KR200362663Y1 - Solar Film with Photo-Catalyst Layer - Google Patents
Solar Film with Photo-Catalyst Layer Download PDFInfo
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- KR200362663Y1 KR200362663Y1 KR20-2004-0017333U KR20040017333U KR200362663Y1 KR 200362663 Y1 KR200362663 Y1 KR 200362663Y1 KR 20040017333 U KR20040017333 U KR 20040017333U KR 200362663 Y1 KR200362663 Y1 KR 200362663Y1
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- Prior art keywords
- layer
- photocatalyst
- film
- silica
- polyester
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- 239000011941 photocatalyst Substances 0.000 title claims abstract description 41
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000010410 layer Substances 0.000 claims abstract description 43
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 23
- 229920000728 polyester Polymers 0.000 claims abstract description 20
- 239000011247 coating layer Substances 0.000 claims abstract description 17
- 239000012790 adhesive layer Substances 0.000 claims abstract description 5
- 230000004888 barrier function Effects 0.000 claims abstract description 3
- 230000000149 penetrating effect Effects 0.000 claims 1
- 239000010408 film Substances 0.000 abstract description 53
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 17
- 229910052710 silicon Inorganic materials 0.000 abstract description 17
- 239000010703 silicon Substances 0.000 abstract description 17
- 239000012788 optical film Substances 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 239000011521 glass Substances 0.000 description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 230000001699 photocatalysis Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 230000000903 blocking effect Effects 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- 239000000088 plastic resin Substances 0.000 description 4
- 239000004447 silicone coating Substances 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 230000000391 smoking effect Effects 0.000 description 2
- FWLHAQYOFMQTHQ-UHFFFAOYSA-N 2-N-[8-[[8-(4-aminoanilino)-10-phenylphenazin-10-ium-2-yl]amino]-10-phenylphenazin-10-ium-2-yl]-8-N,10-diphenylphenazin-10-ium-2,8-diamine hydroxy-oxido-dioxochromium Chemical compound O[Cr]([O-])(=O)=O.O[Cr]([O-])(=O)=O.O[Cr]([O-])(=O)=O.Nc1ccc(Nc2ccc3nc4ccc(Nc5ccc6nc7ccc(Nc8ccc9nc%10ccc(Nc%11ccccc%11)cc%10[n+](-c%10ccccc%10)c9c8)cc7[n+](-c7ccccc7)c6c5)cc4[n+](-c4ccccc4)c3c2)cc1 FWLHAQYOFMQTHQ-UHFFFAOYSA-N 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- 241000208125 Nicotiana Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical class [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000004313 glare Effects 0.000 description 1
- 238000003898 horticulture Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 238000006864 oxidative decomposition reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000037072 sun protection Effects 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2551/00—Optical elements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Laminated Bodies (AREA)
- Catalysts (AREA)
Abstract
본 고안은 광필름에 관한 것으로서, 보다 상세하게는 광촉매층이 형성된 단열성 쏠라 필름에 관한 것이다..The present invention relates to an optical film, and more particularly to an insulating solar film having a photocatalyst layer formed.
즉, 쏠라 필름에 있어서, 폴리에스터(PET) 층(10)과; 상기 폴리에스터 층(10)의 일측면에 형성된 열차단 접착제 층(20)과; 상기 폴리에스터 층(10)의 타측면에 형성된 실리콘(실리카) 코팅 층(40)과; 상기 실리콘 코팅 층(40) 위에 광촉매 용액으로 형성된 광촉매 층(50)을 포함하는데, 상기 실리카 코팅 층(40)의 빈공간(45) 사이로 상기 광촉매 용액(55)이 일부 스며들어가면서 광촉매 층이 형성하였다.That is, in the solar film, the polyester (PET) layer (10); A thermal barrier adhesive layer (20) formed on one side of the polyester layer (10); A silicon (silica) coating layer 40 formed on the other side of the polyester layer 10; The photocatalyst layer 50 formed of a photocatalyst solution on the silicon coating layer 40 is included. The photocatalyst layer 55 is partially penetrated between the empty spaces 45 of the silica coating layer 40 to form a photocatalyst layer. .
