KR920004464A - 알릴에스테르 올리고머 조성물 및 이들로 이루어진 광학재료용 유기 글라스 - Google Patents

알릴에스테르 올리고머 조성물 및 이들로 이루어진 광학재료용 유기 글라스 Download PDF

Info

Publication number
KR920004464A
KR920004464A KR1019910014253A KR910014253A KR920004464A KR 920004464 A KR920004464 A KR 920004464A KR 1019910014253 A KR1019910014253 A KR 1019910014253A KR 910014253 A KR910014253 A KR 910014253A KR 920004464 A KR920004464 A KR 920004464A
Authority
KR
South Korea
Prior art keywords
acid
composition
allyl ester
weight
ester oligomer
Prior art date
Application number
KR1019910014253A
Other languages
English (en)
Other versions
KR100187566B1 (ko
Inventor
우찌다 히로시
마루모 구니오미
Original Assignee
무라다 가쓰
쇼와 덴코 카부시키카이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=16722018&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=KR920004464(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by 무라다 가쓰, 쇼와 덴코 카부시키카이샤 filed Critical 무라다 가쓰
Publication of KR920004464A publication Critical patent/KR920004464A/ko
Application granted granted Critical
Publication of KR100187566B1 publication Critical patent/KR100187566B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C08F290/062—Polyethers
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/14—Esters of polycarboxylic acids
    • C08F218/16—Esters of polycarboxylic acids with alcohols containing three or more carbon atoms
    • C08F218/18—Diallyl phthalate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)

Abstract

내용 없음

Description

알릴에스테르 올리고머 조성물 및 이들로 이루어진 광학재료용 유기 글라스
내용없음

Claims (14)

  1. ⒜ 알릴에스테르 올리고머 20－90중량%, ⒝ 디알릴 프탈레이트 디 알릴 이소프탈레이트, 디알릴 테레프탈레이트, 디알릴 아디프에이트, 트리알릴(이소)시안우레이트 및 트리알릴 트리멜리테이트 중에서 선택된 적어도 한가지의 다가알릴에스테르 모노머 10－8중량%, 및 ⒞ 비닐 벤조에이트, 알릴벤조에이트, 페닐(메타)아크릴레이트 및 벤질(메타)아아크릴레이트 중에서 선택된 적어도 한가지의 일관능 중합성 모노머 40중량%까지를 혼합시켜 형성된 30℃에서 점도가 200－50,000cP이고 30℃에서 굴절률이 1.50－1.57인 알릴에스테르 올리고머 조성물.
  2. 제1항에 있어서, 알릴에스테르 올리고머(a)가 그 말단에 결합된 알릴기 및 다음식으로 표시된 반복단위를 가진 것을 특징으로 하는 조성물.
