KR20070027825A - Process for Salted-dried Corbina flavoring with Ginseng Extracts - Google Patents
Process for Salted-dried Corbina flavoring with Ginseng Extracts Download PDFInfo
- Publication number
- KR20070027825A KR20070027825A KR1020050079657A KR20050079657A KR20070027825A KR 20070027825 A KR20070027825 A KR 20070027825A KR 1020050079657 A KR1020050079657 A KR 1020050079657A KR 20050079657 A KR20050079657 A KR 20050079657A KR 20070027825 A KR20070027825 A KR 20070027825A
- Authority
- KR
- South Korea
- Prior art keywords
- ginseng
- oysters
- salt
- dried
- acid
- Prior art date
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Classifications
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L17/00—Food-from-the-sea products; Fish products; Fish meal; Fish-egg substitutes; Preparation or treatment thereof
- A23L17/75—Coating with a layer, stuffing, laminating, binding or compressing of original fish pieces
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L17/00—Food-from-the-sea products; Fish products; Fish meal; Fish-egg substitutes; Preparation or treatment thereof
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2250/00—Food ingredients
- A23V2250/20—Natural extracts
- A23V2250/21—Plant extracts
- A23V2250/2124—Ginseng
Abstract
본 발명은 인삼굴비의 제조방법에 관한 것이다. 보다 상세하게는 조기의 잡균 오염 방지와 비린내를 제거하기 위하여 정제염을 정제수에 용해시킨 소금용액에 인삼을 에탄올로 추출시킨 인삼추출물과 유기산을 혼합시킨 잡균방지제에 조기를 염지하여 1차건조하는 단계와, 굴비의 적정한 수분 유지와 지방산패를 방지하기 위하여 식염수와 보습제로 당알콜을 혼합한 용액에 1차건조된 굴비를 침지시켜 2차건조하는 단계를 포함하는 것을 특징으로 하는 인삼굴비의 제조방법이다. The present invention relates to a method for producing ginseng gullet. More specifically, in order to prevent early microbial contamination and remove fishy smell, the first step is to dry the salt by dissolving the purified salt in purified water and the first drying in the antibacterial agent mixed with the ginseng extract extracted with ethanol and organic acid. In order to prevent proper retention of oysters and fatty acid loss, the method of producing ginseng oyster fertilizer comprises the step of immersing the primary dried oysters in a solution of sugar alcohol with saline and a moisturizing agent.
본 발명의 인삼굴비는 저장유통 중에 잡균오염이 없어 산패나 비린내 및 이취가 없으며, 장기간 보존하여도 수분함량이 일정하여 부드러워 섭식감과 상품성 및 기호성이 우수하다. The ginseng oyster ratio of the present invention has no germ-free contamination without storage of germs, odors and odors during storage distribution, and has a constant moisture content even after long-term storage, so it is excellent in eating feeling, commerciality and palatability.
특히 본 발명은 저염도 소금용액으로 염장후 보존하더라도 수분활성도가 적절히 유지되어 조리시 단백질의 복원을 좋게 하므로 맛 좋은 굴비를 제공할 수 있다. In particular, the present invention, even after preserving after salting with a low salt salt solution, it is possible to provide a delicious oysters because the water activity is properly maintained to restore the protein during cooking.
Description
본 발명은 조기의 잡균 오염 방지와 비린내를 제거하기 위하여 정제염을 정제수에 용해시킨 소금용액에 인삼을 에탄올로 추출시킨 인삼추출물과 유기산을 혼합시킨 잡균방지제에 조기를 염지하여 1차건조하는 단계와, 굴비의 적정한 수분 유지와 지방산패를 방지하기 위하여 식염수와 보습제로 당알콜을 혼합한 용액에 1차건조된 굴비를 침지시켜 2차건조하는 단계를 포함하는 것을 특징으로 하는 인삼굴비의 제조방법이다. The present invention comprises the steps of first drying by soaking early in the antibacterial agent mixed with ginseng extract and ethanol extracted with ginseng in a salt solution dissolved in purified water in order to prevent early bacterial contamination and fishy smell; In order to prevent proper retention of oysters and fatty acid plaque, a method of producing ginseng oyster fertilizer comprising the step of immersing the first dried oysters in a solution of sugar alcohol with saline and a moisturizing agent.
굴비(Corvina)는 생조기를 소금으로 물간 또는 마른간으로 염지하여 말린 것으로 건석어(乾石魚) 또는 머리에 돌이 들어 있다고 해서 석두어(石頭漁)라고도 한다. Corvina is dried salted or dried salted with salted raw fish or dried liver, or dried stone (석 石 魚) or because the head contains stones, it is also known as Sukduer (石頭 漁).
