KR940007143A - 솔더레지스트용 잉크조성물 - Google Patents
솔더레지스트용 잉크조성물 Download PDFInfo
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- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
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- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/14—Polycondensates modified by chemical after-treatment
- C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
- C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
- C08G59/1455—Monocarboxylic acids, anhydrides, halides, or low-molecular-weight esters thereof
- C08G59/1461—Unsaturated monoacids
- C08G59/1466—Acrylic or methacrylic acids
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- G—PHYSICS
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- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
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- G—PHYSICS
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- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/032—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders
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- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/032—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders
- G03F7/035—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders the binders being polyurethanes
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/22—Secondary treatment of printed circuits
- H05K3/28—Applying non-metallic protective coatings
- H05K3/285—Permanent coating compositions
- H05K3/287—Photosensitive compositions
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
- H05K2203/07—Treatments involving liquids, e.g. plating, rinsing
- H05K2203/0779—Treatments involving liquids, e.g. plating, rinsing characterised by the specific liquids involved
- H05K2203/0783—Using solvent, e.g. for cleaning; Regulating solvent content of pastes or coatings for adjusting the viscosity
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
- H05K2203/07—Treatments involving liquids, e.g. plating, rinsing
- H05K2203/0779—Treatments involving liquids, e.g. plating, rinsing characterised by the specific liquids involved
- H05K2203/0786—Using an aqueous solution, e.g. for cleaning or during drilling of holes
- H05K2203/0793—Aqueous alkaline solution, e.g. for cleaning or etching
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Abstract
본 발명의 광경화형 액상솔더레지스트용 잉크조성물은 핵체수가 4이상의 노볼락형에폭시수지에 (메타)아크릴로일기를 도입함과 동시에, 쇄연장제를 사용하여 고분자량화한 충분한 분자량과 (메타)아크릴로일기를 가진 광중합성수지를 주성분으로 한다.
이 조성물은 해상도, 내열성, 밀착성, 내약품성 및 태크프리성이 뛰어난 경화막을 합성할 수 있어서, 광경화형 레지스트용으로 가장 적합하다. 또한, 산무수물을 반응시키면 알칼리현상도 가능하게 된다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (14)
- 광중합성수지(A), 광중합개시제(B) 및 희석제(C)를 가진 솔더레지스트용 잉크조성물로서, 광중합성수지(A)의 핵체수가 4이상인 노블락형에폭시수지(Ⅰ)에 (메타)아크릴산(Ⅱ)을 반응시켜, (메타)아크릴산(Ⅱ)의 카르복실기와 에폭시수지(Ⅰ)중의 에폭시기와의 반응에 의하여 에폭시수지(Ⅰ)중에 (메타)아크릴로일기를 도입함과 동시에, 상기 카르복실기와 에폭시기와의 반응에 의하여 생성되는 히드록실기 및/또는 에폭시수지(Ⅰ)중의 에폭시기를 통하여 그 히드록실기 및/또는 그 에폭시기와 반응할 수 있는 관능기를 2개 이상 가진 쇄연장제(Ⅲ)로 에폭시수지(Ⅰ)를 고분자화하여 얻을 수 있는 것을 특징으로 하는 솔더레지스트 잉크조성물.
- 제1항에 있어서, 쇄연장제(Ⅲ)가 다가페놀, 다염기산, 다관능아민 및 다가티올로된 군중에서 선택되는 에폭시기와 반응할 수 있는 관능기를 2개 이상가진 화합물인 것을 특징으로 하는 솔더레지스트용 잉크조성물.
- 제1항에 있어서, 쇄연장제(Ⅲ)가 다가페놀인 것을 특징으로 하는 솔더레지스트용 잉크조성물.
- 제1항에 있어서, 쇄연장제(Ⅲ)가 히드록실기와 반응할 수 있는 관능기를 2개 이상 가진 다관능이소시아네이트인 것을 특징으로 하는 솔더레지스트용 잉크조성물.
- 제2항 또는 제3항에 있어서, 노볼락형에폭시수지(Ⅰ)중의 에폭시기 1 화학 당량에 대하여, (메타)아크릴산(Ⅱ)과 쇄연장제(Ⅲ)중의 관능기의 합계가 0.9∼1.1화학 당량이고,더욱이 쇄연장제(Ⅲ)의 사용량이 노볼락형에 폭시수지(Ⅰ) 1몰에 대하여 0.2∼0.8몰인 것을 특징으로 하는 솔더레지스트용 잉크조성물.
