KR900004481A - Method for producing a composite structure of a site-forming compound and a thermoplastic polymer - Google Patents

Method for producing a composite structure of a site-forming compound and a thermoplastic polymer Download PDF

Info

Publication number
KR900004481A
KR900004481A KR1019890013864A KR890013864A KR900004481A KR 900004481 A KR900004481 A KR 900004481A KR 1019890013864 A KR1019890013864 A KR 1019890013864A KR 890013864 A KR890013864 A KR 890013864A KR 900004481 A KR900004481 A KR 900004481A
Authority
KR
South Korea
Prior art keywords
sheet
thermoplastic
layer
weight
polymer
Prior art date
Application number
KR1019890013864A
Other languages
Korean (ko)
Other versions
KR0151850B1 (en
Inventor
로우버셰어 프랭크
엘 스페인 패트릭
에이 팔싱 로저
Original Assignee
이 아이 듀우판 디 네모아 앤드 캄파니
에이베리 인터내쇼날 캄파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 이 아이 듀우판 디 네모아 앤드 캄파니, 에이베리 인터내쇼날 캄파니 filed Critical 이 아이 듀우판 디 네모아 앤드 캄파니
Publication of KR900004481A publication Critical patent/KR900004481A/en
Application granted granted Critical
Publication of KR0151850B1 publication Critical patent/KR0151850B1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
    • B29C51/12—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor of articles having inserts or reinforcements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
    • B29C51/16—Lining or labelling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06—Fibrous reinforcements only
    • B29C70/08—Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers
    • B29C70/086—Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers and with one or more layers of pure plastics material, e.g. foam layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/40—Shaping or impregnating by compression not applied
    • B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/46—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
    • B29C37/0025—Applying surface layers, e.g. coatings, decorative layers, printed layers, to articles during shaping, e.g. in-mould printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
    • B29K2995/0022—Bright, glossy or shiny surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2367/00—Polyesters, e.g. PET, i.e. polyethylene terephthalate

Abstract

내용 없음No content

Description

사이트 성형 화합물 및 열가소성 중합체의 복합체 구조물의 제조방법Method for producing a composite structure of a site-forming compound and a thermoplastic polymer

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

제1도는 SMC1의 두꺼운 단단한 층에 결합된 열성형 열가소성 시이트(2)의 복합체 구조물의 횡단면을 보여준다.1 shows a cross section of a composite structure of thermoformed thermoplastic sheet 2 bonded to a thick rigid layer of SMC1.

제4도는 폴리에스테르 필름 상의 페인트의 롤러 피복 및 열성형 가능한 라미네이트 또는 표면판의 형성을 보여준다.Figure 4 shows the roller coating of paint on a polyester film and the formation of thermoformable laminates or surface plates.

제5도는 표면 판으로부터 복합체 구조물을 제조하는 방법을 보여준다.5 shows a method of making a composite structure from a surface plate.

Claims (50)