Description
본 고안은 광필름에 관한 것으로서, 보다 상세하게는 광촉매층이 형성된 단열성 쏠라 필름에 관한 것이다.The present invention relates to an optical film, and more particularly, to an insulating solar film having a photocatalyst layer formed thereon.
필름 중에 특수하게는 방탄 필름도 있으나, 보통의 광필름에는 편광필름이나, 차광필름 등도 포함되는데, 본 고안은 특히 쏠라 필름 즉, 단열성 필름에 관한 것이다.Among the films, there are particularly bulletproof films, but ordinary optical films include polarizing films, light blocking films, and the like, and the present invention particularly relates to a solar film, that is, a heat insulating film.
편광 필름에서, 내구성을 결여하고 있는 내부 편광필름층의 결점을 보완하기 위한 기술(한국 특허공개번호 특1988-0700282호)이 개발되었는데, 차광기재필름에 대해서 코팅작업시 겔화되는 문제점이 없도록, 우수한 접동성 코팅층을 지니고, 우수한 점착성, 내구성 및 내마모성을 지니는 코팅필름에 대한 기술(한국 특허등록번호 제 10-0180820호)이 공개되었다.In the polarizing film, a technology (Korean Patent Publication No. 1988-0700282) has been developed to compensate for the shortcomings of the internal polarizing film layer that is lacking in durability. A technique for coating films having a sliding coating layer and excellent adhesion, durability and wear resistance (Korean Patent Registration No. 10-0180820) has been disclosed.
종래기술의 일 예에서, 차광기재필름은 50-200 마이크로미터 두께의 플라스틱수지 필름일 수 있는데, 그 플라스틱 수지는 폴리올레핀 수지, 폴리에스테르 수지, 폴리아미드 수지 등에서 선택된다. 상기 기술에서, 플라스틱 수지를 고차광성으로 하기 위해서는 필름으로 성형하기 전에, 아닐린 블랙등의 블랙안료로, 플라스틱 수지필름의 광학밀도가 10 이상이 되도록 배합하는 것이 필요하다.In one example of the prior art, the light-shielding substrate film may be a plastic resin film having a thickness of 50-200 micrometers, wherein the plastic resin is selected from polyolefin resin, polyester resin, polyamide resin and the like. In the above technique, in order to make a plastic resin high light-shielding property, it is necessary to mix | blend so that the optical density of a plastic resin film may be 10 or more with black pigments, such as aniline black, before shape | molding into a film.
쏠라 컨트롤 필름은 시설원예의 피복재료용에서 출발하여, 오일쇼크 이후에는 건물 내의 냉,난방의 고효율화를 위한 목적으로 이용되고 있다. 자동차용 썬팅 필름이 주류를 이루고 있는데, 광선차단의 고유목적보다는 차량 장식용 또는 프라이버시 보호용으로 전이되고 있기도 하다.Solar control film is used for coating materials of facility horticulture and is used for the purpose of high efficiency of cooling and heating in buildings after oil shock. Automotive tinting films are becoming the mainstream, but are shifting to car decoration or privacy protection rather than the unique purpose of light blocking.
또, PET 소재의 쏠라필름은 광선차단뿐 아니라 부가적 효과로서 PET 필름의 강한 물성에 힘입어 유리의 안전 강화 등으로도 이용된다. 그런데, 건축용으로 쓰이는 유리창 접착 단열 필름으로는 단열효과가 높고 자외선 차단 기능이 우수한 제품이 필요하다.In addition, the solar film of PET material is used not only to block light but also to enhance the safety of glass due to the strong physical properties of the PET film as an additional effect. However, the glass window adhesive insulation film used for construction needs a high heat insulation effect and excellent UV protection function.
