KR20110013921A - Photocatalyst sterilization lamp that use led phosphor lamp - Google Patents

Photocatalyst sterilization lamp that use led phosphor lamp Download PDF

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KR20110013921A
KR20110013921A KR1020090071628A KR20090071628A KR20110013921A KR 20110013921 A KR20110013921 A KR 20110013921A KR 1020090071628 A KR1020090071628 A KR 1020090071628A KR 20090071628 A KR20090071628 A KR 20090071628A KR 20110013921 A KR20110013921 A KR 20110013921A
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South Korea
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photocatalyst
lamp
glass fiber
led
fluorescent lamp
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KR1020090071628A
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Korean (ko)
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원영희
오시영
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원영희
오시영
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/02Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using physical phenomena
    • A61L2/08Radiation
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/02Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using physical phenomena
    • A61L2/08Radiation
    • A61L2/088Radiation using a photocatalyst or photosensitiser
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/02Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using physical phenomena
    • A61L2/08Radiation
    • A61L2/10Ultra-violet radiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08Silica
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2202/00Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
    • A61L2202/10Apparatus features
    • A61L2202/11Apparatus for generating biocidal substances, e.g. vaporisers, UV lamps

Abstract

PURPOSE: An optical catalyst germicidal lamp using an LED fluorescent lamp is provided, which can perform sterilization of the indoor/outdoor air at the same time. CONSTITUTION: An optical catalyst germicidal lamp using an LED fluorescent lamp is prepared by: a step of making optical catalyst liquid by coating titanium dioxide with porous inorganic oxide; a step of making photocatalytic coating liquid by mixing an inorganic binder with optical catalyst liquid; a step of forming an optical catalyst glass fiber filter(100) by heat treating fiberglass mesh, dipping the fiberglass mesh into the photocatalytic coating liquid, dehydrating the dipped fiberglass mesh, and drying the fiberglass mesh; and a step of covering the outer surface of the LED fluorescent lamp(200) by an optical catalyst glass fiber filter.

Description

엘이디 형광램프를 이용한 광촉매 살균램프{photocatalyst sterilization lamp that use LED phosphor lamp}Photocatalyst sterilization lamp that use LED phosphor lamp

본 발명은 엘이디 형광램프의 표면을 광촉매 유리섬유필터로 감싸 구성함에 따라, 조명으로서의 기능뿐만 아니라, 실내외 공기의 살균 및 소독이 동시에 이루어지고, 특히 유해가스 제거 및 탈취의 효과를 기대할 수 있는 엘이디 형광램프를 이용한 광촉매 살균램프에 관한 것이다.The present invention is configured by wrapping the surface of the LED fluorescent lamp with a photocatalyst glass fiber filter, not only functions as lighting, but also sterilization and disinfection of indoor and outdoor air at the same time, in particular LED fluorescent lamps that can be expected to remove harmful gases and deodorization It relates to a photocatalyst sterilizing lamp using a lamp.

일반적으로 엘이디(LED)는 반도체의 p-n 접합구조를 이용하여 주입된 소수 캐리어(전자)를 만들어내고, 이들의 재결합에 의하여 발광시키는 것인데 이러한 엘이디로부터 발산되는 빛은 직진성이 강하여 일반 조명으로 사용하기에는 적합하지 않았다. 그러나, 근래에는 엘이디가 갖는 장점이 있기 때문에 그 단점(빛의 직진성)을 극복하여 일반 조명으로 사용하기 위한 램프가 소개되었다.In general, LEDs generate a minority carrier (electrons) injected by using a pn junction structure of a semiconductor, and emit light by recombination of them. Light emitted from these LEDs is strong and suitable for general lighting. Did not do it. However, in recent years, because of the advantages of the LED has been introduced to overcome the disadvantages (the straightness of the light) for use as a general lighting lamp.

대표적으로 엘이디와, 이 엘이디를 고정하기 위한 베이스 프레임과, 그 위에서 빛의 난반사를 유도하는 불투명 아크릴소재의 커버를 조립하여 하나의 모듈로 구성하고, 이 모듈을 여러 개 배열하여 하나의 램프를 만드는 것이었다. 그러나 이러한 종류의 엘이디 램프는 기존의 일반 램프들과 그 모양 및 치수가 확연히 달라 서 항상 새로운 금형으로 새롭게 제작해야 할 뿐만 아니라 제조가 어렵고, 수명이 짧으며 가격이 높아지는 단점이 있다. 특히 빛이 투과량 감소가 심하고 부드럽지 못하기 때문에 널리 사용되지 못하였다. 이러한 문제점을 해결하기 위해 엘이디 광원으로부터 나오는 빛을 램프 초자관 내부의 형광물질에 의해 난반사가 이루어지고 나서 발산되도록 함으로써 빛의 투과량을 높이고, 더 부드러운 빛으로 발산될 수 있도록 하는 엘이디 형광램프가 제공된 바 있다.Representatively, the LED, the base frame for fixing the LED, and the cover of opaque acrylic material that induces diffuse reflection of light thereon are assembled into one module, and the modules are arranged to make one lamp. Was. However, this type of LED lamp is different from the conventional lamps, the shape and dimensions are so different that it is not only to manufacture a new mold always, but also difficult to manufacture, short life and high price. In particular, the light has not been widely used because the decrease in the amount of transmission is severe and soft. In order to solve this problem, LED fluorescent lamps are provided to increase light transmission and to emit softer light by causing light emitted from the LED light source to be diffused after being diffused by the fluorescent material inside the lamp tube. have.

또한, 광촉매란 광(光)을 받으면 촉매 반응을 일으키는 물질이다. 광촉매 중 이산화티타늄이 가장 많이 사용되고 있다. 이는 이산화티타늄이 내산성, 내알카리성 등이 좋으며 인체에 무해하기 때문이다. 각종 오염물질을 무해한 물질로 변화시켜 주는 친환경적 소재이다.In addition, a photocatalyst is a substance which causes a catalytic reaction when it receives light. Titanium dioxide is the most used photocatalyst. This is because titanium dioxide has good acid resistance and alkali resistance and is harmless to the human body. It is an environmentally friendly material that transforms various pollutants into harmless materials.

