KR20240104471A - Small type water purifier using Activiated Carbon fiber and Calcium Mineral particles - Google Patents
Small type water purifier using Activiated Carbon fiber and Calcium Mineral particles Download PDFInfo
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- KR20240104471A KR20240104471A KR1020220186745A KR20220186745A KR20240104471A KR 20240104471 A KR20240104471 A KR 20240104471A KR 1020220186745 A KR1020220186745 A KR 1020220186745A KR 20220186745 A KR20220186745 A KR 20220186745A KR 20240104471 A KR20240104471 A KR 20240104471A
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- activated carbon
- carbon fiber
- layer
- calcium mineral
- mineral particles
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 229910001576 calcium mineral Inorganic materials 0.000 title claims abstract description 36
- 239000002245 particle Substances 0.000 title claims abstract description 36
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 229920000049 Carbon (fiber) Polymers 0.000 title description 4
- 239000004917 carbon fiber Substances 0.000 title description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 33
- 238000000746 purification Methods 0.000 claims abstract description 32
- 239000000835 fiber Substances 0.000 claims description 17
- 229920000742 Cotton Polymers 0.000 abstract description 10
- 238000001179 sorption measurement Methods 0.000 abstract description 10
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 5
- 239000000460 chlorine Substances 0.000 abstract description 5
- 229910052801 chlorine Inorganic materials 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000003205 fragrance Substances 0.000 abstract description 2
- 239000005416 organic matter Substances 0.000 abstract 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 16
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 12
- 229910000019 calcium carbonate Inorganic materials 0.000 description 8
- 235000010216 calcium carbonate Nutrition 0.000 description 8
- 229920001661 Chitosan Polymers 0.000 description 7
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 6
- 229910002092 carbon dioxide Inorganic materials 0.000 description 6
- 230000005484 gravity Effects 0.000 description 6
- 229910001385 heavy metal Inorganic materials 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 3
- 239000000292 calcium oxide Substances 0.000 description 3
- 235000012255 calcium oxide Nutrition 0.000 description 3
- 239000003456 ion exchange resin Substances 0.000 description 3
- 229920003303 ion-exchange polymer Polymers 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 229910000020 calcium bicarbonate Inorganic materials 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 235000019645 odor Nutrition 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000012855 volatile organic compound Substances 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 241000242757 Anthozoa Species 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 235000014653 Carica parviflora Nutrition 0.000 description 1
- 229920000426 Microplastic Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical compound [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 210000003278 egg shell Anatomy 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012510 hollow fiber Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- -1 trihalomethanes Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/16—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
- B01D39/1607—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous
- B01D39/1615—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of natural origin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/20—Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
- B01D39/2055—Carbonaceous material
- B01D39/2065—Carbonaceous material the material being fibrous
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/04—Additives and treatments of the filtering material
- B01D2239/0407—Additives and treatments of the filtering material comprising particulate additives, e.g. adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/04—Additives and treatments of the filtering material
- B01D2239/0414—Surface modifiers, e.g. comprising ion exchange groups
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Water Treatment By Sorption (AREA)
Abstract
본 발명의 활성탄소섬유와 칼슘미네랄입자를 이용한 소형 정수필터는 제1면섬유층, 칼슘미네랄층, 활성탄소입자층, 활성탄소섬유층 및 제2면섬유층을 포함하는 것을 특징으로 한다. 또한 본 발명의 활성탄소섬유와 칼슘미네랄입자를 이용한 소형 정수필터에서, 칼슘미네랄층은 Cd2+, Pb2+, Cu2+, Zn2+ 없고, 상기 활성탄소입자층과 활성탄소섬유층에는 향료, 유기물 및 염소가 없는 것을 특징으로 한다.
본 발명에 의하면, 가격이 저렴한 칼슘미네랄 입자를 사용함으로 필터 제조 원가를 절감할 수 있는 효과가 있고, 칼슘 미네랄 입자의 크기가 작아서 흡착속도가 빠르므로 제품의 크기를 작게 할 수 있는 장점이 있다.The small water purification filter using activated carbon fiber and calcium mineral particles of the present invention is characterized by comprising a first cotton fiber layer, a calcium mineral layer, an activated carbon particle layer, an activated carbon fiber layer, and a second cotton fiber layer. In addition, in the small water purification filter using activated carbon fiber and calcium mineral particles of the present invention, the calcium mineral layer is free of Cd2+, Pb2+, Cu2+, and Zn2+, and the activated carbon particle layer and activated carbon fiber layer are free of fragrance, organic matter, and chlorine. do.
