KR920000877A - 자외선-경화성 실리콘 조성물 - Google Patents

자외선-경화성 실리콘 조성물 Download PDF

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KR920000877A
KR920000877A KR1019910010755A KR910010755A KR920000877A KR 920000877 A KR920000877 A KR 920000877A KR 1019910010755 A KR1019910010755 A KR 1019910010755A KR 910010755 A KR910010755 A KR 910010755A KR 920000877 A KR920000877 A KR 920000877A
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silicone composition
curable silicone
ultraviolet
sio
epoxy
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KR1019910010755A
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KR0184886B1 (ko
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게이지 고바야시
가츠야 가네마루
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이치세 야요이
도시바실리콘 가부시키가이샤
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C08L83/06—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C09D183/06—Polysiloxanes containing silicon bound to oxygen-containing groups

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Epoxy Resins (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Silicon Polymers (AREA)
  • Adhesive Tapes (AREA)
  • Laminated Bodies (AREA)

Abstract

내용 없음

Description

자외선-경화성 실리콘 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. (A)일반식 R1R2SiO[여기서, R1은 수소 원자 또는 일가 탄화수소 그룹이고, R2는 수소 원자, 일가 탄화수소 그룹 또는 일가의 에폭시-관능성 유기그룹(여기서, 모든 유기 그룹들중 두개 이상은 일가의 에폭시-관능성 유기 그룹이다)이다]의 구조 단위를 포함하는 에폭시-관능성 폴리오르가노실옥산 100중량부; (B)(i) MQ[여기서, M은 R3 3SiO1/2단위 (여기서, R3은 알케닐 그룹을 함유하지 않는 일가 탄화수소 그룹이다)이고 Q는 SiO2단위이다] 또는 MAQ[여기서, MA는 R3R4SiO1/2 단위(여기서, R3은 상기한 바와 같고, R4는 알케닐 그룹이다)이고 Q는 상기한 바와 같다]의 단위 구조를 갖는 공중합체, (ⅱ)MAT[여기서, MA는 상기한 바와 같고 T는 R3SiO3/2단위(여기서, R3은 상기한 바와 같다)이다], MTA[여기서, M은 상기한 바와 같고 TA는 R4SiO3/2단위(여기서, R4는 상기한 바와 같다)이다], MTA(여기서, MATA는 상기한 바와같다)의 단위 구조를 갖는 공중합체, 및 (ⅲ)MADQ[여기서, MA및 Q는 상기한 바와같고 D는 R3 2SiO 단위(여기서, R3은 상기한 바와 같다)이다]또는 MDAQ[여기서, M및 Q는 상기한 바와 같고 DA는 R3R4SiO 단위 (여기서, R3및 R4는 상기한 바와 같다)이다]또는 MADAQ(여기서, MA, DA및 Q는 상기한 바와 같다)의 단위 구조를 갖는 공중합체 중에서 선택된, 상기 성분(A)에 가용성인, 하나 이상의 박리도 조절용 공중합체 1내지 80중량부; 및
    (C) 광개시제로서의 오늄염 촉매적-유효량을 포함하는 자외선-경화성 실리콘 조성물.
  2. 제1항에 있어서, 에폭시-관능성 폴리오르가노실옥산(A)중의 모든 유기 그룹의 1내지 20몰%가 에폭시-관능성 유기 그룹인 자외선-경화성 실리콘 조성물.
  3. 제1항에 있어서, 에폭시-관능성 폴리오르가노실옥산(A)중의 에폭시-관능성 유기 그룹 이외의 유기 그룹이 메틸 또는 페닐인 자외선-경화성 실리콘 조성물.
  4. 제1항에 있어서, 발리도 조절용 공중합체(B)의 단위들 중 M또는 MA의 함량이 25 내지 70몰%인 자외선-경화성 실리콘 조성물.
  5. 제1항에 있어서, 박리도 조절용 공중합체(B)의 단위들중 D 또는 DA의 함량이 50몰%이하인 자외선-경화성 실리콘 조성물.
  6. 제1항에 있어서, 박리도 조절용 공중합체(B)가 R4로 표시되는 알케닐 그룹을 함유하는 자외선-경화성 실리콘 조성물.
  7. 제6항에 있어서, R4로 표시되는 알케닐 그룹이 비닐인 자외선-경화성 실리콘 조성물.
  8. 제1항에 있어서, 박리도 조절용 공중합체(B)에서, 알케닐 그룹을 함유하지 않으며 R3으로 표시되는 일가탄화수소 그룹이 메틸 또는 페닐인 자외선-경화성 실리콘 조성물.
  9. 제1항에 있어서, 광개시제(C)가 일반식 R5 2I+MXn-,R5 3S+MXn-,R5 3Se+MXn-,R5 4P+MXn- 또는 R5 4N+MXn-(여기서, R5는 방향족 탄화수소 그룹이고 MXn-는 BF4-,PF6-,AsF6-,SbF6-,SbCl6-,HSO4- 및 ClO4-중에서 선택된 음이온이다)의 오늄염인 자외선-경화성 실리콘 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910010755A 1990-06-29 1991-06-27 자외선-경화성 실리콘 조성물 KR0184886B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP90-169768 1990-06-29
JP16976890 1990-06-29
JP91-142538 1991-05-18
JP3142538A JP2712093B2 (ja) 1990-06-29 1991-05-18 紫外線硬化性シリコーン組成物

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KR920000877A true KR920000877A (ko) 1992-01-29
KR0184886B1 KR0184886B1 (ko) 1999-05-15

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US (1) US5198476A (ko)
EP (1) EP0464706B1 (ko)
JP (1) JP2712093B2 (ko)
KR (1) KR0184886B1 (ko)
DE (1) DE69112515T2 (ko)

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Publication number Publication date
KR0184886B1 (ko) 1999-05-15
EP0464706B1 (en) 1995-08-30
JP2712093B2 (ja) 1998-02-10
DE69112515D1 (de) 1995-10-05
EP0464706A1 (en) 1992-01-08
JPH04226120A (ja) 1992-08-14
US5198476A (en) 1993-03-30
DE69112515T2 (de) 1996-03-21

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