    －(CORCOOBO)－ (Ⅰ)
    －(CORCOO)x－Z－O－CORCOO－ (Ⅱ)
    －(BOCO)y－ACOO－BO－ (Ⅲ)
    상기식에서, R은 2가 포화카르복실산으로부터 유도된 유기잔기를 나타내며, B는 2가 포화알코올로부터 유도된 유기잔기를 나타내며, A는 삼가 또는 그 이상의 다가포화 카르복실산으로부터 유도된 유기잔기를 나타내며, Z는 삼가 또는 그 이상의 다가알코올로부터 유도된 유기잔기를 나타내며, x와 y는 적어도 2인 양의 정수이다.
  3. 제2항에 있어서, 2가 포화카르복실산이 숙신산, 글루타르산, 아디프산, β－메틸아디프산, 피멜산, 코르크산, 아젤라산, 세바스산, 1, 2－1, 3－또는 1, 4－시클로헥산－디카르복실산, 프탈산, 이소프탈산, 테레프탈산, 디페닐－ p, p´－디카르복실산, 디페닐－m, m´－디카르복실산, 1, 4－, 1, 5－, 2, 6－ 또는 2, 7－나프탈렌－디카르복실산, 디페닐메탄－p, p´－디카르복실산, 디페닐메탄－m, m´－디카르복실산 및 메틸테레프탈산중에서 선택되는 것을 특징으로 하는 조성물.
  4. 제2항에 있어서, 2가 포화알코올이 에틸렌글리콜, 프로필렌글리콜, 1, 3－프로판글리콜, 1, 4－부탄디올, 1, 3－부탄디올, 네오펜틸글리콜, 1, 5－펜탄디올, 헥사메틸렌글리콜, 1, 4－시클로헥산 디메탄올, 2－에틸－2, 5－펜탄디올 및 2－에틸－1, 3－헥산디올, 디에틸렌글리콜, 디프로필렌글리콜, 비스페놀 A의 에틸렌옥사이드 부가물 및 비스페놀 A의 프로필렌옥사이드 부가물 중에서 선택되는 것을 특징으로 하는 조성물.
  5. 제2항에 있어서, 삼가 또는 그 이상의 다가 포화카르복실산이 트리멜리트산 및 피로멜리트산중에서 선택되는 것을 특징으로 하는 조성물.
  6. 제2항에 있어서, 삼가 또는 그 이상의 다가포화알코올이 글리세롤, 트리메틸올에탄, 트리메틸올프로판, 펜타에리트리톨 및 소르비톨중에서 선택되는 것을 특징으로 하는 조성물.
  7. 제1항에 있어서, 알릴에스테르 올리고머⒜가 위지스법에 의하여 측정된 요오드가에 의하여 표시된 20－150의 볼포화도를 가진것을 특징으로 하는 조성물.
  8. 제1항에 있어서, 알릴에스테르 올리고머가 수평균 분자량(Mn) 500－50,000 및 중량평균 분자량 (Mw) 1,000－1,000,000을 가지며, Mw/Mn 비가 1.2－40.0인 것을 특징으로 하는 조성물.
  9. 제1항에 있어서, 일관능 중합성 모노머(c)의 양이 15－50중량%인 것을 특징으로 한는 조성물.
  10. 제1항에 있어서, 다가알릴에스테르 모노머(b)의 양이 30중량%까지 인 것을 특징으로 하는 조성물
  11. 제1항에 있어서, 30℃에서 점도가 500－5,000cP인 것을 특징으로 하는 방법.
  12. 제1항에 있어서, 30℃에서 굴절율이 1.51－1.55인 것을 특징으로 하는 조성물.
  13. 제1항의 알릴에스테르 올리고머 조성물을 공중합시켜 얻어진 광학재료용 유기글라스.
  14. 제13항에 있어서, 알릴에스테르 올리고머 조성물을 조성물 100중량부당 피카르보네이트 1－10중량부와 혼합물을 30－100℃에서 주형 중합시킨 것을 특징으로 하는 유기글라스.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910014253A 1990-08-20 1991-08-19 알릴에스테르 올리고머 조성물 및 이들로 이루어진 광학재료용 유기글라스 KR100187566B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2218570A JP2592010B2 (ja) 1990-08-20 1990-08-20 アリルエステルオリゴマー組成物およびそれを用いた光学材料用有機ガラス
JP2-218570 1990-08-20