조기에 소금을 염지한 후 해풍에 1∼2주일간 건조(섭간 또는 얼간)시킨 굴비는 1마리(100g기준시)당 수분 50∼53, 단백질 28∼30, 회분 14∼16, 지방 5∼8, 총당 0.3∼0.5, 염분 14∼16 %와, 불포화지방산 360∼380mg/g, EPA 25∼27mg/g, 포화지방산 170∼190mg/g를 함유하고 있는 영양이 풍부하고 맛있는 수산자원이다. 근래에는 원양어업으로 조기를 잡기 때문에 생조기와 같은 저염분과 고수분의 상태로 염지하는 경우는 많지 않고, 어획 즉시 냉동시켰다가 창고에 반입하여 해동시키면서 염지하는 경우가 많은 데, 염지기간은 어체의 크기에 따라 1주일 이내 또는 그 이상 염지하는 경우도 있다. 물간의 경우에는 포화식염수로 염지하고, 마른간을 할 경우에는 식염을 뿌려 용기에 담아 염장한 후 10마리 또는 20마리씩 엮는다. 염장을 끝낸 굴비는 소금의 삼투현상으로 굴비의 수분이 drip되면서 지나치게 건조가 일어나 중량이 감소하고 굴비의 조직이 딱딱해지는 것을 막기 위하여 냉장고에 저장하였다가, 출고시 하루 이틀 정도 해풍의 음지에서 건조하는 경우가 많고 굴비가공 공장에서는 열풍으로 건조시키는 경우도 있다. 굴비는 저장 및 건조과정에서 공기에 노출될 수 있으므로 유해미생물이나 해충의 번식으로 부패를 촉진시킬 우려도 있다. The salted oysters dried for 1 or 2 weeks (seasoned or boiled) in the sea breeze after salting at an early age are 50 to 53 minutes of water, 28 to 30 proteins, 14 to 16 ashes, 5 to 8 fats, It is a nutritious and delicious fishery resource containing 0.3 to 0.5 in total sugar, 14 to 16% of salt, 360 to 380 mg / g of unsaturated fatty acid, 25 to 27 mg / g of EPA, and 170 to 190 mg / g of saturated fatty acid. In recent years, early fishing is used to catch fish, so it is not common to soak it in low salt and high moisture conditions such as raw fish, and it is often frozen after catching it and brought into the warehouse to thaw. Depending on the size, it may be dyed within a week or more. In the case of water, salted with saturated saline, and in case of dry liver, sprinkle salt and put it in a container and salt it. The salted oyster is an osmotic phenomenon of salt, which drips the moisture of the oyster, which is too dry to reduce the weight and hardens the structure of the oyster. In many cases, the oyster processing plant may be dried by hot air. Oysters may be exposed to air during storage and drying, which may promote decay by breeding harmful microorganisms or pests.
굴비를 포함한 바다 생선은 선도가 좋을 때는 휘발성성분이 적으나, 선도 저하에 따라 휘발성염기(암모니아, Trimethylamine, Dimethylamine 등)의 아민류가 생성되고, 여기에 Piperidine, Acetaldehyde 등이 섞여서 비린내를 내게 된다. 그 밖에 휘발성산(초산, 부틸산, 불포화지방산 등)의 산화에 따라 생성되는 휘발성카보닐화합물, 알콜류, 탄화수소 등이 관여하여 어취를 형성하게 된다. 심하게 선도가 저하되면 부패취를 내는 데, 휘발성알데히드(프로판올, 부탄올, 펜타날, 헥사날 등)와 휘발성황화합물(유화수소, Methanethiol, Dimethyl sulfide 등)에서 나는 냄새이다.Sea fish, including oysters, have less volatile components when freshness is good, but amines of volatile bases (ammonia, trimethylamine, dimethylamine, etc.) are produced as freshness decreases, and piperidine, acetaldehyde, etc. are mixed to give fishy smell. In addition, volatile carbonyl compounds, alcohols, hydrocarbons, etc., produced by the oxidation of volatile acids (acetic acid, butyric acid, unsaturated fatty acids, etc.) are involved to form odor. If the freshness is severely deteriorated, it produces a odor, odor from volatile aldehydes (propanol, butanol, pentanal, hexanal, etc.) and volatile sulfur compounds (hydrogen sulfide, Methanethiol, dimethyl sulfide, etc.).