a. 하기 단계(e)의 성형 온도 보다 적어도 10℃ 높은 일차 유리전이 온도를 갖는 열가소성 중합체 시이트를 삼차원 열성형 구조물로 열성형시키고; b. 삼차원 열성형 구조에 상당하는 형태를 갖는 다이중 하나로 금형 캐비티(cavity)를 규정하도록 돕는 성형 표면과 마주하는 상부다이와 하부다이를 갖는 금형을 열고; c. 다이중 하나의 성형 표면상에 시이트 성형 화합물(SMC)의 충전물과 단계 a의 열성형된 구조물을 넣고; d. 금형강을 채우도록 다이가 충전물을 압축시키도록 금형을 밀폐하고, e. 열성형 구조물에 SMC가 부착 하도록 열 및 압력하에 열성형된 구조물과 충전물을 성형시키고(여기서 금형의 가열은 열가소성 중합체 시이트의 유리전이 온도보다 적어도 10℃ 아래임); f. 다이를 열고 SMC에 견고하게 부착된 열성형된 구조물을 갖는 결과 복합 구조물을 제거시키는 단계로 구성된 열가소성 중합체 표면을 갖는 강성 복합체 구조물을 제조하는 방법.a. Thermoforming a thermoplastic polymer sheet having a primary glass transition temperature at least 10 ° C. above the forming temperature of step (e) into a three-dimensional thermoformed structure; b. Opening a mold having an upper die and a lower die facing the forming surface to help define a mold cavity with one of the dies having a shape corresponding to a three-dimensional thermoforming structure; c. Putting a charge of sheet forming compound (SMC) and the thermoformed structure of step a on the forming surface of one of the dies; d. Seal the mold so that the die compresses the filling to fill the mold steel, e. Forming the thermoformed structure and the filler under heat and pressure to attach the SMC to the thermoformed structure, wherein the heating of the mold is at least 10 ° C. below the glass transition temperature of the thermoplastic polymer sheet; f. A method of making a rigid composite structure having a thermoplastic polymer surface consisting of opening a die and removing the resulting composite structure having a thermoformed structure firmly attached to the SMC. 제1항에 있어서, 열가소성 중합체 시이트가 약 125-1000 미크론 두께이며, SMC가 약 1500-7500 미크론 두께이며 열가소성 중합체 시이트가 145℃ 이상의 일차 유리전이 온도를 가지며, 단계 e에서의 성형이 약 3-15MPa의 압력하에 약 135-160℃에서 수행되는 방법.The process of claim 1 wherein the thermoplastic polymer sheet is about 125-1000 microns thick, the SMC is about 1500-7500 microns thick and the thermoplastic polymer sheet has a primary glass transition temperature of at least 145 ° C. and the molding in step e is about 3- The process is carried out at about 135-160 ° C under a pressure of 15 MPa. 제2항에 있어서, SMC 충전물이 다이의 성형 표면의 40-80%를 덮는 방법.The method of claim 2, wherein the SMC charge covers 40-80% of the forming surface of the die. 제2항에 있어서, 열가소성 중합체 시이트가 약 190-235℃에서 진공하에 3기압까지의 프레셔 어시스트(pressure assist)를 사용하여 열성형되는 방법.The method of claim 2, wherein the thermoplastic polymer sheet is thermoformed using pressure assist up to 3 atmospheres under vacuum at about 190-235 ° C. 4. 제2항에 있어서, 열가소성 중합체 시이트가 폴리아릴레이트를 포함하는 방법.The method of claim 2, wherein the thermoplastic polymer sheet comprises polyarylate. 제5항에 있어서, 폴리아릴레이트가 적어도 하나의 이가 페놀 및 적어도 하나의 디카르복실산으로 구성된 방법.The method of claim 5 wherein the polyarylate consists of at least one divalent phenol and at least one dicarboxylic acid. 제6항에 있어서, 폴리아릴레이트가 이소프탈산, 테레프탈산 또는 이들의 혼합물로 구성된 군으로부터 선택된 방향족 디카르복실산과 2,2-비스(4-히드록시페닐) 프로판의 중합 생성물로 구성되는 방법.7. The process of claim 6, wherein the polyarylate consists of a polymerization product of 2,2-bis (4-hydroxyphenyl) propane with an aromatic dicarboxylic acid selected from the group consisting of isophthalic acid, terephthalic acid or mixtures thereof. 제7항에 있어서, 폴리아릴레이트가 에폭시 관능성을 갖는 올레핀 중합체를 함유하고, 하기(a)∼(c) 단량체의 중합 생성물로 구성된 방법; (a) 올레핀 중합체의 중량을 기준으로 약 0.5-15% 중량의 CH₂= C(R) COOCH₂ CH CH₂O.(여기서 R은 H 또는 1-6개의 탄소 원자를 갖는 알킬기임), (b) 올레핀 중합체의 중량을 기준으로 약 45-99%중량의 CH₂=CHR.(여기서 R은 H 또는 저급 알킬기임), (c) 올레핀 중합체의 중량을 기준으로 약 0.1-40%중량의 CH₂=C(R′)COOR²,(여기서 R¹은 H 또는 저급 알킬이며, R²는 1-8개의 탄소 원자를 갖는 알킬기임).8. The process according to claim 7, wherein the polyarylate contains an olefin polymer having epoxy functionality and is composed of a polymerization product of the following monomers (a) to (c); (a) about 0.5-15% by weight of CH 2 = C (R) COOCH₂ CH CH2O. wherein R is H or an alkyl group having 1-6 carbon atoms), (b) an olefin polymer About 45-99% by weight of CH 2 = CHR, wherein R is H or a lower alkyl group, (c) about 0.1-40% by weight of CH 2 = C (R ′) based on the weight of the olefin polymer ) COOR², where R¹ is H or lower alkyl and R² is an alkyl group having 1-8 carbon atoms. 제8항에 있어서, 단량체가 (a) 글리시딜 메타크릴레이트, (b) 에틸렌 및 (c) 부틸 아크릴레이트로 구성되는 방법.The method of claim 8, wherein the monomers consist of (a) glycidyl methacrylate, (b) ethylene and (c) butyl acrylate. 제8항에 있어서, 폴리아릴레이트가 15%중량 이상의 적어도 하나의 스티렌 및 알파 메틸 스티렌과 적어도 하나의 아크릴로니트릴과 메타크릴로니트릴의 공중합체를 함유하는 방법.The method of claim 8, wherein the polyarylate contains at least 15% by weight of at least one styrene and an alpha methyl styrene and a copolymer of at least one acrylonitrile and methacrylonitrile. 제10항에 있어서, 공중합체가 필수적으로스티렌과 아크릴로니트릴로 구성되는 방법.The method of claim 10, wherein the copolymer consists essentially of styrene and acrylonitrile. 