原産業株式会社 Method for producing anthranilamido compound
CN104496901B (en) * 2006-12-15 2016-05-25 石原产业株式会社 The manufacture method of anthranilamide compound
TWI415827B (en) 2006-12-21 2013-11-21 Du Pont Process for preparing 2-amino-5-cyanobenzoic acid derivatives
WO2009010260A2 (en) * 2007-07-16 2009-01-22 Syngenta Participations Ag Condensed anthranilamide insecticides
CN101550130B (en) * 2008-04-01 2012-11-07 中国中化股份有限公司 Method for preparing 3-halo-1-(3-chloro -2-pyridyl)-1H-pyrazole-5-formyl halide
JP5406581B2 (en) * 2008-04-16 2014-02-05 石原産業株式会社 Method for producing anthranilamido compound
PT2484676E (en) 2008-12-18 2015-05-18 Bayer Cropscience Ag Tetrazol-substituted anthranilic acid amides as pesticides
TW201109057A (en) * 2009-06-02 2011-03-16 Sanofi Aventis Deutschland Medicated module with bypass and needle guard
WO2011009551A1 (en) * 2009-07-23 2011-01-27 Bayer Cropscience Ag Process for producing aryl-substituted pyrazoles
KR101042930B1 (en) * 2009-08-21 2011-06-21 문형태 Child pillow
BR112012014683B1 (en) * 2009-12-15 2017-11-07 Bayer Cropscience Ag PROCESS FOR PRODUCTION OF 5-PYRAZOLCARBOXYLIC ACID DERIVATIVES 1-ALKYL- / 1-ARYL-SUBSTITUTED AND COMPOUND ACID
CN102883606A (en) 2010-02-09 2013-01-16 拜尔农作物科学股份公司 Hydrazine-substituted anthranilic acid derivatives
MX2012011858A (en) 2010-04-16 2012-11-12 Bayer Cropscience Ag Triazole-substituted anthranilic acid amides as pesticides.
ES2554903T3 (en) 2010-06-15 2015-12-28 Bayer Intellectual Property Gmbh Diaramide derivatives of anthranilic acid with cyclic side chains
KR20130089232A (en) 2010-06-15 2013-08-09 바이엘 인텔렉쳐 프로퍼티 게엠베하 Anthranilic acid diamide derivatives
BR112012032259A2 (en) 2010-06-15 2015-09-15 Bayer Ip Gmbh "New ortho-substituted arylamide derivatives".
WO2011157653A1 (en) 2010-06-15 2011-12-22 Bayer Cropscience Ag Anthranilic acid derivatives
JP5926253B2 (en) 2010-07-09 2016-05-25 バイエル・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツングBayer Intellectual Property GmbH Anthranilamide derivatives as pesticides
KR20130099268A (en) 2010-09-29 2013-09-05 이 아이 듀폰 디 네모아 앤드 캄파니 Fungicidal imidazoles
US8871939B2 (en) 2011-01-28 2014-10-28 E I Du Pont De Nemours And Company Method for preparing 2-aminobenzamide derivatives
CN102399211A (en) * 2011-07-29 2012-04-04 山东永农作物科学有限公司 Preparation method of 3-bromo-1-(3-chloro-2-pyridyl) -4,5-dihydro-1H-pyrazole-5-formiate
US9414595B2 (en) 2011-12-19 2016-08-16 Bayer Cropscience Ag Use of anthranilic acid diamide derivatives for pest control in transgenic crops
EP2606732A1 (en) 2011-12-19 2013-06-26 Bayer CropScience AG Use of an anthranilic diamide derivatives with heteroaromatic and heterocyclic substituents in combination with a biological control agent
MX2015007205A (en) 2012-12-06 2016-03-31 Quanticel Pharmaceuticals Inc Histone demethylase inhibitors.
JP6476137B2 (en) 2013-03-06 2019-02-27 バイエル・クロップサイエンス・アクチェンゲゼルシャフト Alkoxyimino substituted anthranilic acid diamides as pesticidal agents
US9108946B2 (en) * 2013-10-17 2015-08-18 Dow Agrosciences Llc Processes for the preparation of pesticidal compounds
WO2015058024A1 (en) 2013-10-17 2015-04-23 Dow Agrosciences Llc Processes for the preparation of pesticidal compounds
KR20160074541A (en) 2013-10-17 2016-06-28 다우 아그로사이언시즈 엘엘씨 Processes for the preparation of pesticidal compounds
CN105636446B (en) 2013-10-17 2018-07-13 美国陶氏益农公司 The method for preparing Pesticidal compound
BR112016007518A2 (en) 2013-10-17 2017-08-01 Dow Agrosciences Llc processes for the preparation of pesticide compounds
EP3057427B1 (en) 2013-10-17 2018-07-18 Dow AgroSciences LLC Processes for the preparation of pesticidal compounds