이산화티타늄 광촉매는 n형 반도체로서 자외선(400mm)을 받으면 전자(Electron) 전공대(Electron Hole)가 형성되어 강한 산화력을 가진 하이드록시 라티칼(-OH)과 슈퍼 옥사이드을 생성한다. 이 하드드록시 라디칼과 슈퍼 옥사이드가 유기 화합물을 산화 분해시켜 물과 탄산가스로 변화시킨다.Titanium dioxide photocatalysts are n-type semiconductors, and when subjected to ultraviolet rays (400 mm), electrons (electrons) are formed to produce hydroxy radicals (-OH) and super oxides with strong oxidizing power. These hard hydroxy radicals and super oxides oxidize and decompose organic compounds into water and carbon dioxide.

이런 원리로 공기 중의 오염물질을 산화, 분해시켜 무해한 물과 탄산가스로 변화시키고 수중의 오염 물질인 유기화합물을 분해시켜 물과 탄산가스로 변화시키게 된다. 또한 세균도 유기 화합물이므로 광촉매의 강한 산화작용에 의해 산화분해되어 살균된다.In this way, air pollutants are oxidized and decomposed into harmless water and carbon dioxide, and organic compounds, which are pollutants in water, are decomposed into water and carbon dioxide. Since bacteria are also organic compounds, they are oxidatively decomposed and sterilized by the strong oxidation of the photocatalyst.

따라서, 현재 이슈화 되고있는 엘이디 형광램프는 단순히 빛을 발산하는 조명으로서의 기능뿐만 아니라, 광촉매와 접목하여 전시장 및 일반 가정 등의 실내외 공기의 살균 및 소독이 동시에 이루어지도록 하고, 특히 공장 및 각종 산업 현장에서 필요한 유해가스 제거 및 탈취 능력을 구비한 엘이디 형광램프의 제공이 시급히 이루어져야 할 것이다.Therefore, LED fluorescent lamps, which are currently being issued, not only function as light emitting light but also combine with photocatalyst to simultaneously disinfect and disinfect indoor and outdoor air in exhibition halls and general homes, and especially in factories and various industrial sites. There should be an urgent need to provide LED fluorescent lamps with the ability to remove and deodorize harmful gases.

본 발명은 엘이디 형광램프를 이용한 광촉매 살균램프에 관한 것으로, 엘이디 광원으로부터 나오는 빛이 램프 초자관 내부의 형광물질에 의해 직진성이 없이 난반사가 이루어지고, 그 상태로 발산되도록 하였기 때문에 종래보다 빛의 투과량을 높이는 동시에, 엘이디 형광램프의 표면을 광촉매 유리섬유필터로 감싸 구성함에 따라, 조명으로서의 기능뿐만 아니라, 실내외 공기의 살균 및 소독이 동시에 이루어지고, 특히 유해가스 제거 및 탈취의 효과를 기대할 수 있는 엘이디 형광램프를 이용한 광촉매 살균램프를 제공하는 데 그 목적이 있다.The present invention relates to a photocatalyst sterilization lamp using an LED fluorescent lamp, and since the light emitted from the LED light source is diffusely reflected without the straightness by the fluorescent material inside the lamp tube, it is emitted in that state, so that the amount of light transmitted At the same time, the surface of the LED fluorescent lamp is wrapped with a photocatalytic glass fiber filter, which not only functions as lighting but also sterilizes and disinfects the indoor and outdoor air at the same time. It is an object of the present invention to provide a photocatalyst sterilizing lamp using a fluorescent lamp.

상기와 같은 목적을 달성하기 위한 본 발명은 30-60㎚크기의 이산화티탄(TiO2)을 다공성 무기산화물로 코팅처리하여 광촉매액을 구비하고; 상기 광촉매액을 무기바인더와 혼합하여 광촉매코팅액을 구비하며; 유리섬유를 격자형으로 직조하여 구성된 유리섬유망체를 30 ~ 50℃의 온도로 가열하여 열처리하고; 상기 광촉매코팅액을 15 ~ 40℃의 온도로 가열한 뒤, 열처리된 유리섬유망체를 가열된 광촉매코팅액에 30 ~ 60분 동안 침지하며; 상기 침지된 유리섬유망체를 탈수처리한 뒤 200 ~ 300℃의 온도에서 5 ~ 30분간 열풍건조하여 광촉매 유리섬유필터를 형성하고; 상기 엘이디(LED) 형광램프의 외측표면을 광촉매 유리섬유필터로 커버하여 구성된 엘이디 형광램프를 이용한 광촉매 살균램프를 제공한다.The present invention for achieving the above object is provided with a photocatalyst liquid by coating a titanium dioxide (TiO 2 ) of 30-60nm size with a porous inorganic oxide; Mixing the photocatalyst liquid with an inorganic binder to provide a photocatalyst coating liquid; Heat-treating the glass fiber network constructed by weaving the glass fiber in a lattice shape to a temperature of 30 to 50 ° C .; After heating the photocatalyst coating solution to a temperature of 15 ~ 40 ℃, the heat-treated glass fiber network is immersed in the heated photocatalyst coating solution for 30 to 60 minutes; Dehydrating the immersed glass fiber network and hot-air-dried for 5 to 30 minutes at a temperature of 200 to 300 ° C. to form a photocatalyst glass fiber filter; It provides a photocatalyst sterilization lamp using an LED fluorescent lamp configured to cover the outer surface of the LED (LED) fluorescent lamp with a photocatalyst glass fiber filter.