일반적으로 생선을 소금의 포화용액(25%이하)으로 염지하게 되면 미생물의 억제에는 효과가 있지만, 과도한 삼투압에 의하여 수분활성 Aw (water activity)이 1.0에서 0.85 이하로 떨어지게 되고, 식염이온의 길항작용 또는 2가 이온이 생선 단백질 분자간의 교차결합을 형성하여 단백질 구조가 강고하게 되어 보수성이 감소하게 된다. 더구나 염장후 굴비를 장기간 보존하게 되면 과도한 건조가 일어나 수분활성도가 Aw 0.2∼0.6로 되어 조리시 수분을 공급하여 복원시켜도 조직의 변화와 단백질의 변성 및 짠맛이 강하여 상품성을 떨어 뜨리게 된다. 따라서 조리시 굴비의 맛을 좋게하고 단백질의 복원을 좋게 하기 위해서는 수분함량 20∼50%(Aw 0.65∼0.85)으로 유지하는 것이 좋으나, 굴비는 비교적 장기간 저장하면서 조리에 쓰는 염장품으로서 미생물이 쉽게 발육하고 저장중에 지방의 산패로 인하여 비린내와 이취가 생성되므로 저농도의 소금으로 염지하면서 잡균의 오염을 억제시켜 저장성을 높일 수 있는 방안이 절실히 요구되고 있다. In general, salting fish with a saturated solution of salt (less than 25%) is effective in inhibiting microorganisms. However, excessive osmotic pressure causes water activity Aw (water activity) to drop from 1.0 to 0.85 or less. Alternatively, divalent ions form cross-links between fish protein molecules, resulting in a strong protein structure resulting in reduced water retention. In addition, if the salt is preserved for a long time after salting, excessive drying occurs and the water activity becomes Aw 0.2-0.6, so that even if it is restored by supplying moisture during cooking, the change of tissues and protein denaturation and salty taste are strong, thereby degrading the commerciality. Therefore, in order to improve the taste of oysters and restore protein during cooking, it is recommended to keep the water content at 20-50% (Aw 0.65 to 0.85). However, oysters are a salt product used for cooking while being stored for a relatively long time, and microorganisms are easily developed. During storage, fishes and odors are generated due to rancidity of fats. Therefore, there is an urgent need for a method of improving storage properties by suppressing contamination of various bacteria while salting with low concentration of salt.
인삼(人蔘 ginseng/Panax schinseng)은 미나리목 오가피나무과(두릅나무과)에 속하는 음지성 여러해살이풀 또는 뿌리이다. 인삼은 원래 온대 지역 산악 지대의 삼림에서 자생하는 음지식물인데, 약용식물로 수요가 증가하여 재배하게 되었다. 인삼은 주로 북위 33도∼48도의 지역(한국)에 자생 분포하며 약효가 가장 높아 이 지역에서 인삼의 재배 및 제조기술이 발달되었다. Ginseng (人蔘 ginseng / Panax schinseng) is a perennial perennial herb or root belonging to the genus Asteraceae. Ginseng is a wild plant that grows naturally in forests in temperate mountain areas. It is a medicinal plant that is grown in demand. Ginseng is natively distributed in the region of 33 degrees to 48 degrees north latitude (Korea) and has the highest medicinal effect.
인삼에는 사포닌(saponin; ginsenoside)이 약 5% 함유되어 있으며, 인삼사포닌은 13종 이상의 사포닌 혼합물로서 진세노사이드의 함량이 높고, 사포닌이 함유된 게닌은 프로파낙사트리올, 프로파낙사디올, 올레아놀산의 3종이 있다. 인삼의 향기의 근원은 β-elemen이 있고 고비점부에는 불안정한 액체이며 공기중에서 용이하게 수지화하는 파낙시놀이 함유되어 있다. 뿌리에 함유된 파낙산은 팔미틴산, 스테아린산, 올레인산, 리놀산 등의 혼합물인데 지질의 가수분해에 의하여 생성된 것이며, 또한 코린도 함유되어 있는 데 혈압강하 성분으로 알려져 있다. 그 밖에도 아미노산과 펩타이드, 비타민, 1당류, 2당류 등이 함유되어 있다. Ginseng contains about 5% of saponin (ginsenoside), and ginseng saponin is a mixture of 13 or more types of saponins with high content of ginsenosides, and saponin-containing genin contains propanaxtriol, propanaxadiol, There are three species of oleanolic acid. The origin of the fragrance of ginseng is β-elemen, the unstable liquid in the high boiling point, and contains panaxinol which is easily resinized in the air. Panaxonic acid contained in the root is a mixture of palmitic acid, stearic acid, oleic acid, linoleic acid, etc., which is produced by hydrolysis of lipids, and also contains corin, which is known as a blood pressure lowering component. In addition, it contains amino acids, peptides, vitamins, monosaccharides and disaccharides.