제3항에 있어서, SMC가 중합가능한 단량체, 충전제 안료 및 유리 섬유와 함께 폴리에스테르 수지로 구성되는 방법.4. The process of claim 3 wherein the SMC consists of a polyester resin with polymerizable monomers, filler pigments and glass fibers. 제12항에 있어서, SMC가 30%중량 이상의 유리 섬유를 함유하는 방법.13. The method of claim 12, wherein the SMC contains at least 30% by weight glass fibers. 제12항에 있어서, 폴리에스테르 수지가 필수적으로 지방족 및 방향족 이무수물 또는 산 및 알킬렌 글리콜의 산 말단 폴리에스테로 구성되고 단량체가 스티렌, 알파 메틸 스티렌 또는 이들의 혼합물인 방법.13. The process of claim 12 wherein the polyester resin consists essentially of aliphatic and aromatic dianhydrides or acid terminated polyesters of acids and alkylene glycols and the monomers are styrene, alpha methyl styrene or mixtures thereof. 제14항에 있어서 폴리에스테르가 필수적으로 프로필렌 글리콜, 이소프탈산과 말레산 무수물로 구성되고 단량체가 스티렌이며 폴리에스테르가 산화 마그네숨, 수산화 마그네숨 또는 탄산 마그네숨과 반응되며 충전제 안료가 탄산 칼슘인 방법.15. The process of claim 14 wherein the polyester consists essentially of propylene glycol, isophthalic acid and maleic anhydride, the monomer is styrene, the polyester is reacted with magnesium oxide, magnesium hydroxide or magnesium carbonate and the filler pigment is calcium carbonate . 제15항에 있어서, SMC가 15%중량 이하의 고 분자량 열가소성 주지로 구성된 낮은 프로파일 첨가제를 함유하는 방법.16. The method of claim 15, wherein the SMC contains a low profile additive composed of up to 15% weight high molecular weight thermoplastics. 제2항에 있어서, 열가소성 중합체 시이트가 SMC와 접촉하게 하는 적어도 하나의 사이즈 층으로 피복되며 사이즈는 폴리우레탄, 아크릴로니트릴/부타디엔/스티렌 삼원 공중합체, 스티렌/아크릴로니트릴 중합체 및 폴리스티렌으로 구성된 군으로부터 선택되는 방법.The group of claim 2 wherein the thermoplastic polymer sheet is covered with at least one size layer that makes contact with the SMC and the size is comprised of polyurethane, acrylonitrile / butadiene / styrene terpolymer, styrene / acrylonitrile polymer, and polystyrene. Selected from. 제17항에 있어서, 열가소성 중합체 시이트 물질이 폴리아릴레이트 또는 폴리(2, 6디메틸 페닐렌 옥사이드)로 개질된 폴리아미드로 구성되고 사이즈 층이 폴리우레탄으로 구성되는 방법.18. The method of claim 17, wherein the thermoplastic polymer sheet material consists of polyamide modified with polyarylate or poly (2, 6dimethyl phenylene oxide) and the size layer consists of polyurethane. 제17항에 있어서, 열가소성 중하체 시이트가 폴리에테르 술파논으로 구성되는 방법.18. The method of claim 17, wherein the thermoplastic neutral sheet is composed of polyether sulfanone. 제2항에 있어서, 열가소성 중합체 시이트가 색상을 갖는 복합체를 제공하기에 충분한 안료를 함유하는 방법.The method of claim 2 wherein the thermoplastic polymer sheet contains sufficient pigment to provide a composite having color. 제2항에 있어서, 열가소성 폴리에스테르 시이트가 SMC시이트와 접촉하지 않는 면에서 거기에 견고히 부착된 페인트와 페인트층에 부착된 광택있는 투명한 열가소성 피니쉬 층을 함유하는 열가소성 안료층을 가지고; 이 때 열가소성 중합체 피복 조성물의 투명층을 매끄러운 광택 표면을 갖는 유연한 중합체 운반 시이트에 적용시키고 상기 투명층에 적용시키고 나서 라미네이트를 형성하기 위해 열성형가능한 중합체 물질에 부착된 착색층에서 건조시킨 투명층에 적용시키고 나서 라미네이트를 형성화기 위해 열성형가능한 중합체 물질에 부착된 착색 층에서 유래한 열성형가능한 열가소성 중합체 물질에 투명층과 착색층을 갖는 유연한 중합체 운반시이트를 열과 압력으로 라미네이팅시킨 후 시이트를 제거하고; 투명층의 외부 표면이 중합체 운반 시이트로부터 이것에 운반된 광택 표면을 보유하는 방법.3. The thermoplastic pigment sheet of claim 2, wherein the thermoplastic polyester sheet has a thermoplastic pigment layer containing paint firmly attached thereto in contact with the SMC sheet and a glossy transparent thermoplastic finish layer attached to the paint layer; The transparent layer of the thermoplastic polymer coating composition was then applied to a flexible polymer conveying sheet having a smooth glossy surface and then applied to the transparent layer and then to the transparent layer dried on a colored layer attached to a thermoformable polymeric material to form a laminate. Laminating a flexible polymer carrier sheet having a transparent layer and a colored layer with heat and pressure to the thermoformable thermoplastic polymer material derived from the colored layer attached to the thermoformable polymeric material to form the laminate, followed by removal of the sheet; Wherein the outer surface of the clear layer retains a glossy surface carried therefrom from the polymer transport sheet. 제21항에 있어서, 페인트 및 투명 열가소성 피니쉬가 폴리비닐 플루오라이드, 폴리비닐리덴 플루오라이드 또는 폴리메틸 메타크릴레이트 또는 폴리에틸 메타크릴레이트와 폴리비닐리덴 플루오라이드의 블렌드로 이루어진 군으로부터 선택된 결합제를 갖는 방법.The method of claim 21 wherein the paint and the transparent thermoplastic finish have a binder selected from the group consisting of polyvinyl fluoride, polyvinylidene fluoride or polymethyl methacrylate or a blend of polyethyl methacrylate and polyvinylidene fluoride. Way. 