CN105636441B (en) 2013-10-17 2018-06-15 美国陶氏益农公司 The method for preparing Pesticidal compound
CN103755700B (en) * 2013-12-26 2015-07-29 青岛科技大学 A kind of pyrazol acid amide compounds and uses thereof
US9029556B1 (en) * 2014-07-31 2015-05-12 Dow Argosciences Llc Process for the preparation of 3-(3-chloro-1H-pyrazol-1-yl)pyridine
US9029555B1 (en) * 2014-07-31 2015-05-12 Dow Agrosciences Llc Process for the preparation of 3-(3-chloro-1H-pyrazol-1-yl)pyridine
WO2016018444A1 (en) 2014-07-31 2016-02-04 Dow Agrosciences Llc Process for the preparation of 3-(3-chloro-1h-pyrazol-1-yl)pyridine
CA2958058A1 (en) 2014-08-19 2016-02-25 Dow Agrosciences Llc Process for the preparation of 3-(3-chloro-1h-pyrazol-1-yl)pyridine
KR20170058388A (en) 2014-09-12 2017-05-26 다우 아그로사이언시즈 엘엘씨 Process for the preparation of 3-(3-chloro-1h-pyrazol-1-yl)pyridine
CN106187998A (en) * 2016-07-20 2016-12-07 南通雅本化学有限公司 A kind of preparation technology of 1 (3 chloropyridine 2 base) 3 bromine 1H pyrazoles 5 formic acid
CN110325036B (en) 2016-12-29 2021-10-26 美国陶氏益农公司 Process for preparing pesticidal compounds
JP2020503336A (en) 2016-12-29 2020-01-30 ダウ アグロサイエンシィズ エルエルシー Method for preparing pesticidal compounds
WO2019123194A1 (en) 2017-12-20 2019-06-27 Pi Industries Ltd. Anthranilamides, their use as insecticide and processes for preparing the same.
JP7403454B2 (en) 2017-12-20 2023-12-22 ピーアイ インダストリーズ リミテッド Pyrazolopyridine-diamides, their use as insecticides and their preparation
CA3090764A1 (en) * 2018-01-30 2019-08-08 Pi Industries Ltd Novel anthranilamides, their use as insecticide and processes for preparing the same
WO2020026259A1 (en) * 2018-07-31 2020-02-06 Sumitomo Chemical India Ltd. Ethyl 2-bromo-4-[2-(3-halopyridin-2-yl)-hydrazinyl]-4-oxobutanoate hbr salt, method of preparation and use thereof
WO2020026260A1 (en) * 2018-07-31 2020-02-06 Sumitomo Chemical India Ltd. Novel 2-(3-halo-5-methyl-1 h-pyrazol-1-yl)-3-halopyridine compounds and intermediates thereof
EA202191554A1 (en) 2018-12-03 2021-09-02 Фмк Корпорейшн METHOD FOR OBTAINING N-PHENYLPYRAZOL-1-CARBOXAMIDES
WO2020130575A1 (en) * 2018-12-17 2020-06-25 주식회사 엘지화학 Electrolyte for lithium secondary battery, and lithium secondary battery comprising same
CN111825653A (en) 2019-04-19 2020-10-27 安道麦马克西姆有限公司 Preparation of substituted pyrazoles and use thereof as anthranilamide precursors
TW202112762A (en) 2019-08-19 2021-04-01 美商富曼西公司 A process for the preparation of carboxylic acid derivatives of 3-halo-4,5-dihydro-1h-pyrazoles
US20220298136A1 (en) * 2019-08-21 2022-09-22 Gharda Chemicals Limited Process for synthesis of pyrazolidinone compounds
CN110483480A (en) * 2019-09-11 2019-11-22 江苏优普生物化学科技股份有限公司 The synthetic method of 2- (3- chloropyridine -2- base) -5- hydroxyl -3- pyrazolidinecarboxylate
TW202128643A (en) 2019-11-11 2021-08-01 美商富曼西公司 Methods for the preparation of ethyl 3-bromo-1-(3-chloropyridin-2-yl)-1h-pyrazole-5-carboxylate
JPWO2021193432A1 (en) 2020-03-25 2021-09-30
CN111620850B (en) * 2020-05-27 2021-06-29 江苏七洲绿色化工股份有限公司 Preparation method of 1- (3-chloropyridine-2-yl) -3-bromo-1H-pyrazole-5-formic ether
WO2022191139A1 (en) 2021-03-09 2022-09-15 石原産業株式会社 Method for producing 3-bromo-1-(3-chloropyridin-2-yl)-1h-pyrazole-5-carboxylic acid ester
WO2023110710A1 (en) 2021-12-13 2023-06-22 Syngenta Crop Protection Ag Method for controlling diamide resistant pests & compounds therefor
CN114957214A (en) * 2022-06-22 2022-08-30 九江善水科技股份有限公司 Preparation method of chlorantraniliprole intermediate
WO2024049748A1 (en) 2022-08-29 2024-03-07 Fmc Corporation A new and efficient process for preparing 3 -halo-4, 5-dihydro-1h-pyrazoles

