KR890700158A - Sulfurized alkaline earth metal hydrocarbyl phenates, their preparation and use - Google Patents

Sulfurized alkaline earth metal hydrocarbyl phenates, their preparation and use

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Publication number
KR890700158A
KR890700158A KR1019880700889A KR880700889A KR890700158A KR 890700158 A KR890700158 A KR 890700158A KR 1019880700889 A KR1019880700889 A KR 1019880700889A KR 880700889 A KR880700889 A KR 880700889A KR 890700158 A KR890700158 A KR 890700158A
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South Korea
Prior art keywords
concentrate
compounds
acid
method
lubricating oil
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KR1019880700889A
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Korean (ko)
Inventor
케인 챨스
크리포드 죤
패트릭 오커너 세인
Original Assignee
리챠드 페널리 퍼셋
비피 케미칼스(애디티브스) 리미티드
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Priority to GB868628609A priority Critical patent/GB8628609D0/en
Priority to GB8628609 priority
Application filed by 리챠드 페널리 퍼셋, 비피 케미칼스(애디티브스) 리미티드 filed Critical 리챠드 페널리 퍼셋
Priority to PCT/GB1987/000848 priority patent/WO1988003945A1/en
Publication of KR890700158A publication Critical patent/KR890700158A/en
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=10608200&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=KR890700158(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12Reaction products
    • C10M159/20Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
    • C10M159/22Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing phenol radicals

Abstract

내용 없음 No information

Description

황화 알칼리 토금속 하이드로카빌 페네이트, 이의 제조방법 및 용도 Sulfurized alkaline earth metal hydrocarbyl phenates, their preparation and use

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음 This information did not disclose more professional information because lumbar Articles

Claims (32)

