KR20170050413A - Transparent Water-in-Silicone emulsion hair conditioning composition - Google Patents

Transparent Water-in-Silicone emulsion hair conditioning composition Download PDF

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Publication number
KR20170050413A
KR20170050413A KR1020150151907A KR20150151907A KR20170050413A KR 20170050413 A KR20170050413 A KR 20170050413A KR 1020150151907 A KR1020150151907 A KR 1020150151907A KR 20150151907 A KR20150151907 A KR 20150151907A KR 20170050413 A KR20170050413 A KR 20170050413A
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KR
South Korea
Prior art keywords
hair
weight
silicone
oil
phage
Prior art date
Application number
KR1020150151907A
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Korean (ko)
Inventor
조인식
구형서
한일민
유승희
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애경산업(주)
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Priority to KR1020150151907A priority Critical patent/KR20170050413A/en
Publication of KR20170050413A publication Critical patent/KR20170050413A/en

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/72Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/02Cosmetics or similar toilet preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • A61K8/064Water-in-oil emulsions, e.g. Water-in-silicone emulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/30Cosmetics or similar toilet preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toilet preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/30Cosmetics or similar toilet preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toilet preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41Amines
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/30Cosmetics or similar toilet preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toilet preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41Amines
    • A61K8/416Quaternary ammonium compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/72Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILET PREPARATIONS
    • A61Q5/00Preparations for care of the hair

Abstract

The present invention relates to a transparent silicone oil-in-water (W / S) emulsifying hair conditioning composition that provides a rich oil feel and soft conditioning in the hair and promotes aesthetic effects with a transparent appearance. More particularly, the present invention relates to an oil phase comprising a silicone oil, a silicone copolyol, an emollient of esters, a polyol, a cationic conditioning agent and water, and the like, wherein the silicone oil, silicone copolyol, emollient of esters, (W / S) emulsified hair conditioning composition characterized in that it is present in an amount of 11 to 30% by weight based on the total weight of the composition.