제2항에 있어서, 열가소성 폴리에스테르 시이트가 SMC시이트와 접촉하지 않는 면에서 거기에 견고히 부착된 페인트를 함유하는 열가소성 안료 층을 가지고; 이 때, 착색된 페인트 층을 매끄러운 광택 표면을 갖고 상기층을 건조시키는 유연한 중합체 운반시이트에 적용시키고 착색된 페인트 층을 상기 착색 층을 건조시킨 투명층에 적용시키고 나서 라미네이트를 형성하기 위해 열성형가능한 중합체 물질에 부착된 착색 층에서 유래한 열성형 가능한 열가소성 중합체 물질에 투명층과 착색층을 갖는 유연한 중합체 운반 시이트를 열과 압력으로 라미네이팅시킨 후 운반 시이트를 제거하고; 안료 함유 페이트 층의 외부 표면이 본질적으로 중합체 운반 시이트로부터 이것에 운반된 광택 표면을 함유하는 방법.3. The thermoplastic polyester sheet of claim 2, wherein the thermoplastic polyester sheet has a thermoplastic pigment layer containing a paint firmly attached thereto in that it is not in contact with the SMC sheet; At this time, the colored paint layer is applied to a flexible polymer carrier sheet having a smooth gloss surface and the layer is dried, and the colored paint layer is applied to the dried transparent layer and then the thermoformable polymer to form a laminate. Thermally and pressure laminating a flexible polymer transport sheet having a transparent layer and a colored layer on the thermoformable thermoplastic polymer material derived from the colored layer attached to the material, followed by removal of the transport sheet; And wherein the outer surface of the pigment containing pate layer essentially contains a glossy surface carried therefrom from the polymer transport sheet. 제23항에 있어서, 페인트가 폴리비닐 플루오라이드 폴리비닐리덴 풀루오라이드 또는 폴리비닐리덴 플루오라이드와 폴리메틸 메타크릴레이트 또는 폴리에틸 메타크릴레이트의 블렌드로 이루어진 군으로부터 선택된 결합제를 갖는 방법.The method of claim 23, wherein the paint has a binder selected from the group consisting of polyvinyl fluoride polyvinylidene fluoride or polyvinylidene fluoride and a blend of polymethyl methacrylate or polyethyl methacrylate. 제2항에 있어서, 적어도 2개의 성형 지역을 갖는 금형이 사용되며 적어도 2개의 열성형 구조물이 그 안에 형성되는 방법.The method of claim 2 wherein a mold having at least two forming zones is used and at least two thermoformed structures are formed therein. 제2항에 있어서, 전부 경화되기 전에 복합체 구조물이 금형으로부터 제거된 다음 부가적인 가열에 의하거나 방사선에 노출시킴으로써 복합체 구조물을 전부 경화시키는 방법.The method of claim 2, wherein the composite structure is removed from the mold before it is fully cured and then fully cured of the composite structure by additional heating or by exposure to radiation. a. 금형 캐비티(cavity)를 규정하도록 돕는 성형 표면과 마주하는 성형 표면과 마주하는 상부 다이와 하부 다이를 갖는 금형을 열고,; b. 다이 중 하나의 성형 표면상에 시이트 성형a. Opening a mold having an upper die and a lower die facing a forming surface facing a forming surface to help define a mold cavity; b. Sheet molding on the forming surface of one of the dies 화합물(SMC)의 충전물과 아래 단계(C)의 성형 온도보다 적어도 10℃ 높은 일차 유리 전이온도를 갖는 열가소성 중합체 시이트를 넣고; c. 금형 캐비티를 채우도록 다이가 충전물을 압축시키도록 금형을 밀폐하고; d. 열가소성 중합체 시이트에 SMC가 부착하도록 열시이트의 유리 전이온도 보다 적어도 10℃아래임); e. 다이를 열고 SMC에 견고하게 부착된 열가소성 중합체 시이트를 갖는 결과 복합 구조물을 제거시키는 단계로 구성된 열가소성 중합체 표면을 갖는 강성 복합체 구조물을 제조하는 방법.A charge of compound (SMC) and a thermoplastic polymer sheet having a primary glass transition temperature of at least 10 ° C. higher than the molding temperature of step (C) below; c. The mold is sealed such that the die compresses the filling to fill the mold cavity; d. At least 10 ° C. below the glass transition temperature of the thermal sheet so that the SMC adheres to the thermoplastic polymer sheet; e. A method of making a rigid composite structure having a thermoplastic polymer surface consisting of opening a die and removing the resulting composite structure having a thermoplastic polymer sheet firmly attached to the SMC. 제27항에 있어서, 열가소성 중합체 시이트가 약 125-1000 미크론 두께이며, SMC가 약 1500-7500 미크론 두께이며 열가소성 중합체 시이트가 145℃ 이상의 일차 유리 전이 온도를 가지며, 단계 d에서의 성형이 약 3-15MPa의 압력하에 약 135-160℃에서 수행되는 방법.The thermoplastic polymer sheet of claim 27, wherein the thermoplastic polymer sheet is about 125-1000 microns thick, the SMC is about 1500-7500 microns thick, and the thermoplastic polymer sheet has a primary glass transition temperature of at least 145 ° C., and the molding in step d is about 3- The process is carried out at about 135-160 ° C under a pressure of 15 MPa. a. 145℃ 이상의 일차 유리전이 온도를 갖는 열가소성 중합체 시이트를 삼차원 열성형 구조물로 열성형시키고; b. 사출 성형기 내에 열성형 구조물을 넣고 열 및 압력하에 열경화성 중합체 물질을 주입하고 상기 물질을 경화시켜서 물질을 열성형된 구조물의 한면에 접착시키고 사출 성형기로부터 결과 구조물을 제거시키는 단계로 구성된 매끄러운 표면을 갖는 장식 복합 구조물을 제조하는 방법.a. Thermoforming a thermoplastic polymer sheet having a primary glass transition temperature of at least 145 ° C. into a three-dimensional thermoformed structure; b. Decoration with a smooth surface consisting of placing a thermoformed structure in an injection molding machine, injecting a thermosetting polymer material under heat and pressure, curing the material to adhere the material to one side of the thermoformed structure and removing the resulting structure from the injection molding machine. Method of making a composite structure. a. 하기 b에 부착된, 145℃ 이상의 일차 유리 전이온도를 갖는 롤리아릴레이트 중합체로 구성된 열가소성 중합체의 유연한 시이트, b. 단량체로 중합된 롤리에스테르 수지로 구성되고 충전 안료 및 유리 섬유를 함유하는 시이트 성형 화합물(SMC)의 강성의 두꺼운 열경화 층으로 필수적으로 구성된 복합 시이트 구조물.a. A flexible sheet of thermoplastic polymer composed of a oliarylate polymer having a primary glass transition temperature of at least 145 ° C. attached to b, b. A composite sheet structure consisting essentially of a rigid polymer layer of a sheet forming compound (SMC) containing a filler pigment and glass fibers polymerized with a monomer of a rolled ester resin. 