According to the present invention, the filter manufacturing cost can be reduced by using inexpensive calcium mineral particles, and the adsorption rate is fast due to the small size of the calcium mineral particles, so the product size can be reduced.
Description
본 발명은 활성탄소섬유와 칼슘미네랄입자를 이용한 소형 정수필터에 관한 것이다. 더욱 상세하게는, 칼슘미네랄입자를 주성분으로 하는 다기능 소형 정수필터에 관한 것이다. The present invention relates to a small water purification filter using activated carbon fiber and calcium mineral particles. More specifically, it relates to a multi-functional small water purification filter containing calcium mineral particles as its main component.
중력방식의 정수장치는 가격이 저렴하며, 필터를 쉽게 교체할 수 있고, 전기를 사용하지 않으며, 설치가 필요 없고, 부피가 작다는 장점들이 있어서 동남아시아 등 저개발 국가의 저소득층 및 전기가 들어오지 않는 지역의 주민들이 많이 선호하고 있는 정수장치이다.Gravity-type water purification devices have the advantages of being inexpensive, filters can be easily replaced, no electricity, no installation required, and small size, so they are used by low-income people in underdeveloped countries such as Southeast Asia and in areas without electricity. This is a widely preferred water purification device.
그러나 종래의 중력식 정수장치는 이온교환에 의해 오염물질 들을 정전기적 인력으로 흡착하기 때문에 접촉시간이 중요하다. 따라서 유속이 빨라질수록 오염물질 제거 성능이 낮아지며, 빠른 정수속도와 높은 중금속 제거율을 동시에 만족시키기가 어려운 문제가 있었다. However, contact time is important because conventional gravity water purification devices adsorb contaminants through electrostatic attraction through ion exchange. Therefore, the faster the flow rate, the lower the pollutant removal performance, and it was difficult to satisfy both a fast water purification rate and a high heavy metal removal rate at the same time.
본 발명의 배경기술은 출원인이 발명한 공개특허공보 제10-2020-0064593호 (공개일: 2020. 6. 8.)“무전원 중력방식 정수기용 필터”는 정수처리속도를 개선하고, 이물질 제거 능력도 우수한 무전원 중력방식 정수기용 필터에 관한 것으로서, 필터는 이온교환수지층, 활성탄층 및 활성탄소섬유층을 포함하여 이루어져 있다. 이 발명은 종래에 비해 정수처리속도를 개선하고 중금속 제거율을 높게 유지하는 것이 특징이다. 본 발명은 상기 무전원 중력방식 정수기용 필터의 문제점을 개선한 발명이다. The background technology of the present invention is the “filter for non-powered gravity water purifier” invented by the applicant in Publication No. 10-2020-0064593 (publication date: June 8, 2020), which improves the water purification speed and has the ability to remove foreign substances. It also relates to an excellent non-powered gravity type water purifier filter, where the filter includes an ion exchange resin layer, an activated carbon layer, and an activated carbon fiber layer. This invention is characterized by improving the water purification speed and maintaining a high heavy metal removal rate compared to the prior art. The present invention is an invention that improves the problems of the filter for the non-powered gravity water purifier.
본 발명의 해결하고자 하는 과제는 이온교환수지를 사용하지 않고, 칼슘미네랄 입자를 사용함으로 필터 제조 원가를 절감할 수 있는 활성탄소섬유와 칼슘미네랄입자를 이용한 소형 정수필터를 제공하는 데에 있다.The problem to be solved by the present invention is to provide a small water purification filter using activated carbon fiber and calcium mineral particles that can reduce the filter manufacturing cost by using calcium mineral particles without using ion exchange resin.
본 발명의 활성탄소섬유와 칼슘미네랄입자를 이용한 소형 정수필터는 제1면섬유층, 칼슘미네랄층, 활성탄소입자층, 활성탄소섬유층 및 제2면섬유층을 포함하는 것을 특징으로 한다. The small water purification filter using activated carbon fiber and calcium mineral particles of the present invention is characterized by comprising a first cotton fiber layer, a calcium mineral layer, an activated carbon particle layer, an activated carbon fiber layer, and a second cotton fiber layer.