  1. (a) 윤활유, 및 (b) (i) 적어도 1개의 다음 일반식(I)의 카복실산 또는 이의 무수물, 산 화합물 또는 에스테르, 또는 (ii)C 36-100 디-또는 폴리 카복실산 또는 이의 무수물, 산 염화물 또는 에스테르를, 조성물의 중량을 기준으로 하여 2 내지 35중량%의 양으로 혼입시켜 개질시킨, 윤활유 가용성-황화 알칼리 토금속 하이드로 카빌 페네이트를 함유하는, TBN(총 염기수)이 300이상인 가공 윤활유 조성물에 혼입시키기 적합한 부가 농축물. (a) lubricating oil, and (b) (i) at least one of the following carboxylic acids or their anhydrides of the general formula (I), an acid compound or an ester, or (ii) C 36-100 di- or polycarboxylic acids or anhydrides thereof, acid in which modified the chloride or the ester, based on the weight of the composition was mixed in an amount of 2 to 35% by weight, the lubricating oil soluble-sulfurized alkaline earth metal hydrocarbyl page containing carbonate, TBN (total yeomgisu) processing the lubricating oil composition with more than 300 adding a concentrate suitable for incorporation.
    상기식에서, R은 C 10-24 알킬 또는 알케닐 그룹이고, R 1 은 수소, C 1-4 알킬그룹 또는 -CH 2 -COOH-그룹이다. Wherein, R is a C 10-24 alkyl or alkenyl group, R 1 is hydrogen, C 1-4 alkyl group or -CH 2 -COOH- group.
  2. 제1항에 있어서, 윤활유가 조성물의 10 내지 90중량%를 이루는 부가농축물. The method of claim 1, wherein the lubricating oil is added forming a concentrate from 10 to 90% by weight of the composition.
  3. 제1항 또는 제2항에 있어서, 윤활유 가용성-황화 알칼리 토금속 하이드로카빌 페네이트의 알칼리 토금속이 칼슘, 마그네슘 또는 바륨인 부가 농축물. According to claim 1 or 2, wherein the lubricating oil soluble-sulfurized alkaline earth metal hydrocarbyl phenate of alkaline earth metal is calcium, magnesium or barium is added concentrate.
  4. 제3항에 있어서, 알칼리 토금속이 칼슘인 부가 농축물. The method of claim 3, wherein the added alkaline earth metal is calcium concentrate.
  5. 제1항 내지 제4항중 어느 한 항에 있어서, 윤활유 가용성-황화 알칼리 토금속 하이드로카빌 페네이트의 하이드로카빌 페네이트 잔기가 적어도 1개의 알킬 페놀(여기서, 알킬 페놀의 알킬그룹은 9 내지 28개의 탄소원자를 함유한다)그룹으로부터 유도된 부가 농축물. Claim 1 to claim 4 Compounds according to any one of the preceding, the lubricating oil soluble-sulfurized alkaline earth metal hydrocarbyl phenate in the hydrocarbyl phenate moiety is at least one alkylphenol (wherein the alkyl group of the alkylphenol has from 9 to 28 carbon atoms shall contain) the added concentrate derived from the group.
  6. 제5항에 있어서, 하이드로카빌 페네이트 잔기가, 페놀을 프로필렌 테트라머로 알킬화시켜 수득한 C 12 알킬 페놀로부터 유도된 부가 농축물. Claim 5 wherein, the hydrocarbyl phenate moiety is, the added concentrate derived from a C 12 alkyl phenol obtained by alkylating phenol by meoro tetra propylene.
  7. 제1항 또는 6항중 어느 한항에 있어서, R이 직쇄 알킬 또는 알케닐 그룹인 일반식(I) 카복실산 적어도 1개를 혼입시킨 부가 농축물. Of claim 1 or 6. Compounds according to any hanhang, R is a straight-chain alkyl or alkenyl group of general formula (I) acid addition concentrate was mixed into at least one.
  8. 제7항에 있어서, 일반식(I)의 카복실산에서의 R의 C 10-24 직쇄 알킬 그룹이고 R 1 은 수소인 부가 농축물. The method of claim 7 wherein the R in the general formula (I) carboxylic acid C 10-24 straight chain alkyl group and R 1 is a hydrogen addition concentrations.
  9. 제1항 내지 6항중 어느 한항에 있어서, 포화산과 불포화산을 둘다 포함하는 산을 함유하는 시산용의, 일반식(I) 카복실산의 혼합물을 혼입시킨 부가 농축물. Claim 1 to 6. Compounds according to any hanhang, adding the concentrate was mixed with the general formula (I) a mixture of the carboxylic acid, for the acids containing an acid containing both a saturated acid and an unsaturated acid.
  10. 제1항 내지 제6항중의 어느 한 항에 있어서, 스테아르산을 혼입시킨 부가 농축물. To claim 1, wherein according to any one of the sixth Compounds, adding the concentrate was mixed with the stearic acid.
  11. 제1항 내지 제6항중의 어느 한 항에 있어서, C 36-100 디-또는 폴리-카복실산 또는 이의 무수물을 혼입시킨 부가 농축물. To claim 1, wherein according to any one of the sixth Compounds, C 36-100 di- or poly-carboxylic acid or adding the concentrate was mixed with the anhydride thereof.
  12. 제11항에 있어서, 폴리이소부텐 숙신산 또는 폴리이소부텐 숙신산 무수물을 혼입시킨 부가 농축물. The method of claim 11, wherein the polyisobutene succinic acid or a polyisobutene succinic anhydride was added to the concentrate incorporated.
  13. 제1항 내지 제12항중의 어느 한 항에 있어서, 성분(b)(i) 또는 성분(b)(ii)를 농축물의 중량을 기준으로 하여 10 내지 35중량%의 양으로 혼입시킨 부가 농축. Claim 1 to according to any one of claim 12 Compounds ingredient (b) (i) or component (b) (ii) to the based on the weight of the concentrate 10 to which additional concentration incorporated in an amount of 35% by weight.
  14. 제13항에 있어서, 성분(b)(i) 또는 (b)(ii)를 농축물의 중량을 기준으로 하여 12 내지 20중량%의 양으로 혼입시킨 부가 농축물. 14. The method of claim 13 wherein component (b) (i) or (b) (ii) to the based on the weight of the concentrate of 12 to 20 add the concentrate was mixed in an amount of weight%.
  15. 제1항 내지 제14항중의 어느 한 항에 있어서, 조성물의 TBN이 350이상인 부가 농축물. To claim 1, wherein in any one of Compounds 14, additional concentrate the TBN of the composition not less than 350.
  16. 제15항에 있어서, 조성물의 TBN이 400이상인 부가 농축물. 16. The method of claim 15, the additional TBN concentrate 400 or more of the composition.
  17. 제1항 내지 제16항중의 어느 한 항에 있어서, 점도가 100℃에서 1000CS??미만인 부가 농축물. To claim 1, wherein according to any one of claim 16 Compounds, additional concentrate viscosity is less than 1000CS ?? at 100 ℃.
  18. 제17항에 있어서, 점도가 100℃에서 500??미만인 부가 농축물. The method of claim 17, wherein the additional concentrate viscosity is lower than at 100 ℃ 500 ??.