Description

Transparent Water-in-Silicone Emulsion Hair Conditioning Composition < RTI ID = 0.0 > (W /
The present invention relates to a clear silicone oil water-in-oil (W / S) emulsifying hair conditioning composition, and more particularly to a silicone oil oil, a silicone copolyol, an emollient of esters, a polyol, a cationic conditioning agent and water, (W / S) emulsifying hair conditioning composition that provides an oily feel and smooth conditioning and promotes aesthetic effects with a transparent appearance.
Hair is damaged by various physicochemical causes such as dyeing, perming, friction during shampooing and combing. Hair conditioners are commonly used to nourish damaged hair and manage it with soft hair.
Conventional hair conditioners are mostly oil-in-water (O / W) emulsion hair conditioning agents, which contain oily components such as silicone and vegetable oils. However, when the oily components are over-applied to improve the conditioning effect, , Excessive amount of surfactant is used, thereby causing skin irritation.
In addition, the transparent hair conditioner includes a composition based on a water-soluble incremental polymer and a composition in which an excess amount of a polyol is applied to an ordinary water-in-oil type (O / W) emulsion. In order to contain a large amount of oily components such as silicone and vegetable oil in both directions There is a limit in formulation.
Prior art discloses a transparent conditioner comprising aminoacrylate copolymer, cationic surfactant, polyol and silicone of Korean Patent Laid-Open Publication No. 10-2008-0094135, and C 18 -C 30 Of long-chain cationic surfactants and polyols. However, such a conventional conditioner of the transparent formulation has a disadvantage in that when a high-content silicone oil is used, its stability and transparency are lowered, and therefore, the conditioner does not have a beautiful appearance.
The present invention has been made to solve the above-mentioned problems of the prior art by providing a hair conditioning agent containing silicone oil, silicone copolyol and ester emollients to provide a rich oil feeling and smooth conditioning, and a transparent appearance Silicone oil-in-water (W / S) emulsifying hair conditioning composition.
According to an aspect of the present invention,
(a) from 10 to 30% by weight of a volatile or nonvolatile low molecular weight silicone oil; (b) 0.5 to 5% by weight of a silicone copolyol; (c) 0.5 to 5% by weight of an emulsion of an ester; (d) 5 to 50% by weight of a polyol; (e) 0.5 to 5% by weight of a cationic conditioning agent; And the balance water; Characterized in that the oil phase comprising (a) to (c) is present in an amount of from 11 to 30% by weight, based on the total weight of the composition, of a transparent silicone oil in water (W / S) emulsified hair conditioning composition, (W / S) emulsified hair conditioning composition.
As described above, the composition according to the present invention is a transparent silicone oil-in-water (W / S) emulsion which uses silicone oil as a trauma, and provides a rich oil feeling and smooth conditioning in hair, a transparent and beautiful appearance, great.
Hereinafter, the present invention will be described in more detail.
The silicone oil-in-water (W / S) emulsified hair conditioning composition of the present invention,
(a) from 10 to 30% by weight of a volatile or nonvolatile low molecular weight silicone oil; (b) 0.5 to 5% by weight of a silicone copolyol; (c) 0.5 to 5% by weight of an emulsion of an ester; (d) 5 to 50% by weight of a polyol; (e) 0.5 to 5% by weight of a cationic conditioning agent; And the balance water; (W / S) emulsifying hair conditioning composition according to claim 1, wherein the oil phase containing (a) to (c) is present in an amount of 11 to 30% by weight based on the total weight of the composition.
In the present invention, the silicone oil has a high water repellency and, unlike the hydrocarbon oil component, has a mild feeling without tackiness and imparts a rich oil feeling to the hair.
The silicone oil is a volatile silicone having a cyclic structure or a low molecular silicone oil having a linear structure and a viscosity of 10 cs or less and is contained in an amount of 10 to 30% by weight based on the total weight of the composition.
When the content of the silicone oil is less than 10% by weight, the solvent of the external phase is insufficient. When the content of the silicone oil is more than 30% by weight, the viscosity stability of the formulation is deteriorated.
The silicone oil is preferably at least one selected from cyclopentasiloxane, dimethicone and cyclomethicone.
In the present invention, the silicone copolyol is a silicone emulsifier and is contained in an amount of 0.5 to 5% by weight based on the total weight of the composition.
When the content of the silicone copolyol is less than 0.5% by weight, the emulsifier is insufficient to form emulsions. When the content of the silicone copolyol is more than 5% by weight, the viscosity of the formulation may excessively increase and the feeling of use may be adversely affected.
The silicone copolyol is preferably dimethicone or alkyl dimethicone to which at least one member selected from the group consisting of polyethylene glycol and polypropylene glycol is added.
More preferably, the silicone copolyol is selected from the group consisting of phage-10 dimethicone, phage-12 dimethicone, cetyl-phage / phage-10/1 dimethicone, bis- phage / phage- And piperazine / piperidine-18/18 dimethicone.
The composition of the present invention comprises an emollient of esters.
The emollient is a hydrophilic substance such as a fatty acid ester and acts to prevent evaporation of moisture. The emollient acts as a conditioning agent for the hair, provides luster and helps soft and flexible hair growth. Especially, .
The emollient is preferably contained in an amount of 0.5 to 5% by weight based on the total weight of the composition. If the emollient is less than 0.5% by weight, the effect is insignificant, and if exceeding 5% by weight, the stability of the formulation may be impaired.
Wherein the emollient is at least one selected from dicaprylly carbonate, diisostearyl malate, dicetearyl dimer dilinoleate and dicaprylly malateate, preferably at least one selected from the group consisting of It is Dicaprylyl Cabonate.
The composition of the present invention comprises a polyol to match the refractive index of the water phase to the refractive index of the oil phase.