본 발명 엘이디 형광램프를 이용한 광촉매 살균램프는 엘이디 광원으로부터 나오는 빛이 램프 초자관 내부의 형광물질에 의해 직진성이 없이 난반사가 이루어지고, 그 상태로 발산되도록 하였기 때문에 종래보다 빛의 투과량을 높이는 엘이디 형광램프의 효과와 더불어, 상기 엘이디 형광램프의 표면을 광촉매 유리섬유필터로 감싸 구성함에 따라, 조명으로서의 기능뿐만 아니라, 실내외 공기의 살균 및 소독이 동시에 이루어지도록 하고, 특히 유해가스 제거 및 탈취 효과를 기대할 수 있어 공기정화에도 탁월한 매우 유용한 발명이다.In the photocatalyst sterilizing lamp using the LED fluorescent lamp of the present invention, since the light emitted from the LED light source is diffusely reflected without the straightness by the fluorescent material inside the lamp tube, the LED fluorescence increases the amount of light transmitted than before. In addition to the effect of the lamp, the surface of the LED fluorescent lamp is wrapped with a photocatalyst glass fiber filter, so that not only functions as lighting, but also to sterilize and disinfect indoor and outdoor air at the same time, and particularly to remove harmful gases and deodorization effect is expected. It is a very useful invention that is excellent for air purification.

이하 첨부된 도면에 따라 본 발명 엘이디 형광램프를 이용한 광촉매 살균램프의 구성 및 작용을 더욱 상세히 설명하면 다음과 같다.Hereinafter, the configuration and operation of the photocatalyst sterilizing lamp using the present invention LED fluorescent lamp according to the accompanying drawings in more detail.

도 1은 본 발명에 따른 광촉매 살균램프의 분해사시도이고, 도 2는 본 발명에 따른 광촉매 살균램프의 단면도이며, 도 3a는 본 발명의 일 실시예에 따른 분해사시도이고, 도 3b는 본 발명의 일 실시예에 따른 사시도이며, 도 4a는 본 발명에 따른 광촉매 살균램프의 분해사시도이고, 도 4b는 본 발명에 따른 광촉매 살균램프의 단면도이며, 도 5a는 본 발명의 다른 실시예에 따른 분해사시도이고, 도 5b는 본 발명의 다른 실시예에 따른 단면도이다.1 is an exploded perspective view of a photocatalyst sterilizing lamp according to the present invention, Figure 2 is a cross-sectional view of the photocatalyst sterilizing lamp according to the present invention, Figure 3a is an exploded perspective view according to an embodiment of the present invention, Figure 3b of the present invention 4A is an exploded perspective view of a photocatalyst sterilizing lamp according to the present invention, FIG. 4B is a cross-sectional view of a photocatalyst sterilizing lamp according to the present invention, and FIG. 5A is an exploded perspective view according to another embodiment of the present invention. 5B is a cross-sectional view according to another embodiment of the present invention.

먼저, 본 발명에 따른 엘이디 형광램프를 이용한 광촉매 살균램프(10)는 30-60㎚크기의 이산화티탄(TiO2)을 다공성 무기산화물로 코팅처리하여 광촉매액을 구비 하고; 상기 광촉매액을 무기바인더와 혼합하여 광촉매코팅액을 구비하며; 유리섬유를 격자형으로 직조하여 구성된 유리섬유망체를 30 ~ 50℃의 온도로 가열하여 열처리하고; 상기 광촉매코팅액을 15 ~ 40℃의 온도로 가열한 뒤, 열처리된 유리섬유망체를 가열된 광촉매코팅액에 30 ~ 60분 동안 침지하며; 상기 침지된 유리섬유망체를 탈수처리한 뒤 200 ~ 300℃의 온도에서 5 ~ 30분간 열풍건조하여 광촉매 유리섬유필터(100)를 형성하고; 상기 광촉매 유리섬유필터(100)를 엘이디(LED) 형광램프(200)의 외측표면을 감싸도록 커버하여 구성된 것을 기술상의 요점으로 한다.First, the photocatalyst sterilizing lamp 10 using the LED fluorescent lamp according to the present invention comprises a photocatalyst liquid by coating a titanium dioxide (TiO 2 ) having a size of 30-60 nm with a porous inorganic oxide; Mixing the photocatalyst liquid with an inorganic binder to provide a photocatalyst coating liquid; Heat-treating the glass fiber network constructed by weaving the glass fiber in a lattice shape to a temperature of 30 to 50 ° C .; After heating the photocatalyst coating solution to a temperature of 15 ~ 40 ℃, the heat-treated glass fiber network is immersed in the heated photocatalyst coating solution for 30 to 60 minutes; Dehydrating the immersed glass fiber network and hot-air-dried at a temperature of 200 to 300 ° C. for 5 to 30 minutes to form a photocatalyst glass fiber filter 100; The photocatalyst glass fiber filter 100 is configured to cover the outer surface of the LED (LED) fluorescent lamp 200 to the technical point.

상기 광촉매 유리섬유필터(100)는 30-60㎚크기의 이산화티탄(TiO2)을 다공성 무기산화물로 코팅처리하여 광촉매액을 구비하고, 상기 광촉매액을 무기바인더와 혼합하여 광촉매코팅액을 구비한 뒤, 유리섬유를 격자형으로 직조하여 구성된 유리섬유망체를 30 ~ 50℃의 온도로 가열하여 열처리하고, 상기 광촉매코팅액을 15 ~ 40℃의 온도로 가열한 뒤, 열처리된 유리섬유망체를 가열된 광촉매코팅액에 30 ~ 60분 동안 침지하고, 상기 침지된 유리섬유망체를 탈수처리한 뒤 200 ~ 300℃의 온도에서 5 ~ 30분간 열풍건조하여 구성된다.The photocatalyst glass fiber filter 100 has a photocatalyst liquid by coating a titanium dioxide (TiO 2 ) having a size of 30-60 nm with a porous inorganic oxide, and a photocatalyst coating liquid by mixing the photocatalyst liquid with an inorganic binder. After heating the glass fiber mesh formed by weaving the glass fibers in a lattice shape to a temperature of 30 ~ 50 ℃, and heating the photocatalyst coating solution to a temperature of 15 ~ 40 ℃, the heat-treated glass fiber network photocatalyst It is immersed in the coating solution for 30 to 60 minutes, dehydrated glass fiber network and then dried by hot air for 5 to 30 minutes at a temperature of 200 ~ 300 ℃.