- 제4항에 있어서, 노볼락형에폭시수지(Ⅰ)중의 에폭시기 1화학 당량에 대하여 (메타)아크릴산(Ⅱ)이 0.9∼1.1몰이고, 쇄연장제(Ⅲ)의 사용량이 노볼락형에폭시수지(Ⅰ) 1몰에 대하여 0.2∼0.8몰인 것을 특징으로 하는 솔더레지스트용 잉크조성물.
- 제2항 또는 제3항에 있어서, 광중합성수지(A)가 (메타)아크릴산(Ⅱ)에 더하여, 다시 분자중에 1개의 카르복실기와 2개 이상의 (메타)아크릴로일기를 가진 다관능(메타)아크릴레이트(Ⅳ)를 반응시켜 얻을 수 있는 것을 특징으로 하는 솔더레지스트용 잉크조성물.
- 노볼락형에폭시수지(Ⅰ)중의 에폭시기 1화학 당량에 대하여 (메타)아크릴산(Ⅱ), 다관능(메타)아크릴레이트(Ⅳ) 및 쇄연장제(Ⅲ)중의 관능기의 합계가 0.9∼1.1 화학 당량이고, 또한 (메타)아크릴산(Ⅱ)과 다관능(메타)아크릴레이트(Ⅳ)의 화학 당량비가 (9:1)∼(5:5)이고, 더욱이 쇄연장제(Ⅲ)의 사용량이 에폭시수지(Ⅰ) 1몰에 대하여 0.2∼0.8몰인 것을 특징으로 하는 솔더레지스트용 잉크조성물.
- 제4항에 있어서, 광중합성수지(A)가 (메타)아크릴산(Ⅱ)에 더하여, 다시 분자중에 1개의 카르복실기와 2개이상의 (메타)아크릴로일기를 가진 다관능(메타)아크릴레이트(Ⅳ)를 반응시켜 얻을 수 있는 것을 특징으로 하는 솔더레지스트용 잉크조성물.
- 제9항에 있어서, 노볼락형에폭시수지(Ⅰ)중의 에폭시기 1화학 당량에 대하여, (메타)아크릴산(Ⅱ) 및 다관능(메타)아크릴레이트(Ⅳ)중의 관능기의 합계가 0.9∼1.1 화학 당량이고, 또한 (메타)아크릴산(Ⅱ)과 다관능(메타)아크릴레이트(Ⅳ)의 화학 당량비가 (9:1)∼(5:5)이고, 더욱이 쇠연장제(Ⅲ)의 사용량이 에폭시수지(Ⅰ) 1몰에 대하여 0.2∼0.8몰인 것을 특징으로 하는 솔더레지스트용 잉크조성물.
- 제1항에 있어서, 광중합성수지(A)가 다시 분자중에 1개의 이소시아네이트기와 2개 이상의 (메타)아크릴로일기를 가진 다관능(메타)아크릴레이트(Ⅴ)를 반응시켜 얻을 수 있는 것을 특징으로 하는 솔더레지스트용 잉크 조성물.
- 제1항에 있어서, 광중합수지(A)가 다시 산무수물(Ⅵ)을 반응시켜 얻을 수 있는 것을 특징으로 하는 솔더레지스트용 잉크조성물.
- 제1항에 있어서, 광중합개시제(B)가 솔더레지스트용 잉크조성물 중에 0.5∼25중량% 함유되어 있는 것을 특징으로 하는 솔더레지스트용 잉크조성물.
