KR20090057591A - The manufacture method of the none toxic ffungicide used natural material - Google Patents

The manufacture method of the none toxic ffungicide used natural material Download PDF

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Publication number
KR20090057591A
KR20090057591A KR1020070124243A KR20070124243A KR20090057591A KR 20090057591 A KR20090057591 A KR 20090057591A KR 1020070124243 A KR1020070124243 A KR 1020070124243A KR 20070124243 A KR20070124243 A KR 20070124243A KR 20090057591 A KR20090057591 A KR 20090057591A
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South Korea
Prior art keywords
solution
natural
toxic
mixing
nano
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KR1020070124243A
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Korean (ko)
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정정철
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대은엠비코(주)
정정철
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Priority to KR1020070124243A priority Critical patent/KR20090057591A/en
Publication of KR20090057591A publication Critical patent/KR20090057591A/en

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/22Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/02Sulfur; Selenium; Tellurium; Compounds thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/06Coniferophyta [gymnosperms], e.g. cypress
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/26Meliaceae [Chinaberry or Mahogany family], e.g. mahogany, langsat or neem
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/34Rosaceae [Rose family], e.g. strawberry, hawthorn, plum, cherry, peach, apricot or almond
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/36Rutaceae [Rue family], e.g. lime, orange, lemon, corktree or pricklyash
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N2300/00Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48

Abstract

A method for manufacturing non-toxic fungicide using a natural material is provided to suppress the breeding of pathogenic bacteria and strengthen the immunity. A method for manufacturing non-toxic fungicide using a natural material comprises: a step of pulverizing plant seed having sterilization activity; a step of steaming the pulverized plant seed to obtain seed extract; a step of maturing the seed extract in a drum containing a charcoal; a step of isolating supernatant from the matured seed extract to obtain a pasture solution; a step of mixing with nano sulfur solution and nano silicon solution, and adding humic acid and chitosan to produce nutrition immune material; a step of mixing the pasture solution and nutrition immune material and adding vitamin to obtain stabilization mixed solution.