The polyol is used to adjust the refractive index to increase the transparency of the conditioner composition, and may also act as a moisturizer.
The polyol is contained in an amount of 5 to 50% by weight based on the total weight of the composition. Since the refractive index differs depending on the type of the polyol, the polyol contains an appropriate amount depending on the kind of the polyol so that the refractive index of the water phase matches the refractive index of the oil.
The polyol is preferably at least one selected from the group consisting of sorbitol, sucrose, glycerin, butylene glycol, propylene glycol, caprylyl glycoll, myristyl glycol and cetyl glycol.
In the present invention, the cationic conditioning agent is attached to the hair to soften the hair after drying.
The cationic conditioning agent is preferably contained in an amount of 0.5 to 5% by weight based on the total weight of the composition. If the content is less than 0.5% by weight, the effect is insignificant, and if exceeding 5% by weight, stickiness is caused.
The cationic conditioning agent is preferably a cationic surfactant such as a quaternary ammonium salt or a tertiary amidoamine. More specifically, it is preferably a cationic surfactant such as cocamidopropyl dimethylamine, stearamidopropyldimethylamine Stearamidopropyl Dimethylamine, Behenamidopropyl Dimethylamine, Cetrimonium Chloride, Steartrimonium Chloride, Behentrimonium Chloride and palmitamidopropyltrimonium chloride. (Palmitamidopropyltrimonium Chloride).
In the present invention, it is preferable that the silicone oil, the silicone copolyol and the oil phase containing the molyant in the esters include 11 to 30% by weight based on the total weight of the composition.
If the content of the oil phase is less than 11% by weight, the content of the external phase is insufficient and the formation of emulsions is difficult. When the content of the oil phase exceeds 30% by weight, the viscosity of the formulation is lowered.
In the present invention, the transparent silicone oil-in-water (W / S) emulsifying hair conditioning composition may contain a preservative, a pH adjuster, a flavor, an antioxidant, a moisturizer, a conditioning agent, , Protein and vegetable oil can be appropriately compounded as needed.
In the present invention, the transparent silicone oil-in-water (W / S) emulsified hair conditioning composition can be manufactured into a hair conditioner, a hair conditioner, a hair pack, a hair treatment, a hair cream, It can be used in both types that do not dry out, and those that wash after applying to hair, but the latter is more preferable.
Hereinafter, preferred embodiments of the present invention will be described in detail. Prior to this, terms and words used in the present specification and claims should not be construed as limited to ordinary or dictionary terms, and the inventor should appropriately interpret the concepts of the terms appropriately It should be interpreted in accordance with the meaning and concept consistent with the technical idea of the present invention based on the principle that it can be defined.
Therefore, the configuration of the embodiment described in the present specification is merely the most preferred embodiment of the present invention, and does not represent all the technical ideas of the present invention, so that various equivalents and variations Examples should be understood.
Examples 1 to 6 and Comparative Examples 1 to 3
The hair conditioning compositions of Examples 1 to 6 and Comparative Examples 1 to 3 according to the present invention were prepared as shown in Table 1.
Raw material name Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4
One Diagechon One 2 One One One One - One One One
2 Cyclopentasiloxane 15 15 10 25 15 15 15 15 15 -
3 Dicaprylyl carbonate One One One One 3 One One - One One
4 Palmitamidopropyltrimonium chloride 2 2 2 2 2 4 2 2 - 2
5 Propylene glycol 10 10 10 10 10 10 10 10 10 10
6 Sorbitol Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount
7 Benzyl alcohol 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5
8 Purified water Balance Balance Balance Balance Balance Balance Balance Balance Balance Balance
9 Spices Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount
The production methods of Examples 1 to 6 and Comparative Examples 1 to 3 are as follows.
(1) Raw materials 1 to 3 are dissolved by stirring at room temperature (25 ° C).
(2) The raw materials 4 to 8 are dissolved by stirring at 50 캜.
(3) While (1) is stirred at high speed, (2) is added to emulsify.
(4) The raw material 9 is added and stirred to homogeneously mix.
Test Example 1: Viscosity and transparency observation
To ensure that a stable, transparent silicone oil-in-water (W / S) emulsified hair conditioning composition was prepared, the viscosity of the prepared composition was measured at 25 ° C using a Brookfield viscometer and the transparency was visually observed.
Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4
Viscosity
(cPs)
35,600 40,500 39,000 25,600 33,400 32,000 - 35,500 35,100 -
transparency Transparency Transparency Transparency Transparency Transparency Transparency - Transparency Transparency -
As shown in Table 2, in Examples 1 to 6 according to the present invention, a transparent formulation having a high viscosity of 25,000 or more was formed, and a beautiful appearance in which a rich oiliness was felt was observed. On the other hand, no emulsion was formed when the silicone copolyol was not contained (Comparative Example 1) or when the content of oily phase (silicone oil, copolyol and emollient) was very low (Comparative Example 4).
Test Example 2: Evaluation of hair conditioning efficacy
In order to evaluate the hair conditioning effects of Examples 1 to 6 and Comparative Examples 2 to 3 in Table 3, panel evaluation was carried out in the following manner.
Table 10 shows the results of evaluating 10 women aged 25 to 35 according to the following evaluation items.
- Criteria: Very poor (1), Bad (2), Average (3), Good (4), Very good (5)
Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Comparative Example 2 Comparative Example 3
Massage feeling when using 3.5 3.8 3.8 3.5 3.7 3.5 3.0 3.3
Softness when rinsing 4.0 3.8 3.9 4.0 4.5 3.9 3.0 3.0
When rinse, 4.2 3.7 3.7 4.1 4.5 3.8 2.5 2.5
Softness in wet conditions 3.8 3.5 3.5 4.0 4.2 3.6 3.3 2.8
Softness in dry condition 4.2 4.0 3.9 4.1 4.1 4.5 3.3 3.0
As can be seen from the above Table 3, Examples 1 to 6 are superior to Comparative Examples 2 to 3 in terms of hair conditioning effect during use and after use.

