KR20180023767A - Perfume composition representing the fragrance of Aerides japonicum - Google Patents

Abstract

The present invention relates to a flavoring composition for reproducing fragrance of Aerides japonicum, and more specifically, to a flavoring composition for reproducing fragrance of Aerides japonicum, which comprises: a fragrance component of the Aerides japonicum; and at least one component selected from a group consisting of hedine, phenyl ethyl alcohol and florol as active ingredients. In the composition of the present invention, the sensory evaluation result shows that the similarity degree with the intrinsic fragrance of the Aerides japonicum is high and the satisfaction of the fragrance is excellent, thereby being used as the fragrance composition, a home care product containing the fragrance composition, a personal care product, a cosmetic composition, and a composition for external application for skin.

Description

Perfume composition representing the fragrance of Aerial japonicum,

The present invention I pungran (Aerides The present invention relates to a perfume composition that reproduces the fragrance of flowers of japonicum flowers. More particularly, The present invention relates to a fragrance composition recreating the fragrance of a flowering flower comprising at least one component selected from the group consisting of hedine, phenyl ethyl alcohol and florol as an active ingredient. The present invention also relates to a home care product, a personal care product, a cosmetic composition, and a composition for external application for skin, which comprises the perfume composition.

Aerial japonicum is an evergreen perennial plant belonging to the Orchidaceae. It is a plant of the genus Arthropoda , which is a member of the Ordinance of the Ministry of Agriculture, Forestry and Fisheries, Article 184 (Enforcement Dec.30, 2015) It is a precious plant designated as a rare plant according to the paragraph. The plants are known to grow on trees or rocks in evergreen forests, and are known to grow in Jeju and Jeonnam (Maagado) in Korea. They are also reported to be distributed in Japan and some parts of China.

As I began to circulate in the horticultural market in the 1960s, I have been over-fertilized and the population has gradually decreased. Recently, the National Arboretum has been investigating the habitats of the wild boran for three years.

I also bloom from June to August with light green and white flowers, and 4 to 10 flowers are formed at the end of the flower stem of 5-12 cm length just out of the root. The bract is egg-shaped, the end is dull, and the calyx is 11 to 13 mm long, with a long elliptical shape and a dull end. Petal is shorter than calyx. Lip petal is similar in length to calyx and is divided into 3 pieces, all of which have light red spots, the outer piece is small and the middle piece is wedge shaped. Anther is white and lumps are yellow.

I also have a beautiful and fragrant flower, which is very different from other flowers. However, the existing solvent extraction method or steam distillation method is inevitable in that the loss of flavor due to heat is inevitable and the fragrance ingredient contained in the air is captured There is a problem in that there is a lot of difference from the original fragrance of the flowering flower even if it is collected. Therefore, there has been a demand for the development of a perfume composition which is differentiated and has new characteristics by artificially reproducing the natural flower fragrance.

Under these circumstances, the present inventors have also analyzed the fragrance component and the content of the flowering flower in order to reproduce the differentiated fragrance inherent to the flowering flower, and even when the analyzed component is artificially mixed with the analyzed content, It is difficult to obtain a similar fragrance, and by adding a new fragrance ingredient which does not exist in the natural fragrance flower, it is possible to reproduce the fragrance of the fragrance fragrance almost similarly.

Korean Patent Publication No. 10-1999-0004222

The object of the present invention is to provide an aerial japonicum ); And at least one component selected from the group consisting of hedione, phenyl ethyl alcohol and florol as an active ingredient is provided. will be.

Another object of the present invention is to provide a home care product comprising the perfume composition.

It is still another object of the present invention to provide a personal care product comprising the perfume composition.

It is still another object of the present invention to provide a cosmetic composition comprising the perfume composition.

Another object of the present invention is to provide a composition for external application for skin comprising the above-mentioned perfume composition.

The present invention solve the problems as described above and, as one aspect for achieving the object of the present invention, I pungran (Aerides japonicum ); And at least one component selected from the group consisting of hedine, phenyl ethyl alcohol and florol as an active ingredient is provided. .

In the present invention, " Aerides japonicum "is an evergreen perennial plant belonging to the orchid family. It is a wild flower of Korea. It is a perennial herbaceous perennial plant which grows on large tree trunks or rocks of evergreen broad-leaved trees in Jeju Island, Geomundo, Hongdo and Namhae Islands.

In the present invention, "fragrance" refers to an odor that enters the nose as a fragrant but slightly pungent odor. The fragrance of the present invention means a fragrance of a flowering flower as well as a sweet fragrance.

In the present invention, the term "fragrance" is an organic substance having a strong aroma added to add flavor to cosmetics, food products, and the like, and has excellent volatility at room temperature. Spices can be roughly classified into natural fragrance obtained from roses, lemons, etc., isolated fragrance separated and purified from raw materials such as low-priced natural fragrance and coal tar, and synthetic fragrance synthesized through chemical reaction. It is also called artificial fragrance by combining isolated flavor and synthetic flavor. By application, cosmetics can be divided into fragrances and food fragrances. Cosmetics fragrance is aimed only at fragrance, but food fragrance is mainly flavor with flavor. The perfume composition of the present invention is a perfume composition that reproduces the fragrance of a flowering flower. The perfume composition of the present invention further comprises hedione, phenyl ethyl alcohol and florol in the fragrance component of the flowering flower, And the similarity and satisfaction with the fragrance of the flowering flower (Table 8).