제30항에 있어서, 열가소성 중합체 시이트가 약 125-1000 미크론 두께이며 SMC가 약 1500-7500 미크론 두께인 복합 시이트 구조물.The composite sheet structure of claim 30, wherein the thermoplastic polymer sheet is about 125-1000 microns thick and the SMC is about 1500-7500 microns thick. 제31항에 있어서, 롤리아릴레이트가 적어도 하나의 이가 페놀 및 적어도 하나의 디카르복실산으로 구성된 복합시이트 구조물.32. The composite sheet structure of claim 31, wherein the rolyarylate consists of at least one dihydric phenol and at least one dicarboxylic acid. 제32항에 있어서, 폴리아릴레이트가 이소프탈산, 테레프탈산 또는 이들의 혼합물로 구성된 군으로부터 선택된 방향족 디카르복실산과 2,2-비스(4-히드록시페닐)프로판의 중합 생성물로 구성된 복합 시이트 구조물.33. The composite sheet structure of claim 32, wherein the polyarylate consists of a polymerization product of 2,2-bis (4-hydroxyphenyl) propane and an aromatic dicarboxylic acid selected from the group consisting of isophthalic acid, terephthalic acid or mixtures thereof. 제33항에 있어서, 폴리아릴레이트가 에폭시 관능성을 갖는 올레핀 중합체를 함유하고, 하기(a)-(c)단량체의 중합 생성물로 구성된 복합 시이트 구조물 : (a) 올레핀 중합체의 중량을 기준으로 약 0.5-15중량%의 CH₂=C(R)COOCH₂CH CH₂O(여기서 R은 H 또는 1-6개의 탄소 원자를 갖는 알킬기임), (b) 올레핀 중합체의 중량을 기준으로 약 45-99중량%의 CH₂=CHR(여기서 R은 H 또는 저급 알킬기임), (c) 올레핀 중합체의 중량을 기준으로 약 0.1-40중량%의 CH₂=C(R¹)COOR²(여기서 R¹은 H 또는 저급 알킬이며, R²는 1-8개의 탄소원자를 갖는 알킬기임).34. The composite sheet structure of claim 33, wherein the polyarylate contains an olefin polymer having epoxy functionality and is comprised of a polymerization product of (a)-(c) monomers: (a) about based on the weight of the olefin polymer 0.5-15 weight percent CH2 = C (R) COOCH₂CH CH2O, where R is H or an alkyl group having 1-6 carbon atoms, (b) about 45-99 weight percent CH₂ based on the weight of the olefin polymer = CHR (where R is H or lower alkyl), (c) about 0.1-40% by weight of CH2 = C (R¹) COOR², where R¹ is H or lower alkyl and R² is 1, based on the weight of the olefin polymer -An alkyl group having 8 carbon atoms. 제34항에 있어서, 단량체가 (a) 글리시딜 메타크릴레이트, (b) 에틸렌 및 (c) 부틸 아크릴레이트로 구성된 복합 시이트 구조물.35. The composite sheet structure of claim 34, wherein the monomers consist of (a) glycidyl methacrylate, (b) ethylene and (c) butyl acrylate. 제35항에 있어서, 폴리아릴레이트가 15중량%까지의 적어도 하나의 스티렌 및 알파 메틸 스티렌과 적어도 하나의 아크릴로이트릴 및 메타크릴로니트릴의 공중합체를 함유하는 복합 시이트 구조물.36. The composite sheet structure of claim 35, wherein the polyarylate contains up to 15% by weight of at least one styrene and alpha methyl styrene and a copolymer of at least one acrylonitrile and methacrylonitrile. 제36항에 있어서, 공중합체가 필수적으로 스티렌과 아크릴로니트릴로 구성된 복합 시이트 구조물.37. The composite sheet structure of claim 36, wherein the copolymer consists essentially of styrene and acrylonitrile. 제31항에 있어서, 열가소성 폴리에스테르가 필수적으로 (a) 2,2-비스(4-히드록시페닐)프로판 테레프탈산과 이소프탈산의 중합 생성물로 필수적으로 구성된 폴리아릴레이트 약 85 내지 98중량%, (b) (1) 올레핀 중합체의 중량을 기준으로 약 0.5-15중량%의 글리시딜 메타 크릴레이트, (2) 올레핀 중합체의 중량을 기준으로 약 45-99중량%의 에틸렌 및 (3) 올레핀 중합체의 중량을 기준으로 약 0.1-40중량%의 부틸 아크릴레이트의 중합 생성물로 필수적으로 구성된 에폭시 관능성을 함유하는 올레핀 중합체 약 2-15중량%로 필수적으로 구성된 복합 시이트 구조물.The polyarylate of claim 31, wherein the thermoplastic polyester is (a) about 85 to 98 weight percent polyarylate consisting essentially of a polymerization product of 2,2-bis (4-hydroxyphenyl) propane terephthalic acid and isophthalic acid, b) about 0.5-15% by weight of glycidyl methacrylate based on the weight of the olefin polymer, (45) about 45-99% by weight ethylene based on the weight of the olefin polymer and (3) the olefin polymer A composite sheet structure consisting essentially of about 2-15% by weight of an olefin polymer containing epoxy functionality consisting essentially of a polymerization product of about 0.1-40% by weight of butyl acrylate based on the weight of the product. 제31항에 있어서, 열가소성 폴리에스테르가 (a) 필수적으로 2,2-비스(4-히드록시페놀)프로판 테레프탈산과 이소프탈산의 중합생성물로 구성된 폴리아릴레이트 약 84 내지 98.7중량%, (b) (1) 올레핀 중합체의 중량을 기준으로 약 0.5-15중량%의 글리시딜 메타크릴레이트, (2) 올레핀 중합체의 중량을 기준으로 약 45-99중량%의 에틸렌 및 (3) 올레핀 중합체의 중량을 기준으로 약 0.1 내지 40중량%의 부틸 아크릴레이트의 중합 생성물로 필수적으로 구성된 에폭시 관능성을 함유하는 올레핀 중합체 약 1-22중량 및 (c) 필수적으로 스티렌 및 아크릴로니트릴로 구성된 공중합체 약 0.3-15중량%로 필수적으로 구성된 복합 시이트 구조물.The polyarylate of claim 31, wherein the thermoplastic polyester is (a) about 84 to 98.7 weight percent of polyarylate consisting essentially of a polymerization product of 2,2-bis (4-hydroxyphenol) propane terephthalic acid and isophthalic acid, (b) (1) about 0.5-15 weight percent glycidyl methacrylate based on the weight of the olefin polymer, (2) about 45-99 weight percent ethylene based on the weight of the olefin polymer and (3) the weight of the olefin polymer From about 1-22 weight of olefin polymer containing epoxy functionality consisting essentially of a polymerization product of about 0.1 to 40 weight percent of butyl acrylate, and (c) a copolymer consisting essentially of styrene and acrylonitrile. Composite sheet structure consisting essentially of -15% by weight. 