KR940011552A - Thermoplastic resin composition - Google Patents

Thermoplastic resin composition Download PDF

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Publication number
KR940011552A
KR940011552A KR1019920021010A KR920021010A KR940011552A KR 940011552 A KR940011552 A KR 940011552A KR 1019920021010 A KR1019920021010 A KR 1019920021010A KR 920021010 A KR920021010 A KR 920021010A KR 940011552 A KR940011552 A KR 940011552A
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KR
South Korea
Prior art keywords
styrene
acrylate
weight
copolymer
resin composition
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KR1019920021010A
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Korean (ko)
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KR960004676B1 (en
Inventor
백종현
김진곤
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최근선
주식회사 럭 키
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Priority to KR1019920021010A priority Critical patent/KR960004676B1/en
Publication of KR940011552A publication Critical patent/KR940011552A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene
    • C08L25/14—Copolymers of styrene with unsaturated esters

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명은 (1)폴리올레핀수지 5-95중량부, (2)스티렌계수지 5-95중량부, (3)성분 (1) 및 (2)의 합 100중량부에 대해, 스티렌/아크릴레이트 공중합체 5-50중량부 및 (4)상기 성분(1), (2) 및 (3)의 합 100중량부에 대해, 스티렌계 열가소성 탄성중합체 1-30중량부를 포함함을 특징으로 하는 열가소성 수지 조성물에 관한 것이다.The present invention relates to styrene / acrylate air with respect to 100 parts by weight of (1) 5-95 parts by weight of polyolefin resin, (2) 5-95 parts by weight of styrene resin, and (3) components (1) and (2). 5-50 parts by weight of the copolymer and (4) a thermoplastic resin composition comprising 1-30 parts by weight of a styrene-based thermoplastic elastomer based on 100 parts by weight of the sum of the components (1), (2), and (3). It is about.

Description

열가소성 수지 조성물Thermoplastic resin composition

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (8)