In the present invention, the fragrance components of the flowers of the flowers in the sky are also collectively referred to as the components analyzed by taking the fragrance of the flowers. Generally, fragrance is extracted by extraction with a solvent, distillation using water vapor, etc. However, the above methods are not suitable for extracting fragrance components by heating, , And the like, and there are many differences from the perfume characteristics of the original material. In addition, it is difficult to apply natural monuments such as spruce trees easily. Headspace and SPME (solid-phase microextraction) methods have been developed to overcome these disadvantages. These two methods do not require any pretreatment of the sample without solvent and do not require a large amount of sample, and can analyze the fragrance component with the sample itself so that it can reproduce the original fragrance of the sample Method.

In the present invention, the fragrance components of the above-mentioned meadow flowers include, but are not limited to, limonene, nerol, linalool, citral, and geraniol as main components Other additional components are alpha-pinene, anethol, L-carvone, methyl salicylate, myrcene, para- Para-cymene, and methyl benzoate.

The limonene is one kind of hydrocarbons belonging to terpenes, which is also called 1,8-p-mentadiene, and has a similar aroma to oranges and is used as a raw material for perfumes. D-limonene, which is one of the optical isomers, is contained in about 90% of the main component of orange oil, and is also contained in plant essential oils such as lemon oil, lime oil, and bergamot oil, and is widely distributed in plants. L-limonene, another optical isomer, is contained in the oils of pine and other plants, such as spearmint oil and turpentine oil, as well as peppermint oil. The nerol is a monoterpene contained in various gasoline such as lemongrass and hops. It is a colorless liquid and has a rose-like color and is used in perfume production. The linalool is a type of monterpene of the terpene family. It is known to have an excellent sedative effect. It has a pleasant fragrance and is used as a raw material for natural deodorant and fragrance. The citral is a type of terpene monoterpene which is known to be an oily liquid and does not dissolve in water but to be mixed with an alcohol ether. It has strong lemon flavor and is used as a food flavor or a soap flavor. Geraniol is a monoterpenoid and alcohol, and is a major component of rose oil, palmarosa oil and citronella oil, and also contains a small amount of essential oils such as geranium and lemon. It is not soluble in water but easily soluble in most organic solvents and appears to be a colorless or pale yellow oil. Geraniol has a rose-like fragrance and is also used to flavor peaches, raspberries, grapefruits, apples, plums, lime, oranges, lemons, watermelons, pineapples and blueberries.

In one embodiment of the present invention, the fragrance components of the flowering flowers were analyzed using the headspace method. As a result, the major fragrance components of the flowering flowers were limonene, nerol, linalool, citral and geraniol were identified and alpha-pinene, anethol, L-carvone, methyl salinate, Methyl salicylate, myrcene, para-cymene and methyl benzoate were identified (Table 1).

The fragrance composition of the present invention further includes hedione, phenyl ethyl alcohol, and florol in the fragrance component of the above-mentioned Iris flower, so that I can reproduce the fragrance of the flower in the landscape. Specifically, the perfume composition of the present invention may contain florol or phenylethyl alcohol in the fragrance component of the above-mentioned floristic flower, and more specifically, the fragrance composition of the present invention may contain the fragrance component of the above- Roll or phenylethyl alcohol, and may additionally contain a hedonic. In one embodiment of the present invention, it was confirmed that the fragrance added with florol or phenylethyl alcohol to the fragrance component of the above-mentioned meadow flowers has the highest degree of similarity and satisfaction with the fragrance of the spider flowers (Table 8).

The hedione is a kind of ester, which is a diffusible perfume, and is also called methyl dihydrojasmonate. In addition, a jasmine-like flavor is produced, and a racemic mixture has a floral-like aroma and a citrus-like aroma. The phenylethyl alcohol is a colorless liquid which can be mixed with most organic solvents and is known to be partially soluble in water and is also referred to as 2-phenylethanol. It also has a rose-like appearance and is generally used as a perfume or fragrance ingredient. The florol is fresh, soft and has a natural floral scent, and is used as a raw material in many of these fragrances without any particular modification, and 4-methyl-2- (2-methylpropyl) 2- (2-methylpropyl) oxan-4-ol).

In one embodiment of the present invention, it was confirmed that, in the case of the fragrance added with florol, phenylethyl alcohol and / or hedonic in the fragrance component of the above-mentioned meadow flowers, the degree of similarity and satisfaction with the faded flower fragrance was also excellent 8).

Specifically, the present invention provides a fragrance composition recreating the fragrance of a flower of a wild flower comprising the following ingredients.