제31항에 있어서, 상기 열가소성 중합체의 두 번째 유연성 시이트를 원래 유연성 시이트의 마주하는 면상에서 강성 두꺼운 SMC 층에 부착시켜 두 유연성 시이트 사이에 결합된 SMC층을 갖는 구조물을 형성하는 복합 시이트 구조물.32. The composite sheet structure of claim 31, wherein the second flexible sheet of thermoplastic polymer is attached to a rigid thick SMC layer on the opposing face of the original flexible sheet to form a structure having an SMC layer bonded between the two flexible sheets. 제31항에 있어서, 강성 두꺼운 열경화 층이 단량체, 충전제 안료 및 유리 섬유로 중합된 폴리에스테르 수지로 구성된 복합 시이트 구조물.32. The composite sheet structure of claim 31, wherein the rigid thick thermoset layer consists of a polyester resin polymerized with monomers, filler pigments, and glass fibers. 제41항에 있어서, 폴리에스테르 수지가 필수적으로 지방족 및 방향족 이 무수물 또는 산 및 알킬렌 글리콜의 산 말단 폴리에스테르로 구성되고 중합된 단량체가 스티렌, 또는 알파 메틸스티렌으로 구성된 복합 시이트 구조물.42. The composite sheet structure of Claim 41, wherein the polyester resin consists essentially of aliphatic and aromatic anhydrides or acid terminated polyesters of acids and alkylene glycols and the polymerized monomers comprise styrene, or alpha methylstyrene. 제42항에 있어서, 폴리에스테르 수지가 필수적으로 프로필렌 글리콜, 이소프탈산과 말레산 무수물로 구성되고 단량체가 스티렌이며 폴리에스테르가 산화 마그네슘, 수산화 마그네슘 또는 탄산 마그네슘과 반응되며 충전제 안료가 탄산 칼슘인 복합 시이트 구조물.43. The composite sheet of Claim 42, wherein the polyester resin consists essentially of propylene glycol, isophthalic acid and maleic anhydride, the monomer is styrene, the polyester is reacted with magnesium oxide, magnesium hydroxide or magnesium carbonate and the filler pigment is calcium carbonate. structure. 제43항에 있어서, SMC가 열 경화성 층 15중량% 이하의 고 분자량 열가소성 수지로 구성된 낮은 프로파일 첨가제를 함유하는 복합 시이트 구조물.44. The composite sheet structure of Claim 43, wherein the SMC contains a low profile additive comprised of up to 15 wt.% Of a high molecular weight thermoplastic resin. 제31항에 있어서, 열가소성 폴리에스테르 시이트가 SMC 시이트와 접촉하지 않는 면에서 거기에 견고히 부착된 페인트를 함유하는 열가소성 안료 층과 페인트에 결합된 광택 투명 열가소성 피니쉬 층을 갖는 복합 구조물.32. The composite structure of claim 31 wherein the thermoplastic polyester sheet has a thermoplastic pigment layer containing a paint firmly attached thereto in contact with the SMC sheet and a luster transparent thermoplastic finish layer bonded to the paint. 제31항에 있어서, 열가소성 폴리에스테르 시이트가 SMC 시이트와 접촉하지 않는 면에서 거기에 견고히 결합된 페인트를 함유하는 열가소성 안료 층을 갖는 복합 구조물.32. The composite structure of claim 31 wherein the thermoplastic polyester sheet has a layer of thermoplastic pigment containing paint rigidly bonded thereto in that it is not in contact with the SMC sheet. 제45항에 있어서, 착색된 투명 층이 복합체의 외부 표면을 형성하고 20°에서 측정된 적어도 80의 광택도를 갖고 적어도 80의 상 명확성을 갖는 복합체.46. The composite of claim 45, wherein the colored transparent layer forms an outer surface of the composite and has a glossiness of at least 80 measured at 20 ° and a phase clarity of at least 80. 제47항에 있어서, 페인트 및 투명 열가소성 피니쉬가 폴리비닐 플루오라이드, 폴리비닐리덴 플루오라이드 또는 폴리메틸 메타크릴레이트 또는 폴리에틸 메타크릴레이트와 폴리비닐리덴 플루오라이드의 블렌드로 구성된 군으로부터 선택된 결합제를 갖는 복합체 구조물.48. The paint of claim 47 wherein the paint and transparent thermoplastic finish has a binder selected from the group consisting of polyvinyl fluoride, polyvinylidene fluoride or polymethyl methacrylate or a blend of polyethyl methacrylate and polyvinylidene fluoride. Composite structures. a. b)에 견고히 결합된 광택 투명 열가소성 피니쉬의 10-125 미크론 두께 층, b. c)에 견고히 결합된 페인트를 함유하는 열가소성 안료의 5-75 미크론 두께 층, c. d)에 견고히 결합된 1-25 미크론 두께의 열가소성 사이즈 층, d. e)dp 결합된 열가소성 폴리에스테르의 유연한 시이트의 250-1250 미크론 두께 층, e. 단량체로 중합되고 충전제 안료와 유리 섬유를 함유하는 500-25000 미크론 두께 강성 열경화성 층으로 구성된 외부 자동차 또는 트럭 몸체 부품으로서 유용한 복합체 구조물.a. 10-125 micron thick layer of glossy transparent thermoplastic finish firmly bonded to b), b. 5-75 micron thick layer of thermoplastic pigments containing paint firmly bonded to c), c. a 1-25 micron thick thermoplastic size layer firmly bonded to d), d. e) a 250-1250 micron thick layer of flexible sheet of dp bonded thermoplastic polyester, e. A composite structure useful as an exterior automotive or truck body part polymerized with monomers and composed of a 500-25000 micron thick rigid thermoset layer containing filler pigments and glass fibers. 제49항의 a 내지 d 층으로 구성된 열성형 시이트 구조물.60. The thermoformed sheet structure consisting of the a to d layers of claim 49. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019890013864A 1988-09-26 1989-09-26 Process for forming a composite structure of thermoplastic polymer and sheet molding compound KR0151850B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/249,152 US4959189A (en) 1988-09-26 1988-09-26 Process for forming a composite structure of thermoplastic polymer and sheet molding compound
US88-249,152 1988-09-26
US249,152 1988-09-26