인삼의 약효는 중국에서 가장 오래된 본초학서(本草學書)인 《신농본초경》에서는 365종의 약물중에서 인삼이 상품약으로 기록되어 있고, 인삼은 오장을 보호하고 정신을 안정시키며, 눈을 밝게 한다. 또, 오래 복용하면 몸이 가벼워지고 오래 살 수 있다는 등의 약효가 명시되어 있는데, 이는 과학적으로 밝혀진 인삼의 효능과 잘 부합한다. 한국에서는 1884년(고종 21) 황도연(黃道淵) 찬(撰), 황필수(黃泌秀) 편(編)으로 된 《방약합편》이, 오늘날에도 흔히 사용되고 있는 한방 처방서인데, 여기서는 467방의 처방이 보제(補劑)인 상통처방(上統處方), 화제(和劑)인 중통처방, 공제(功劑)인 하통처방의 삼통분류(三統分類)로 나누어져 있다. 이 의서에서 인삼은 132종의 처방에 배합되어 있고, 이들 처방의 약 94%가 상통, 중통의 처방에 포함되어 있다. 이상과 같은 사실에서 인삼은 주로 보약 또는 강장제로 사용되었다. 일반적으로 인삼의 약효는 강장, 강심, 건위, 보정, 진정, 자양(滋養) 등의 약으로 널리 사용되고, 위장 등의 기능 쇠약에 의한 물질대사 기능의 저하에 부활제(賦活劑)로 사용되며, 병약자의 위부정체감(胃部停滯感), 소화불량, 구토, 흉통, 이완성설사, 식욕부진 등에도 응용된다. 인삼의 기본적인 약리작용을 적응소(adaptogen) 효과로 생물체가 가지고 있는 비특이적(非特異的)인 저항력을 증대시킴으로써 병적 이상 상태를 정상화시키는 작용이 인삼의 기본적이고 대표적인 약리작용이다.Ginseng's medicinal effect is recorded as a commodity medicine among the 365 kinds of drugs in the New Agricultural Herbal Medicine, the oldest herbology book in China, and ginseng protects the five intestines, stabilizes the mind and brightens the eyes. . In addition, the long-term taking lightens the body, such as long-lived, such as the effect is clearly stated, which is well matched with the efficacy of scientifically proven ginseng. In Korea, `` Medicinal Medicines '' consisting of Hwang Do-yeon and Hwang Pil-su, in 1884 (Gojong 21), is a herbal prescription that is still used today. It is divided into three types of complementary prescriptions, upper topical prescriptions, and subtractive prescriptions. In this document, ginseng is formulated in 132 kinds of prescriptions, and about 94% of these prescriptions are included in prescriptions for upper and middle pain. In the above fact, ginseng was mainly used as a medicine or tonic. In general, the effects of ginseng are widely used as medicines such as tonic, stiffness, health, correction, soothing, and nourishment, and are used as an activator to reduce metabolic function caused by a weakness of the stomach. It is also applied to the feeling of gastric identity of the sick, indigestion, vomiting, chest pain, laxative diarrhea, and loss of appetite. The basic and representative pharmacological action of ginseng is to normalize pathological abnormality by increasing the non-specific resistance of living organisms by adapting the basic pharmacological action of ginseng.
최근 세계 각국의 연구 결과에 의하면 인삼의 뿌리에는 약효 유효 성분으로 사포닌글리코시드(사포닌배당체)인 긴세노사이드류, 스테로이드, 비타민B군, 콜린 등이 함유되어 있다는 것이 확인되었다. 또 인삼의 함유에탄올엑스(알코올 추출물)ㅇ달임약 등은 부신피질호르몬의 하나인 당질코르티코이드(glucocorticoid)의 분비를 촉진하고, 대뇌피질을 자극하여 콜린의 작동성을 강화할 뿐만 아니라, 혈압 강하, 호흡 촉진, 인슐린 작용 증강, 적혈구, 헤모글로빈 증가 등의 약효를 나타낸다. 긴세노사이드류는 항피로작용(抗疲勞作用), 작업능력 촉진작용, 성선(性腺)의 발육 촉진작용, 혈당값 강하작용, DNA합성 촉진작용 등의 약효를 나타내며, 인삼의 약효 성분은 약리적 작용을 바탕으로 하여 항산화작용 및 항암작용이 있는 것으로 밝혀지고 있다. Recent studies from around the world confirmed that the root of ginseng contains saponin glycosides (saponin glycosides), ginsenosides, steroids, B vitamins, and choline. Ginseng-containing ethanol extracts (alcohol extracts) and decoctions promote the secretion of glucocorticoids, one of the adrenal cortex hormones, and stimulate the cerebral cortex to enhance choline's operability, lowering blood pressure and promoting breathing. , Potentiates insulin action, erythrocytes, hemoglobin, etc. Ginsenosides exhibit anti-fatigue, work-promoting, sex gland development, hypoglycemic activity, DNA synthesis, and other pharmacological effects. Based on this, it has been found to have antioxidant activity and anticancer activity.
유기산은 천연에 존재하는 카르복신산으로서 초산, 구연산, 주석산, 안식향산 등이 있으며 수용액 상태에서 산성을 띄게 되어 청량음료, 산미료, 보존료 등으로 많이 쓰이고 있다. 식용이 가능한 주정은 주로 에탄올로서 살균제, 소독제 등으로 많이 쓰이고 있다. Organic acids are carboxylic acids that exist in nature and include acetic acid, citric acid, tartaric acid, and benzoic acid. They are acidic in aqueous solution and are used as soft drinks, acidulants, and preservatives. Edible alcohol is mainly ethanol and is used as a disinfectant and disinfectant.