Specifically, the perfume composition comprises 1 to 70 parts by weight of limonene, 1 to 50 parts by weight of nerol, 1 to 50 parts by weight of linar, 1 to 50 parts by weight of citral, 1 to 30 parts by weight of More specifically, the total content of the five components may be 30 to 90 parts by weight based on 100 parts by weight of the total composition, and more specifically, the total content of the five components May be 50 to 80 parts by weight based on 100 parts by weight of the total composition.

The perfume composition may further contain 0.1 to 10.0 parts by weight of alpha-pinene, 0.1 to 10.0 parts by weight of anethole, 0.1 to 10.0 parts by weight of el-carbon, 0.1 to 10.0 parts by weight of methyl salicylate, 0.1 to 10.0 parts by weight of myrcene, 0.1 to 10.0 parts by weight of para-cymene and 0.1 to 10.0 parts by weight of methylbenzoate.

In addition, the perfume composition may contain 0.1-20.0 parts by weight of hedonic acid, 0.1-20.0 parts by weight of phenylethyl alcohol, and 0.1-20.0 parts by weight of flurorol per 100 parts by weight of the total composition.

In another aspect of the present invention, there is provided a home care product comprising the perfume composition.

For the purposes of the present invention, "home care products" are intended to refer to products used for household cleaning (e.g., hard surface cleaners, manual and automatic dish care, toilet cleaners and sanitizers, (For example, detergents, fabric softeners, pretreatment stain removers), directional compounds to remove odors or, in some cases, be used as a perfume substitute. , And the like, but the present invention is not limited thereto, and can be applied to all the home care compositions into which the perfume is injected. Specifically, the home care products include laundry detergents, laundry detergent additives, laundry bars, fabric softeners, kitchen detergents, wood and furniture polishes, floor polishes, bath and tile cleaners, toilet cleaners, hard surface cleaners, window cleaners, anti- But are not limited to, cleaners, auto-dishwashing agents and sheeting agents, carpet cleaners, prewash spotters, rust stain cleaners, descalers, deodorants and perfumes.

Products for use in the home care products of the present invention, such as laundry products, may be, but are not limited to, a textile care product comprising the perfume composition and a cationic polymer, an amphoteric surfactant, or a mixture thereof. The cationic polymer used in the textile care product may be selected from the group consisting of cationic guar, cationic cellulose, dimethyldiallylammonium chloride polymer, acrylamide-dimethyldiallylammonium chloride copolymer, PVP-dimethylaminoethyl methacrylate copolymer, Dimethyl diallylammonium chloride copolymer, acrylamide-dimethylaminoethyl methacrylate methyl chloride copolymer, trimethylaminoethyl methacrylate polymer, and the like, but is not limited thereto. The amphoteric surfactant used in the textile care product is selected from the group consisting of alkylamidopropyl betaine, alkyldimethylbetaine, alkylmonoamphoacetate, cocoamphocarboxy glycinate, sarcosinate and alkylamphodiacetate, and the like. Any one or more may be used, but are not limited to.

While the home care products of the present invention, such as those for use in such laundry products, require several cleaning additives, certain simple formulations, such as bleach additives, may require only oxygen bleaching agents and surfactants. The cleaning adjunct may include builders, enzymes, bleaches, bleach activators, catalytic materials, and the like. Specifically, the cleaning adjunct may be selected from the group consisting of a foam promoter, a foam inhibitor (defoamer), a dispersant polymer, a color speckle, a silver care agent, an antioxidant and / or an anticorrosive, a dye, a filler, a bactericide, May contain various active or specialized substances such as stabilizers, stabilizers, enzyme stabilizers, pro-peptides, antioxidants, solubilizers, carriers, processing aids and pigments and in the case of liquid formulations, solvents, chelating agents, Antioxidants, perfumes, processing aids, and other fabric care agents, surfaces, and skin care agents, which may be included in the compositions of the present invention.

The home care product of the present invention, such as a perfume, may be a volatile perfume composition comprising the gel or solidified inventive perfume composition of the present invention and may be a liquid perfume composition comprising the perfume composition of the present invention prepared in liquid form have. In addition, the perfume composition may contain 0.001 to 30% by weight, specifically 1 to 30% by weight, more specifically 1 to 10% by weight, of the perfume composition of the present invention in the weight of the total product. When the perfume composition is added in an amount of less than 0.001% by weight, the fragrance is difficult to be appreciated because the fragrance is very low. When the perfume composition is added in an amount of more than 30% by weight, the fragrance becomes too strong for use as a fragrance. When the perfume composition of the present invention is used as a fragrance additive, the composition can be added as it is or mixed with optional ingredients useful in a flavoring or fragrance. In particular, they may be mixed with one or more of the natural extracts used in the field of a wide variety of natural, synthetic, synthetic chemicals, natural fragrances, flavors, flavors or fragrances. Additionally, the perfume may include one or more ingredients or excipients commonly used with flavors and fragrances, such as carrier materials, thickeners, flavor enhancers and other adjuvants commonly known and used in the art have.

