KR920004326A - 트리사이클로[5.2.1.0.^2.6] decan-8(g)-one의 조제방법 - Google Patents
트리사이클로[5.2.1.0.^2.6] decan-8(g)-one의 조제방법 Download PDFInfo
- Publication number
- KR920004326A KR920004326A KR1019910013467A KR910013467A KR920004326A KR 920004326 A KR920004326 A KR 920004326A KR 1019910013467 A KR1019910013467 A KR 1019910013467A KR 910013467 A KR910013467 A KR 910013467A KR 920004326 A KR920004326 A KR 920004326A
- Authority
- KR
- South Korea
- Prior art keywords
- catalyst
- diatomaceous earth
- mpa
- suitably
- producing
- Prior art date
Links
- 238000002360 preparation method Methods 0.000 title 1
- 239000003054 catalyst Substances 0.000 claims 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 7
- 238000000034 method Methods 0.000 claims 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 5
- 239000005909 Kieselgur Substances 0.000 claims 4
- 229910052759 nickel Inorganic materials 0.000 claims 4
- 238000012423 maintenance Methods 0.000 claims 3
- NJXPYZHXZZCTNI-UHFFFAOYSA-N 3-aminobenzonitrile Chemical compound NC1=CC=CC(C#N)=C1 NJXPYZHXZZCTNI-UHFFFAOYSA-N 0.000 claims 2
- 229910004298 SiO 2 Inorganic materials 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 2
- 229910052749 magnesium Inorganic materials 0.000 claims 2
- 239000011777 magnesium Substances 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical class [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims 1
- 239000000378 calcium silicate Substances 0.000 claims 1
- 229910052918 calcium silicate Inorganic materials 0.000 claims 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims 1
- ZADYMNAVLSWLEQ-UHFFFAOYSA-N magnesium;oxygen(2-);silicon(4+) Chemical class [O-2].[O-2].[O-2].[Mg+2].[Si+4] ZADYMNAVLSWLEQ-UHFFFAOYSA-N 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 229910000480 nickel oxide Inorganic materials 0.000 claims 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/511—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/385—Saturated compounds containing a keto group being part of a ring
- C07C49/417—Saturated compounds containing a keto group being part of a ring polycyclic
- C07C49/423—Saturated compounds containing a keto group being part of a ring polycyclic a keto group being part of a condensed ring system
- C07C49/453—Saturated compounds containing a keto group being part of a ring polycyclic a keto group being part of a condensed ring system having three rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2603/00—Systems containing at least three condensed rings
- C07C2603/56—Ring systems containing bridged rings
- C07C2603/58—Ring systems containing bridged rings containing three rings
- C07C2603/60—Ring systems containing bridged rings containing three rings containing at least one ring with less than six members
- C07C2603/66—Ring systems containing bridged rings containing three rings containing at least one ring with less than six members containing five-membered rings
- C07C2603/68—Dicyclopentadienes; Hydrogenated dicyclopentadienes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Liquid Crystal Substances (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (6)
- 기온, 기압하에 산화 니켈 및 마그네슘을 포함하여, 그 질량비가 (0.0075~0.075) : 1이고 니켈의 몰(MOLE)당 비수용성 유지 촉매가 17.0~60.0그램이 되고, 활성니켈 금속면의 표면적은 니켈의 110~180m2/g이어야 하며, BET전체를 면적의 65~97%는 반경 rp〈2.5mm을 갖는 유지 촉매(suppated catalyst)에 의해서 8(9)-히드록시 트리시크로 [5.2.1.02.6]테-3-켄을 전환함으로서 트리시클로[5.2.1.02.6]테카-8(9)-논을 특징으로 하는 제조 방법.
- 제1항에 있어서, 유지촉매제의 BET전 표면적은 160~450m2/g촉매, 특히 180~380m2/g촉매, 적절하게는 200~350m2/g촉매, 적절하게는 200~350m2/g촉매를 특징으로 하는 제조방법.
- 제1항 또는 제2항에 있어서, 몰비가 (0.015~0.06) : 1, 특히 (0.022~0.055) : 1인 Mg와 Ni를 갖는 지지촉매제의 제조방법.