또한 본 발명의 활성탄소섬유와 칼슘미네랄입자를 이용한 소형 정수필터에서 In addition, in a small water purification filter using activated carbon fiber and calcium mineral particles of the present invention,
칼슘미네랄층의 두께는 10~30mm이고, 활성탄소입자층의 두께는 5~30mm이며, 활성탄소섬유층의 두께는 3~10mm이다. The thickness of the calcium mineral layer is 10 to 30 mm, the thickness of the activated carbon particle layer is 5 to 30 mm, and the thickness of the activated carbon fiber layer is 3 to 10 mm.
본 발명에 의하면, 이온교환수지를 사용하지 않기 때문에, 미세플라스틱을 유발하지 않고 석유화학의 사용을 절감하기 때문에 친환경적이다. According to the present invention, since ion exchange resin is not used, it is environmentally friendly because it does not cause microplastics and reduces the use of petrochemicals.
또한 본 발명에 의하면, 가격이 저렴한 칼슘미네랄 입자를 사용함으로 필터 제조 원가를 절감할 수 있는 효과가 있다. In addition, according to the present invention, the filter manufacturing cost can be reduced by using inexpensive calcium mineral particles.
또한 본 발명에 의하면, 칼슘 미네랄 입자의 크기가 작아서 흡착속도가 빠르므로 제품의 크기를 작게 할 수 있는 장점이 있다. In addition, according to the present invention, the size of the calcium mineral particles is small and the adsorption rate is fast, so there is an advantage in that the size of the product can be reduced.
도 1은 본 발명의 일실시예에 따른 활성탄소섬유와 칼슘미네랄입자를 이용한 소형 정수필터의 단면도.
도 2는 본 발명의 본 발명의 일실시예에 따른 소형 정수필터의 구조도.
도 3은 본 발명의 소형 정수필터 사용을 나타낸 사진. Figure 1 is a cross-sectional view of a small water purification filter using activated carbon fiber and calcium mineral particles according to an embodiment of the present invention.
Figure 2 is a structural diagram of a small water purification filter according to an embodiment of the present invention.
Figure 3 is a photograph showing the use of a small water purification filter of the present invention.
이하, 본 발명을 도면을 참고하여 상세하게 설명한다. Hereinafter, the present invention will be described in detail with reference to the drawings.
도 1은 본 발명의 일실시예에 따른 활성탄소섬유와 칼슘미네랄입자를 이용한 소형 정수필터의 단면도이고, 도 2는 본 발명의 일실시예에 따른 소형 정수필터의 구조도이고, 도 3은 본 발명의 소형 정수필터 사용을 나타낸 사진이다. Figure 1 is a cross-sectional view of a small water purification filter using activated carbon fiber and calcium mineral particles according to an embodiment of the present invention, Figure 2 is a structural diagram of a small water purification filter according to an embodiment of the present invention, and Figure 3 is a schematic diagram of the present invention. This photo shows the use of a small water purification filter.
도 1은 본 발명의 일실시예에 따른 활성탄소섬유와 칼슘미네랄입자를 이용한 소형 정수필터의 단면도이다.Figure 1 is a cross-sectional view of a small water purification filter using activated carbon fiber and calcium mineral particles according to an embodiment of the present invention.
도 1에 도시된 바와 같이, 본 발명의 일 실시예에 따른 소형 정수필터(10)는 위에서부터 제1면섬유층(14: Natural pulp fiber), 칼슘미네랄층(11: Calcium Minerals), 활성탄소입자층(12: AC(Carbon graules)), 활성탄소섬유층(13: ACF(Cabon fiber)) 및 제2면섬유층(15: Natural pulp fiber) 순서대로 적층되어 구성된다. As shown in Figure 1, the small water purification filter 10 according to an embodiment of the present invention includes, from the top, a first cotton fiber layer (14: Natural pulp fiber), a calcium mineral layer (11: Calcium Minerals), and an activated carbon particle layer. (12: AC (Carbon graules)), activated carbon fiber layer (13: ACF (Cabon fiber)), and second cotton fiber layer (15: Natural pulp fiber) are laminated in that order.