In another aspect of the present invention, there is provided a personal care product comprising the perfume composition. The present invention also provides a cosmetic composition comprising the perfume composition.

In the present invention, "personal care product" is intended to encompass all types of cosmetic products, including cosmetics, hair care products, toiletries, cosmeceuticals, beauty aids, , Personal hygiene and cleansing products, but are not limited thereto, and can be applied to personal care compositions into which perfumes are injected. Specifically, the present invention relates to a cosmetic composition comprising a composition selected from the group consisting of deodorant, antiperspirant, spray, stick and roll-on product, shaving preparation, skin lotion, Nail polish remover, nail cream and lotion, exfoliant, sunscreen, insect repellent, anti-aging agent, lipstick, foundation, face powder, eyeliner , Eye shadow, blushes, makeup, mascara, moisturizing preparation, body and hand preparation, skin care preparation, face and neck preparation, tonic, dressing, hair grooming aid, aerosol fixative, fragrance preparation, aftershave, - up formulation, soft focus preparations, night and day skin care preparations, non-pigmented hair preparations, tanning preparations, synthetic and non-synthetic soap bars, Makeup remover, facial cleanser, cold cream, sunscreen, mousse, spritz, shampoo, shampoo, baby shampoo, baby shampoo, shaving cream, squeegee, nose strip, personal care nonwovens, baby shampoo, baby conditioner, Face masks and muds, face masks, colognes and lotions, hair cuticle coats, shower gels, face and bodywashes, personal care rinse-offs, gels, foam baths, scrubbing cleansers, astringents, nail conditioners, eye shadow sticks, Hair brush, lip balm, lip gloss, hair care pump spray and other non-aerosol sprays, hair-freeze-control gel, hair rib-in conditioner, hair pomade, hair detergent, hair fixative, hair bleach, skin Lotions, pre-shave and pre-electric shave, anhydrous creams and lotions, oil / water, water / type, multiple macros Microemulsions, water-resistant creams and lotions, acne skin preparations, mouthwashes, massage oils, toothpastes, clear gels and sticks, ointment bases, local wound healing agents, aerosol talc, barrier sprays, vitamins and antioxidants, herbal extracts, Hair styling aids, hair-, eye-, nail- and skin-soft products, emit control personal care products, hair conditioning mists, skin care moisturizing mist, skin wipes, pores But are not limited to, skin wipes, pore cleansers, Blemish Reductors, skin exfoliators, skin removers, skin towelette and cloth, depilatories, personal care lubricants and nail coloring aids.

The personal care products of the present invention, such as cosmetics, can be used as a solution, an external ointment, a cream, a foam, a nutritional lotion, a softening longevity pack, a pack, a flexible water, a milky lotion, a makeup base, an essence, But may be formulated as a suspension, emulsion, paste, gel, lotion, powder, soap, surfactant-containing cleansing, oil, powder foundation, emulsion foundation, wax foundation, patch, But is not limited thereto.

The cosmetics of the present invention may further comprise at least one cosmetically acceptable carrier to be incorporated in cosmetics for general skin, and examples thereof include oil, water, a surfactant, a humectant, a lower alcohol, a thickener, a chelate Coloring matters, preservatives, fragrances, and the like may be appropriately compounded, but the present invention is not limited thereto. The cosmetically acceptable carrier included in the cosmetic of the present invention varies depending on the formulation.

When the formulation of the present invention is an ointment, a paste, a cream or a gel, the carrier component may be an animal oil, vegetable oil, wax, paraffin, starch, tragacanth, cellulose derivative, polyethylene glycol, silicone, bentonite, silica, talc, zinc oxide Mixtures of these may be used.

When the formulation of the present invention is a powder or a spray, lactose, talc, silica, aluminum hydroxide, calcium silicate, polyamide powder or a mixture thereof may be used as the carrier component, Propellants such as fluorohydrocarbons, propane / butane or dimethyl ether.

When the formulation of the present invention is a solution or emulsion, a solvent, a dissolving agent or an emulsifying agent is used as a carrier component, and examples thereof include water, ethanol, isopropanol, ethyl carbonate, ethyl acetate, benzyl alcohol, benzyl benzoate, 1,3-butyl glycol oil may be used, in particular fatty acid esters of cottonseed oil, peanut oil, corn oil, olive oil, castor oil and sesame oil, glycerol aliphatic esters, polyethylene glycols or sorbitan may be used have.

When the formulation of the present invention is a suspension, a carrier such as water, a liquid diluent such as ethanol or propylene glycol, a suspension such as ethoxylated isostearyl alcohol, polyoxyethylene sorbitol ester and polyoxyethylene sorbitan ester, Crystalline cellulose, aluminum metahydroxide, bentonite, agar or tracant, etc. may be used.

When the formulation of the present invention is a soap, an alkali metal salt of a fatty acid, a fatty acid hemiester salt, a fatty acid protein hydrolizate, isethionate, a lanolin derivative, an aliphatic alcohol, a vegetable oil, glycerol, .