- 제1항에 있어서, 희석제(C)가 광합성수지(A) 100중량부에 대하여 5∼500중량부 함유되어 있는 것을 특징으로 하는 솔더레지스트용 잉크조성물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
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JP24200092 | 1992-09-10 | ||
JP92-242000 | 1992-09-10 | ||
JP93-176787 | 1993-07-16 | ||
JP17678793A JP3288140B2 (ja) | 1993-07-16 | 1993-07-16 | ソルダーレジスト用インキ組成物 |
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KR940007143A true KR940007143A (ko) | 1994-04-26 |
KR0126118B1 KR0126118B1 (ko) | 1997-12-18 |
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Application Number | Title | Priority Date | Filing Date |
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KR1019930018102A KR0126118B1 (ko) | 1992-09-10 | 1993-09-09 | 솔더레지스트용 잉크조성물 |
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US (1) | US6015651A (ko) |
EP (1) | EP0587189B1 (ko) |
KR (1) | KR0126118B1 (ko) |
DE (1) | DE69333313T2 (ko) |
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GB9708510D0 (en) * | 1997-04-25 | 1997-06-18 | Dow Deutschland Inc | Nitrogen containing epoxy resins for photocurable coating applications |
US6583198B2 (en) * | 1997-11-28 | 2003-06-24 | Hitachi Chemical Company, Ltd. | Photo curable resin composition and photosensitive element |
JP2002533775A (ja) * | 1998-12-22 | 2002-10-08 | バンティコ アクチエンゲゼルシャフト | フォトレジスト被膜の製造方法 |
US6553735B1 (en) * | 2001-11-06 | 2003-04-29 | Nan Ya Plastics Corporation | Joint structure as reinforcing rib to injected frame of door leaf with glass |
DE10223313A1 (de) * | 2002-05-24 | 2003-12-11 | Bakelite Ag | Modifizierte Epoxyacrylate |
KR100571366B1 (ko) * | 2004-01-27 | 2006-04-14 | 주식회사 코오롱 | 액상 포토 솔더 레지스트 조성물 |
US20060033793A1 (en) * | 2004-08-10 | 2006-02-16 | Webster Grant A | Coupling agent patterning |
EP2168994A1 (en) | 2008-09-25 | 2010-03-31 | Huntsman Advanced Materials (Switzerland) GmbH | Photocurable composition |
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JPS61243869A (ja) * | 1985-04-19 | 1986-10-30 | Taiyo Ink Seizo Kk | レジストインキ組成物 |
DE3588111T2 (de) * | 1985-06-29 | 1996-10-31 | Asahi Chem Res Lab | Kunststoffzusammensetzung für Lötschutztinte |
JPH0639518B2 (ja) * | 1986-04-28 | 1994-05-25 | 東京応化工業株式会社 | 耐熱性感光性樹脂組成物 |
JPS63258975A (ja) * | 1986-12-26 | 1988-10-26 | Toshiba Corp | ソルダーレジストインキ組成物 |
JPH0717737B2 (ja) * | 1987-11-30 | 1995-03-01 | 太陽インキ製造株式会社 | 感光性熱硬化性樹脂組成物及びソルダーレジストパターン形成方法 |
US4980234A (en) * | 1987-12-23 | 1990-12-25 | Minnesota Mining And Manufacturing Co. | Epoxide resin compositions and method |
JPH0359022A (ja) * | 1989-07-27 | 1991-03-14 | Nippon Chibagaigii Kk | 熱硬化性樹脂 |
JP2988736B2 (ja) * | 1991-03-11 | 1999-12-13 | 株式会社アサヒ化学研究所 | 一液型感光性熱硬化性樹脂組成物 |
JP2904321B2 (ja) * | 1991-10-30 | 1999-06-14 | 互応化学工業株式会社 | 液状レジストインク組成物 |
US5928839A (en) * | 1992-05-15 | 1999-07-27 | Morton International, Inc. | Method of forming a multilayer printed circuit board and product thereof |
-
1993
- 1993-09-09 KR KR1019930018102A patent/KR0126118B1/ko not_active IP Right Cessation
- 1993-09-10 DE DE69333313T patent/DE69333313T2/de not_active Expired - Fee Related
- 1993-09-10 EP EP93114613A patent/EP0587189B1/en not_active Expired - Lifetime
-
1997
- 1997-04-28 US US08/846,167 patent/US6015651A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP0587189A2 (en) | 1994-03-16 |
DE69333313T2 (de) | 2004-09-09 |
KR0126118B1 (ko) | 1997-12-18 |
EP0587189A3 (en) | 1994-08-10 |
DE69333313D1 (de) | 2004-01-08 |
EP0587189B1 (en) | 2003-11-26 |
US6015651A (en) | 2000-01-18 |
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