Publications (2)

Publication Number Publication Date
KR900004481A true KR900004481A (en) 1990-04-12
KR0151850B1 KR0151850B1 (en) 1998-10-15

Family

ID=22942259

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019890013864A KR0151850B1 (en) 1988-09-26 1989-09-26 Process for forming a composite structure of thermoplastic polymer and sheet molding compound

Country Status (9)

Country Link
US (1) US4959189A (en)
EP (1) EP0361823B1 (en)
JP (1) JP2984286B2 (en)
KR (1) KR0151850B1 (en)
AU (1) AU632249B2 (en)
BR (1) BR8904867A (en)
CA (1) CA1325506C (en)
DE (1) DE68921130T2 (en)
ES (1) ES2070910T3 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100482501B1 (en) * 2002-05-14 2005-04-14 현대자동차주식회사 A method for manufacturing glass fiber reinforced thermosetting composite

Families Citing this family (62)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5342666A (en) * 1986-10-28 1994-08-30 Rexham Industries Corp. Injection molded plastic article with integral weatherable pigmented film surface
USRE36457E (en) * 1986-10-28 1999-12-21 Rexam Industries, Corp. Injection molded plastic article with integrated weatherable pigmented film surface
US5707697A (en) * 1987-03-27 1998-01-13 Avery Dennison Corporation Dry paint transfer product having high DOI automotive paint coat
US5326516A (en) * 1989-10-03 1994-07-05 Plasticolors, Inc. Method of preparing a cured pigmented thermosetting polymer composition exhibiting improved color values and reduced haze
US5259036A (en) * 1991-07-22 1993-11-02 Shure Brothers, Inc. Diaphragm for dynamic microphones and methods of manufacturing the same
JP2657160B2 (en) * 1992-02-14 1997-09-24 信越ポリマー株式会社 Method of manufacturing cover member for illuminated push button switch
US5543225A (en) * 1992-05-22 1996-08-06 Aqua Glass Corporation Multilayer fiber reinforced polymeric shaped article
US5215796A (en) * 1992-05-22 1993-06-01 Aqua Glass Corporation Multilayer polymeric shaped article
US5411688A (en) * 1992-06-29 1995-05-02 Duotec Products Associates Method for forming plastic molded panels with inserts
KR950704108A (en) * 1992-12-23 1995-11-17 스티븐 에이. 슈니버거 METHOD FOR MANUFACTURING COMPOSITE ARTICLES HAVING ENHANCED EXTERIOR SURFACE FINISHES
DE4313925A1 (en) * 1993-04-28 1994-11-03 Roehm Gmbh Polymer moldings made of casting resins with shiny metallic, possibly colored surfaces
DE19517069A1 (en) * 1995-05-10 1996-11-14 Basf Lacke & Farben Films for coating molded part blanks and their use in automotive engineering
DE19517068A1 (en) * 1995-05-10 1996-11-14 Basf Lacke & Farben Films coated with several layers and their use in automotive engineering
DE19517067A1 (en) * 1995-05-10 1996-11-14 Basf Lacke & Farben Films coated with several layers and their use in automotive engineering
EP0831998A4 (en) 1995-06-07 2000-03-01 Avery Dennison Corp Extrusion process for protective coatings for outdoor siding panels and the like
US20040209057A1 (en) * 1995-06-07 2004-10-21 Enlow Howard H. Extruded polymeric high transparency films
US6254712B1 (en) 1998-12-08 2001-07-03 Avery Dennison Corporation Extrusion coating process for making high transparency protective and decorative films
ZA964731B (en) 1995-06-07 1997-01-07 Avery Dennison Corp A Legal Bo Extrusion coating process for making protective and decorative films
JP3479757B2 (en) * 1995-08-25 2003-12-15 豊田合成株式会社 Decorative molding method for thermoplastic resin molded products
AUPN516795A0 (en) * 1995-09-01 1995-09-28 Armacel Pty Limited Layered structural article
US5601770A (en) * 1995-09-29 1997-02-11 Airtech International, Inc. Method for producing sheet molding compounds utilizing a multilayered, multistructured, multipolymer release / barrier film
US20050225006A1 (en) * 1995-11-01 2005-10-13 Patent Holding Company Method for molding metal-covered component
US6428738B1 (en) * 1995-11-01 2002-08-06 Patent Holding Company Method of manufacturing an in-mold laminate component
US6576308B2 (en) 1996-05-23 2003-06-10 Pliant Corporation Carrier release sheet for styrene molding process and process system
WO1998006573A1 (en) * 1996-08-12 1998-02-19 Huntsman Deerfield Film Corporation Carrier release sheet for molding compound
EP0847852A3 (en) 1996-12-10 2004-03-03 Basf Aktiengesellschaft Laminated films or panels and articles formed therefrom
US5958587A (en) * 1997-04-21 1999-09-28 Owens-Illinois Closure Inc. Method of removing blemishes in compression molded articles
US6221304B1 (en) * 1997-07-30 2001-04-24 Visteon Global Technologies, Inc. Method of manufacturing a film coated article
US6620371B1 (en) 1998-05-22 2003-09-16 Patent Holding Company Method of manufacturing an in-mold laminate component
US6082762A (en) 1998-05-22 2000-07-04 Larry J. Winget Air bag cover having a decorative applique preform bonded thereto and method of making same
DE19840807A1 (en) * 1998-09-07 2000-03-16 Basf Coatings Ag Films coated with several layers and their use in automotive engineering
US6440546B1 (en) 1999-10-13 2002-08-27 Ream Industries Corp. Gloss-adjusting mask layer with particulate filler
US6541076B2 (en) 1999-12-20 2003-04-01 Patent Holding Company Method of priming SMC parts
KR100356860B1 (en) * 2000-09-05 2002-10-18 현대자동차주식회사 manufacturing method for door latch plate
DE10059801A1 (en) * 2000-12-01 2002-06-13 Bayerische Motoren Werke Ag Pressed fiber compound material, for Class A vehicle body parts, is of prepared layers with a low fiber content in the outer layer and a higher fiber content in the structure layer, impregnated with a heat-setting resin
WO2002071898A1 (en) * 2001-03-07 2002-09-19 Harman International Industries, Inc. Thermoset composite material baffle for loudspeaker
US20040030176A1 (en) * 2001-09-05 2004-02-12 Ohrbom Walter H. Gamma hydroxy carbamate compounds and method of making and using the same
ES2190363B1 (en) * 2001-10-09 2004-11-01 Protecnos, S.A. PROCEDURE FOR DECORATION OF MOLDED PARTS IN PLASTIC MATERIAL.
US8057903B2 (en) * 2001-11-30 2011-11-15 Sabic Innovative Plastics Ip B.V. Multilayer articles comprising resorcinol arylate polyester and method for making thereof
AU2003226674A1 (en) * 2002-03-21 2003-10-08 Menzolit Fibron Gmbh Method for coating fiber-reinforced plastic structural parts and structural part so produced
US6855283B2 (en) * 2002-07-25 2005-02-15 Patent Holdings Company Method for forming a sheet, fiber and resin composite
DE10256827A1 (en) * 2002-12-04 2004-06-24 Schott Glas Production of a coated plastic substrate used in the production of optical components, comprises preparing a carrier foil, forming a decorated carrier foil, and forming a decorated plastic molded part by applying a functional layer
US20060175855A1 (en) * 2002-12-23 2006-08-10 Green Tokai Co., Ltd. Color matched automtive trim and body part
US7199970B2 (en) 2003-11-03 2007-04-03 Material Sciences Corporation Damped disc drive assembly, and method for damping disc drive assembly
US7172800B2 (en) 2003-11-03 2007-02-06 Material Sciences Corporation Sheet molding compound damper component, and methods for making and using the same
JP2006051926A (en) * 2004-07-16 2006-02-23 Yamaha Motor Co Ltd Vehicle body cover for saddle-riding-type vehicle, saddle-riding-type vehicle equipped with the same, and manufacturing method of vehicle body cover
DE102005039709A1 (en) 2005-08-23 2007-03-01 Johns Manville International, Inc., Denver Glass fiber nonwovens, resin mats and process for their preparation
CN101484511B (en) * 2006-06-29 2012-08-22 艾利丹尼森公司 Polyvinylidene fluoride films and laminates thereof
JP5096467B2 (en) * 2006-08-14 2012-12-12 ビーエーエスエフ ソシエタス・ヨーロピア Composite material
EP2094748B1 (en) * 2006-12-21 2012-10-17 E.I. Du Pont De Nemours And Company Crosslinkable vinyl fluoride copolymer coated film and process for making same
WO2010101874A1 (en) * 2009-03-02 2010-09-10 Faurecia Automotive Seating, Inc. Seat back including integrated backrest and reinforcing composite layer
EP2292685B1 (en) 2009-09-07 2012-06-27 The Procter & Gamble Company Bottle cap made from a material comprising polypropylene, particulate calcium carbonate and additives
WO2012155966A1 (en) 2011-05-18 2012-11-22 Senoplast Klepsch & Co. Gmbh Multilayer composites having improved physical properties
WO2013030385A1 (en) 2011-09-01 2013-03-07 Senoplast Klepsch & Co. Gmbh Composite body
EP2599624A1 (en) 2011-11-29 2013-06-05 Senoplast Klepsch & Co. GmbH Compound body
KR101827463B1 (en) 2014-06-27 2018-02-08 사빅 글로벌 테크놀러지스 비.브이. Induction heated mold apparatus with multimaterial core and method of using the same
JP6548011B2 (en) * 2015-06-24 2019-07-24 株式会社浅野研究所 Thermoforming apparatus and thermoforming method
US20170314838A1 (en) 2016-04-29 2017-11-02 Thermo King Corporation Method of manufacturing an enclosure for a transport refrigeration unit, transport refrigeration unit and transport unit
US20190322019A1 (en) * 2016-06-30 2019-10-24 Basf Se Method for producing a functionalized, three-dimensional molded body
US10882259B2 (en) * 2017-06-01 2021-01-05 Thermo King Corporation Manufacturing method for an aesthetic structural part
GB2569266A (en) * 2017-10-13 2019-06-19 Nottingham Univ Hospitals Nhs Trust Methods of forming solid or liquid charged capsules
JP6691624B2 (en) * 2019-04-22 2020-04-28 株式会社浅野研究所 Thermoforming apparatus and thermoforming method