이산화티탄(TiO2)의 크기가 30-60㎚로 형성될 경우, 미립화된 이산화티탄(TiO2)의 구조에 따라 전체적인 이산화티탄(TiO2)의 표면적이 증가하여 광촉매의 살균효율을 증가시킬 수 있으며, 다공성 무기산화물에 의해 마련된 기공 사이로 이산화티탄(TiO2)이 침투하여 고정될 수 있는 것이다. When the size of titanium dioxide (TiO 2 ) is formed to 30-60 nm, the surface area of the titanium dioxide (TiO 2 ) may increase according to the structure of the atomized titanium dioxide (TiO 2 ) to increase the sterilization efficiency of the photocatalyst. In addition, titanium dioxide (TiO 2 ) may penetrate and be fixed between pores provided by a porous inorganic oxide.

또한, 유리섬유는 용융한 유리를 섬유 모양으로 한 광물섬유를 의미하는 것 으로, 고온에 견디며, 불에 타지 않고, 화학적 내구성이 있기 때문에 부식하지 않는 성질을 구비하므로 엘이디 형광램프를 감싸더라고 변형이 발생하지 않기 때문에 상기와 같은 유리섬유를 망체로 직조하여 유리섬유망체를 형성하는 것이다.In addition, glass fiber refers to a mineral fiber made of molten glass as a fiber shape, and because it is resistant to high temperature, does not burn, and does not corrode because it is chemically durable, the glass fiber is deformed even when it is wrapped around the LED fluorescent lamp. Since it does not occur, the glass fiber is woven into the mesh to form a glass fiber mesh.

상기 유리섬유망체를 30 ~ 50℃의 온도에서 예열하는 이유는 코팅이 보다 신속하고 안전하게 이루어지도록 하기 위함이며, 고온일 경우 성분변화 및 코팅력이 오히려 저하될 수 있으므로 30 ~50℃로 예열하는 것이다.The reason for preheating the glass fiber mesh at a temperature of 30 to 50 ° C is to make the coating more quickly and safely, and to preheat it to 30 to 50 ° C because the change in composition and coating power may be lowered at high temperatures. .

상기 유리섬유망체는 광촉매코팅액에서 함침된 후 건조하여 광촉매유리섬유필터(100)로 완성되는 데, 이 때 광촉매코팅액은 15 ~ 40℃의 온도를 유지하고, 침지시간은 30 ~ 60분가량 실시하여 유리섬유망체에 광촉매코팅액이 꼼꼼히 코팅될 수 있도록 한다.The glass fiber network is impregnated in the photocatalyst coating liquid and dried to complete the photocatalyst glass fiber filter 100, wherein the photocatalyst coating liquid is maintained at a temperature of 15 ~ 40 ℃, the immersion time is carried out about 30 ~ 60 minutes The photocatalytic coating solution is carefully coated on the glass fiber mesh.

또한, 광촉매코팅액에서 코팅이 완료된 유리섬유망체는 건조가 신속히 이루어지도록 탈수처리하게 되는데, 원심분리기를 이용한 회전식 탈수방식을 비롯하여 롤러사이를 통과하는 가압방식 등 공지된 다양한 방법으로 탈수처리할 수 있다.In addition, the glass fiber mesh is coated in the photocatalyst coating solution is subjected to a dehydration treatment so that the drying is carried out quickly, it can be dewatered by a variety of known methods such as a rotary dehydration method using a centrifuge, a pressure method passing between the rollers.

상기 탈수처리된 유리섬유망체는 표면에 광촉매코팅액이 흐르지않을 정도로 코팅되어져 있고, 수분을 증발하여 광촉매코팅액의 성분을 유리섬유망체에 고정하도록 200 ~300℃의 온도의 열풍을 5 ~ 30분간 처리하여 건조가 이루어지도록 하며, 건조가 완료되면 광촉매 유리섬유필터(100)가 완료되는 것이다.The dehydrated glass fiber mesh is coated so that the photocatalytic coating liquid does not flow on the surface, and the hot air at a temperature of 200 to 300 ° C. is treated for 5 to 30 minutes to evaporate moisture to fix the component of the photocatalyst coating liquid to the glass fiber mesh. Drying is made, and when the drying is completed, the photocatalyst glass fiber filter 100 is completed.

상기와 같이 구비된 광촉매 유리섬유필터(100)는 엘이디(LED) 형광램프(200)의 외측표면을 감싸도록 커버되어 본 발명 엘이디 형광램프를 이용한 광촉매 살균램프(10)가 완성되는 것이다.The photocatalyst glass fiber filter 100 provided as described above is covered to surround the outer surface of the LED fluorescent lamp 200 to complete the photocatalyst sterilization lamp 10 using the LED fluorescent lamp of the present invention.

참고로, 상기 엘이디(LED) 형광램프(200)는 공지된 다양한 종류의 엘이디(LED) 형광램프(200)가 적용될 수 있으며, 특히 상기 엘이디(LED) 형광램프(200)는 엘이디를 구비하는 엘이디 모듈(210), 상기 엘이디 모듈(210)이 복수로 길이 방향으로 배열되고, 그 양측 단부에 전원연결용 커넥터(220)가 고정되는 회로기판(230)과, 상기 회로기판(230)에 설치되며 교류를 직류로 변환시키기 위한 전류변환기구(240)와, 상기 회로기판(230)이 삽입되고, 내부에 형광물질(250)이 도포되며, 양측 끝단에 램프소켓(260)이 고정되어 기밀이 유지되는 원통 파이프 모양의 램프 초자관(270)을 포함하여 구성될 수 있다.For reference, the LED fluorescent lamp 200 may be applied to a variety of known LED (LED) fluorescent lamp 200, in particular the LED (LED) fluorescent lamp 200 is an LED having an LED Module 210, the LED module 210 is arranged in a plurality of longitudinal directions, the circuit board 230 is fixed to both ends of the power supply connector 220, and is installed on the circuit board 230 A current conversion mechanism 240 for converting AC into DC and the circuit board 230 are inserted therein, a fluorescent material 250 is applied therein, and lampholders 260 are fixed at both ends to maintain airtightness. It may be configured to include a cylindrical tube-shaped lamp vitreous tube 270.

