KR20110026933A - A supplying apparatus for supplying waste combustible materials, apparatus for producing fuel oil by continual pyrolysis thereof - Google Patents
A supplying apparatus for supplying waste combustible materials, apparatus for producing fuel oil by continual pyrolysis thereof Download PDFInfo
- Publication number
- KR20110026933A KR20110026933A KR20090084793A KR20090084793A KR20110026933A KR 20110026933 A KR20110026933 A KR 20110026933A KR 20090084793 A KR20090084793 A KR 20090084793A KR 20090084793 A KR20090084793 A KR 20090084793A KR 20110026933 A KR20110026933 A KR 20110026933A
- Authority
- KR
- South Korea
- Prior art keywords
- pyrolysis
- waste
- gas
- gate
- combustible waste
- Prior art date
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B47/00—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
- C10B47/28—Other processes
- C10B47/32—Other processes in ovens with mechanical conveying means
- C10B47/44—Other processes in ovens with mechanical conveying means with conveyor-screws
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/07—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of solid raw materials consisting of synthetic polymeric materials, e.g. tyres
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/10—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1003—Waste materials
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4006—Temperature
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Abstract
Disclosed is an energy efficient eco-friendly flammable waste continuous pyrolysis emulsifier. The present invention transfers the crushed combustible waste pieces by a predetermined amount, and the raw material feed supply device for supplying the waste transferred to a predetermined amount in an oxygen-free or low-oxygen atmosphere state, a pyrolysis device, a plurality of thermal decomposition of the supplied waste in a continuous stable operating conditions A pyrolysis unit consisting of a combustion furnace for supplying a heat source using oil and non-condensable gas as fuel in the pyrolysis chambers and the pyrolysis chambers, a reforming tower for removing foreign substances from the pyrolyzed pyrolysis gas, and a reformed gas for the reforming tower. It is composed of a pyrolysis gas condensing device composed of condensing means for producing and storing high quality oil, and a residue discharging device for automatically and safely discharging the remaining residue after disconnection from external air. Therefore, the present invention continuously supply the crushed combustible waste pieces continuously in the pyrolysis chamber under anoxic or low oxygen atmosphere conditions, and produce pyrolyzed pyrolysis gas as a high quality mixed refined oil, non-liquefied non-liquefied By using the condensation gas as a heat source for pyrolysis, it provides an effect that can be expected energy-efficient eco-friendly flammable waste pyrolysis emulsification equipment.
Description
The present invention relates to the recycling of flammable waste such as rubber, waste synthetic resins, waste plastics, and more particularly, by supplying flammable waste continuously in a state in which the outside air is blocked to be completely pyrolyzed to produce high quality refined oil. In addition, the present invention relates to a supply device for supplying flammable waste in which residual gas is used as a pyrolysis heat source, and a pyrolysis emulsification device for continuous pyrolysis thereof.
In general, in the field of waste treatment, the liquor of the prior art is mostly incinerated with air, but recovers the heat of incineration generated as much as possible, removes the harmful substances contained in the combustion gas below the legal limit, and then removes a large amount of the combustion gas. At the same time as the discharge to the atmosphere, a series of treatments are performed to solidify the landfill by burning the residue and fly ash generated.
However, the secondary pollution due to the accumulation of harmful substances remaining in the combustion gas discharged to the atmosphere during the waste treatment process and the residual harmful substances solidified and buried, as a factor of serious environmental degradation, the development of new waste treatment technology is required. It is becoming.
In order to meet such a demand, the development of the technology which can recycle a waste in recent years is actively going on.
For example, a method of recycling polymer wastes such as waste plastics made from petroleum as a raw material of flammable wastes, which decomposes a polymer material by applying heat in an oxygen-free condition and converts it into a low-molecular material to return it to oil. Pyrolysis emulsion technology.
Existing flammable waste pyrolysis emulsifying apparatus has two methods: a batch type in which waste is charged into a pyrolysis chamber to apply heat from the outside, and a continuous type of pyrolysis while continuously injecting waste into the pyrolysis chamber.