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1404394B2 (en) * 1958-05-16 1970-08-13 Möller, Hans Günter, 2870 Delmenhorst Hanover 1958, 3000 Hanover procedure for. Manufacture of a plastic tub
GB935961A (en) * 1960-05-02 1963-09-04 Johns Manville Method of forming shaped laminates
US3419458A (en) * 1964-05-07 1968-12-31 Cee Bee Mfg Co Inc Decorative extruded plastic stripping and laminated products including the same
US3679510A (en) * 1970-08-06 1972-07-25 Riegel Paper Corp Weather resistant moldable laminate
US3974124A (en) * 1973-06-06 1976-08-10 Woodall Industries Inc. Energy absorbing vehicle body material
US4075266A (en) * 1976-11-01 1978-02-21 Friedrich Theysohn Method for coating foil material
US4161471A (en) * 1978-04-13 1979-07-17 E. I. Du Pont De Nemours And Company Elastomer modified unsaturated molding compositions
US4239808A (en) * 1979-06-13 1980-12-16 The General Tire & Rubber Company In-mold coating of sheet molding compound moldings
US4444829A (en) * 1979-10-10 1984-04-24 Allied Corporation Polyamide release film for sheet molding compound
US4470787A (en) * 1983-05-11 1984-09-11 Mts Systems Corporation Hydraulic press
US4557889A (en) * 1981-09-26 1985-12-10 Kawasaki Yucoh Co., Ltd. Method and apparatus for producing sheet molding compound parts by compression
US4643789A (en) * 1982-07-23 1987-02-17 Transfer Print Foils Method for preparing a decorated insert and continuous insert molding operation
US4482604A (en) * 1983-02-04 1984-11-13 Monsanto Company Bonded reinforced plastic structures
US4612149A (en) * 1983-04-25 1986-09-16 The Budd Company Compression molding a charge using vacuum
US4488862A (en) * 1983-04-25 1984-12-18 The Budd Company Compression molding apparatus having vacuum chamber
US4551085A (en) * 1983-04-25 1985-11-05 The Budd Company Compression molding apparatus having vacuum chamber
US4515543A (en) * 1983-09-02 1985-05-07 The Budd Co. In-mold coating part ejection system
US4643089A (en) * 1985-01-18 1987-02-17 Pitney Bowes Inc. Apparatus for controlling printing means
CA1267763A (en) * 1986-03-19 1990-04-17 Kenneth A. Iseler Vacuum compression molding method using preheated charge
EP0247359B1 (en) * 1986-04-25 1993-08-18 Inoac Corporation Interior material for vehicles and method for its manufacture
US4779542A (en) * 1987-07-31 1988-10-25 Stageright Corporation Fold and roll staging
GB2220879B (en) * 1988-06-24 1992-11-18 Polistock Nv A method of producing laminated panels

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100482501B1 (en) * 2002-05-14 2005-04-14 현대자동차주식회사 A method for manufacturing glass fiber reinforced thermosetting composite

Also Published As

Publication number Publication date
DE68921130D1 (en) 1995-03-23
EP0361823A2 (en) 1990-04-04
EP0361823B1 (en) 1995-02-15
AU632249B2 (en) 1992-12-17
EP0361823A3 (en) 1992-04-22
JP2984286B2 (en) 1999-11-29
KR0151850B1 (en) 1998-10-15
CA1325506C (en) 1993-12-28
BR8904867A (en) 1990-05-08
ES2070910T3 (en) 1995-06-16
AU4166789A (en) 1990-03-29
JPH02269029A (en) 1990-11-02
DE68921130T2 (en) 1995-10-12
US4959189A (en) 1990-09-25

Similar Documents

Publication Publication Date Title
KR900004481A (en) Method for producing a composite structure of a site-forming compound and a thermoplastic polymer
US3413188A (en) Glass fiber-wood laminates and methods of producing such laminates
EP1123791B1 (en) Decorative sheet for in-mould decorating injection moulding, decorative moulding and in-mould decorating injection moulding method
EP0411152B1 (en) Decorative sheet and method of production thereof
CN103619587A (en) Decorative sheet for three-dimensional molding and method for producing same, and decorative molded article using decorative sheet and method for producing same
JP2007520378A (en) Structure-reinforced resin article and manufacturing method thereof
US3679510A (en) Weather resistant moldable laminate
AU3216489A (en) Multilayered sheets having excellent adhesion
CN102597084A (en) Formulations comprising isosorbide-modified unsaturated polyester resins and low profile additives which produce low shrinkage matrices
CN1799828A (en) Molded product with decoration surface layer and manufacturing method thereof
EP0385887A1 (en) Sheet material useful in forming protective and decorative coatings
EP0281701A2 (en) Synthetic in-mold label
US4149920A (en) Process for moulding unsaturated polyester articles
KR20220166822A (en) Hot fillable articles made from multilayer thermoformable films and sheets
JPH091586A (en) Surface decorated resin molded product and method for simultaneous molding and decorating
JP4334665B2 (en) Cosmetic material
WO1992011139A1 (en) Multilayered sheets having excellent adhesion
JP3086349B2 (en) In-mold coating composition
US5756168A (en) Laminate article and method for making same
CA2162103C (en) Method for the thermal adhesion of parts made of acrylic plastic and parts made of engineering plastics
IE43554B1 (en) Synthetic resin containers
JP3830113B2 (en) Fiber-reinforced plastic molded product and method for producing the same
JP3453027B2 (en) Thermal adhesive film for polyacetal resin molded product, molded product thereof, and method for producing molded product
JP3738462B2 (en) Artificial marble and its manufacturing method
CA2211460A1 (en) Re-usable cement forms

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20020610

Year of fee payment: 5

LAPS Lapse due to unpaid annual fee