본 발명의 실시예에 따르면, 상기 이산화티탄(TiO2)은 공지된 다양한 방식에 의해 구비될 수 있으며, 특히 항균금속성분인 은(Ag)과, 무기수산화물을 공침법에 의해 반응하고, 이를 수중에 분산하여 콜로이드화함에 따라 항균금속 함유 무기수산화물 졸을 제조하고; 수산화티타늄(Ti(OH)2)수분산액에 과산화수소를 첨가하고 가열하여 과산화티타늄산 용액을 제조한 후; 상기 과산화티타늄산 용액을 상기 항균금속 함유 무기수산화물 졸과 혼합한 후 수열합성반응하여 항균금속성분을 구비하도록 구성될 수 있다.According to an embodiment of the present invention, the titanium dioxide (TiO 2 ) may be provided by a variety of known methods, in particular silver (Ag), an antimicrobial metal component, the inorganic hydroxide reacts by a coprecipitation method, and in water Preparing an antimicrobial metal-containing inorganic hydroxide sol by dispersing it in colloidal form; Adding hydrogen peroxide to the titanium hydroxide (Ti (OH) 2 ) aqueous dispersion and heating to prepare a titanium peroxide solution; The titanium peroxide solution may be mixed with the antimicrobial metal-containing inorganic hydroxide sol and then hydrothermally synthesized to provide an antimicrobial metal component.

또한, 본 발명의 실시예에 따르면, 상기 무기산화물은 티타늄(Ti), 알루미늄(Al), 구리(Cu), 아연(Zn) 중 어느 하나를 선택하여 구성될 수 있다.In addition, according to an embodiment of the present invention, the inorganic oxide may be configured by selecting any one of titanium (Ti), aluminum (Al), copper (Cu), zinc (Zn).

본 발명의 실시예에 따려면, 상기 건조된 광촉매 유리섬유필터(100)는 중공의 파이프 형태로 가공하되, 빛의 자극에 의해 백색으로 발광하도록 300mesh 이상 의 미립자 상태 형광물질을 광촉매 유리섬유필터(100) 10 중량부 : 형광물질 0.5 ~ 2 중량부의 비율로 균일한 분포로 도포하여 구성되며, 상기 도포 비율을 빛의 자극에 의해 백색으로 발광하되, 지나치게 밝을 경우 눈의 js강을 해칠 우려가 있으므로 광촉매 유리섬유필터(100) 10 중량부를 기준으로, 0.5 ~ 2 중량부의 형광물질을 도포한다.According to an embodiment of the present invention, the dried photocatalyst glass fiber filter 100 is processed in the form of a hollow pipe, the photocatalyst glass fiber filter (300 micrometer or more particulate state fluorescent material to emit white light by stimulation of light) 100 parts by weight: It is composed by applying a uniform distribution in the proportion of 0.5 to 2 parts by weight of the fluorescent substance, and the application ratio is emitted to white by the stimulation of light, but if too bright may damage the js steel of the eyes Based on 10 parts by weight of the photocatalyst glass fiber filter 100, 0.5 to 2 parts by weight of the fluorescent material is applied.

광촉매 유리섬유필터(100)는 그 구조가 엘이디(LED) 형광램프(200)가 압입되도록 원통형으로 이루어지되, 광촉매 유리섬유필터(100)의 내주연의 크기가 엘이디(LED) 형광램프(200)의 외주연과 대응하는 사이즈로 구성될 수 있으며, 경우에 따라서는 직사각형의 광촉매 유리섬유필터(100)로 엘이디(LED) 형광램프(200)를 감싸고, 광촉매 유리섬유필터(100)의 양측단부를 벨크로와 같은 수단으로 고정하여 탈착이 용이하도록 한다.The photocatalyst glass fiber filter 100 has a cylindrical structure such that the LED fluorescent lamp 200 is press-fitted, but the size of the inner circumference of the photocatalyst glass fiber filter 100 is the LED fluorescent lamp 200. It may be configured in a size corresponding to the outer periphery of, in some cases, the LED (lamp) fluorescent lamp 200 is wrapped in a rectangular photocatalyst glass fiber filter 100, both ends of the photocatalyst glass fiber filter 100 Secured by means such as Velcro for easy removal.

본 발명의 실시예에 따르면, 상기 형광물질(250)은 자외선에 의해 가시광선 영역의 빛을 내는 야그(YAG: Yttrium Aluminum Garnet: Y3A15012)의 란탄 계열 물질로서 La, Ce, Pr, Nd, Sm, Eu, Y, Ho 이온, 원소 중 적어도 하나의 성분으로 이루어지거나 이들이 포함된 염으로 구성된다.According to an embodiment of the present invention, the fluorescent material 250 is a lanthanum-based material of YAG (Yttrium Aluminum Garnet: Y3A15012) that emits light in the visible region by ultraviolet light, and La, Ce, Pr, Nd, Sm, Eu, Y, Ho ions, salts consisting of or containing at least one component of the element.

본 발명의 실시예에 따르면, 상기 광촉매 유리섬유필터(100)는 내주면에 엘이디(LED) 형광램프(200)와 이격하도록 다수의 이격돌기(110)가 추가로 구성된다.According to the exemplary embodiment of the present invention, the photocatalyst glass fiber filter 100 further includes a plurality of spaced apart protrusions 110 to be spaced apart from the LED fluorescent lamp 200 on an inner circumferential surface thereof.