Description

The manufacture method of the none toxic ffungicide used natural material}
The present invention relates to a method for producing a non-toxic bactericide using natural substances, and more particularly, wood vinegar and nano-grained sulfur, silica, To prepare a non-toxic fungicide using natural materials by adding Nim Oil (Neem Oil) to a mixture of selenium, germanium and amino acids, minerals, humic acid and chitosan to synthesize a vitamin solution.
Conventional fungicides are prepared by using copper sulfate, basic chloride, basic sulfate, organic copper, etc. as the main components of the disinfectant. However, basic copper chloride or copper sulfate is a highly toxic substance, which is beneficial to humans as well as to sterilizing pathogenic bacteria in plants. And also, the destruction of amphibians, frogs, snakes, etc., devastating ecosystems and further harming humans. In recent years, eco-friendly farming, which is a method of producing agricultural products from non-toxic and eco-friendly farming methods, has been gradually produced. It is spreading.
      In addition, in some cases, methods of killing pathogenic bacteria using natural agents of pathogenic bacteria and eco-friendly farming methods that kill anthrax by putting antibiotics on makgeolli are widely used in farms. It is possible to kill them, but there is a drawback of failing to increase the immunity of plants necessary to prevent the invasion of pathogenic bacteria or to prevent recurrence after treatment.
On the other hand, eco-friendly disinfectants that use Bordeaux liquor and antibiotics mixed with wood vinegar are sold, but these natural disinfectants also prevent the invasion of pathogens and kill pathogenic bacteria such as anthrax, but they do not increase the immunity of the plant itself. Bordeaux particles in a gel form is attached to the surface of the plant to block the sun to inhibit the photosynthesis action of the plant.
The present invention has been made to solve the conventional problems, without extracting the wood vinegar extracted by steaming plant seeds having a sterilization ability such as apricot, peach, ginkgo, gilyeong, Sancho without using wood vinegar produced when carbonizing wood By virtue of its ability to strongly inhibit the propagation of pathogenic bacteria and use solutions prepared by mixing nanoized sulfur, silica and amino acids, minerals, and humic acids with chitosan, plants absorb these solutions to enhance immunity with growth and development. By preventing the reinvasion of bacteria and killing the pathogenic bacteria currently propagating with the strong sterilizing power of Nim Oil, a method for producing non-toxic fungicides capable of preventing the invasion of pathogenic bacteria in plants, sterilization and suppression of re-occurrence after death. It aims to provide.
In order to solve the problems of the prior art as described above, the method for producing a non-toxic fungicide using natural materials according to the present invention,
A pulverizing step of pulverizing seeds of the plant having sterilization ability; An extraction step of extracting the seed extract by steaming the plant seeds ground in the grinding step with steam; A ripening step of aging the seed extract in a barrel containing charcoal for a predetermined time; A wood vinegar extracting step of taking supernatant from the seed extracts that have undergone the aging step; Making a mixed solution by mixing the nanosulfur solution and the nanosilicon solution, and preparing a nutrient-immune substance by mixing minerals, humic acids and chitosan in the mixed solution to produce a zero-sided immune substance; A stabilizing mixing step of mixing the wood vinegar solution of the wood vinegar extract step and the nutrient-immune substance of the nutrient-immune substance manufacturing step at a predetermined ratio and adding vitamins; The non-toxic fungicide manufacturing step of preparing a non-toxic fungicide by adding a nim oil to the stabilized mixture after the stabilization mixing step;
The nutrient-immune substance is sulfur-amino acid, silicon, amino acid, humic sulfur, humic silicon, in which nano sulfur or nano silicon, which is an inorganic substance, is combined with minerals or humic acid due to the ionization property of (-) electrons derived from chitosan. In general, the bound form of protein is difficult to absorb the inorganic material directly, whereas the plant absorbs the inorganic material and uses it as a growth material to concentrate the separated sulfur or silicon for long-term storage in the plant. Plant nutrients are produced that can increase plant immunity.
The plant seeds preferably contain any one or two or more of apricots, peaches, ginkgo, gilyeong, sancho.
It is preferable that the said plant seed is 25-35: 20-30: 20-30: 10-15: 0.1-10 of the weight ratio of apricot: peach: ginkgo: Gilkyung: Sancho.
The mixed solution is preferably a mixture of 20,000 ~ 30,000ppm concentration nano sulfur solution and nano silicon solution in a weight ratio of 15 to 25: 75 to 85, respectively.
In the step of producing the nutrient-immune substance, minerals, humic acid and chitosan are each added at a ratio of 2 to 5%, 2 to 5%, and 0.5 to 2% by weight of the mixed solution, and preferably mixed for 30 minutes to 1 hour. Do.
In the stabilizing mixing step, the wood vinegar and the nutritional immune substance is preferably 70 to 80%: 20 to 30% by weight.
In the stabilizing mixing step, it is preferable to stir for 30 minutes to 1 hour at 40 ~ 70 ℃ while gradually adding a vitamin corresponding to 0.01 ~ 1% of the total weight of the wood vinegar and the nutritional immune substance.
In the non-toxic bactericide manufacturing step, the nim oil is preferably 2 to 10% of the weight of the stabilized mixture.
In the step of producing the nutrient-immune substance, it is preferable to add any one or two of the nano germanium solution, the nano selenium solution to the mixed solution.
In the step of preparing the nutrient-immune substance, the nano germanium solution is 3 to 5% by weight of the mixed solution at a concentration of 1,000 to 3,000 ppm, and the nano selenium solution is 2 to 3% by weight of the mixed solution at a concentration of 400 to 500 ppm. Is preferably.
