MX2020004749A - Mejoramientos en o relacionados con compuestos organicos. - Google Patents
Mejoramientos en o relacionados con compuestos organicos.Info
- Publication number
- MX2020004749A MX2020004749A MX2020004749A MX2020004749A MX2020004749A MX 2020004749 A MX2020004749 A MX 2020004749A MX 2020004749 A MX2020004749 A MX 2020004749A MX 2020004749 A MX2020004749 A MX 2020004749A MX 2020004749 A MX2020004749 A MX 2020004749A
- Authority
- MX
- Mexico
- Prior art keywords
- relating
- organic compounds
- allylic oxidation
- mixture
- guayane
- Prior art date
Links
- 150000002894 organic compounds Chemical class 0.000 title 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 125000000746 allylic group Chemical group 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- NUWMTBMCSQWPDG-SDDRHHMPSA-N Rotundone Chemical compound C1([C@H](CC[C@H](C2)C(C)=C)C)=C2[C@@H](C)CC1=O NUWMTBMCSQWPDG-SDDRHHMPSA-N 0.000 abstract 1
- NUWMTBMCSQWPDG-UHFFFAOYSA-N Rotundone Natural products C1C(C(C)=C)CCC(C)C2=C1C(C)CC2=O NUWMTBMCSQWPDG-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 150000004032 porphyrins Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/005—General concepts, e.g. reviews, relating to methods of using catalyst systems, the concept being defined by a common method or theory, e.g. microwave heating or multiple stereoselectivity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
La presente invención se relaciona con un proceso de oxidación alílica que comprende: formar una mezcla que contiene a-guayano y un complejo de catalizador de porfirina de hierro (III)-X en un solvente sostenible, introducir oxígeno molecular en la mezcla y efectuar la oxidación alílica para producir una cetona a,ß-insaturada, rotundona.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB1720211.0A GB201720211D0 (en) | 2017-12-05 | 2017-12-05 | Improvements in or relating to organic compounds |
PCT/EP2018/083322 WO2019110493A1 (en) | 2017-12-05 | 2018-12-03 | Improvements in or relating to organic compounds |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2020004749A true MX2020004749A (es) | 2020-08-20 |
Family
ID=60950269
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2020004749A MX2020004749A (es) | 2017-12-05 | 2018-12-03 | Mejoramientos en o relacionados con compuestos organicos. |
Country Status (9)
Country | Link |
---|---|
US (1) | US10865173B2 (es) |
EP (1) | EP3720836B1 (es) |
JP (1) | JP7343501B2 (es) |
CN (1) | CN111433179B (es) |
ES (1) | ES2969700T3 (es) |
GB (1) | GB201720211D0 (es) |
MX (1) | MX2020004749A (es) |
SG (1) | SG11202004164QA (es) |
WO (1) | WO2019110493A1 (es) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020179503A1 (ja) * | 2019-03-01 | 2020-09-10 | 長谷川香料株式会社 | セスキテルペン酸素付加体の製造方法、化合物および組成物 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DD291748A5 (de) | 1990-02-01 | 1991-07-11 | Bitterfeld Chemie | Verfahren zur herstellung von allylhydroxylierten terpenoiden kohlenwasserstoffen |
CA2074880A1 (en) * | 1991-08-12 | 1993-02-13 | James E. Lyons | Allylic oxidation of olefins |
WO2011106166A1 (en) * | 2010-02-26 | 2011-09-01 | Vertellus Specialties Inc. | Methods for using allylic oxidation catalysts to perform oxidation reactions |
EP2569427B1 (en) | 2010-05-10 | 2017-11-08 | Firmenich SA | Method for producing patchoulol and 7-epi-alpha-selinene |
EP2402301A1 (en) | 2010-06-29 | 2012-01-04 | Givaudan SA | 1-hydroxy-octahydroazulenes as fragrances |
GB201318886D0 (en) * | 2013-10-25 | 2013-12-11 | Givaudan Sa | Improvements i or relating to organic compounds |
JP6522551B2 (ja) | 2016-06-10 | 2019-05-29 | 長谷川香料株式会社 | (−)−ロタンドンの製造方法 |
-
2017
- 2017-12-05 GB GBGB1720211.0A patent/GB201720211D0/en not_active Ceased
-
2018
- 2018-12-03 JP JP2020530550A patent/JP7343501B2/ja active Active
- 2018-12-03 ES ES18811829T patent/ES2969700T3/es active Active
- 2018-12-03 EP EP18811829.3A patent/EP3720836B1/en active Active
- 2018-12-03 MX MX2020004749A patent/MX2020004749A/es unknown
- 2018-12-03 CN CN201880078746.0A patent/CN111433179B/zh active Active
- 2018-12-03 US US16/765,235 patent/US10865173B2/en active Active
- 2018-12-03 SG SG11202004164QA patent/SG11202004164QA/en unknown
- 2018-12-03 WO PCT/EP2018/083322 patent/WO2019110493A1/en unknown
Also Published As
Publication number | Publication date |
---|---|
JP2021505572A (ja) | 2021-02-18 |
SG11202004164QA (en) | 2020-06-29 |
ES2969700T3 (es) | 2024-05-22 |
GB201720211D0 (en) | 2018-01-17 |
WO2019110493A1 (en) | 2019-06-13 |
EP3720836B1 (en) | 2023-11-15 |
CN111433179A (zh) | 2020-07-17 |
CN111433179B (zh) | 2023-05-23 |
US20200283363A1 (en) | 2020-09-10 |
JP7343501B2 (ja) | 2023-09-12 |
US10865173B2 (en) | 2020-12-15 |
EP3720836A1 (en) | 2020-10-14 |
BR112020009239A2 (pt) | 2020-10-13 |
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