한편 본 발명과 관련된 종래기술은 한국특허공개 2002-54308(인삼굴비 및 그의 제조방법)은 인삼으로 수삼, 미삼, 백삼 또는 홍삼을 갈거나 또는 물로 추출한 엑기스를 물에 첨가하여 인삼액을 제조한 후, 조기를 일정시간 침적하여 인삼액을 조기살내로 침투시킨 후 꺼내어 건조시켜 인삼굴비를 제조하는 방법이고, 한국특허공개 10-2004-60271(인삼굴비의 가공방법 및 인삼굴비)는 녹차잎으로부터 추출한 폴리페놀액과 인삼으로부터 추출한 인삼엑기스를 혼합하여 조기에 침지시키는 방법이다. 한국특허공개 10-2003-3681(천연재료를 함유한 굴비의 가공방법)은 녹차, 뽕잎, 솔잎, 은행잎, 인삼, 홍삼, 홍차, 감초, 구기자, 오갈피, 당귀, 황기, 영지버섯, 산삼, 장뇌삼, 동충하초 중에서 선택된 추출물 또는 분말을 함유하며, 선택적으로 맥반석 또는 게르마늄석을 적용하여 가공굴비를 제조하는 방법이다. 한국특허공개10-2004-77108(고추장굴비의 제조방법)은 한약재추출물액과 인삼분말을 적정한 비율로 조절하여 굴비를 발효시켜 염도를 낮추고 비린내를 저감시키는 방법에 관한 것이다. 한국특허공개 10-2002-54309(고추장 및 인삼소스로 염장한 굴비 무침)은 굴비살을 잘게 찢어서 고추장 및 인삼소스로 버무리거나, 조미료를 버무려 염장한 굴비무침에 관한 것이다. 그러나 이들 종래기술은 본 발명과는 기술적 구성이 다른 것이다.Meanwhile, the related art related to the present invention is Korean Patent Laid-Open Publication No. 2002-54308 (Ginseng Oyster Ratio and its manufacturing method) after ginseng, rice ginseng, white ginseng, or red ginseng is ground with ginseng or extracted with water to prepare ginseng solution. , By depositing early for a certain time to penetrate the ginseng solution into the premature flesh, take it out and dry it to manufacture ginseng gulbi, Korean Patent Publication No. 10-2004-60271 (processing method and ginseng gulbi) extracted from green tea leaves It is a method of prematurely immersing a mixture of polyphenol solution and ginseng extract extracted from ginseng. Korean Patent Publication No. 10-2003-3681 (Method of processing oysters containing natural ingredients) is green tea, mulberry leaf, pine needle, ginkgo leaf, ginseng, red ginseng, black tea, licorice, wolfberry, ogalpi, tangui, hwanggi, ganoderma lucidum, wild ginseng, camphor ginseng It contains a extract or powder selected from Cordyceps sinensis, and optionally by applying elvan or germanium stone is a method for producing a processed gulbi ratio. Korean Patent Laid-Open Publication No. 10-2004-77108 (Method of manufacturing red pepper oyster ratio) relates to a method of reducing the salinity and reducing fishy by fermenting oysters by adjusting the herbal extract extract and ginseng powder at an appropriate ratio. Korean Patent Laid-Open No. 10-2002-54309 (toasted with oysters seasoned with red pepper paste and ginseng sauce) relates to oysters seasoned with red pepper paste and tossed with red pepper paste and ginseng sauce, or seasoned with seasonings. However, these prior arts have a technical configuration different from the present invention.
본 발명은 소금용액에 인삼을 에탄올로 추출시킨 인삼추출물과 유기산을 혼합시킨 잡균방지제에 조기를 염지하여 1차건조하고, 식염수와 보습제로 당알콜을 혼합한 용액에 1차건조된 굴비를 침지시켜 2차건조하여 인삼굴비를 제조한다. The present invention is firstly dried by soaking the ginseng extract and organic acid mixed ginseng extract with ethanol in a salt solution and dried first, and immersed in the first dried oysters in a solution of sugar alcohol with saline and moisturizer 2 Dry ginseng to prepare ginseng gulbi.
본 발명의 굴비는 저농도 소금용액을 사용하여도 조기의 잡균오염 및 지방산패 방지, 비린내 제거, 굴비의 적정한 수분활성도를 유지시켜 조리시 단백질의 복원이 좋고 짠맛이 적당한 맛 좋은 인삼굴비를 제공하는 데 있다. The oyster fertilizer of the present invention provides a delicious ginseng oyster fertilizer with good recovery of protein and good salty taste during cooking by preventing early bacterial contamination and removing fatty acid plaque, removing fishy smell, and maintaining proper water activity of oyster fertilizer even when using low concentration salt solution. have.