In the cosmetic of the present invention, the content of the perfume composition may vary depending on the formulation. For example, wash-off type cosmetics, such as make-up removers, detergents, and the like, where the active ingredient remains on the skin in a short period of time, may be relatively high concentrations. On the other hand, in the case of leave-on type cosmetics such as lotion, cream, essence and the like in which the active ingredient remains on the skin for a long period of time, the concentration may be lower than that of the wash-off type cosmetics.

The personal care products of the present invention, for example, hair care products, can be used as a shampoo (including complex shampoos such as two-in-one conditioning shampoos), hair conditioners, rinses after shampooing, hair dyeing, But are not limited to, styling agents (including setting aids such as gels and sprays, and grooming adjuvants such as pomades, conditioners, permanent liquids, and relaxants), and hair smoothing products. The hair care product may include, but is not limited to, the perfume composition of the present invention and any one or more selected from the group consisting of a cationic surfactant, an amphoteric surfactant, a nonionic surfactant, and a cationic polymer. The cationic surfactant used in the hair care product may be at least one selected from the group consisting of cetrimonium chloride, stearamidopropyldimethylamine, dicetyldimethylammonium chloride and ester quatro. It does not. The amphoteric surfactant used in the hair care product may be at least one selected from the group consisting of cocamidopropyl betaine, cocoamphocarboxy glycinate and coco amphocarboxy propionate, but is not limited thereto. The nonionic surfactant used in the hair care product may be at least one selected from the group consisting of lauryl acid diethanolamide, coconut fatty acid diethanolamide, coconut fatty acid monoethanolamide, lauryldimethylamine oxide and palm oil alkyldimethylamine oxide May be used, but is not limited thereto. The cationic polymer used in hair care products is a natural cationic polymer group consisting of guar hydroxypropyl trimonium chloride, hydroxypropyl guar hydroxypropyl trimonium chloride and quaternary hydroxyethyl cellulose; And a synthetic cationic polymer group consisting of dimethyldiallylammonium chloride polymer, acrylamide dimethyl allylammonium chloride copolymer and polyvinyl pyrrolidone dimethyl amino ethyl methacrylate copolymer, may be used. It is not limited. The hair dye may be a hair dye containing the perfume composition of the present invention, a precursor and a coupler, but is not limited thereto.

The personal care products of the present invention, such as body care products, may be used as a single component or as a single component for bath and shower additives, fragrance and flavor containing preparations, hair care products, deodorants and depot preparations, decorative preparations, Can be used in combination with a stabilizer. The body care product may be a body oil, a body lotion, a body gel, a treatment cream, a skin protective ointment, a shaving preparation such as a shaving foam or gel, a skin powder such as a baby powder, a moisturizing gel, a moisturizing spray, Sprays, cellulite gels, and peeling agents. Suitable bath and shower additives include shower gel, bath-salt, bubble bath and soap. Formulations containing fragrant and flavor substances include perfumes, lotions and shaving lotions (aftershave formulations). The body care product may be in the form of a cream, ointment, paste, foam, gel, lotion, powder, makeup, spray, stick or aerosol, but is not limited thereto. The body care product may also include, but is not limited to, a stabilizing mixture, and optionally additional UV absorbers, sterically hindered amines, complexing agents, and phenolic or non-phenolic antioxidants.

As another embodiment of the present invention, there is provided an external preparation for skin comprising the perfume composition.

), 궤양 등에 산포하는 것을 의미하고, 외용정제는 용해정 또는 질정을 의미하며, 외용액제는 물, 에타놀, 유류 등을 용매로 하는 액상제제이고, 양치질, 습포, 세척, 점안, 점비(点鼻) 등에 사용한다. 또한, 연고제는 피부에 바르는 적당한 조도의 반고형제, 경고는 상온고형, 체온으로 연화하는 피부적용제이고, 좌제는 항문, 질, 요도에 적용하는 제제이다. In the present invention, the "external preparation" is a preparation for external use such as external preparation, external tablet, external preparation, ointment, warning agent and suppository. The external application agent is zinc white starch and the like, erosion of skin mucosa (

), Ulcer and the like, the external tablet means dissolution tablet or vaginal, and the external liquid agent is a liquid preparation using water, ethanol, oil or the like as a solvent and is used as a liquid preparation for mouth rinsing, ). In addition, the ointment agent is a semi-solid agent for moderate illumination applied to the skin, a warning is a solid application at room temperature, a skin application agent softened at body temperature, and a suppository agent for anus, vagina, and urethra.

The term "external preparation for skin" means a preparation acting on the external skin of external preparations. In the present invention, the term " external preparation for skin " Specifically, the external preparation for skin may be used as a pharmaceutical or quasi-drug in the form of cream, gel, patch, spray, ointment, warning agent, lotion, liniment, pasta or cataplasma. Do not.