In the pyrolysis chamber having a narrow volume, all of them heat the heat required for pyrolysis in a short time. As a result, carbon is coated on the wall of the pyrolysis chamber, resulting in rapid heat transfer and poor thermal decomposition. In addition, various problems such as the various facilities of the pyrolysis chamber did not operate smoothly due to rapid feed heating.
In addition, in the discharge of residues generated after pyrolysis, there are many problems in discharging the residues automatically and safely in a state of being blocked with external air.
For this reason, although many pyrolysis apparatuses have been developed, they are not practically used in the industrial field.
Accordingly, an object of the present invention has been made in view of the above-mentioned point, and to provide a supply apparatus for supplying crushed combustible waste pieces while maintaining an anoxic or low oxygen atmosphere so as to increase the thermal decomposition efficiency of combustible waste. .
It is also an object of the present invention to maximize the contact area with the heat source required for pyrolysis of the combustible waste continuously supplied from the supply device for supplying the above-mentioned combustible waste, so that complete pyrolysis is achieved, and the gas generated by pyrolysis is improved. And it provides a combustible waste continuous pyrolysis emulsification apparatus that can be condensed to produce a high quality mixed refined oil.
It is also an object of the present invention to provide a flammable waste continuous pyrolysis emulsification apparatus having safety and efficiency of continuous operation by automatically discharging the remaining residue after the completion of pyrolysis in a state disconnected from external air.
The supply device for supplying the combustible waste of the present invention for achieving the above object is, in the apparatus for supplying combustible waste to the pyrolysis chamber of the pyrolysis emulsification apparatus of the combustible waste, raw material for transferring the crushed combustible waste pieces by a predetermined amount It is equipped with a transfer means and a plurality of gates that can be opened and closed, and automatically supplies the waste transferred to the pyrolysis chamber in a certain amount in an oxygen-free or low-oxygen atmosphere by blocking the inflow of external air by repeatedly opening and closing the connected multiple gates. Contains input means.
The combustible waste continuous pyrolysis emulsifying apparatus for achieving the object of the present invention, in the pyrolysis emulsifying apparatus for pyrolyzing combustible waste to produce oil, transfer the crushed combustible waste pieces by a predetermined amount, and the waste to be transported in a certain amount without oxygen A supply device that continuously supplies while maintaining a low oxygen atmosphere, a plurality of pyrolysis chambers that pyrolyze the combustible waste pieces continuously under stable operating conditions, and a combustion source that supplies oil and non-condensable gas as fuel to the pyrolysis chambers as fuel. A pyrolysis device consisting of a furnace, a residue discharge device for automatically discharging the residue left after pyrolysis in the state of being disconnected from external air, a reforming tower for reforming pyrolysis gas, and a plurality of condensers for condensing the reforming gas to produce oil. And a pyrolysis gas condensation device.
The supply apparatus for supplying the combustible waste of the present invention and the pyrolysis emulsifying apparatus for continuous pyrolysis thereof, have two or more stages of pyrolysis chambers having a large volume and area regardless of the shape of the combustible waste that is crushed and supplied during continuous pyrolysis of the combustible waste. In order to maximize the contact area with the heat source required for pyrolysis, complete pyrolysis is achieved, and the remaining residues are kept in a dry state and discharged automatically by the continuous automatic discharge device that is essential for continuous operation. In addition, the gas generated by pyrolysis is passed through the filtering device to remove internal foreign substances and reformed in a metal catalyst reforming tower to produce high quality mixed refined oil.
In addition, thermal decomposition can be performed regardless of the shape and density of materials such as waste synthetic resin, waste vinyl, composite waste vinyl, and waste rubber, and energy-efficient and environmentally-friendly pyrolysis using non-condensable gas as a heat source for pyrolysis facilities. By providing emulsification technology, it is possible to increase the recycling of flammable waste, which has the effect that can be put to practical use in many industrial sites in the future.
Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings.
1 is an overall configuration diagram schematically showing a flammable waste continuous pyrolysis emulsion apparatus according to the present invention.