(1)폴리올레핀수지 5-95중량부, (2)스티렌계수지 5-95중량부, (3)성분 (1) 및 (2)의 합 100중량부에 대해, 다음 일반식(I)로 나타내어지는 스티렌/아크릴레이트 공중합체 5-50중량부,(1) 5-95 parts by weight of polyolefin resin, (2) 5-95 parts by weight of styrene resin, and (3) 100 parts by weight of the sum of the components (1) and (2) are represented by the following general formula (I) 5-50 parts by weight of losing styrene / acrylate copolymer, (상기식에서, A및 A1는 각각 독립적으로 H또는 CH3이고, B는 페닐기이며, B1는 아민, 황 또는 산소이고,R은 포화 C4-C30탄화수소 또는 불포화 C3-C30탄화수소 이며, n은 85∼99.9이고, m은 0.1∼15이다) 및 (4)상기 성분(1), (2) 및 (3)의 합 100중량부에 대해, 스티렌계 열가소성 탄성중합체 1-30중량부를 포함함을 특징으로하는 열염가소성 수지 조성물.Wherein A and A 1 are each independently H or CH 3 , B is a phenyl group, B 1 is an amine, sulfur or oxygen, and R is a saturated C 4 -C 30 hydrocarbon or an unsaturated C 3 -C 30 hydrocarbon N is 85 to 99.9, m is 0.1 to 15) and (4) 1 to 30 weight of styrene-based thermoplastic elastomer based on 100 parts by weight of the sum of the components (1), (2) and (3). Thermo-plastic resin composition comprising a part. 제1항에 있어서, 상기 폴리올레핀수지(1)가 폴리프로필렌의 단독중합체 또는 공중합체, 선형 저밀도 폴리에틸렌, 저밀도 폴리에틸렌, 초저밀도 폴리에틸렌, 고밀도 폴리에틸렌, 에틸렌 비닐 아세테이트 또는 에틸렌 에틸 아크릴레이트임을 특징으로 하는 열가소성 수지 조성물.The thermoplastic resin according to claim 1, wherein the polyolefin resin (1) is a homopolymer or copolymer of polypropylene, linear low density polyethylene, low density polyethylene, ultra low density polyethylene, high density polyethylene, ethylene vinyl acetate or ethylene ethyl acrylate. Composition. 제1항에 있어서. 상기 스티렌계 수지(2)가 스티렌 단량체의 단독 중합체 ; α-메틸스티렌, 아크릴로니트릴, 메틸메아크릴레이트 및 아크릴FP이트중에서 선택된 1종 이상의 단량체와 스티렌과의 공중합체; 고충격 폴리스티렌(HIPS) 또는 아크릴로니트릴-부타디엔-스티렌(ABS) 공중합체임을 특징으로 하는 열가소성 수지 조성물.The method of claim 1. The styrene resin (2) is a homopolymer of a styrene monomer; copolymers of styrene with at least one monomer selected from α-methylstyrene, acrylonitrile, methyl methacrylate and acryl FPite; A high impact polystyrene (HIPS) or acrylonitrile-butadiene-styrene (ABS) copolymer, characterized in that the thermoplastic resin composition. 제1항에 있어서, 상기 스티렌/아크릴레이트 공중합체(3)에서 아크릴레이트 단량체가 C4-C30인 포화탄화수소 또는 C3-C30인 불포화 탄화수소를 함유하는 아크릴레이트임을 특징으로 하는 열가소성 수지 조성물.The thermoplastic resin composition according to claim 1, wherein in the styrene / acrylate copolymer (3), the acrylate monomer is a saturated hydrocarbon of C 4 -C 30 or an acrylate containing C 3 -C 30 unsaturated hydrocarbon. . 제1항 또는 제4항에 있어서, 상기 스티렌/아크릴레이트 공중합체(3)에서 아크릴레이트 단량체가 알릴메타 크릴레이트, 데실아크릴레이트, 옥타데실아크릴레이트, N-n-옥타테실 아크릴아마이드, 2-(9-옥타데카노일)에틸렌 글리콜 1-아크릴레이트, 2-에틸헥실메타크릴레이트, 헥사데세닐메타크릴레이트, 부틸 아크릴레이트, 헥사코사닐 메타크릴레이트 또는 옥타데세닐 메타크릴레이트임을 특징으로 하는 열가소성 수지 조성물.The acrylate monomer in the styrene / acrylate copolymer (3) is selected from the group consisting of allyl methacrylate, decyl acrylate, octadecyl acrylate, Nn-octadecyl acrylamide, 2- (9). Octadecanoyl) ethylene glycol 1-acrylate, 2-ethylhexyl methacrylate, hexadecenyl methacrylate, butyl acrylate, hexacosanyl methacrylate or octadecenyl methacrylate Composition. 제1항에 있어서, 상기 성분(3)으로 폴리올레핀 수지와 스티렌/아크릴레이트 공중합체를 개시제와 반응시켜 제조된 폴리올레핀-스티렌/아크릴레이트 그라프트 공중합체를 포함함을 특징으로 하는 열가소성 수지 조성물.The thermoplastic resin composition according to claim 1, wherein the component (3) comprises a polyolefin-styrene / acrylate graft copolymer prepared by reacting a polyolefin resin and a styrene / acrylate copolymer with an initiator. 제1항에 있어서, 상기 스티렌계 열가소성 탄성중합체(4)는 A가 스티렌 블록 중합체이고, B가 공액디엔계 탄화수소 화합물 또는 수소 첨가에 의해 이중결합이 포화된 탄화수소인 것으로 A-B-A형의 구조를 가짐을 특징으로 하는 열가소성 수지 조성물.According to claim 1, wherein the styrene-based thermoplastic elastomer (4) is A is a styrene block polymer, B is a conjugated diene-based hydrocarbon compound or a double bond saturated hydrocarbon by hydrogen addition has a structure of type ABA The thermoplastic resin composition characterized by the above-mentioned. 제1항 또는 제7항에 있어서, 상기 스티렌계 열가소성 탄성중합체(4)가 스티렌 부타디엔 스티렌 블록 공중합체(SBS), 스티렌 에틸렌 부틸렌 스티렌 블록공중합체(SEBS) 또는 스티렌 에틸렌 프로필렌 스티렌 블록공중합체(SEPB)임을 특징으로 하는 열가소성 수지 조성물.The styrene-based thermoplastic elastomer (4) according to claim 1 or 7, wherein the styrene-based thermoplastic elastomer (4) is a styrene butadiene styrene block copolymer (SBS), styrene ethylene butylene styrene block copolymer (SEBS) or styrene ethylene propylene styrene block copolymer ( SEPB) is a thermoplastic resin composition. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019920021010A 1992-11-10 1992-11-10 Thermoplastic resin composition KR960004676B1 (en)

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KR1019920021010A KR960004676B1 (en) 1992-11-10 1992-11-10 Thermoplastic resin composition

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KR960004676B1 KR960004676B1 (en) 1996-04-11

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030015679A (en) * 2001-08-17 2003-02-25 현대자동차주식회사 A thermoplastic of composition comprising polypropylene and ABS having highly-compatibility
KR100760457B1 (en) * 2005-12-30 2007-10-04 제일모직주식회사 ABS Acrylonitrile butadiene styrene resin composition with good vacuum-forming ability

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030015679A (en) * 2001-08-17 2003-02-25 현대자동차주식회사 A thermoplastic of composition comprising polypropylene and ABS having highly-compatibility
KR100760457B1 (en) * 2005-12-30 2007-10-04 제일모직주식회사 ABS Acrylonitrile butadiene styrene resin composition with good vacuum-forming ability

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KR960004676B1 (en) 1996-04-11

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