KR20230160342A - 열경화성 수지 조성물, 유전체 기판, 및 마이크로스트립 안테나 - Google Patents
열경화성 수지 조성물, 유전체 기판, 및 마이크로스트립 안테나 Download PDFInfo
- Publication number
- KR20230160342A KR20230160342A KR1020237036072A KR20237036072A KR20230160342A KR 20230160342 A KR20230160342 A KR 20230160342A KR 1020237036072 A KR1020237036072 A KR 1020237036072A KR 20237036072 A KR20237036072 A KR 20237036072A KR 20230160342 A KR20230160342 A KR 20230160342A
- Authority
- KR
- South Korea
- Prior art keywords
- resin composition
- thermosetting resin
- curing agent
- group
- titanate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000011342 resin composition Substances 0.000 title claims abstract description 262
- 229920001187 thermosetting polymer Polymers 0.000 title claims abstract description 217
- 239000000758 substrate Substances 0.000 title claims description 91
- 229920005989 resin Polymers 0.000 claims abstract description 157
- 239000011347 resin Substances 0.000 claims abstract description 157
- 239000000945 filler Substances 0.000 claims abstract description 134
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 71
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 45
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 45
- 239000011777 magnesium Substances 0.000 claims abstract description 45
- AOWKSNWVBZGMTJ-UHFFFAOYSA-N calcium titanate Chemical compound [Ca+2].[O-][Ti]([O-])=O AOWKSNWVBZGMTJ-UHFFFAOYSA-N 0.000 claims abstract description 30
- DJOYTAUERRJRAT-UHFFFAOYSA-N 2-(n-methyl-4-nitroanilino)acetonitrile Chemical compound N#CCN(C)C1=CC=C([N+]([O-])=O)C=C1 DJOYTAUERRJRAT-UHFFFAOYSA-N 0.000 claims abstract description 24
- VEALVRVVWBQVSL-UHFFFAOYSA-N strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 claims abstract description 22
- FFQALBCXGPYQGT-UHFFFAOYSA-N 2,4-difluoro-5-(trifluoromethyl)aniline Chemical compound NC1=CC(C(F)(F)F)=C(F)C=C1F FFQALBCXGPYQGT-UHFFFAOYSA-N 0.000 claims abstract description 12
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 12
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910021523 barium zirconate Inorganic materials 0.000 claims abstract description 12
- DQBAOWPVHRWLJC-UHFFFAOYSA-N barium(2+);dioxido(oxo)zirconium Chemical compound [Ba+2].[O-][Zr]([O-])=O DQBAOWPVHRWLJC-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910002115 bismuth titanate Inorganic materials 0.000 claims abstract description 12
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 12
- 239000011701 zinc Substances 0.000 claims abstract description 12
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 12
- IJBYNGRZBZDSDK-UHFFFAOYSA-N barium magnesium Chemical compound [Mg].[Ba] IJBYNGRZBZDSDK-UHFFFAOYSA-N 0.000 claims abstract description 11
- HFGPZNIAWCZYJU-UHFFFAOYSA-N lead zirconate titanate Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Zr+4].[Pb+2] HFGPZNIAWCZYJU-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052451 lead zirconate titanate Inorganic materials 0.000 claims abstract description 11
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- 239000003822 epoxy resin Substances 0.000 claims description 209
- 229920000647 polyepoxide Polymers 0.000 claims description 209
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 88
- 239000003054 catalyst Substances 0.000 claims description 50
- 229920003986 novolac Polymers 0.000 claims description 43
- 125000004432 carbon atom Chemical group C* 0.000 claims description 41
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- 238000000034 method Methods 0.000 claims description 40
- 125000003118 aryl group Chemical group 0.000 claims description 33
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- 125000001624 naphthyl group Chemical group 0.000 claims description 29
- 230000005855 radiation Effects 0.000 claims description 27
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- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims description 22
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- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 16
- 239000006096 absorbing agent Substances 0.000 claims description 14
- 125000002947 alkylene group Chemical group 0.000 claims description 14
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical group OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 claims description 13
- 229930185605 Bisphenol Natural products 0.000 claims description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Chemical group CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 claims description 8