Here, "mineral" used in the present invention is a liquid state of a solution (ion), which is typically extracted from lactic acid (lactic acid) from minerals, calcium, potassium, magnesium, iron, zinc, selenium (selenium), manganese, silicon, lithium , Germanium, boron, etc., and the mineral solution used in the present invention is Ca, K, Mg, Fe, Zn, Se, Mn, Si, Li, Ge, B is 52, 300, 300, 500, 600, 20, 150, 20, 200, 20, 100ppm or more. "Vitamin" is dissolved in vitamin C in lactic acid (lactic acid) is used in a concentration of more than 30%. "Neem Oil" is an oil extracted from the seeds of Neem tree (Azadirachta indica A.Juss).
The present invention as described above, the material used in the disinfectant was prepared using only environmentally friendly materials for pest management notified by the Minister of Agriculture and Forestry, and in advance, tar, herbicidal components, heavy metals that are harmful substances included in the preparation of wood vinegar solution After removal, it was used. Sulfur and silicon, which are good for plant immunity and growth, were combined with amino acids using chitosan to be proteinized to improve the absorption growth of plants. When the above substances were mixed, cohesive, separable and unreasonable In order to avoid mixing, vitamins are used as stabilizers to provide a stable substance, and a natural substance nontoxic fungicide is prepared by adding nim oil, a powerful natural fungicide, which prevents the development of pathogenic bacteria in crop production. After the sterilization of Nim Oil, the disease develops the plant's immunity. By preventing the recurrence of the disease, all of the materials used are environmentally friendly materials, so it is greatly effective in producing eco-friendly foods that can be safely eaten.
The present invention will be described in detail through the following examples. However, these examples are for illustrative purposes only and the present invention is not limited thereto.
Example 1
The present invention for achieving the above object,
As a natural substance, seeds of apricot, peach, ginkgo, gilyeong and sancho, which have bactericidal properties, were mixed in a weight ratio of 30: 25: 25: 15: 5 and crushed by a grinder.
The mesh net was placed on the bottom of the pressure cooker, and the milled plant seeds were placed on the upper part of the mesh net, and then steamed for 4 hours with a steam of 120 ° C. under 2 Kg / cm 2 pressure to let the plant seed extract flow out of the bottom of the mesh net.
The extracted seed extract contains a large amount of tar, heavy metals, and herbicide components, so that the charcoal is aged for 4.5 hours in a barrel filled with charcoal to allow the charcoal to absorb tar, heavy metals, and herbicide components. It was.
Meanwhile, nano sulfur and nano silicon having a concentration of 20,000 to 30,000 ppm were mixed at a ratio of 20:80 by weight, respectively, and the mixture was added at a ratio of 3.5% of minerals, 3.5% of humic acid, and 1% of chitosan in the weight ratio of about 30 minutes. Nutrients were prepared by mixing well in the degree mixer.
The herb nutrient mixture was prepared by mixing the above-prepared wood vinegar and plant nutrients in a ratio of 75% to 25% by weight.
At this time, the nutrient mixture made from the wood is mixed with the alkaline component of the herbal component and the acidic component of the humic acid to become a weak alkali component, but since the combination of the two substances is not stable, lumps can be formed or cannot be completely combined, so the two substances are not completely separated. Vitamins (vitamins dissolved in lactic acid (lactic acid)) to be combined to prepare a stabilized mixture by mixing and stirring for about 30 minutes at a temperature of 55 ℃ while slowly adding 0.5% by weight of the herb nutrient mixture.
To this prepared stabilizing mixture was added 5% Nim oil corresponding to the weight ratio of the stabilizing mixture, and then stirred and mixed to prepare a non-toxic bactericide of natural substances.
Example 2
In Example 1, the ground plant seeds were steamed at intervals of 30 minutes up to 3 to 5 hours when steamed.
The final effect was not different.
Example 3
In Examples 1 to 2, 2 to 5% of the minerals mixed, 2 to 5% of the humic acid and 0.5 to 2% of the chitosan were prepared in 0.5% units, respectively. .
In addition, the mixing time in the mixer was varied from 10 minutes to 30 minutes.
The final effect was not different.
Example 4
[Example 1] to [Example 3], when making the herb nutrient mixture, the wood vinegar is changed to 70% to 80% by weight in 2% units, and accordingly the nutrient-immune substance is 30 to 20% by weight (2%). Unit).
The final effect was not different.
Example 5
In Examples 1 to 4, the vitamins to be added were changed to 0.01% and 0.1 to 1% (in 0.1% units) by weight of the herb nutrient mixture when the stabilized mixture was prepared.
The final effect was not different.
Example 6
In Example 1 to Example 5, when preparing a stabilized liquid mixture, the temperature was changed to 40 to 70 ° C. (10 ° C. units), and the stirring time was changed to 30 minutes to 1 hour (10 minute units). I was.
The final effect was not different.
Example 7
In Examples 1 to 6, when preparing a non-toxic bactericide of natural substances, the nim oil added to the stabilized mixed solution was changed to 2 to 10% in 1% units.
The final effect was improved sterilization according to the amount of nim oil.
Example 8
In Example 1 to Example 7, 3%, 4%, and 5% of the nano germanium solution having a concentration of 1,000 to 3,000 ppm was added to the mixed solution of the nanosulfur solution and the nanosilicon solution in the weight ratio of the mixed solution. Independently of the nano germanium solution, 400% to 500ppm nanoselenium solution was added at a weight ratio of 2%, 2.5%, and 3% of the mixed solution.
Non-toxic fungicides of natural substances with the pharmacological effects of germanium and selenium have been produced.

