KR890701597A - 알칼리 금속염의 루이스염기 착화합물 - Google Patents

알칼리 금속염의 루이스염기 착화합물

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Publication number
KR890701597A
KR890701597A KR1019890701103A KR890701103A KR890701597A KR 890701597 A KR890701597 A KR 890701597A KR 1019890701103 A KR1019890701103 A KR 1019890701103A KR 890701103 A KR890701103 A KR 890701103A KR 890701597 A KR890701597 A KR 890701597A
Authority
KR
South Korea
Prior art keywords
alkali metal
ligand
lithium
complex
metal salt
Prior art date
Application number
KR1019890701103A
Other languages
English (en)
Inventor
스네이트 로날드
사이몬 라이트 도미니크
Original Assignee
원본미기재
더 어소시에이티드 옥텔 캄파니 리미티드
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 원본미기재, 더 어소시에이티드 옥텔 캄파니 리미티드 filed Critical 원본미기재
Publication of KR890701597A publication Critical patent/KR890701597A/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/005—Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/22—Amides of acids of phosphorus
    • C07F9/24—Esteramides
    • C07F9/2404—Esteramides the ester moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/2408—Esteramides the ester moiety containing a substituent or a structure which is considered as characteristic of hydroxyalkyl compounds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

알칼리 금속염의 루이스염기 착화합물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 알칼리금속, 또는 이의 하이드라이드 또는 알킬을 무수조건 및 불활성 대기하에 탄화수소 용매중에서 리간드(L)의 존재하에 음이온 X의 무수 암모늄염과 반응시킴을 특징으로 하여, 하기 일반식의 알칼리 금속염 착화합물을 제조하는 방법.
    (MxX,nL)y
    상기식에서, M은 알칼리금속이며, X는 음이온이고, L은 유기 전자-공여 리간드(루이스 염기)이며, x는 음이온 X 의 원자가이고, n은 착화합물 중에서 알카릴 금속염에 대한 리간드의 몰비율이 n:1 이 되는 수이며, y는 무한대까지의 정수이다.
  2. 제1항에 있어서, 반응종료시에 반응매질을 냉각시키고/거나 알칸을 가함으로써, 생성된 알칼리금속 착화합물을 결정 형태로 회수하는 방법.
  3. 제1항 또는 2항에 있어서, 일반식 중 M이 Li 이고, X가 할라이드 또는 티오시아네이트이며, 탄화수소 용매중 무수조건하에 리간드 L의 존재하에서 리튬 하이드라이드 또는 리튬 알킬을 무수 암모늄 할라이드 또는 티오시아네이트와 반응시킴을 특징으로 하는 방법.
  4. 제3항에 있어서, 리튬 반응물이 n-부틸리튬인 방법.
  5. 제1항 또는 2항에 있어서, 일반식중 M이 Na 또는 K인 방법.
  6. 제1항 또는 2항에 있어서, 나트륨 하이드라이드와 n-부틸리튬의 혼합물을 알칼리금속 반응물로서 사용하고, 암모늄염이 티오시아네이트인 방법.
  7. 제3항, 4항 또는 5항에 있어서, 암모늄염이 암모늄 클로라이드, 브로마이드, 요오다이드, 티오시아네트 또는 플루오로보레이트인 방법.
  8. 제1항 내지 7항중 어느 한항에 있어서, L이 헥사메틸포스포르아미드(HMPA), 테트라메틸에틸렌디아민(TMEDA), 펜타메틸디에틸렌트리아민(PMDETA), 1,2-디메톡시 에탄(글림), 비스(2-메톡시에틸)에테르(디글림), 디옥산 또는 테트라하이드로푸란(THF)인 방법.
  9. 제1항 내지 8항중 어느 한항에 있어서, 반응용해가 n-헥산 또는 톨루엔인 방법.
  10. 하기 일반식의 알칼리 금속염 착화합물.
    (M'xX,nL)y
    상기식에서, M'은 하나이상의 알칼리금속(여기서, 적어도 하나는 리튬 이외의 금속이다)이고, X,L,n,x 및 y 는 제1항에서 정의한 바와같다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890701103A 1987-10-21 1988-10-21 알칼리 금속염의 루이스염기 착화합물 KR890701597A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB8724662 1987-10-21
GB878724662A GB8724662D0 (en) 1987-10-21 1987-10-21 Lewis base complexes of alkali metal salts
PCT/GB1988/000915 WO1989003835A1 (en) 1987-10-21 1988-10-21 Lewis base complexes of alkali metal salts