Publications (2)

Publication Number Publication Date
KR920004464A true KR920004464A (ko) 1992-03-27
KR100187566B1 KR100187566B1 (ko) 1999-06-01

Family

ID=16722018

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019910014253A KR100187566B1 (ko) 1990-08-20 1991-08-19 알릴에스테르 올리고머 조성물 및 이들로 이루어진 광학재료용 유기글라스

Country Status (5)

Country Link
US (1) US5218067A (ko)
EP (1) EP0472168B1 (ko)
JP (1) JP2592010B2 (ko)
KR (1) KR100187566B1 (ko)
DE (1) DE69111714T2 (ko)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040021842A (ko) * 2002-09-05 2004-03-11 (주) 그린페이퍼텍 천연 쑥 향과 고농축 약쑥액을 함유하는 미용용지 및 이의제조방법
US8097190B2 (en) 2006-09-06 2012-01-17 Koc Solution Co., Ltd. Optical resin composition having excellent impact resistance and method for fabricating optical lens using the same

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3266162B2 (ja) * 1992-08-26 2002-03-18 昭和電工株式会社 光学材料用組成物
IT1265046B1 (it) * 1993-08-06 1996-10-28 Enichem Sintesi Articoli ad elevato indice di rifrazione,composizioni liquide polimerizzabili e metodo per ottenerle
TW385317B (en) * 1995-02-12 2000-03-21 Akzo Nobel Nv Ophthalmic lenses
WO1999038899A1 (en) 1998-01-30 1999-08-05 Ppg Industries Ohio, Inc. Polymerizable polyol(allyl carbonate) composition
US6506864B1 (en) 2000-04-10 2003-01-14 Ppg Industries Ohio, Inc. Polymerizable composition of allyl functional monomers
ATE344285T1 (de) * 2000-04-10 2006-11-15 Ppg Ind Ohio Inc (co)polymerisierbare zusammensetzung, die allylfunktionelle monomere enthält
JP2002069133A (ja) * 2000-06-16 2002-03-08 Showa Denko Kk プラスチックレンズ材料、該材料の製造方法、プラスチックレンズ用組成物、該組成物を硬化してなるプラスチックレンズ、及び該プラスチックレンズの製造方法
US6846900B2 (en) * 2001-03-26 2005-01-25 Showa Denko K.K. Polyvalent carboxylic acid ester, process for producing the carboxylic acid ester, plastic lens composition using the carboxylic ester, plastic lens obtained by curing the composition and process for producing the plastic lens
AU2002309285A1 (en) * 2001-07-02 2003-02-17 Showa Denko K. K. Plastic lens material, plastic lens composition, plastic lens obtained by curing the composition and process for producing the plastic lens
JP2007502882A (ja) * 2003-08-20 2007-02-15 コーニンクレッカ　フィリップス　エレクトロニクス　エヌ　ヴィ 非浸出接着剤系及び液浸対物系におけるその使用
TWI412576B (zh) * 2006-04-06 2013-10-21 Showa Denko Kk Transparent conductive substrate
JP5090040B2 (ja) * 2006-04-06 2012-12-05 昭和電工株式会社 透明導電性基板

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57212401A (en) * 1981-06-24 1982-12-27 Hoya Corp High refractive index plastic lens
IT1160172B (it) * 1983-01-13 1987-03-04 Anic Spa Composizione liquida polimerizzabile, atta a produrre polimeri con elevate caratteristiche ottiche e meccaniche e polimeri e manufatti ottenuti da detta composizione
IT1203364B (it) * 1987-03-16 1989-02-15 Enichem Sintesi Composizione liquida polimerizzabile per la produzione di articoli ottici ad elevato indice di rifrazione
JPH01103613A (ja) * 1987-10-15 1989-04-20 Daiso Co Ltd 光学用有機ガラス

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040021842A (ko) * 2002-09-05 2004-03-11 (주) 그린페이퍼텍 천연 쑥 향과 고농축 약쑥액을 함유하는 미용용지 및 이의제조방법
US8097190B2 (en) 2006-09-06 2012-01-17 Koc Solution Co., Ltd. Optical resin composition having excellent impact resistance and method for fabricating optical lens using the same

Also Published As

Publication number Publication date
JP2592010B2 (ja) 1997-03-19
KR100187566B1 (ko) 1999-06-01
DE69111714T2 (de) 1996-04-25
US5218067A (en) 1993-06-08
JPH04100001A (ja) 1992-04-02
DE69111714D1 (de) 1995-09-07
EP0472168A1 (en) 1992-02-26
EP0472168B1 (en) 1995-08-02

Similar Documents

Publication Publication Date Title
KR920004464A (ko) 알릴에스테르 올리고머 조성물 및 이들로 이루어진 광학재료용 유기 글라스
PT915926E (pt) Processo aperfeicoado para preparacao de poliesteres de elevado peso molecular
KR100284388B1 (ko) 광학재료용 조성물
KR950704395A (ko) 열경화성 피복 조성물(thermosetting coating compositions)
CA2366515A1 (en) Process for esterifying 1,3-propanediol
ATA132697A (de) Neue acrylatpolymerisate, deren grundlage polyesterharze oder polyester-oligomere sind, deren herstellung und verwendung in beschichtungsmitteln
KR920006402A (ko) 연쇄 정지된 불포화 폴리에스테르 수지
KR910015616A (ko) 폴리(1,3-프로필렌테레프탈레이트) 경질 단편을 갖는 코폴리에테르에스테르 탄성중합체
KR930010083A (ko) 내연성 저필링 폴리에스테르 및 그의 제조 방법
US3639352A (en) Polyesters of improved dyeability and light fastness
GB1026993A (en) Polyester compositions for bonding glass fibre mats
KR950014173A (ko) 지방족 공중합 폴리에스터를 이용한 필름의 제조방법
Parker Unsaturated polyesters
CA1241141A (en) Storable, low shrinkage, curable unsaturated polyester resins
CA1149545A (en) Styrene suppressed unsaturated polyester resin compositions
EP0355596A3 (de) Kälteschlagzähe thermoplastische Polyesterformmassen
KR900009277A (ko) 접착성이 낮은 유리섬유로 충전된 폴리에스테르수지
US3261886A (en) Liquid polyester compositions containing a major amount of methyl methacrylate
KR890014676A (ko) 난연성 할로겐화 폴리에스테르 수지 조성물 및 그것으로 피복한 전선
KR920002684A (ko) 내연성 폴리올레핀계 섬유 및 필름
KR900003289A (ko) 할로겐함유 폴리에스테르수지 조성물과 전선
KR910004740A (ko) 감소된 물 흡수성을 갖는 신규 폴리에스테르수지 조성물
JPS5643321A (en) Improved production process of modified polyester
KR920001215A (ko) 광학재료
KR970061958A (ko) 폴리에스테르 수지계를 위한 비대칭 글리콜 및 방향족 이가산 기재의 저 프로필 첨가제