활성탄소섬유(Activated Carbon Fiber: ACF)는 아크릴수지, 석유 또는 석탄에서 얻어지는 피치 등의 유기물을 섬유로 만든 다음 특수한 열처리 공정을 거쳐 만들어지는 탄소섬유를 활성화시켜 제조한다. 활성탄소섬유는 활성탄에 비해 기공이 대부분 미세기공으로 구성된다.Activated Carbon Fiber (ACF) is manufactured by turning organic materials such as acrylic resin and pitch obtained from petroleum or coal into fiber and then activating the carbon fiber through a special heat treatment process. Compared to activated carbon, activated carbon fiber consists mostly of micropores.
활성탄소섬유는 환경 활성탄의 흡착 성능을 향상시키기 위하여 섬유의 형태로 가공한 물질. 접착 섬유, 폴리아크릴로니트릴 섬유, 피치계 탄소 섬유 등이 있다. 활성탄소섬유는 흡착ㆍ탈착 속도가 빠르고 정화 효과가 뛰어나 유기 폐가스를 효과적으로 처리할 수 있고, 기공 크기가 비교적 균일하여 분자체 효과가 뛰어나고, 섬유 직경(6~10㎛)이 작아서 균일한 흡착 특성을 얻을 수 있다. Activated carbon fiber is a material processed into a fiber form to improve the adsorption performance of environmental activated carbon. There are adhesive fibers, polyacrylonitrile fibers, pitch-based carbon fibers, etc. Activated carbon fiber has a fast adsorption and desorption speed and an excellent purification effect, so it can effectively treat organic waste gas. Its pore size is relatively uniform, so it has an excellent molecular sieve effect, and its small fiber diameter (6~10㎛) provides uniform adsorption characteristics. You can get it.
또한 활성탄소섬유는 내부기공이 모두 외부 표면에 직접 연결되어 있어서 물질 전달 속도가 매우 빠르고, 인장강도와 탄성률이 우수하며, 열/전기전도도, 밀도 등의 물성 조절이 쉽고, 내열성, 내부식성, 내층격성이 우수하고, 고온에서의 열팽창 수축이 거의 없는 성질 등 활성탄에 비해 매우 우수한 특성이 있다. In addition, activated carbon fiber has all internal pores directly connected to the external surface, so the mass transfer speed is very fast, the tensile strength and elastic modulus are excellent, and physical properties such as thermal/electrical conductivity and density can be easily adjusted, as well as heat resistance, corrosion resistance, and inner layer. It has excellent properties compared to activated carbon, including excellent toughness and almost no thermal expansion or contraction at high temperatures.
본 발명의 일실시예에서 바람직한 활성탄소입자층(12)의 두께는 5~30mm인 것이 특징이다. In one embodiment of the present invention, the thickness of the activated carbon particle layer 12 is preferably 5 to 30 mm.
탄산칼슘(calcium carbonate)은 대리석·방해석·조개껍데기·달걀껍데기·산호 등에서 산출되는 무기 화합물이다. 탄산칼슘은 화학식 CaCO3으로 자연계에 존재하는 염 중에서 가장 많고, 일반적으로 무색의 결정 또는 백색 고체로, 비중 2.93이며, 825℃에서 분해한다. 탄산칼슘은 가열하면 이산화탄소를 발생하고 생석회를 얻는다. Calcium carbonate is an inorganic compound produced from marble, calcite, seashells, eggshells, corals, etc. Calcium carbonate, with the chemical formula CaCO3, is the most abundant salt in nature and is generally a colorless crystal or white solid with a specific gravity of 2.93 and decomposes at 825°C. When calcium carbonate is heated, it generates carbon dioxide and quicklime is obtained.
탄산칼슘 반응은 이산화탄소와 생석회를 공업적으로 얻기 위한 중요한 반응이다. 화학식 CaCO3 → CaO+CO2↑ 순수한 물에는 용해하지 않으나, 이산화탄소를 함유하는 물에는 용해하여, 탄산수소칼슘을 생성하며 녹는다. CaCO3+CO2+H2O ↔ Ca(HCO3)2 또, 탄산칼슘에 산을 작용시키면 이산화탄소를 발생한다.Calcium carbonate reaction is an important reaction for obtaining carbon dioxide and quicklime industrially. Chemical formula CaCO3 → CaO+CO2↑ It is insoluble in pure water, but dissolves in water containing carbon dioxide, producing calcium bicarbonate. CaCO3+CO2+H2O ↔ Ca(HCO3)2 Also, when acid acts on calcium carbonate, carbon dioxide is generated.