- 제1항 또는 제2항에 있어서, 한항 또는 여러항에서, 유지제로서 규산 칼슘형, 규산 마그네슘염, 규산 알루미늄염, A1203, Si02 및/또는 규조토 특히 A1203, SiO2및/또는 규조토 적절하게는 SiO2및/또는 규조토 그리고 아주 적절한 규조토를 갖는 유지촉매제의 제조방법.
- 제1항 또는 제2항에 있어서, 한항 또는 여러항에서 전환이 150~300℃, 특히 180~280℃, 적절하게는 200~260℃에서 수행되는 유지촉매제는 제조방법.
- 제1항 또는 제2항에 있어서, 한항 또는 여러항에서 전환이 압력 0.1~1MPa, 특히 0.15~0.8MPa, 적절하게는 0.15~0.6MPa에서 수행하는 유지촉매제의 제조방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP4025526.3 | 1990-08-11 | ||
DE4025526A DE4025526A1 (de) | 1990-08-11 | 1990-08-11 | Verfahren zur herstellung von tricyclo (5.2.1.0(pfeil hoch)2(pfeil hoch)(pfeil hoch),(pfeil hoch)(pfeil hoch)6(pfeil hoch))decan-8(9)-on |
Publications (2)
Publication Number | Publication Date |
---|---|
KR920004326A true KR920004326A (ko) | 1992-03-27 |
KR950003330B1 KR950003330B1 (ko) | 1995-04-10 |
Family
ID=6412092
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019910013467A KR950003330B1 (ko) | 1990-08-11 | 1991-08-03 | 트리사이클로[5.2.1.0^2.6] decan-8(9)-one의 제조방법. |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0471227B1 (ko) |
JP (1) | JPH0672117B2 (ko) |
KR (1) | KR950003330B1 (ko) |
AT (1) | ATE101112T1 (ko) |
DE (2) | DE4025526A1 (ko) |
DK (1) | DK0471227T3 (ko) |
ES (1) | ES2063415T3 (ko) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102005026793B3 (de) * | 2005-06-10 | 2007-04-26 | Celanese Chemicals Europe Gmbh | Verfahren zur Herstellung alicyclischer, gesättigter Ketone aus alicyclischen, ungesättigten, sekundären Alkoholen |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE953076C (de) * | 1953-05-09 | 1956-11-29 | Ruhrchemie Ag | Verfahren zur Umlagerung von 8-Oxytricyclodecen-(4) in 8-Ketotricyclodekan |
-
1990
- 1990-08-11 DE DE4025526A patent/DE4025526A1/de not_active Withdrawn
-
1991
- 1991-07-26 DE DE91112560T patent/DE59100990D1/de not_active Expired - Fee Related
- 1991-07-26 AT AT91112560T patent/ATE101112T1/de not_active IP Right Cessation
- 1991-07-26 ES ES91112560T patent/ES2063415T3/es not_active Expired - Lifetime
- 1991-07-26 DK DK91112560.7T patent/DK0471227T3/da active
- 1991-07-26 EP EP91112560A patent/EP0471227B1/de not_active Expired - Lifetime
- 1991-08-03 KR KR1019910013467A patent/KR950003330B1/ko not_active IP Right Cessation
- 1991-08-06 JP JP3196702A patent/JPH0672117B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DK0471227T3 (da) | 1994-03-14 |
EP0471227A1 (de) | 1992-02-19 |
DE59100990D1 (de) | 1994-03-17 |
JPH04279543A (ja) | 1992-10-05 |
DE4025526A1 (de) | 1992-02-13 |
JPH0672117B2 (ja) | 1994-09-14 |
EP0471227B1 (de) | 1994-02-02 |
KR950003330B1 (ko) | 1995-04-10 |
ES2063415T3 (es) | 1995-01-01 |
ATE101112T1 (de) | 1994-02-15 |
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A201 | Request for examination | ||
E902 | Notification of reason for refusal | ||
G160 | Decision to publish patent application | ||
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant | ||
FPAY | Annual fee payment |
Payment date: 20000307 Year of fee payment: 6 |
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LAPS | Lapse due to unpaid annual fee |