Legal Events

Date Code Title Description
A201 Request for examination
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
J206 Request for trial to confirm the scope of a patent right
J206 Request for trial to confirm the scope of a patent right
J204 Request for invalidation trial [patent]
J206 Request for trial to confirm the scope of a patent right
J301 Trial decision

Free format text: TRIAL DECISION FOR CONFIRMATION OF THE SCOPE OF RIGHT_DEFENSIVE REQUESTED 20010317

Effective date: 20011228

Free format text: TRIAL DECISION FOR CONFIRMATION OF THE SCOPE OF RIGHT_DEFENSIVE REQUESTED 20010316

Effective date: 20011228

J204 Request for invalidation trial [patent]
J2X1 Appeal (before the patent court)

Free format text: CONFIRMATION OF THE SCOPE OF RIGHT_DEFENSIVE

J2X2 Appeal (before the supreme court)

Free format text: APPEAL BEFORE THE SUPREME COURT FOR CONFIRMATION OF THE SCOPE OF RIGHT_DEFENSIVE

J301 Trial decision

Free format text: TRIAL DECISION FOR CONFIRMATION OF THE SCOPE OF RIGHT_DEFENSIVE REQUESTED 20011127

Effective date: 20030610

Free format text: TRIAL DECISION FOR INVALIDATION REQUESTED 20011127

Effective date: 20030610

J2X1 Appeal (before the patent court)

Free format text: CONFIRMATION OF THE SCOPE OF RIGHT_DEFENSIVE

J2X1 Appeal (before the patent court)

Free format text: INVALIDATION

J202 Request for trial for correction [limitation]
J301 Trial decision

Free format text: TRIAL DECISION FOR CORRECTION REQUESTED 20031106

Effective date: 20040728

J203 Request for trial for invalidation of correction [invalidation of limitation]

Free format text: TRIAL FOR INVALIDATION OF CORRECTION FOR INVALIDATION OF CORRECTION

J203 Request for trial for invalidation of correction [invalidation of limitation]

Free format text: TRIAL FOR INVALIDATION OF CORRECTION FOR INVALIDATION OF CORRECTION

J222 Remand (patent court)

Free format text: REMAND (PATENT COURT) FOR CONFIRMATION OF THE SCOPE OF RIGHT_DEFENSIVE

J302 Written judgement (patent court)

Free format text: JUDGMENT (PATENT COURT) FOR CONFIRMATION OF THE SCOPE OF RIGHT_DEFENSIVE REQUESTED 20020131

Effective date: 20021114

J303 Written judgement (supreme court)

Free format text: JUDGMENT (SUPREME COURT) FOR CONFIRMATION OF THE SCOPE OF RIGHT_DEFENSIVE REQUESTED 20021205

Effective date: 20050113

J301 Trial decision

Free format text: TRIAL DECISION FOR INVALIDATION OF CORRECTION REQUESTED 20040907

Effective date: 20050228

Free format text: TRIAL DECISION FOR INVALIDATION OF CORRECTION REQUESTED 20041015

Effective date: 20050228

J2X1 Appeal (before the patent court)

Free format text: INVALIDATION OF CORRECTION

EXTG Ip right invalidated
J302 Written judgement (patent court)

Free format text: JUDGMENT (PATENT COURT) FOR CONFIRMATION OF THE SCOPE OF RIGHT_DEFENSIVE REQUESTED 20050113

Effective date: 20051028

Free format text: JUDGMENT (PATENT COURT) FOR CONFIRMATION OF THE SCOPE OF RIGHT_DEFENSIVE REQUESTED 20030710

Effective date: 20051028

Free format text: JUDGMENT (PATENT COURT) FOR INVALIDATION OF CORRECTION REQUESTED 20050330

Effective date: 20051028

J302 Written judgement (patent court)

Free format text: JUDGMENT (PATENT COURT) FOR INVALIDATION REQUESTED 20030712

Effective date: 20051028

J301 Trial decision

Free format text: TRIAL DECISION FOR CONFIRMATION OF THE SCOPE OF RIGHT_DEFENSIVE REQUESTED 20071005

Effective date: 20071031

Free format text: TRIAL DECISION FOR INVALIDATION OF CORRECTION REQUESTED 20071005

Effective date: 20071031