상기 이격돌기(110)는 실리콘과 같이 탄성을 구비하여 엘이디(LED) 형광램프(200)에 충격을 가하지 않는 소재로 구성됨이 바람직하고, 이격돌기(110)의 작용으로 광촉매 유리섬유필터(100)와 엘이디(LED) 형광램프(200) 사이에 공간이 확보 되어 엘이디(LED) 형광램프(200)에서 발산되는 열에 의해 광촉매 유리섬유필터(100)가 변형되는 것을 방지할 뿐 아니라, 엘이디(LED) 형광램프(200)의 빛이 사이 공간을 통해 발산되면서 광촉매 유리섬유필터(100)에 의한 살균 및 공기정화 효과를 높일 수 있다.The spacer 110 is preferably made of a material that does not impact the LED fluorescent lamp 200 by having elasticity, such as silicon, and the photocatalyst glass fiber filter 100 by the action of the spacer 110. And a space is secured between the LED fluorescent lamp 200 to prevent the photocatalyst glass fiber filter 100 from being deformed by the heat emitted from the LED fluorescent lamp 200, as well as the LED As the light of the fluorescent lamp 200 is emitted through the interspace, the sterilization and air purification effect by the photocatalyst glass fiber filter 100 may be enhanced.

또한, 상기 광촉매 유리섬유필터(100)는 엘이디(LED) 형광램프(200)에 고정 및 탈착이 용이하도록 양측에 탄성밴드(120)를 비롯하여 벨크로 등과 같은 다양한 고정수단이 추가로 구비될 수 있다. 탄성밴드(120)의 경우 엘이디(LED) 형광램프(200)의 램프소켓(260)의 외주면을 적당히 가압하면서 감싸 광촉매 유리섬유필터(100)가 엘이디(LED) 형광램프(200)에서 임의로 분리되지 않도록 고정하고, 엘이디(LED) 형광램프(200)를 교체할 경우에도 간편하게 교체할 수 있어 사용이 간편하다.In addition, the photocatalyst glass fiber filter 100 may be further provided with various fixing means such as an elastic band 120, Velcro and the like on both sides to facilitate fixing and detachment to the LED fluorescent lamp (200). In the case of the elastic band 120, the photocatalyst glass fiber filter 100 is not separated from the LED fluorescent lamp 200 by wrapping it while pressing the outer peripheral surface of the lamp socket 260 of the LED fluorescent lamp 200 appropriately. It is easy to use, even when replacing the LED (LED) fluorescent lamp 200 can be easily replaced.

참고로, 도 6a는 삼파장 엘이디 형광램프에 광촉매 유리섬유필터가 씌워진 모습을 보인 분해사시도이고, 도 6b는 삼파장 엘이디 형광램프에 광촉매 유리섬유필터가 씌워진 모습을 보인 사시도로서, 광촉매 유리섬유필터(100)는 막대형의 엘이디 형광램프(200)뿐만 아니라, 다양한 형상을 갖는 형광등 램프(200, 200', 200')에 적용될 수 있으며, 특히 컴팩드한 삼파장 엘이디 형광등(200')에 광촉매 유리섬유필터(100)가 씌워져 본 발명이 구성될 수 있다. 또한, 도 7a는 원형 엘이디 형광램프에 광촉매 유리섬유필터가 씌워진 모습을 보인 사시도이고, 도 7b는 도 7a의 단면도로서, 원형의 엘이디 형광등(200'')에도 광촉매 유리섬유필터(100)가 씌워져 본 발명 엘이디 형광램프를 이용한 광촉매 살균램프(10)가 구성될 수 있다.For reference, Figure 6a is an exploded perspective view showing a photocatalyst glass fiber filter is covered with a three-wavelength LED fluorescent lamp, Figure 6b is a perspective view showing a photocatalyst glass fiber filter is covered with a three-wavelength LED fluorescent lamp, a photocatalyst glass fiber filter (100 ) Can be applied to the fluorescent lamps 200, 200 ', and 200' of various shapes, as well as the rod-shaped LED fluorescent lamp 200, in particular, the photocatalyst glass fiber filter to the compact three-wavelength LED fluorescent lamp (200 ') 100 may be covered to constitute the present invention. FIG. 7A is a perspective view showing a photocatalyst glass fiber filter coated on a circular LED fluorescent lamp, and FIG. 7B is a cross-sectional view of FIG. 7A, wherein the photocatalyst glass fiber filter 100 is also covered on a circular LED fluorescent lamp 200 ″. Photocatalyst sterilization lamp 10 using the LED fluorescent lamp of the present invention can be configured.

상기와 같은 본 발명 엘이디 형광램프를 이용한 광촉매 살균램프(10)는 엘이디 광원으로부터 나오는 빛이 램프 초자관(270) 내부의 형광물질(250)에 의해 직진성이 없이 난반사가 이루어지고, 그 상태로 발산되도록 하였기 때문에 종래보다 빛의 투과량을 높이도록 하는 엘이디 형광램프(200)의 효과와 더불어, 상기 엘이디 형광램프(200)의 표면을 광촉매 유리섬유필터(100)로 감싸 구성함에 따라, 조명으로서의 기능뿐만 아니라, 실내외 공기의 살균 및 소독이 동시에 이루어지도록 하고, 특히 유해가스 제거 및 탈취 효과를 기대할 수 있어 공기정화에도 탁월한 장점이 있다.In the photocatalyst sterilizing lamp 10 using the LED fluorescent lamp of the present invention as described above, light emitted from the LED light source is diffusely diffused without the straightness by the fluorescent material 250 inside the lamp tube 24. In addition to the effect of the LED fluorescent lamp 200 to increase the amount of light transmission than before, by wrapping the surface of the LED fluorescent lamp 200 with a photocatalyst glass fiber filter 100, only as a function as illumination In addition, the sterilization and disinfection of the indoor and outdoor air is made at the same time, in particular can be expected to remove harmful gases and deodorizing effect is excellent in air purification.