The pyrolysis emulsifying apparatus shown in FIG. 1 is largely composed of a
The
The
The pyrolysis
The pyrolysis emulsification operation of producing oil by continuously supplying flammable waste in the apparatus of FIG. 1 having such a configuration will be described in detail.
After combustible waste such as rubber, waste synthetic resin, plastic waste, etc. are crushed in a crusher (not shown), the crushed combustible waste pieces are put into the
Figure 2a is a detailed view showing the
Referring to FIG. 2A, the raw material conveying means 110 has a
When crushed combustible waste pieces such as waste plastic are supplied, the
The automatic feeding means 120 has
As described above, the opening, closing and closing of the primary, secondary and tertiary sealed
3A is a detailed view illustrating a
3A, the
Waste pieces automatically introduced from the tertiary
The waste pieces put into the
The non-pyrolyzed melt introduced into the
The pyrolysis gas pyrolyzed in the first and
4A and 4B are detailed and side views showing the
Referring to Figure 4a, the
As shown in FIG. 4A, the cooling means 310 is provided with a
Pyrolysis is performed through the first and
Discharge means 320 is a plurality of discharge pipes (321,322) commonly connected to the cooling means 310, as shown in Figure 4b, the separation gate to the common connection to alternately distribute the residue to the plurality of discharge pipes (321,322) 323 is provided. The plurality of
When the residue to be discharged from the cooling means 310 is transported, the
While the residues loaded into the
Meanwhile, the high temperature pyrolysis gas discharged from the first and
5A is a detailed view illustrating the
Referring to FIG. 5A, the
The pyrolysis gas is transferred to the reforming
As described above, the remaining non-condensable gas is passed through the non-condensable
6A and 6B illustrate the overall detailed configuration diagram of the apparatus of FIG. 1, and each configuration has been described above.
As described above, the pyrolysis emulsifying apparatus of the present invention can increase the energy consumption efficiency according to the operation of the equipment for producing oil by supplementing and operating the gas produced by itself after consuming the energy required for the first operation.
1 is a block diagram showing a flammable waste continuous pyrolysis emulsion apparatus according to the present invention,
2A-2B are detailed views of the supply apparatus of the apparatus of FIG. 1;
3A-3C are detailed views of the pyrolysis apparatus of the apparatus of FIG. 1;
4a-4b is a detailed view showing the residue discharge device of the device of Figure 1,
5A-5B are detailed views showing the pyrolysis gas condenser of the apparatus of FIG. 1;
6A-6B are detailed configuration diagrams corresponding to the FIG. 1 apparatus.
<Description of the symbols for the main parts of the drawings>
100: supply device 110: raw material transfer means
120: automatic injection means 200: pyrolysis device
210,220
240: exhaust duct 250: gas discharge pipe
300: residue discharge device 310: cooling means
320: discharge means 400: pyrolysis gas condenser
410: reforming tower 420: condensation means
430: storage means
Claims (13)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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KR20090084793A KR101243191B1 (en) | 2009-09-09 | 2009-09-09 | Apparatus for producing fuel oil by continual pyrolysis of waste combustible materials |
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KR20090084793A KR101243191B1 (en) | 2009-09-09 | 2009-09-09 | Apparatus for producing fuel oil by continual pyrolysis of waste combustible materials |
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Publication Number | Publication Date |
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KR20110026933A true KR20110026933A (en) | 2011-03-16 |
KR101243191B1 KR101243191B1 (en) | 2013-03-13 |
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Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