  19. (A) TBN이 최종 부가 농축물의 TBN미만인 황화 알칼리 토금속 하이드로 카빌 페네이트, (B) 반용 도중의 중간 지점에서 1회 또는 수회 첨가되는 알칼리 토금속 염기, (C) C 2-4 디가 알콜, 디-또는 트리-(C 2-4 )글리콜, 알킬렌 글리콜 알킬 에테르 또는 폴리알킬렌 글리콜 알킬 에테르, (D) 윤활유, (E) 성분 (B)를 가한 후 연속하여, 또는 각각 첨가되는 이산화탄소, 및 (F) 농축물의 중량을 기준으로 하여 2 내지 35중량 %를 제공하기 충분한 양의, (i)일반식(I)의 카복실산 또는 이의 산 무수물, 산염화물 또는 에스테르, 또는 (ii)C 36-100 디-또는 폴리-카복실산 또는 이의 산 무수물, 산 염화물 또는 에스테르(여기에서, 성분(A) 내지 (F)의 중량비는 TBN이 300이상인 농축물을 생성하도록 선택한다)를 승온에서 반응시켜 수득할 수 있는, 가공 윤활유에 혼입시키기 적합한 부가 농 (A) an alkaline earth metal base to be TBN final addition concentration was added once or several times at the mid-point of water is less than TBN sulfurized alkaline earth metal hydrocarbyl phenate, (B) during banyong, (C) C 2-4 di-alcohols, di - or tri - (C 2-4) glycol, an alkylene glycol alkyl ether or polyalkylene glycol alkyl ether, (D) successively after adding the lubricating oil, (E) component (B), or carbon dioxide were added, and (F) based on the weight of the concentrate sufficient to provide from 2 to 35% by weight amount, (i) the general formula (I) carboxylic acid or its acid anhydride, acid chloride or ester, or (ii) C 36-100 D or poly-carboxylic acid or its acid anhydride, acid chloride or ester (wherein component (a) weight ratio of to (F) are selected to produce a concentrate or higher TBN 300) that can be obtained by reacting at elevated temperature , suitable for incorporation in addition agricultural processing lubricant 축물. Chukmul.
  20. (A) TBN이 최종 부가 농축물의 TBN미만인 황화 알칼리 토금속 하이드로카빌 페네이트, (B) 반응도중의 중간 지점에서 1회 또는 수회 첨가되는 알칼리 토금속 염기, (C) C 2-4 디가 알콜, 디-또는 트리-(C 2-4 )글리콜, 알킬렌 글리콜 알킬 에테르 또는 폴리알킬렌 글리콜 알킬 에테르, (D) 윤활유, (E) 성분(B)를 가한 후 연속하여, 또는 각각 첨가되는 이산화탄소, 및 (F) 농축물의 중량을 기준으로 하여 2 내지 35중량 %를 제공하기 충분한 양의 (i) 일반식(I)의 카복실산 또는 이의 산 무수물, 산 염화물 또는 에스테르, 또는 (ii) C 36-100 디-또는 폴리-카복실산 또는 이의 산무수물, 산 염화물 또는 에스테르(여기에서, 성분(A) 내지 (F)의 중량비는 TBN이 300이상인 농축물을 생성하도록 선택한다)를 승온에서 반응시킴을 특징으로 하여, 제1항 내지 제18항중의 어느 한 항에 청구 (A) an alkaline earth metal base to be TBN is once or several times was added at the mid-point of the end of the addition is less than the concentrate TBN sulfurized alkaline earth metal hydrocarbyl phenate, (B) reaction, (C) C 2-4 di-alcohols, di - or tri - (C 2-4) glycol, an alkylene glycol alkyl ether or polyalkylene glycol alkyl ether, (D) successively after adding the lubricating oil, (E) component (B), or carbon dioxide were added, and (F) based on the weight of the concentrate sufficient to provide 2 to 35% by weight of the amount (i) of formula (I) carboxylic acid or its acid anhydride, acid chloride or ester, or (ii) C 36-100 D or poly-carboxylic acid or an acid anhydride, acid chloride or ester thereof and characterized by Sikkim (here, the weight ratio of components (a) to (F) is TBN is to choose to create a 300 or higher concentrations) of the reaction at an elevated temperature , the first term to be charged to any one of claim 18 Compounds 부가 농축물을 제조하는 방법. Method for producing an additional concentrate.
  21. 제21항에 있어서, 성분(B)가 석회인 방법. 22. The method of claim 21, wherein the component (B) is lime.
  22. 제20항 또는 제21항에 있어서, 성분(A)에 대한 성분(B)의 중량비가 0.2 내지 5인 방법. Claim 20 or claim 21 wherein component (A) The method in which the weight ratio of component (B) 0.2 to 5 about.
  23. 제20항 또는 제22항중의 어느 한 항에 있어서, 성분(C)가 에틸렌 클리콜인 방법. Claim 20 or according to any one of claim 22 Compounds ingredient method of (C) is ethylene glycol.
  24. 제20항 내지 제22항중의 어느 한 항에 있어서, 성분(C)가 메틸 디콜인 방법. To claim 20 according to any one of claim 22 Compounds ingredient method of (C) is methyl dikol.
  25. 제20항 내지 제24항중의 어느 한 항에 있어서, 이산화탄소(성부(E))를, 성분(A) 내지 (D)와 성분(F)사이의 반응 말기에, 성분(B)를 1회 첨가한 후 연속하여 가하는 방법. 21. The method of claim 20 to any one of claim 24 Compounds, carbon dioxide (part (E)) The component (A) to (D) and the component (F) in the reaction end-stage between the addition once the component (B) the continuous method of applying a post.
  26. 제20항 내지 제25항중의 어느 한 항에 있어서, 희석제가 존재하는 방법. 21. The apparatus of claim 20 according to any one of the preceding Compounds of claim 25, wherein the diluent is present.
  27. 제20항 내지 제26항중의 어느 한 항에 있어서, 성분(A)로서 이미 존재하는 황에 대한 추가의 황을 반응 혼합물에 가하는 방법. To claim 20 according to any one of claim 26 Compounds, methods of applying more of the sulfur to sulfur already present as component (A) in the reaction mixture.
  28. 제20항 내지 제27항중의 어느 한 항에 있어서, 반응을 촉매의 존재하에 수행하는 방법. 21. The apparatus of claim 20 according to any one of the preceding Compounds of claim 27, wherein to carry out the reaction in the presence of a catalyst.
  29. 제28항에 있어서, 촉매가 염화칼슘인 방법. 29. The method of claim 28, wherein the catalyst is calcium chloride.
  30. 윤활유, 및 0.5 내지 120의 TBN을 제공하기 충분한 양의 제1항 내지 제18항중의 어느 한 항에 청구한 부가 농축물을 함유하는 가공 윤활유 조성물. Processing the lubricating oil composition containing the added concentrate charged to the lubricating oil, and 0.5 of claim 1 in an amount sufficient to provide a TBN of from 120 to to any one of claim 18 Compounds.
  31. 제30항에 있어서, 윤활유가 선박용 윤활유이고 9 내지 100의 TBN을 제공하기 충분한 양의 부가 농축물이 존재하는 가공 윤활유 조성물. The method of claim 30 wherein processing the lubricating oil composition of the lubricating oil is a marine lubricating oil a sufficient amount of the added concentrate exists to provide a TBN of 9 to 100.
  32. 제30항에 있어서, 윤활유가 자동차 기관용 윤활유이고 4 내지 20의 TBN을 제공하기 충분한 양의 부가 농축물이 존재하는 가공 윤활유 조성물. The method of claim 30 wherein processing the lubricating oil composition of the lubricant to the lubricant car agencies, and a sufficient amount of the added concentrate exists to provide a TBN of from 4 to 20.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임. ※ Note: Will you disclose by the first application information.
KR1019880700889A 1986-11-29 1987-11-26 Sulfurized alkaline earth metal hydrocarbyl phenates, their preparation and use KR890700158A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB868628609A GB8628609D0 (en) 1986-11-29 1986-11-29 Lubricating oil additives
GB8628609 1986-11-29
PCT/GB1987/000848 WO1988003945A1 (en) 1986-11-29 1987-11-26 Sulphurised alkaline earth metal hydrocarbyl phenates, their production and use thereof