Claims (10)

  1. In the method for producing a fungicide,
    A grinding step of pulverizing the seeds of the plant having sterilization ability;
    An extraction step of extracting the seed extract by steaming the plant seeds ground in the grinding step with steam;
    Aging step of aging the seed extract in a barrel containing charcoal for a predetermined time;
    Wood vinegar extracting step taking the supernatant from the seed extract after the aging step;
    Preparing a nutrient-immune substance by mixing a nano-sulfur solution and a nano-silicon solution to make a mixed solution, and mixing the mixed solution with minerals, humic acid and chitosan to produce a nutrient-immune substance;
    A stabilizing and mixing step of mixing the wood vinegar solution of the wood vinegar extract step and the nutrient-immune substance of the nutrient-immune substance manufacturing step at a predetermined ratio, and adding vitamins;
    Non-toxic fungicide manufacturing step of preparing a non-toxic fungicide by adding a nim oil to the stabilized mixture after the stabilization mixing step; to prepare a non-toxic fungicide using a natural material.
  2. The method of claim 1,
    The plant seeds,
    Method for producing a non-toxic fungicide using a natural substance, comprising any one or two or more of apricot, peach, ginkgo, gilyeong, sancho.
  3. The method of claim 2,
    The plant seeds,
    Apricot: Peach: Ginkgo: Gilkyung: Sancho weight ratio of 25 ~ 35: 20 ~ 30: 20 ~ 30: 10 ~ 15: 0.1 ~ 10 method for producing a non-toxic fungicide using natural substances.
  4. The method of claim 1,
    The mixed liquid,
    Method for producing a non-toxic fungicide using a natural material, characterized in that the nano sulfur solution and nano silicon solution of 20,000 ~ 30,000ppm concentration are mixed in a weight ratio of 15 ~ 25: 75 ~ 85, respectively.
  5. The method of claim 4, wherein
    In the nutritional immune substance manufacturing step,
    Mineral, humic acid, chitosan is added to the ratio of 2 to 5%, 2 to 5%, 0.5 to 2% of the weight ratio of the mixed solution, respectively, and non-toxic fungicide using a natural material, characterized in that mixing for 30 minutes to 1 hour Manufacturing method.
  6. The method of claim 1,
    In the stabilization mixing step,
    The wood vinegar and the nutrient-immune substance is a non-toxic fungicide using natural substances, characterized in that 70 to 80%: 20 to 30% by weight.
  7. The method of claim 6,
    The stabilization mixing step,
    Method for producing a non-toxic fungicide using a natural substance, characterized in that the mixture is stirred for 30 minutes to 1 hour at 40 ~ 70 ℃ while gradually adding a vitamin corresponding to 0.01 ~ 1% of the total weight of the wood vinegar and the nutritional immune substance .
  8. The method according to any one of claims 1 to 7,
    In the non-toxic fungicide manufacturing step,
    The nim oil is a non-toxic bactericide manufacturing method using a natural substance, characterized in that 2 to 10% of the weight of the stabilized mixture.
  9. The method of claim 8,
    In the nutritional immune substance manufacturing step,
    Method for producing a non-toxic bactericide using natural materials, characterized in that any one or two of the nano germanium solution, nano selenium solution is further added to the mixed solution.
  10. The method according to claim 9,
    In the nutritional immune substance manufacturing step,
    The nano germanium solution is 3 to 5% by weight of the mixed solution at a concentration of 1,000 ~ 3,000ppm, the nano selenium solution is a natural material, characterized in that 2 to 3% by weight of the mixed solution at a concentration of 400 ~ 500ppm Non-toxic fungicide manufacturing method using.
KR1020070124243A 2007-12-03 2007-12-03 The manufacture method of the none toxic ffungicide used natural material KR20090057591A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101112783B1 (en) * 2011-05-09 2012-03-13 (주)에이스나노텍 Germicide containing natural ingredients
KR101132712B1 (en) * 2009-09-25 2012-04-06 윤채혁 Environment-friendly organic agricultural products for soil insect pest control
KR101349101B1 (en) * 2012-06-14 2014-01-09 김동찬 Natural germicide composition and methods for manufacturing a natural germicide

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101132712B1 (en) * 2009-09-25 2012-04-06 윤채혁 Environment-friendly organic agricultural products for soil insect pest control
KR101112783B1 (en) * 2011-05-09 2012-03-13 (주)에이스나노텍 Germicide containing natural ingredients
KR101349101B1 (en) * 2012-06-14 2014-01-09 김동찬 Natural germicide composition and methods for manufacturing a natural germicide

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