Publications (1)

Publication Number Publication Date
KR890701597A true KR890701597A (ko) 1989-12-21

Family

ID=10625675

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019890701103A KR890701597A (ko) 1987-10-21 1988-10-21 알칼리 금속염의 루이스염기 착화합물

Country Status (13)

Country Link
US (1) US5206394A (ko)
EP (1) EP0317087B1 (ko)
JP (1) JPH02501928A (ko)
KR (1) KR890701597A (ko)
AU (1) AU615011B2 (ko)
CA (1) CA1336000C (ko)
DE (1) DE3874862T2 (ko)
DK (1) DK305089A (ko)
ES (1) ES2052741T3 (ko)
GB (2) GB8724662D0 (ko)
GR (1) GR3006278T3 (ko)
PT (1) PT88806B (ko)
WO (1) WO1989003835A1 (ko)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8915531D0 (en) * 1989-07-06 1989-08-23 Ass Octel Alkaline earth,transition and lanthanide metal inorganic salt complexes
US6420581B1 (en) 1999-06-29 2002-07-16 Flexsys America L.P. Manufacture of zinc hexasulfide amine complexes
JP5087754B2 (ja) * 2010-04-27 2012-12-05 信越化学工業株式会社 環状ポリオルガノシロキサンシラザンおよびその製造方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3734963A (en) * 1969-03-18 1973-05-22 Exxon Co Inorganic lithium-amine complexes
US4152401A (en) * 1969-03-18 1979-05-01 Exxon Research & Engineering Co. Chelated lithium aluminum compounds
US3933879A (en) * 1969-03-18 1976-01-20 Exxon Research And Engineering Company Chelated lithium aluminum compounds
US4094876A (en) * 1969-03-18 1978-06-13 Exxon Research & Engineering Co. Chelated lithium aluminum compounds
US4156603A (en) * 1969-03-18 1979-05-29 Exxon Research & Engineering Co. Reductions with chelated lithium hydridoaluminates or hydridoborates
USRE28456E (en) * 1969-03-18 1975-07-01 Inorganic lithium amine complexes
US4088666A (en) * 1969-03-18 1978-05-09 Exxon Research & Engineering Co. Reductions with chelated lithium hydridoaluminates or hydridoborates
US3758585A (en) * 1970-07-27 1973-09-11 Exxon Research Engineering Co Complexes of inorganic sodium compounds and chelating amines
US3758580A (en) * 1971-11-26 1973-09-11 Exxon Research Engineering Co Separation of tertiary chelating polyamines
US3755447A (en) * 1971-11-26 1973-08-28 Exxon Research Engineering Co Polyalkylene polyamine separation and purification
NO134211C (ko) * 1974-05-28 1976-09-01 Dale Johannes
CH623353A5 (ko) * 1976-09-08 1981-05-29 Ciba Geigy Ag
DE2722221A1 (de) * 1977-05-17 1978-11-23 Studiengesellschaft Kohle Mbh Alkalimetallkomplexverbindungen, verfahren zu ihrer herstellung und ihre verwendung zur hydrierung und nitridierung von alkalimetallen
NZ189722A (en) * 1978-03-03 1981-05-15 Nat Res Dev Manganese complexes and sorption of gases
US4900856A (en) * 1988-05-26 1990-02-13 Ethyl Corporation Preparation of metal halide-amine complexes

Also Published As

Publication number Publication date
CA1336000C (en) 1995-06-20
ES2052741T3 (es) 1994-07-16
WO1989003835A1 (en) 1989-05-05
PT88806B (pt) 1993-01-29
GR3006278T3 (ko) 1993-06-21
AU615011B2 (en) 1991-09-19
EP0317087A1 (en) 1989-05-24
EP0317087B1 (en) 1992-09-23
US5206394A (en) 1993-04-27
DE3874862T2 (de) 1993-02-04
AU2605388A (en) 1989-05-23
GB8824778D0 (en) 1988-11-30
GB2211189B (en) 1991-06-26
DK305089D0 (da) 1989-06-20
DE3874862D1 (de) 1992-10-29
JPH02501928A (ja) 1990-06-28
GB8724662D0 (en) 1987-11-25
GB2211189A (en) 1989-06-28
DK305089A (da) 1989-06-20

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