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KR101118052B1 (en) * | 2011-09-21 | 2012-04-12 | 알파환경기술(주) | Oil recycling device for high polymer waste materials |
WO2016037103A1 (en) * | 2014-09-04 | 2016-03-10 | Ag Energy Solutions, Inc. | Apparatuses, systems, cooling augers, and methods for cooling biochar |
US9567539B2 (en) | 2013-09-05 | 2017-02-14 | Ag Energy Solutions, Inc. | Apparatuses, systems, mobile gasification systems, and methods for gasifying residual biomass |
US9631151B2 (en) | 2014-09-04 | 2017-04-25 | Ag Energy Solutions, Inc. | Apparatuses, systems, tar crackers, and methods for gasifying having at least two modes of operation |
KR20200023565A (en) * | 2018-08-23 | 2020-03-05 | (주)켄텍에너지 | Pyrolysis gasification system |
KR102387903B1 (en) * | 2021-03-10 | 2022-04-19 | 주식회사 케이스카이 | Power generating system using waste plastic |
KR102396342B1 (en) * | 2021-05-20 | 2022-05-11 | (주)리보테크 | Oil circulation-treatment method and oil circulation-treatment apparatus for pyrolysis equipment, and pyrolysis treatment equipment comprising the same |
KR102441714B1 (en) * | 2021-04-30 | 2022-09-08 | 주식회사 웨이스트에너지솔루션 | Pyrolysis petrolizing apparatus |
KR20220128939A (en) * | 2021-03-15 | 2022-09-22 | 이정율 | Wastesynthetic resin emulsifier equipped with air-pneumatic input device |
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KR102539139B1 (en) * | 2022-10-04 | 2023-06-01 | 창원대학교 산학협력단 | A catalytic reaction process that decomposes the wax component of the pyrolysis oil produced in the waste plastic pyrolysis process |
US11827859B1 (en) | 2022-05-03 | 2023-11-28 | NuPhY, Inc. | Biomass gasifier system with rotating distribution manifold |
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KR100787958B1 (en) * | 2004-09-25 | 2007-12-31 | 구재완 | Successive pyrolysis system of waste synthetic-highly polymerized compound |
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2009
- 2009-09-09 KR KR20090084793A patent/KR101243191B1/en not_active IP Right Cessation
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KR101118052B1 (en) * | 2011-09-21 | 2012-04-12 | 알파환경기술(주) | Oil recycling device for high polymer waste materials |
US9567539B2 (en) | 2013-09-05 | 2017-02-14 | Ag Energy Solutions, Inc. | Apparatuses, systems, mobile gasification systems, and methods for gasifying residual biomass |
WO2016037103A1 (en) * | 2014-09-04 | 2016-03-10 | Ag Energy Solutions, Inc. | Apparatuses, systems, cooling augers, and methods for cooling biochar |
US9631151B2 (en) | 2014-09-04 | 2017-04-25 | Ag Energy Solutions, Inc. | Apparatuses, systems, tar crackers, and methods for gasifying having at least two modes of operation |
KR20200023565A (en) * | 2018-08-23 | 2020-03-05 | (주)켄텍에너지 | Pyrolysis gasification system |
KR102387903B1 (en) * | 2021-03-10 | 2022-04-19 | 주식회사 케이스카이 | Power generating system using waste plastic |
KR20220128939A (en) * | 2021-03-15 | 2022-09-22 | 이정율 | Wastesynthetic resin emulsifier equipped with air-pneumatic input device |
KR102441714B1 (en) * | 2021-04-30 | 2022-09-08 | 주식회사 웨이스트에너지솔루션 | Pyrolysis petrolizing apparatus |
KR102396342B1 (en) * | 2021-05-20 | 2022-05-11 | (주)리보테크 | Oil circulation-treatment method and oil circulation-treatment apparatus for pyrolysis equipment, and pyrolysis treatment equipment comprising the same |
KR20230049799A (en) | 2021-10-06 | 2023-04-14 | 두산에너빌리티 주식회사 | Reforming system of pyrolysis-gas |
KR20230065650A (en) * | 2021-11-05 | 2023-05-12 | 김용진 | Low-temperature catalytic carbonizer |
KR20230069677A (en) * | 2021-11-12 | 2023-05-19 | 배덕관 | Transfer equipment for Ultrasonic pyrolysis of Polymer waste |
US11827859B1 (en) | 2022-05-03 | 2023-11-28 | NuPhY, Inc. | Biomass gasifier system with rotating distribution manifold |
KR102539139B1 (en) * | 2022-10-04 | 2023-06-01 | 창원대학교 산학협력단 | A catalytic reaction process that decomposes the wax component of the pyrolysis oil produced in the waste plastic pyrolysis process |
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