도 1은 본 발명에 따른 광촉매 살균램프의 분해사시도,1 is an exploded perspective view of a photocatalyst sterilizing lamp according to the present invention;

도 2는 본 발명에 따른 광촉매 살균램프의 단면도,2 is a cross-sectional view of a photocatalyst sterilizing lamp according to the present invention;

도 3a는 본 발명의 일 실시예에 따른 분해사시도,Figure 3a is an exploded perspective view according to an embodiment of the present invention,

도 3b는 본 발명의 일 실시예에 따른 사시도,3b is a perspective view according to an embodiment of the present invention;

도 4a는 본 발명에 따른 광촉매 살균램프의 분해사시도,4A is an exploded perspective view of a photocatalyst sterilizing lamp according to the present invention;

도 4b는 본 발명에 따른 광촉매 살균램프의 단면도,4b is a cross-sectional view of a photocatalyst sterilizing lamp according to the present invention;

도 5a는 본 발명의 다른 실시예에 따른 분해사시도,Figure 5a is an exploded perspective view according to another embodiment of the present invention,

도 5b는 본 발명의 다른 실시예에 따른 단면도,5B is a cross-sectional view according to another embodiment of the present invention;

도 6a는 삼파장 엘이디 형광램프에 광촉매 유리섬유필터가 씌워진 모습을 보인 분해사시도,FIG. 6A is an exploded perspective view showing a photocatalyst glass fiber filter coated on a three-wavelength LED fluorescent lamp; FIG.

도 6b는 삼파장 엘이디 형광램프에 광촉매 유리섬유필터가 씌워진 모습을 보인 사시도, Figure 6b is a perspective view showing a photocatalyst glass fiber filter is applied to the three-wavelength LED fluorescent lamp,

도 7a는 원형 엘이디 형광램프에 광촉매 유리섬유필터가 씌워진 모습을 보인 사시도,7A is a perspective view showing a photocatalyst glass fiber filter on a circular LED fluorescent lamp;

도 7b는 도 7a의 단면도.FIG. 7B is a sectional view of FIG. 7A; FIG.

<도면의 주요부분에 대한 부호의 설명><Description of the symbols for the main parts of the drawings>

10 : 엘이디 형광램프를 이용한 광촉매 살균램프10: Photocatalyst sterilization lamp using LED fluorescent lamp

100 : 광촉매 유리섬유필터 110 : 이격돌기100: photocatalyst glass fiber filter 110: spacer

120 : 탄성밴드 200 : 엘이디 형광램프120: elastic band 200: LED fluorescent lamp

210 : 엘이디 모듈 220 : 전원연결용 커넥터210: LED module 220: connector for power connection

230 : 회로기판 240 : 전류 변환기구230: circuit board 240: current converter port

250 : 형광물질 260 : 램프소켓250: fluorescent material 260: lamp socket

270 : 램프 초자관270: lamp supertube

Claims (7)