The present invention relates to a composition for reproducing the fragrance of a flowering flower, and it has been confirmed through sensory evaluation that the degree of similarity with the intrinsic fragrance of the flowering flower is high and the satisfaction of the fragrance is excellent through the sensory evaluation. The fragrance composition and the fragrance composition A personal care product, a cosmetic composition, and a composition for external application for skin.

Hereinafter, the present invention will be described in detail with reference to Examples and Experimental Examples. However, the following Examples and Experimental Examples are merely illustrative of the present invention, and the present invention is not limited to the following Examples and Experimental Examples.

Experimental Example  One. Headspace method  Used I also have  Analysis of fragrance components of flowers

The headspace analysis method is a method capable of collecting sample fragrance as it is in a natural state. In the present invention, the headspace analysis method was used and the following component analysis was performed using the method described in the literature. I also put a hermetically sealed wrap around the flower part of the wind, and circulated air passed through the tenax column while forcibly circulating the outside air with a power device to collect the fragrance ingredient.

The tenax column, in which the odor was collected, was connected to a gas chromatographic analyzer to analyze the type and content of the collected fragrance. The results are shown in Table 1 below.

<Analysis condition>

Analytical Instruments: Hewlett Packard 6890

Detector: MSD

Column: HP-20M 0.2 mm ID x 25 m

Injection temperature: 250 ° C

Detector temperature: 250 ° C

Oven temperature: 55 占 폚 (0 minutes) to 215 占 폚 (40 minutes), 4.0 占 폚 / min

Split Ratio: 30: 1

Mobile phase gas: helium 18 cm / sec

Injection amount: 0.3 ml

I also analyzed the fragrance component of the flowering flower Perfume name weight (%) Limonene 31.7 Nerol 22.9 Linalool 10.9 Citral 7.5 Geraniol 5.1 Alpha-Pinene 4.4 Anethol 2.8 El-Carbon (L-Carvone) 2.5 Methyl salicylate 1.9 Myrcene 1.8 Para-cymene 1.5 Methyl Benzoate &lt; RTI ID = 0.0 &gt; 0.9 Other 6.1 total 100.0

In addition, six perfume industry proprietors evaluated sensory evaluation of each element and flower fragrance analyzed for each flower, and I also selected five major fragrance components of the flowering flowers, and the selected fragrance components were indicated by ○, And the results are shown in Table 2 below. &Lt; tb &gt;&lt; TABLE &gt; Id = Table 2 Columns = 2 &lt; tb &gt;

Perfume name Propeller A Propeller B Propeller C Propeller D Propeller E Propeller F Limonene ○ ○ ○ ○ ○ ○ Nerol ○ ○ ○ ○ ○ ○ Linalool ○ ○ ○ ○ ○ Citral ○ ○ ○ ○ Geraniol ○ ○ ○ ○ Alpha-Pinene ○ ○ ○ Anethol ○ ○ ○ El-Carbon (L-Carvone) ○ ○ Methyl salicylate ○ ○ ○ Myrcene ○ ○ Para-cymene ○ ○ Methyl Benzoate &lt; RTI ID = 0.0 &gt; ○ ○

As a result of the analysis, as shown in Tables 1 and 2, it can be seen that the main fragrance components of the flowers in the landscape are limonene, nerol, linanol, citral, and geraniol, which account for about 78% , And the main flavor components of Nadobulani flowers, which were selected based on the fragrance strength felt in the flowering flowers, were not the same as those of the six perfume industry proponents.

Experimental Example  2. I also have  Production and comparison analysis of fragrance reproduction of flower fragrance

<2-1> I also have  Flavor Reproduction Flavor of Flower ( Comparative Example  1)

Based on the nasal air blossom fragrance components (Table 1) analyzed in Experimental Example 1, fragrances of naphtha blossom flowers having the composition and contents shown in Table 3 were prepared. Then, comparative analysis was carried out by the process of <2-2> as described below with respect to the fragrance component of the flowering flower of Table 1 and the fragrance reproduction fragrance of the flowering flower of the flowering flower of Table 3 below. Comparative Example 1 was prepared so as to have the same composition and content as those of the nodular flower flower fractions analyzed in Experimental Example 1 above.

I also found that the fragrance reproducible with fragrance flowers (Comparative Example 1) Perfume name weight (%) Limonene 31.7 Nerol 22.9 Linalool 10.9 Citral 7.5 Geraniol 5.1 Alpha-Pinene 4.4 Anethol 2.8 El-Carbon (L-Carvone) 2.5 Methyl salicylate 1.9 Myrcene 1.8 Para-cymene 1.5 Methyl Benzoate &lt; RTI ID = 0.0 &gt; 0.9 Other 6.1 total 100.0

<2-2> I also have  Flavor Reproduction Flavor of Flower ( Comparative Example  1) Sensory evaluation

The sensory evaluations of the similarity and satisfaction with the fragrance of the flowering flower were also performed on the fragrance for reproducing the fragrance reproduced from the nadomura flower (Comparative Example 1) prepared in the above Experimental Example <2-1>. The sensory evaluation subjects were 20 normal healthy men and women aged 25 to 35 years. The evaluation of the similarity of each of the fragrance reproducible fragrances of the airflow flowers of Comparative Example 1 to each of the perfume fractions was evaluated by the 5-point rating method according to the following Table 4. The satisfaction was evaluated by the 5-point rating method according to the following Table 5 The evaluation results are shown in Table 6 below. The evaluation room and the sample preparation room were separated so that the evaluator had no prior knowledge of the sample.