도 1에 도시된 최선의 실시예는 칼슘미네랄층(11)두께는 10~30mm이고, 활성탄소입자층(12)의 두께는 5~30mm이며, 활성탄소섬유층(13)의 두께는 3~10mm이다. In the best embodiment shown in Figure 1, the thickness of the calcium mineral layer 11 is 10 to 30 mm, the thickness of the activated carbon particle layer 12 is 5 to 30 mm, and the thickness of the activated carbon fiber layer 13 is 3 to 10 mm. .
도 2는 본 발명의 일실시예에 따른 소형 정수필터의 구조도이다. Figure 2 is a structural diagram of a small water purification filter according to an embodiment of the present invention.
본 발명의 일실시예에 따른 소형 정수필터는 위에서부터 제1면섬유층, 칼슘미네랄층, 활성탄소입자층, 활성탄소섬유층 및 제2면섬유층으로 구성된다. A small water purification filter according to an embodiment of the present invention is composed of a first cotton fiber layer, a calcium mineral layer, an activated carbon particle layer, an activated carbon fiber layer, and a second cotton fiber layer from the top.
상기 칼슘미네랄층에 Cd2+, Pb2+, Cu2+, Zn2+ 이 제거된다. 상기 활성탄소입자층에 향료(Odor), 유기물(Organics) 및 염소(Chlorine)가 제거되고, 상기 활성탄소섬유층에도 향료, 유기물 및 염소가 제거된다. Cd2+, Pb2+, Cu2+, and Zn2+ are removed from the calcium mineral layer. Odors, organics and chlorine are removed from the activated carbon particle layer, and fragrances, organic substances and chlorine are also removed from the activated carbon fiber layer.
본 발명의 일실시예에 따른 활성탄소섬유와 칼슘미네랄입자를 이용한 소형 정수필터는 키토산섬유를 사용한다. 상기 키토산섬유는 속이 비어있는 중공섬유일 수 있다. 키토산섬유에 화학처리를 통해 성능을 향상 시킬 수 있다. A small water purification filter using activated carbon fiber and calcium mineral particles according to an embodiment of the present invention uses chitosan fiber. The chitosan fiber may be a hollow fiber. The performance of chitosan fiber can be improved through chemical treatment.
키토산섬유를 사용하면, 중금속 제거, 잔류염소, 화학물질 제거를 동시에 할 수 있어 다른 소재를 넣을 필요가 없으므로, 필터 제조 공정이 단순해지는 장점이 있다. 키토산섬유는 무수히 많은 미세공(micropore)으로 형성되므로 흡착용량이 크며, 미세공이 표면에 발달되어 있기 때문에 흡착속도가 매우 빠르다. 이는 유리잔류염소, 트리할로메탄류, 클로로포름 등 휘발성 유기화합물(VOC), 납 등을 효과적으로 흡착할 수 있다. 또한 아민 냄새 제거, 메틸메르 캅탄 제거 능력을 가지고 있다. Using chitosan fiber has the advantage of simplifying the filter manufacturing process because it can remove heavy metals, residual chlorine, and chemicals at the same time, eliminating the need to add other materials. Chitosan fiber has a large adsorption capacity because it is formed of countless micropores, and because the micropores are developed on the surface, the adsorption speed is very fast. It can effectively adsorb free residual chlorine, trihalomethanes, volatile organic compounds (VOCs) such as chloroform, lead, etc. It also has the ability to remove amine odor and methyl mercaptan.