30-60㎚크기의 이산화티탄(TiO2)을 다공성 무기산화물로 코팅처리하여 광촉매액을 구비하고;30-60 nm size titanium dioxide (TiO 2 ) is coated with a porous inorganic oxide to provide a photocatalyst solution; 상기 광촉매액을 무기바인더와 혼합하여 광촉매코팅액을 구비하며;Mixing the photocatalyst liquid with an inorganic binder to provide a photocatalyst coating liquid; 유리섬유를 격자형으로 직조하여 구성된 유리섬유망체를 30 ~ 50℃의 온도로 가열하여 열처리하고;Heat-treating the glass fiber network constructed by weaving the glass fiber in a lattice shape to a temperature of 30 to 50 ° C .; 상기 광촉매코팅액을 15 ~ 40℃의 온도로 가열한 뒤, 열처리된 유리섬유망체를 가열된 광촉매코팅액에 30 ~ 60분 동안 침지하며;After heating the photocatalyst coating solution to a temperature of 15 ~ 40 ℃, the heat-treated glass fiber network is immersed in the heated photocatalyst coating solution for 30 to 60 minutes; 상기 침지된 유리섬유망체를 탈수처리한 뒤 200 ~ 300℃의 온도에서 5 ~ 30분간 열풍건조하여 광촉매 유리섬유필터(100)를 형성하고;Dehydrating the immersed glass fiber network and hot-air-dried at a temperature of 200 to 300 ° C. for 5 to 30 minutes to form a photocatalyst glass fiber filter 100; 상기 광촉매 유리섬유필터(100)를 엘이디(LED) 형광램프(200)의 외측표면을 감싸도록 커버하여 구성된 것을 특징으로 하는 엘이디 형광램프를 이용한 광촉매 살균램프.Photocatalyst sterilizing lamp using an LED fluorescent lamp, characterized in that the photocatalyst glass fiber filter 100 is covered to cover the outer surface of the LED (LED) fluorescent lamp (200). 제 1항에 있어서, 상기 이산화티탄(TiO2)은 항균금속성분인 은(Ag)과, 무기수산화물을 공침법에 의해 반응하고, 이를 수중에 분산하여 콜로이드화함에 따라 항균금속 함유 무기수산화물 졸을 제조하고; The method of claim 1, wherein the titanium dioxide (TiO 2 ) is reacted with silver (Ag), which is an antibacterial metal component and inorganic hydroxide by coprecipitation method, and dispersed in water to colloid to form an antimicrobial metal-containing inorganic hydroxide sol. To manufacture; 수산화티타늄(Ti(OH)2)수분산액에 과산화수소를 첨가하고 가열하여 과산화티 타늄산 용액을 제조한 후;Adding hydrogen peroxide to the titanium hydroxide (Ti (OH) 2 ) aqueous dispersion and heating to prepare a titanium peroxide solution; 상기 과산화티타늄산 용액을 상기 항균금속 함유 무기수산화물 졸과 혼합한 후 수열합성반응하여 항균금속성분을 구비하도록 구성된 것을 특징으로 하는 엘이디 형광램프를 이용한 광촉매 살균램프.The photocatalyst sterilization lamp using an LED fluorescent lamp, characterized in that the titanium peroxide solution is mixed with the antimicrobial metal-containing inorganic hydroxide sol and then hydrothermally synthesized to have an antimicrobial metal component. 제 2항에 있어서, 상기 무기산화물은 티타늄(Ti), 알루미늄(Al), 구리(Cu), 아연(Zn) 중 어느 하나를 선택하여 구성된 것을 특징으로 하는 엘이디 형광램프를 이용한 광촉매 살균램프.The photocatalyst sterilizing lamp of claim 2, wherein the inorganic oxide is selected from titanium (Ti), aluminum (Al), copper (Cu), and zinc (Zn). 제 1항 내지 제 3항 중 어느 한 항에 있어서, 상기 건조된 광촉매 유리섬유필터(100)는 중공의 파이프 형태로 가공하되, 빛의 자극에 의해 백색으로 발광하도록 300mesh 이상의 미립자 상태 형광물질을 광촉매 유리섬유필터(100) 10 중량부 : 형광물질 0.5 ~ 2 중량부의 비율로 균일한 분포로 도포하여 구성된 것을 특징으로 하는 엘이디 형광램프를 이용한 광촉매 살균램프.The photocatalyst glass fiber filter 100 of claim 1, wherein the dried photocatalyst glass fiber filter 100 is processed in the form of a hollow pipe, and photocatalytic particles of a particulate state fluorescent substance of 300 mesh or more to emit white light by stimulation of light. Glass fiber filter 100 10 parts by weight: Photocatalyst sterilizing lamp using an LED fluorescent lamp, characterized in that the coating is configured in a uniform distribution in the proportion of 0.5 to 2 parts by weight of the fluorescent material. 제 1항 내지 제 3항 중 어느 한 항에 있어서, 상기 엘이디(LED) 형광램프(200)는 엘이디를 구비하는 엘이디 모듈(210), 상기 엘이디 모듈(210)이 복수로 길이 방향으로 배열되고, 그 양측 단부에 전원연결용 커넥터(220)가 고정되는 회로기판(230)과, 상기 회로기판(230)에 설치되며 교류를 직류로 변환시키기 위한 전류변환기구(240)와, 상기 회로기판(230)이 삽입되고, 내부에 형광물질(250)이 도포되 며, 양측 끝단에 램프소켓(260)이 고정되어 기밀이 유지되는 원통 파이프 모양의 램프 초자관(270)을 포함하여 구성된 것을 특징으로 하는 엘이디 형광램프를 이용한 광촉매 살균램프.According to any one of claims 1 to 3, wherein the LED (LED) fluorescent lamp 200 is an LED module 210 having an LED, the LED module 210 is arranged in a plurality of longitudinal direction, A circuit board 230 having a power supply connector 220 fixed to both ends thereof, a current conversion mechanism 240 installed on the circuit board 230 for converting alternating current into direct current, and the circuit board 230. ) Is inserted, the fluorescent material 250 is applied therein, and the lamp socket 260 is fixed to both ends of the cylindrical pipe-shaped lamp vitreous tube 270 to be kept airtight, characterized in that it comprises a Photocatalyst sterilization lamp using LED fluorescent lamp. 제 4항 또는 제 5항에 있어서, 상기 형광물질(250)은 자외선에 의해 가시광선 영역의 빛을 내는 야그(YAG: Yttrium Aluminum Garnet: Y3A15012)의 란탄 계열 물질로서 La, Ce, Pr, Nd, Sm, Eu, Y, Ho 이온, 원소 중 적어도 하나의 성분으로 이루어지거나 이들이 포함된 염으로 이루지는 것을 특징으로 하는 엘이디 형광램프를 이용한 광촉매 살균램프.According to claim 4 or 5, wherein the fluorescent material 250 is a lanthanum-based material of Yttrium Aluminum Garnet (YAG: Y3A15012) that emits light in the visible region by ultraviolet light, La, Ce, Pr, Nd, Sm, Eu, Y, Ho ions, photocatalyst sterilization lamp using an LED fluorescent lamp, characterized in that consisting of or consisting of at least one component of the element. 제 1항 내지 제 6항 중 어느 한 항에 있어서, 상기 광촉매 유리섬유필터(100)는 내주면에 엘이디(LED) 형광램프(200)와 이격하도록 다수의 이격돌기(110)가 추가로 구비되는 것을 특징으로 하는 엘이디 형광램프를 이용한 광촉매 살균램프.According to any one of claims 1 to 6, The photocatalyst glass fiber filter 100 has a plurality of spaced apart projections 110 are further provided on the inner circumferential surface so as to be spaced apart from the LED fluorescent lamp (200). Photocatalyst sterilizing lamp using LED fluorescent lamp.
KR1020090071628A 2009-08-04 2009-08-04 Photocatalyst sterilization lamp that use led phosphor lamp KR20110013921A (en)

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KR102021420B1 (en) * 2019-02-27 2019-09-16 우태영 Air filter made of glass or aluminum structure using photocatalyst precoat and manufaturing method there of
KR102287973B1 (en) * 2020-09-22 2021-08-09 주식회사 에스엠닥터 Medi lamp
KR102355888B1 (en) 2020-11-17 2022-01-25 한경대학교 산학협력단 Ionizer for air purification with improved photochemical reaction using photocatalyst and uv-c led

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102021420B1 (en) * 2019-02-27 2019-09-16 우태영 Air filter made of glass or aluminum structure using photocatalyst precoat and manufaturing method there of
WO2020175847A1 (en) * 2019-02-27 2020-09-03 우태영 Glass or aluminum structure air filter using photocatalyst precoat and manufacturing method therefor
CN113507973A (en) * 2019-02-27 2021-10-15 禹泰荣 Glass and aluminum structure air filter with photocatalyst pre-coating and manufacturing method thereof
US11766632B2 (en) 2019-02-27 2023-09-26 Tae Young WOO Glass or aluminum structure air filter using photocatalyst precoat and manufacturing method therefor
KR102287973B1 (en) * 2020-09-22 2021-08-09 주식회사 에스엠닥터 Medi lamp
US11291742B1 (en) 2020-09-22 2022-04-05 S.M.Doctor Co., Ltd Air stertilization lamp device
KR102355888B1 (en) 2020-11-17 2022-01-25 한경대학교 산학협력단 Ionizer for air purification with improved photochemical reaction using photocatalyst and uv-c led

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