- 125000005708 carbonyloxy group Chemical group [*:2]OC([*:1])=O 0.000 claims description 8
- 125000004122 cyclic group Chemical group 0.000 claims description 8
- 125000001174 sulfone group Chemical group 0.000 claims description 8
- 125000000101 thioether group Chemical group 0.000 claims description 8
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 7
- 238000011144 upstream manufacturing Methods 0.000 claims description 7
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- 239000003989 dielectric material Substances 0.000 claims description 4
- -1 heterocyclic hydroxy compounds Chemical class 0.000 description 74
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 72
- 230000000694 effects Effects 0.000 description 40
- 150000002989 phenols Chemical class 0.000 description 40
- 239000011256 inorganic filler Substances 0.000 description 36
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 36
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- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 24
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- 239000000243 solution Substances 0.000 description 23
- 238000000465 moulding Methods 0.000 description 22
- 239000002245 particle Substances 0.000 description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 21
- 125000000217 alkyl group Chemical group 0.000 description 21
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 21
- 238000005452 bending Methods 0.000 description 20
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 19
- XYFCBTPGUUZFHI-UHFFFAOYSA-N phosphine group Chemical group P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 239000007788 liquid Substances 0.000 description 17
- 229910052757 nitrogen Inorganic materials 0.000 description 17
- 239000005011 phenolic resin Substances 0.000 description 17
- 238000001816 cooling Methods 0.000 description 16
- 238000010926 purge Methods 0.000 description 16
- 239000000203 mixture Substances 0.000 description 15
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 12
- 125000003545 alkoxy group Chemical group 0.000 description 12
- 239000003086 colorant Substances 0.000 description 12
- 238000004891 communication Methods 0.000 description 12
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- 238000011156 evaluation Methods 0.000 description 12
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 12
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 11
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 11
- 125000002529 biphenylenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C12)* 0.000 description 10
- 125000004185 ester group Chemical group 0.000 description 10
- 125000000524 functional group Chemical group 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 10
- 150000003003 phosphines Chemical class 0.000 description 10
- 239000002994 raw material Substances 0.000 description 10
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- 230000000052 comparative effect Effects 0.000 description 9
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- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 9
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- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical group CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 8
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 8
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- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
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- 125000005199 aryl carbonyloxy group Chemical group 0.000 description 8
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- 230000018044 dehydration Effects 0.000 description 8
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- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 8
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
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- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 8
- 125000000962 organic group Chemical group 0.000 description 7
- 150000004714 phosphonium salts Chemical class 0.000 description 7
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
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- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 150000004780 naphthols Chemical class 0.000 description 6
- 125000001424 substituent group Chemical group 0.000 description 6
- SFRDXVJWXWOTEW-UHFFFAOYSA-N 2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)CO SFRDXVJWXWOTEW-UHFFFAOYSA-N 0.000 description 5