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3159654A (en) * 1958-09-25 1964-12-01 Norwich Pharma Co New series of carboxylic acid esters of 5-nitro-2-furyl alkylidene hydroxyalkyl semicbazones
NL279140A (en) 1961-05-31
DE3545786A1 (en) 1985-12-21 1987-06-25 Schering Ag Pyrazoline derivatives, their preparation, and their use as insecticides
AU598633B2 (en) * 1987-01-05 1990-06-28 E.I. Du Pont De Nemours And Company 1-sub-phenyl-3-sub-phenylamino(thio) carbonyl-pyrazolines as insecticides
DE3808896A1 (en) * 1988-03-17 1989-09-28 Hoechst Ag PLANT PROTECTION AGENTS BASED ON PYRAZOL CARBON SEA DERIVATIVES
IT1216152B (en) 1988-03-18 1990-02-22 Merloni Elettrodomestici Spa HYDRAULIC PUMP, PARTICULARLY FOR DISHWASHER OR SIMILAR.
DE4142778C2 (en) 1991-12-23 1997-11-20 Man Takraf Foerdertechnik Gmbh Spreader positioning device for container cranes
NL9202078A (en) * 1992-11-30 1994-06-16 Rijkslandbouwhogeschool Novel N-acyl-anthranilic acid compounds, and use of N- acyl-anthranilic acid compounds in insect control
JPH09176124A (en) 1995-12-25 1997-07-08 Nissan Chem Ind Ltd Pyrazoline derivative and plant blight controlling agent
JP4004082B2 (en) 1996-05-23 2007-11-07 三井化学株式会社 Method for producing cyclic nitroguanidine derivatives
JP4041922B2 (en) 1996-05-24 2008-02-06 日産化学工業株式会社 Method for producing pyrazole carboxylic acid ester derivative
US6114425A (en) 1997-07-17 2000-09-05 Unitex Chemical Corporation Plasticized polyvinyl chloride compound
MY138097A (en) * 2000-03-22 2009-04-30 Du Pont Insecticidal anthranilamides
WO2001070761A1 (en) * 2000-03-23 2001-09-27 The University Of Toledo Uses of alkylammonium salts in protein renaturation
AR036872A1 (en) 2001-08-13 2004-10-13 Du Pont ANTRANILAMIDE COMPOSITE, COMPOSITION THAT INCLUDES IT AND METHOD FOR CONTROLLING AN INVERTEBRATE PEST
CA2454298A1 (en) 2001-08-13 2003-02-27 Gary David Annis Substituted 1h-dihydropyrazoles, their preparation and use

