MD4217C1 - Process for anaerobic production of biohydrogen from organic waste - Google Patents

Process for anaerobic production of biohydrogen from organic waste

Info

Publication number
MD4217C1
MD4217C1 MD20120010A MD20120010A MD4217C1 MD 4217 C1 MD4217 C1 MD 4217C1 MD 20120010 A MD20120010 A MD 20120010A MD 20120010 A MD20120010 A MD 20120010A MD 4217 C1 MD4217 C1 MD 4217C1
Authority
MD
Moldova
Prior art keywords
hydrogen
distillery
refuse
production
biogas
Prior art date
Application number
MD20120010A
Other languages
Romanian (ro)
Russian (ru)
Other versions
MD4217B1 (en
Inventor
Виктор КОВАЛЁВ
Валентин БОБЕЙКЭ
Ольга КОВАЛЁВА
Владимир НЕННО
Думитру УНГУРЯНУ
Георге ДУКА
Original Assignee
Государственный Университет Молд0
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Государственный Университет Молд0 filed Critical Государственный Университет Молд0
Priority to MD20120010A priority Critical patent/MD4217C1/en
Publication of MD4217B1 publication Critical patent/MD4217B1/en
Publication of MD4217C1 publication Critical patent/MD4217C1/en

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel

Landscapes

  • Treatment Of Sludge (AREA)

Abstract

The invention relates to microbiological processing of organic waste from food and agricultural product processing industry with the production of an ecologically clean energy product - biogas, consisting primarily of hydrogen. The invention can also be used for the purification of highly polluted waste waters or in other areas of the national economy, where are formed organic waste of vegetal and animal origin.The proposed process for production of biohydrogen includes the anaerobic fermentation of distillery refuse from wine stock distillation processes and alcohol production in the presence of methanogenesis chemical inhibitors, which are biologically active vegetal substances of isoprenoid nature, added to the amount of 1·10-3±5·10-4 mass % of the waste weight. The fermentation is carried out at pH=5.2…7.5 in mesophilic conditions, at 33±1°C, at the stirring of distillery refuse and continuous removal of hydrogen from bioreactor. As methanogenesis inhibitors can be used triterpenic compounds gypsogenin or gypsogenin glycosides with the following general structural formula:or neotigogenin saponin - a C27-spirostan steroid with the following structural formula:.It can also be used limonene (1-methyl-4-isopropenylcyclohexene-1), menthol (3-methyl-6-isopropylcyclohexanol) or β-carotene.The process provides a hydrogen formation rate within the limits 1.9…2.2 L(H2)/L(distillery refuse)·h, and the content of molecular hydrogen in the resulting biogas reaches 59…68 vol. %, at the same time methane is practically absent in the biogas.
MD20120010A 2012-01-23 2012-01-23 Process for anaerobic production of biohydrogen from organic waste MD4217C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
MD20120010A MD4217C1 (en) 2012-01-23 2012-01-23 Process for anaerobic production of biohydrogen from organic waste

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
MD20120010A MD4217C1 (en) 2012-01-23 2012-01-23 Process for anaerobic production of biohydrogen from organic waste

Publications (2)

Publication Number Publication Date
MD4217B1 MD4217B1 (en) 2013-04-30
MD4217C1 true MD4217C1 (en) 2013-11-30

Family

ID=48227602

Family Applications (1)

Application Number Title Priority Date Filing Date
MD20120010A MD4217C1 (en) 2012-01-23 2012-01-23 Process for anaerobic production of biohydrogen from organic waste

Country Status (1)

Country Link
MD (1) MD4217C1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MD4289C1 (en) * 2013-08-17 2015-01-31 Государственный Университет Молд0 Process for producing biogas

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MD4362C1 (en) * 2014-03-04 2016-03-31 Государственный Университет Молд0 Process for producing biohydrogen and biomethane

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5942424A (en) * 1997-06-19 1999-08-24 Lockheed Martin Energy Research Corporation Method for the enzymatic production of hydrogen
US6942998B1 (en) * 2000-07-18 2005-09-13 The United States Of America As Represented By The United States Department Of Energy Process for generation of hydrogen gas from various feedstocks using thermophilic bacteria
US7083956B2 (en) * 2003-07-07 2006-08-01 Gas Technology Institute Method for hydrogen production from organic wastes using a two-phase bioreactor system
US7232669B1 (en) * 2006-03-10 2007-06-19 Feng Chia University Process for enhancing anaerobic biohydrogen production
CN101033473A (en) * 2005-12-30 2007-09-12 逢甲大学 Method of accelerating anaerobe to produce hydrogen
WO2009101528A1 (en) * 2008-02-14 2009-08-20 Ooo "Maks K" Method for ecologising food industry technologies and a system for carrying out said method
KR20090099915A (en) * 2008-03-19 2009-09-23 한국과학기술연구원 Method and apparatus for bio-hydrogen gas production from organic waste by using inhibitor for methane producing microorganisms and gas purging
CN101880116A (en) * 2009-05-04 2010-11-10 上海盛创环保科技有限公司 Medicine adding method for improving hydrogen production efficiency by sludge anaerobism in sewage plant
MD188Z (en) * 2009-11-23 2010-11-30 Государственный Университет Молд0 Process for biochemical treatment of wine-making waste
MD4189B1 (en) * 2011-07-15 2012-12-31 Univ De Stat Din Moldova Process for anaerobic fermentation of liquid organic waste

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5942424A (en) * 1997-06-19 1999-08-24 Lockheed Martin Energy Research Corporation Method for the enzymatic production of hydrogen
US6942998B1 (en) * 2000-07-18 2005-09-13 The United States Of America As Represented By The United States Department Of Energy Process for generation of hydrogen gas from various feedstocks using thermophilic bacteria
US7083956B2 (en) * 2003-07-07 2006-08-01 Gas Technology Institute Method for hydrogen production from organic wastes using a two-phase bioreactor system
CN101033473A (en) * 2005-12-30 2007-09-12 逢甲大学 Method of accelerating anaerobe to produce hydrogen
US7232669B1 (en) * 2006-03-10 2007-06-19 Feng Chia University Process for enhancing anaerobic biohydrogen production
WO2009101528A1 (en) * 2008-02-14 2009-08-20 Ooo "Maks K" Method for ecologising food industry technologies and a system for carrying out said method
KR20090099915A (en) * 2008-03-19 2009-09-23 한국과학기술연구원 Method and apparatus for bio-hydrogen gas production from organic waste by using inhibitor for methane producing microorganisms and gas purging
CN101880116A (en) * 2009-05-04 2010-11-10 上海盛创环保科技有限公司 Medicine adding method for improving hydrogen production efficiency by sludge anaerobism in sewage plant
MD188Z (en) * 2009-11-23 2010-11-30 Государственный Университет Молд0 Process for biochemical treatment of wine-making waste
MD4189B1 (en) * 2011-07-15 2012-12-31 Univ De Stat Din Moldova Process for anaerobic fermentation of liquid organic waste

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Марков С.А. Биоводород: возможное использование водорослей и бактерий для получения молекулярного водорода. International Scientific Journal of Alternative Energy and Ecology ISJAEE, no. 1(45), 2007, p. 30-45 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MD4289C1 (en) * 2013-08-17 2015-01-31 Государственный Университет Молд0 Process for producing biogas

Also Published As

Publication number Publication date
MD4217B1 (en) 2013-04-30

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