Claims (11)

  1. (a) from 10 to 30% by weight of a volatile or nonvolatile low molecular weight silicone oil; (b) 0.5 to 5% by weight of a silicone copolyol; (c) 0.5 to 5% by weight of an emulsion of an ester; (d) 5 to 50% by weight of a polyol; (e) 0.5 to 5% by weight of a cationic conditioning agent; And the balance water; (W / S) emulsifying hair conditioning composition comprising:
    Wherein the oil phase comprising (a) to (c) is present in an amount of 11 to 30% by weight based on the total weight of the composition.
  2. The method according to claim 1,
    Wherein the silicone oil is at least one selected from cyclopentasiloxane, dimethicone and cyclomethicone. ≪ RTI ID = 0.0 > 11. < / RTI >
  3. The method according to claim 1,
    Wherein the silicon copolyol is a dimethicone or an alkyl dimethicone to which at least one member selected from the group consisting of polyethylene glycol and polypropylene glycol is added.
  4. The method of claim 3,
    The silicone copolyols may be selected from the group consisting of phage-10 dimethicone, phage-12 dimethicone, cetyl-phage / phage-10/1 dimethicone, bis- phage / phage- 14/14 dimethicone and phage / (W / S) emulsifying hair conditioning composition according to claim 1 or 2, wherein the emulsifying agent is at least one selected from the group consisting of water-in-oil emulsion and water-in-oil emulsion.
  5. The method according to claim 1,
    Wherein the emollient is dicaprylyl carbonate. ≪ RTI ID = 0.0 > 11. < / RTI >
  6. The method according to claim 1,
    Wherein the polyol is at least one selected from the group consisting of sorbitol, sucrose, glycerin, butyleneglycol, propylene glycol, caprylyl glycoll, myristyl glycol and cetyl glycol. (W / S) emulsifying hair conditioning composition.
  7. The method according to claim 1,
    Wherein the cationic conditioning agent is a quaternary ammonium salt or a tertiary amidoamine cationic surfactant. ≪ RTI ID = 0.0 > 11. < / RTI >
  8. 8. The method of claim 7,
    The cationic conditioning agent may be selected from the group consisting of Cocamidopropyl Dimethylamine, Stearamidopropyl Dimethylamine, Behenamidopropyl Dimethylamine, Cetrimonium Chloride, (W / S) emulsifying hair characterized in that it is at least one selected from the group consisting of stearothermonium chloride, behentrimonium chloride, and palmitamidopropyltrimonium chloride. Conditioning composition.
  9. The method according to claim 1,
    The silicone oil-in-water (W / S) emulsified hair conditioning composition further comprises at least one additive selected from preservatives, pH adjusters, flavors, colorants, antioxidants, moisturizers, conditioning agents, vitamins, proteins and vegetable oils (W / S) emulsifying hair conditioning composition.
  10. 9. A hair product, characterized in that it is made of the transparent silicone water-in-oil (W / S) emulsifying hair conditioning composition according to any one of claims 1 to 9.
  11. 11. The method of claim 10,
    Wherein the hair product is a hair conditioner, a hair conditioner, a hair pack, a hair treatment or a hair cream.
KR1020150151907A 2015-10-30 2015-10-30 Transparent Water-in-Silicone emulsion hair conditioning composition KR20170050413A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021054523A1 (en) * 2019-09-17 2021-03-25 주식회사 맥클린코스메틱 Liquid treatment composition, and method for producing same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021054523A1 (en) * 2019-09-17 2021-03-25 주식회사 맥클린코스메틱 Liquid treatment composition, and method for producing same

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