Also Published As

Publication number Publication date
JP4564748B2 (en) 2010-10-20
TW201018664A (en) 2010-05-16
KR20040029434A (en) 2004-04-06
US20070203342A1 (en) 2007-08-30
EP1417175B1 (en) 2013-07-24
EP1417175A1 (en) 2004-05-12
IN2005MU00437A (en) 2005-12-02
US20050245580A1 (en) 2005-11-03
PL214276B1 (en) 2013-07-31
HUP0401019A2 (en) 2004-09-28
IN215218B (en) 2008-03-28
CN1541206A (en) 2004-10-27
TW201022229A (en) 2010-06-16
HUP0401019A3 (en) 2005-11-28
KR100953251B1 (en) 2010-04-16
US20040198987A1 (en) 2004-10-07
AU2002355952B2 (en) 2008-02-28
IN2004MU00007A (en) 2005-11-18
US6965032B2 (en) 2005-11-15
BR0212185A (en) 2004-10-05
PL369031A1 (en) 2005-04-18
PT1417175E (en) 2013-10-17
CN1307161C (en) 2007-03-28
CA2454306A1 (en) 2003-02-27
JP2005502658A (en) 2005-01-27
ZA200309911B (en) 2005-05-25
IL159507A0 (en) 2004-06-01
TWI356822B (en) 2012-01-21
ES2428888T3 (en) 2013-11-12
CA2454306C (en) 2012-11-13
DK1417175T3 (en) 2013-10-28
TWI327566B (en) 2010-07-21
BR0212185B1 (en) 2013-09-10
US7227025B2 (en) 2007-06-05
US7402676B2 (en) 2008-07-22
WO2003016283A1 (en) 2003-02-27
IN205622B (en) 2007-06-29
HU230124B1 (en) 2015-08-28
TWI371450B (en) 2012-09-01

Similar Documents

Publication Publication Date Title
MXPA04001323A (en) Substituted dihydro 3-halo-1h-pyrazole-5-carboxylates their preparation and use.
AU2002319814A1 (en) Substituted 1h-dihydropyrazoles, their preparation and use
BG106340A (en) Substituted oxoazaheterocyclyl compounds
DE69831868D1 (en) Antithrombosemittel
TW200602322A (en) Phosphodiesterase 4 inhibitors, including n-substituted diarylamine analogs
TW200738672A (en) Intermediated for the preparation of 4,5-dihydro-pyrazolo [3,4-c] pyrid-2-ones
DE60330150D1 (en) Derivate des 2-trifluormethyl-6-aminopurins als phosphodiesterase 4 inhibitoren
AP2002002637A0 (en) Novel piperazine
IL135536A0 (en) Ortho-anthranilamide derivatives and pharmaceutical compositions containing the same
BG106585A (en) Kinase inhibitors as therapeutic agents
HK1078850A1 (en) Novel alkoxypyridine-derivatives
MXPA02011370A (en) Substituted iminoazines.
AU7824900A (en) Compounds and methods for inhibiting mrp1
UA85502C2 (en) Diazaindole-dicarbonyl-piperazinyl antiviral agents
ATE280767T1 (en) ANTIDIABETIC THIAZOLIDINDIONES AND THEIR PRODUCTION
AP2001002188A0 (en) 5HT1 antagonists for antidepressant therapy.
DE60114640D1 (en) Antithrombosemittel
TR200302288T2 (en) New compounds and methods for therapy.
BG105766A (en) New process for preparing pesticidal intermediates
MXPA04005988A (en) 3,4-dihydro-1h-isoquinoloin-2-yl-derivatives.
MXPA04005151A (en) Therapeutic compounds.
MY129094A (en) Condensed polycyclic compounds
IL156768A0 (en) Process for preparing (+/-) trans-4-p-fluorophenyl-3-hydroxymethyl-1-methylpiperidine
MXPA02001406A (en) Substituted heterocyclyl-2h-chromenes.
GB9806409D0 (en) Processes for preparing intermediates

Legal Events

Date Code Title Description
FG Grant or registration