- GSKNLOOGBYYDHV-UHFFFAOYSA-N 2-methylphenol;naphthalen-1-ol Chemical compound CC1=CC=CC=C1O.C1=CC=C2C(O)=CC=CC2=C1 GSKNLOOGBYYDHV-UHFFFAOYSA-N 0.000 description 5
- GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 description 5
- 229920000877 Melamine resin Polymers 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 5
- 229910002113 barium titanate Inorganic materials 0.000 description 5
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 5
- 230000005540 biological transmission Effects 0.000 description 5
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- JRNGUTKWMSBIBF-UHFFFAOYSA-N naphthalene-2,3-diol Chemical compound C1=CC=C2C=C(O)C(O)=CC2=C1 JRNGUTKWMSBIBF-UHFFFAOYSA-N 0.000 description 5
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- CQOZJDNCADWEKH-UHFFFAOYSA-N 2-[3,3-bis(2-hydroxyphenyl)propyl]phenol Chemical compound OC1=CC=CC=C1CCC(C=1C(=CC=CC=1)O)C1=CC=CC=C1O CQOZJDNCADWEKH-UHFFFAOYSA-N 0.000 description 4
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 description 4
- QDBOAKPEXMMQFO-UHFFFAOYSA-N 4-(4-carbonochloridoylphenyl)benzoyl chloride Chemical compound C1=CC(C(=O)Cl)=CC=C1C1=CC=C(C(Cl)=O)C=C1 QDBOAKPEXMMQFO-UHFFFAOYSA-N 0.000 description 4
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- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 4
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- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 4
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- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 4
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 4
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- NXPPAOGUKPJVDI-UHFFFAOYSA-N naphthalene-1,2-diol Chemical compound C1=CC=CC2=C(O)C(O)=CC=C21 NXPPAOGUKPJVDI-UHFFFAOYSA-N 0.000 description 4
- 239000012299 nitrogen atmosphere Substances 0.000 description 4
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- 150000004053 quinones Chemical class 0.000 description 4
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- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 4
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- 239000000377 silicon dioxide Substances 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 4
- 229910052596 spinel Inorganic materials 0.000 description 4
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- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical class SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 4
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- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 3
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| JP2004315653A (ja) | 2003-04-16 | 2004-11-11 | Hitachi Chem Co Ltd | 樹脂組成物とその利用 |
| JP2018041998A (ja) | 2015-01-28 | 2018-03-15 | 日本化薬株式会社 | アンテナ、およびアンテナを有する電子装置 |
| JP2020105523A (ja) | 2020-02-21 | 2020-07-09 | 味の素株式会社 | 樹脂組成物 |
| JP6870778B1 (ja) | 2020-12-11 | 2021-05-12 | 昭和電工マテリアルズ株式会社 | 成形用樹脂組成物及び電子部品装置 |
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| JP2004124066A (ja) * | 2002-08-07 | 2004-04-22 | Toray Ind Inc | 高誘電体組成物 |
| JP3680854B2 (ja) | 2003-04-04 | 2005-08-10 | 東レ株式会社 | ペースト組成物およびこれを用いた誘電体組成物 |
| JP2008106106A (ja) | 2006-10-24 | 2008-05-08 | Hitachi Chem Co Ltd | 高誘電率樹脂組成物,プリプレグ及びプリント配線板用積層板 |
| CN103351578B (zh) * | 2013-07-19 | 2015-08-19 | 广东生益科技股份有限公司 | 一种用于形成天线用的介质基板的介质层的树脂组合物及其用途 |
| JP6066865B2 (ja) * | 2013-08-15 | 2017-01-25 | 信越化学工業株式会社 | 高誘電率エポキシ樹脂組成物および半導体装置 |
| TWI506077B (zh) | 2013-12-31 | 2015-11-01 | Taiwan Union Technology Corp | 樹脂組合物及其應用 |
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2023
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004315653A (ja) | 2003-04-16 | 2004-11-11 | Hitachi Chem Co Ltd | 樹脂組成物とその利用 |
| JP2018041998A (ja) | 2015-01-28 | 2018-03-15 | 日本化薬株式会社 | アンテナ、およびアンテナを有する電子装置 |
| JP2020105523A (ja) | 2020-02-21 | 2020-07-09 | 味の素株式会社 | 樹脂組成物 |
| JP6870778B1 (ja) | 2020-12-11 | 2021-05-12 | 昭和電工マテリアルズ株式会社 | 成形用樹脂組成物及び電子部品装置 |
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| JP7347713B2 (ja) | 2023-09-20 |
| WO2022202792A1 (ja) | 2022-09-29 |
| WO2022202781A1 (ja) | 2022-09-29 |
| KR20230161473A (ko) | 2023-11-27 |
| JP7396534B2 (ja) | 2023-12-12 |
| JP2023164926A (ja) | 2023-11-14 |
| JP7351434B2 (ja) | 2023-09-27 |
| KR20230160869A (ko) | 2023-11-24 |
| TW202248340A (zh) | 2022-12-16 |
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| JPWO2022202781A1 (https=) | 2022-09-29 |
| TW202248273A (zh) | 2022-12-16 |
| JP2023179419A (ja) | 2023-12-19 |
| JPWO2022202804A1 (https=) | 2022-09-29 |
| TW202248274A (zh) | 2022-12-16 |
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