5-point Rating Method for Similarity score Similarity One Very different 2 a little bit different 3 so so 4 A little similar 5 Very similar

Five-point rating method for satisfaction score satisfaction One Not very good 2 It's not good. 3 so so 4 A little good 5 very good

Evaluation results - similarity and satisfaction rater Similarity satisfaction number age gender One 26 female 3 2 2 28 female 4 3 3 31 female 2 3 4 26 female 3 2 5 28 female One 4 6 35 female 2 3 7 29 female 3 3 8 26 female 4 4 9 31 female 5 3 10 32 female 3 4 11 34 south 4 2 12 28 south 4 3 13 25 south 3 3 14 26 south 5 2 15 27 south 3 3 16 31 south 5 2 17 30 south 4 2 18 29 south 2 2 19 34 south One 3 20 26 south 2 2 Average 29.1 3.15 2.75

As a result of the analysis, the degree of similarity between the fragrance reproducible perfume of Comparative Example 1 and the fragrance of the flowers in the above Table 1 was low, and the perfume reproduction perfume of Comparative Example 1 The satisfaction of the incense was evaluated to be insufficient. As a result, it was judged that it is impossible to reproduce the fragrance of the flowering flower only by the headspace analysis result. Therefore, it was confirmed that it is desirable to reproduce the fragrance of the flowering flower by adding a new fragrance ingredient based on the head space result.

Experimental Example  3. Added a new fragrance ingredient I also have  Fragrance

<3-1> I also have  Manufacture of fragrances to improve fragrance of flowers

In order to improve the degree of similarity and satisfaction of the perfume of Comparative Example 1 prepared in Experimental Example 2, a fragrance improving fragrance of a napweed flower with a new perfume ingredient was prepared.

Specifically, a new combination of improving fragrances was prepared by using artificial synthetic materials such as hedon, phenylethyl alcohol and florol to the constituents of the perfume of Comparative Example 1. The content of the herbicide, phenylethyl alcohol and florol was determined according to the judgment of the professional group of the oriental herb, and the total content of the three kinds of ingredients was added in such a manner that the total content was 10 to 20 parts by weight, Lt; RTI ID = 0.0 &gt; 100 &lt; / RTI &gt; parts by weight. The compositions of the improved fragrances of the new combination are shown in Table 7 below.

Composition table of fresh perfume composition (unit: parts by weight) Perfume name Comparative Example  One Manufacturing example  One Manufacturing example  2 Manufacturing example  3 Manufacturing example  4 Limonene 31.7 40.5 20.5 31.0 31.4 Nerol 22.9 15.4 16.4 24.5 21.5 Linalool 10.9 14.2 22.2 11.8 8.7 Citral 7.5 4.2 4.1 2.5 5.4 Geraniol 5.1 5.6 5.6 4.1 5.1 Alpha-Pinene 4.4 2.8 7.1 2.4 3.3 Anethol 2.8 2.5 2.5 3.7 5.7 El-Carbon (L-Carvone) 2.5 1.2 1.5 4.6 3.7 Methyl salicylate 1.9 1.3 1.1 2.0 2.5 Myrcene 1.8 5.3 9.2 6.6 2.9 Para-cymene 1.5 1.7 1.0 1.6 1.9 Methyl Benzoate &lt; RTI ID = 0.0 &gt; 0.9 1.8 0.9 0.4 1.1 Hedione - 0.8 - 1.8 2.4 Phenyl Ethyl Alcohol - 1.2 2.1 - 1.1 Florol - - 3.3 1.1 2.1 Other 6.1 1.5 2.5 1.9 1.2 total 100.0 100.0 100.0 100.0 100.0

<3-2> I also have  Sensory evaluation of fragrance improving fragrance of flowers

The flavor improving fragrances (Nos. 1 to 4) of Nadobaran flower prepared in Experimental Example <3-1> were also subjected to sensory evaluation on the degree of similarity and satisfaction with the fragrance of the flowering flowers. The sensory evaluation subjects were 20 normal healthy men and women aged 25 to 35 years. The evaluation of the similarity of each of the fragrance improving fragrances of each of the above-mentioned Preparative Examples 1 to 4 to the fragrance of fragrance flowers was evaluated by the five-point rating method according to the above Table 4. The satisfaction was evaluated by the 5-point rating method And the evaluation results are shown in Table 8 below. The evaluation room and the sample preparation room were separated so that the evaluator had no prior knowledge of the sample.