본 발명은 소금용액에 인삼을 에탄올로 추출시킨 인삼추출물과 유기산을 혼합시킨 잡균방지제에 조기를 염지하여 1차건조하는 단계와, 식염수와 보습제로 당알콜을 혼합한 용액에 1차건조된 굴비를 침지시켜 2차건조하는 단계로 인삼굴비를 제조한다. The present invention is the first drying step by soaking early in the antibacterial agent mixed with ginseng extract and organic acid extracted ginseng in ethanol in salt solution, and immersed primary dried oyster in the solution of sugar alcohol with saline and moisturizer Ginseng oyster ratio in the second drying step.
상기 본 발명에서 바람직하게는 상기 잡균방지제는 8∼15%의 식염수용액에 대하여 인삼추출물과 유기산이 각각 3∼5중량% 첨가된다.In the present invention, preferably, the antibacterial agent is added to the ginseng extract and the organic acid 3 to 5% by weight relative to 8 to 15% saline solution.
상기 본 발명에서 바람직하게는 상기 8∼15%의 식염수에 보습제로 당알콜이 1∼3중량% 포함된다.In the present invention, preferably 1 to 3% by weight of sugar alcohol is contained in the 8 to 15% saline as a moisturizing agent.
상기 본 발명에서 바람직하게는 상기 당알콜은 솔비톨, 말티톨, 만니톨, 글리시톨, 에리스리톨, 리비톨, 자일리톨, 갈락티톨 또는 환원물엿 중에서 선택된 어느 하나 이상이 포함된다.In the present invention, the sugar alcohol preferably includes any one or more selected from sorbitol, maltitol, mannitol, glycitol, erythritol, ribitol, xylitol, galactitol or reduced syrup.
상기 본 발명에서 바람직하게는 상기 유기산은 초산, 구연산, 주석산, 사과산, 호박산 또는 안식향산 중에서 어느 하나 이상이 선택된다.In the present invention, the organic acid is preferably any one or more selected from acetic acid, citric acid, tartaric acid, malic acid, succinic acid or benzoic acid.
상기 본 발명에서 바람직하게는 상기 건조된 굴비의 염농도는 4∼10%이고, 수분활성도(Aw)는 0.65∼0.85로 한다.In the present invention, preferably, the salt concentration of the dried oysters is 4 to 10%, and the water activity (Aw) is 0.65 to 0.85.
상기 본 발명에서 바람직하게는 상기 굴비의 염지 및 침지는 20∼35℃에서 1∼5일간 처리한 후 건조하는 것으로 한다.In the present invention, preferably, the salting and dipping of the oysters is dried after treatment at 20 to 35 ° C. for 1 to 5 days.
상기 본 발명에서 상기 인삼추출물은 인삼, 수삼, 미삼, 백삼 또는 홍삼 중에서 선택된 어느 하나 이상을 에탄올 또는 열수로 추출하고 여과한 것을 사용할 수 있다.In the present invention, the ginseng extract may be any one or more selected from ginseng, ginseng, misam, white ginseng or red ginseng extracted with ethanol or hot water and filtered.
한편 본 발명은 식염수 및 당알콜이 혼합된 혼합물에 알로에 분말 0.5∼3중량%을 선택적으로 더 첨가하여 본 발명의 목적에 부합하는 인삼굴비를 얻을 수 있다.Meanwhile, the present invention can selectively add 0.5 to 3% by weight of aloe powder to the mixture of saline and sugar alcohol to obtain a ginseng oyster ratio that satisfies the purpose of the present invention.
이하, 본 발명의 내용을 단계별로 보다 상세하게 설명하면 다음과 같다. Hereinafter, the content of the present invention in more detail step by step as follows.
* 잡균방지제 처리 및 1차건조* Antibacterial agent treatment and primary drying
조기를 염지함에 있어서 소금 농도가 높으면 강한 삼투현상으로 인하여 단백질 구조의 변화를 일으켜 조직이 강고하게 되고 보수성이 감소하게 되어 짠맛이 강하므로 종래 보다 소금 농도를 낮추고 자, 정제수에 소금을 용해시켜 8∼15% 식염수를 제조한다. In the early salting, if the salt concentration is high, the protein structure changes due to the strong osmotic phenomena, which makes the structure stronger and the water retention decreases, and the salty taste is stronger. Thus, to lower the salt concentration than before, dissolve the salt in purified water. Prepare 15% saline.
인삼추출물은 잘게 분쇄한 인삼, 수삼, 미삼, 백삼 또는 홍삼을 갈거나 또는 미세하게 분쇄한 후, 에탄올에 넣고 30∼50℃에서 5∼10시간 동안 추출하여 인삼추출물을 얻는다. 또한 상기의 인삼을 오토클레이브에서 찐후 열수추출하여 인삼추출물을 제조할 수도 있다. Ginseng extract is ground or finely ground ginseng, ginseng, rice ginseng, white ginseng or red ginseng, finely pulverized, put into ethanol and extracted for 5 to 10 hours at 30-50 ℃ to obtain a ginseng extract. In addition, the ginseng may be prepared by steaming hot ginseng extract in an autoclave.