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KR890700158A true KR890700158A (en) 1989-03-10

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Application Number Title Priority Date Filing Date
KR88700896A KR960010992B1 (en) 1986-11-29 1987-11-26 Alkaline earth metal hydrocarbyl phenates, their sulphurised derivatives, their production and the use thereof
KR1019880700889A KR890700158A (en) 1986-11-29 1987-11-26 Sulfurized alkaline earth metal hydrocarbyl phenates, their preparation and use
KR88700889A KR960010991B1 (en) 1986-11-29 1987-11-26 Sulphurised alkaline earth metal hydrocarbyl phenates, their production and use thereof
KR1019880700896A KR897000159A (en) 1986-11-29 1987-11-26 Alkaline earth metal hydrocarbyl phenates, their sulfide, organic conductors, their preparation and use thereof

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KR88700889A KR960010991B1 (en) 1986-11-29 1987-11-26 Sulphurised alkaline earth metal hydrocarbyl phenates, their production and use thereof
KR1019880700896A KR897000159A (en) 1986-11-29 1987-11-26 Alkaline earth metal hydrocarbyl phenates, their sulfide, organic conductors, their preparation and use thereof

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EP (2) EP0273588B2 (en)
JP (2) JPH0631383B2 (en)
KR (4) KR960010992B1 (en)
CN (2) CN1012074B (en)
AT (2) AT79396T (en)
AU (2) AU609075B2 (en)
BR (2) BR8707550A (en)
CA (2) CA1305697C (en)
DE (4) DE3781126T3 (en)
DK (2) DK419788A (en)
ES (2) ES2051752T3 (en)
FI (2) FI93653C (en)
GB (1) GB8628609D0 (en)
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IN (2) IN172581B (en)
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AU608792B2 (en) 1991-04-18
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JPH0631384B2 (en) 1994-04-27
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