Evaluation results - similarity and satisfaction rater Similarity satisfaction number age gender Manufacturing example
One Manufacturing example
2 Manufacturing example
3 Manufacturing example
4 Manufacturing example
One Manufacturing example
2 Manufacturing example
3 Manufacturing example
4 One 26 female 5 5 3 4 3 3 4 5 2 28 female 5 4 2 5 4 4 5 5 3 31 female 3 3 4 3 4 4 4 4 4 26 female 3 3 4 4 4 3 5 5 5 28 female 4 2 4 4 3 3 3 5 6 35 female 3 4 3 4 3 4 3 3 7 29 female 4 2 3 5 3 3 3 5 8 26 female 5 5 5 4 4 3 4 4 9 31 female 4 4 4 3 2 4 3 5 10 32 female 5 2 4 4 5 5 4 3 11 34 south 4 4 3 3 4 3 3 3 12 28 south 3 3 3 5 4 5 3 5 13 25 south 2 4 4 5 2 3 3 4 14 26 south 3 5 2 5 4 3 4 5 15 27 south 2 2 3 4 4 5 5 4 16 31 south 2 3 5 5 3 2 5 4 17 30 south 4 5 One 3 2 3 3 4 18 29 south 5 2 2 4 3 3 4 4 19 34 south One 2 4 5 5 2 5 5 20 26 south 2 4 4 4 2 4 4 4 Average 29.1 3.45 3.4 3.35 4.15 3.4 3.45 3.85 4.3

The subjects and methods of evaluation were carried out in the same manner as in Experimental Example 2 above.

As a result of the result of the similarity evaluation, the comparative example 1 in which only the major components of the flowers of the airs were combined showed a low degree of similarity as shown in Table 6. On the other hand, as shown in Production Examples 1 to 4 of Table 8, The similarity was evaluated to be increased when ethyl alcohol, fluorol and / or hedonic was added. In particular, it was confirmed that the degree of similarity of Production Example 4 in which both phenylethyl alcohol, fluorol and heddone were further mixed was the greatest increase, and it was confirmed that the degree of similarity was remarkably higher than that of the combination of the above three components 8).

In addition, as a result of the satisfaction evaluation, the comparative example 1 in which only the main components of the flowers were combined showed low satisfaction as shown in the above Table 6. On the other hand, as can be seen from the production examples 1 to 4 of Table 8 , Phenylethyl alcohol, florol, and / or hedione were added. In particular, it was confirmed that the degree of similarity of Production Example 4 in which both phenylethyl alcohol, fluorol and heddone were further mixed was the greatest increase, and it was confirmed that the satisfactory degree of satisfaction was higher than that of the combination of the above three kinds of ingredients 8).

Therefore, it was also confirmed that the composition containing phenylethyl alcohol, florol and / or hedione in addition to the fragrance components of the flowering flowers has high satisfaction with the fragrance similarity and flavor of the flowering flowers, It was found that the perfume composition recreating the fragrance can be utilized as a home care product, a personal care product, and a composition for external application for skin.

Claims (10)

I too, Aerides japonicum ); And at least one component selected from the group consisting of hedione, phenyl ethyl alcohol and florol as an active ingredient.
[Claim 4] The composition according to claim 1, wherein the fragrance component of the flower of the Iris flower is at least one selected from the group consisting of Limonene, Nerol, Linalool, Citral and Geraniol &Lt; RTI ID = 0.0 &gt; and / or &lt; / RTI &gt;
[3] The composition according to claim 2, wherein the flavor component of the flower of the spore flowers is selected from the group consisting of Alpha-Pinene, Anethol, L-Carvone, Methyl salicylate, Wherein the perfume composition further comprises at least one component selected from the group consisting of Myrcene, Para-cymene and Methyl Benzoate.
The perfume composition of claim 1, wherein the perfume composition comprises from 0.1 to 20.0 parts by weight of hedonic, from 0.1 to 20.0 parts by weight of phenylethyl alcohol, and from 0.1 to 20.0 parts by weight of fluorol, based on the total perfume composition. .
The perfume composition of claim 2, wherein the perfume composition comprises 1 to 70 parts by weight of limonene, 1 to 50 parts by weight of nerol, 1 to 50 parts by weight of linar, 1 to 50 parts by weight of citral, and 1 to 30 By weight of geraniol.
The perfume composition of claim 3, wherein the perfume composition comprises 0.1 to 10.0 parts by weight of alpha-pinene, 0.1 to 10.0 parts by weight of anethole, 0.1 to 10.0 parts by weight of el-carbon, 0.1 to 10.0 parts by weight of methyl salicylate 0.1 to 10.0 parts by weight of myrcene, 0.1 to 10.0 parts by weight of para-cymene and 0.1 to 10.0 parts by weight of methyl benzoate.
7. A home care product comprising a perfume composition according to any one of claims 1 to 6.
9. A personal care product comprising a perfume composition according to any one of the preceding claims.
A cosmetic composition comprising the perfume composition according to any one of claims 1 to 6.
A composition for external application for skin comprising the perfume composition according to any one of claims 1 to 6.