상기의 식염수에 인삼추출물과 유기산이 혼합된 잡균방지제를 제조한 후, 조기를 20∼35℃에서 1∼5일간 침지시켜 조리시 먹기에 적합한 굴비의 염농도를 4∼10%(건물기준)로 하기 위하여 통풍이 잘 되는 곳에 방치하거나 열풍으로 쪼여서 수분과 불순물을 drip시키며 건조한다.After preparing the antibacterial agent in which the ginseng extract and the organic acid are mixed in the saline solution, the salt concentration of oysters suitable for eating at the time of cooking is immersed at 20 to 35 ° C. for 1 to 5 days to be 4 to 10% (building basis). In order to do this, leave it in a well-ventilated place or dry it with hot air to drip moisture and impurities.
* 보습제의 처리 및 2차건조* Moisturizer Treatment and Secondary Drying
굴비의 저장 유통 중에 일어날 수 있는 비린내와 지방산패를 억제시키고 굴비의 과도한 건조를 막기 위하여 식염수에 보습제로 당알콜 중에서 1∼3중량%의 솔비톨, 말티톨 또는 환원물엿을 혼합한다.To prevent fishy and fatty acid plaques that may occur during the storage distribution of oysters and to prevent excessive drying of oysters, 1 to 3% by weight of sorbitol, maltitol or reduced starch syrup is mixed with saline as a moisturizing agent.
식염수에 보습제가 혼합된 용액에 1차건조된 굴비를 20∼35℃에서 1∼5일 정도 침지시키고 건져낸 굴비를 통풍이 잘 되는 음지에서 2∼3일 동안 또는 열풍으로 건조시켜 수분과 불순물을 drip시킨다. 적당한 수분함량이 되면 굴비를 크기별로 고른 후 10마리 또는 20마리씩 줄에 엮어서 냉장고에 저장한다. The first dried oysters were immersed in a solution mixed with saline solution for 1-5 days at 20-35 ℃, and the dried oysters were dried for 2 ~ 3 days or in hot air with hot air to drip moisture and impurities. Let's do it. When the water content is adequate, the oysters are picked by size and woven in 10 or 20 rows in a fridge.
이하 본 발명을 다음의 실시예, 비교예 및 시험예에 의해 보다 상세히 설명하고자 한다. 그러나 이들은 본 발명의 일예로서 이들에 의해 본 발명의 권리범위가 한정되는 것은 아니다.Hereinafter, the present invention will be described in more detail by the following examples, comparative examples and test examples. However, these are only examples of the present invention, and the scope of the present invention is not limited thereto.
<실시예 1><Example 1>
정제수에 소금을 용해시킨 8% 식염수에 인삼추출물과 구연산을 각각 5중량%을 혼합하여 얻은 잡균방지제에 조기를 침지시킨 후, 1차 건조하였다.Early immersion was carried out in an antibacterial agent obtained by mixing 5% by weight of ginseng extract and citric acid in 8% saline solution in which salt was dissolved in purified water, followed by primary drying.
상기의 식염수에 보습제로 솔비톨 3중량%를 혼합한 용액에 1차건조된 굴비를 침지시키고 건져낸 굴비를 통풍이 잘 되는 음지에서 굴비의 조리시 먹기에 적합한 염농도(4∼10%)와 수분활성도(Aw 0.65∼0.85)로 건조시킨 후, 굴비를 크기별로 골라 10마리씩 줄에 엮어서 냉장고에 저장하였다. Salt concentration (4-10%) suitable for eating oysters when cooking oysters in a well-ventilated shade by dipping primary dried oysters in a solution in which sorbitol 3% by weight as a moisturizer was added to the saline solution. Aw 0.65 to 0.85), and then oysters were selected by size and woven in rows of 10 animals and stored in a refrigerator.
<실시예 2><Example 2>
10%의 소금용액에 인삼추출물과 구연산을 각각 4% 첨가하고, 식염수에 솔비톨 2중량%를 첨가하는 것을 제외하고는 실시예 1과 동일하게 굴비를 제조하였다. 4% of ginseng extract and citric acid were added to the 10% salt solution, and oyster was prepared in the same manner as in Example 1 except that 2% by weight of sorbitol was added to the saline solution.
<실시예 3><Example 3>
12%의 소금용액에 인삼추출물과 구연산을 각각 3% 첨가하고, 식염수에 솔비톨 1중량%를 첨가하는 것을 제외하고는 실시예 1과 동일하게 굴비를 제조하였다. The oyster was prepared in the same manner as in Example 1 except that 3% of ginseng extract and citric acid were added to the 12% salt solution, and 1% by weight of sorbitol was added to the saline solution.