본 발명의 일실시예에서 키토산섬유는 카드뮴, 철, 구리와 같은 중금속 이온들에 대한 흡착 능력은 매우 약하다. 이러한 중금속 이온들을 제거하기 위해 키토산섬유를 이용하여 표면개질할 경우 카드뮴, 철, 구리의 흡착량 및 흡착속도가 개선된다. 본 발명의 일실시예에 따른 활성탄소섬유와 칼슘미네랄입자를 이용한 소형 정수필터는 통수 속도가 두 배 이상 개선됨과 동시에 중금속 제거율도 우수하다. In one embodiment of the present invention, chitosan fiber has a very weak adsorption ability for heavy metal ions such as cadmium, iron, and copper. When the surface is modified using chitosan fiber to remove these heavy metal ions, the adsorption amount and adsorption rate of cadmium, iron, and copper are improved. A small water purification filter using activated carbon fiber and calcium mineral particles according to an embodiment of the present invention improves the water flow rate by more than two times and also has an excellent heavy metal removal rate.
또한 본 발명의 활성탄소섬유와 칼슘미네랄입자를 이용한 소형 정수필터는 무전원 중력방식 정수기용 필터에 비해 우월한 정수 효과가 있다.In addition, the small water purification filter using activated carbon fiber and calcium mineral particles of the present invention has a superior water purification effect compared to filters for non-powered gravity water purifiers.
이상에서 본 발명의 바람직한 실시예를 설명하였으나, 본 발명의 실시예와 실질적으로 균등한 범위까지 본 발명의 권리범위가 미치는 것으로 해석되어야 하며, 본 발명의 기술사상 범위 내에서 당해 발명이 속하는 기술분야에서 통상의 지식을 가진 자에 의해 다양한 변형 실시가 가능하다.Although the preferred embodiments of the present invention have been described above, the scope of the present invention should be interpreted as extending to a range substantially equivalent to the embodiments of the present invention, and the technical field to which the invention belongs within the scope of the technical idea of the present invention Various modifications can be made by those skilled in the art.
본 발명의 활성탄소섬유와 칼슘미네랄입자를 이용한 소형 정수필터는 가격이 저렴한 칼슘미네랄 입자를 사용함으로 필터 제조 원가를 절감할 수 있는 효과가 있으므로 정수기용 필터 산업에 매우 유용한 발명이다.The small water purification filter using activated carbon fiber and calcium mineral particles of the present invention is a very useful invention in the water purifier filter industry because it has the effect of reducing filter manufacturing costs by using inexpensive calcium mineral particles.
10: 정수기용 필터
11: 칼슘미네랄층 12: 활성탄소입자층
13: 활성탄소섬유층 14: 제1면섬유층
15: 제2면섬유층 10: Filter for water purifier
11: Calcium mineral layer 12: Activated carbon particle layer
13: activated carbon fiber layer 14: first cotton fiber layer
15: Second cotton fiber layer
Claims (3)
제1면섬유층, 칼슘미네랄층, 활성탄소입자층, 활성탄소섬유층 및 제2면섬유층을 포함하는 것을 특징으로 하는 활성탄소섬유와 칼슘미네랄입자를 이용한 소형 정수필터.
In the filter for water purifier,
A small water purification filter using activated carbon fiber and calcium mineral particles, comprising a first surface fiber layer, a calcium mineral layer, an activated carbon particle layer, an activated carbon fiber layer, and a second surface fiber layer.
The small water purification filter using activated carbon fiber and calcium mineral particles according to claim 1, wherein the calcium mineral layer has a thickness of 10 to 30 mm.
The small water purification filter using activated carbon fiber and calcium mineral particles according to claim 1, wherein the thickness of the activated carbon particle layer is 5 to 30 mm, and the thickness of the activated carbon fiber layer is 3 to 10 mm.
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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KR100298977B1 (en) | 1993-03-31 | 2001-10-22 | 시게후치 마사토시 | Water Purification Method and Apparatus |
KR200430713Y1 (en) | 2006-08-30 | 2006-11-13 | 차선재 | A water filter containing chitosan. |
KR20200064593A (en) | 2018-11-29 | 2020-06-08 | 최순범 | Filter for non-electric power gravity type water purifier |
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Publication number | Priority date | Publication date | Assignee | Title |
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KR100298977B1 (en) | 1993-03-31 | 2001-10-22 | 시게후치 마사토시 | Water Purification Method and Apparatus |
KR200430713Y1 (en) | 2006-08-30 | 2006-11-13 | 차선재 | A water filter containing chitosan. |
KR20200064593A (en) | 2018-11-29 | 2020-06-08 | 최순범 | Filter for non-electric power gravity type water purifier |
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