<실시예 4><Example 4>
15%의 소금용액에 인삼추출물과 구연산을 각각 3% 첨가하고, 식염수에 솔비톨 1중량%를 첨가하는 것을 제외하고는 실시예 1과 동일하게 굴비를 제조하였다. 3% of ginseng extract and citric acid were added to the 15% salt solution, and oyster was prepared in the same manner as in Example 1 except that 1% by weight of sorbitol was added to the saline solution.
<실시예 5><Example 5>
보습제로 말티톨을 사용한 것을 제외하고는 실시예 1과 동일하게 굴비를 제조하였다. Gulbi was prepared in the same manner as in Example 1 except that maltitol was used as a moisturizer.
<실시예 6><Example 6>
보습제로 환원물엿을 사용한 것을 제외하고는 실시예 1과 동일하게 굴비를 제조하였다. Oyster was prepared in the same manner as in Example 1 except that the reduced syrup was used as a moisturizer.
<비교예>Comparative Example
조기를 포화식염수에 3일간 염지하여 건져낸 후, 음지에서 3일간 건조하여 냉장고에 저장하였다. Dried early soaked in saturated saline for 3 days, dried for 3 days in the shade and stored in the refrigerator.
<시험예 1> ; 총균수의 측정<Test Example 1>; Measurement of total bacteria
실시예 1 내지 6과 같이 제조된 굴비에 대하여 대조군(비교예)의 굴비와 총균수를 다음과 같이 비교하였다. 총균수는 검체 25g에 225mL의 펩톤수를 가한 후 균질기로 균질화한 것을 검액으로 사용하였다. 검액의 1mL로 희석한 후 각 단계별로 1mL를 멸균된 페트리디시 3매에 무균적으로 분주하고 약 45∼48℃로 유지한 PCA(plate count agar) 약 15∼17mL를 무균적으로 가하여 검액과 혼합 하였다. 고형화 후 배지를 37℃에서 24시간동안 배양하고 평판당 30∼300개의 집락을 생성한 평판을 선택하여 집락수를 계수 시료 g 당 cfu를 구하였다. 총균수를 측정한 결과를 다음의 표 1로부터 알 수 있듯이 저농도 소금용액에 잡균방지제로 유기산과 에탄올을 첨가함으로써 우수한 염지효과를 나타냈다.The oyster ratio and total bacterial count of the control group (comparative example) were compared with the oyster ratio prepared as in Examples 1 to 6 as follows. The total bacterial count was added to 225 mL of peptone water to 25 g of the sample and homogenized with a homogenizer. After dilution with 1 mL of the sample solution, 1 mL of each sample was aseptically dispensed into 3 sterile Petri dishes and aseptically added about 15-17 mL of PCA (plate count agar) maintained at about 45-48 ° C. It was. After solidification, the medium was incubated at 37 ° C. for 24 hours, and a plate was selected that produced 30 to 300 colonies per plate, and the number of colonies was determined to obtain cfu per g of counting samples. As a result of measuring the total number of bacteria, as shown in Table 1 below, an excellent dyeing effect was obtained by adding organic acid and ethanol as a antibacterial agent to a low concentration salt solution.
표 1. 총균수Table 1. Total bacteria
<시험예 2><Test Example 2>
관능검사는 훈련된 20명의 관능검사 요원을 대상으로 그릴에서 구운 굴비의 염도, 씹힘성, 비린내, 맛, 기호도를 조사하였다. 5점 척도법으로 점수를 기록하였으며 본 실험에서 실시된 관능검사의 측정 결과는 모두 SAS(Statistical Analysis System)프로그램으로 이용하여 분산 분석으로 분석하였다. 그 결과를 다음의 표 2에서 알 수 있듯이 염도(적당한 짠맛의 정도), 씹힘성, 비린내유무, 맛, 기호도 등 여러 가지 면에서 본 발명이 우수함을 알 수 있다.The sensory test was conducted to examine the salinity, chewiness, fishy taste, taste and palatability of grilled oysters. The score was recorded by the 5-point scale, and all the sensory test results were analyzed by analysis of variance using SAS (Statistical Analysis System) program. As can be seen in the following Table 2, it can be seen that the present invention is excellent in various aspects such as salinity (adequate saltiness), chewability, fishy presence, taste, and preference.
표 2. 관능검사 결과 Table 2. Sensory Test Results
본 발명의 인삼굴비는 저농도 염분으로 염지하더라도 저장유통 중에 산패나 비린내가 없으며, 건조시켜 장기간 보존시에도 수분함량이 일정하여 딱딱하지 않아 섭식감이 좋으며, 잡균오염이 적기 때문에 상품성이 좋고 기호성과 보존성이 우수한 인삼굴비를 제공한다.The ginseng oyster ratio of the present invention does not have rancidity or fishy smell during storage distribution even though it is salted with low concentration of salt, and it has good water content even when it is dried for a long time, so it is not stiff and good for eating. This provides excellent ginseng oyster ratio.
도 1은 본 발명의 제조공정도를 나타낸다.1 shows a manufacturing process diagram of the present invention.
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