유리창에 쓰는 특수 단열필름의 일 예로 미국 특허(청) 제 3,775,226 호가 있으며, 이것은 특수가공 처리된 미세한 알미늄 미립자를 고도의 정밀한 진공 컴퓨터에 의해 폴리에스터 필름에 증착시켜 만든 것이다.An example of a special thermal insulation film for glass windows is U.S. Patent No. 3,775,226, which is made by depositing specially processed fine aluminum particles onto a polyester film by a high precision vacuum computer.
한편, 특수한 용도가 아닌 일반적인 경우의 일 예로는 실리콘(실리카) 코팅 필름을 사용한다. 일반적으로 실리콘실리카 코팅 필름은 건축자재 분야에 널리 쓰이는 것으로서, PET 또는 OPP와 같은 통상의 투명 필름 상에 필름의 권취시 또는 적층시 필름 상호간이 서로 쉽게 분리되도록 하기 위하여 실리콘 수지와 경화제류 및 용제류로 혼합 구성된 실리콘 코팅액을 도포하는 기술(한국 특허출원번호 제 10-1991-0009466호)이 공개되어 있다.On the other hand, as an example of a general case that is not a special use uses a silicon (silica) coating film. In general, silicone silica coating film is widely used in the field of construction materials, silicone resins, hardeners and solvents in order to easily separate the film from each other when the film is wound or laminated on a common transparent film such as PET or OPP It is disclosed a technology for applying a silicone coating solution consisting of a mixture (Korean Patent Application No. 10-1991-0009466).
상기 기술은, 미량의 염료가 첨가된 새로운 조성의 실리콘 코팅액을 기존의 투명필름상에 코팅하므로써, 코팅처리된 부분이 색상을 나타내도록 하여 실리콘 코팅 작업시 작업자가 실리콘 코팅 여부의 판별을 쉽게 할 수 있도록 한 것이다. 즉, 실리콘 코팅되지 않은 필름이 실리콘 코팅처리된 필름속에 섞여 들어가는 것을 미연에 방지하며, 최종 공정인 슬릿팅(Slitting) 작업 후 육안검사 만으로도 코팅되지 않은 부분이 코팅된 부분속에 혼입되었는지의 여부를 손쉽게 판별할 수 있도록 한 새로운 실리콘실리카 코팅 필름을 제공하는데 그 목적이 있는 기술이다.The technique can be applied to the existing transparent film by coating a silicone coating liquid of a new composition with a small amount of dye, so that the coated portion shows a color, it is easy for the operator to determine whether the silicone coating during the silicone coating operation. It would be. That is, it prevents the uncoated film from being mixed into the silicon-coated film and easily checks whether the uncoated part is incorporated into the coated part by visual inspection after the final slitting operation. It is a technology aimed at providing a new silicone silica coating film which can be discriminated.
본 고안은 바람직한 기능을 더 갖는, 광촉매층을 포함하는 단열성 쏠라 필름을 제공하는 데에 그 목적이 있다.The present invention has an object to provide a heat-insulating solar film comprising a photocatalyst layer, further having a desirable function.
도 1은 본 고안에 따른 쏠라 필름의 구조를 나타낸 도면.1 is a view showing a structure of a solar film according to the present invention.
도 2는 본 고안의 쏠라 필름의 광촉매 층의 형성과정을 나타낸 도면.2 is a view showing a process of forming a photocatalyst layer of the solar film of the present invention.
도 3은 본 고안의 쏠라 필름의 실리카 코팅 층의 단면 구조를 나타낸 도면.Figure 3 is a view showing a cross-sectional structure of the silica coating layer of the solar film of the present invention.
<도면 주요 부분에 대한 부호의 설명><Description of the code | symbol about the principal part of drawings>
10 : 폴리에스터 층 20 : 점착제 층10: polyester layer 20: adhesive layer
30 : 이면지 40 : 실리콘(실리카) 층30: backing paper 40: silicon (silica) layer
45 : 실리콘(실리카) 층의 빈공간 50 : 광촉매 용액 층45: empty space of the silicon (silica) layer 50: photocatalyst solution layer
55 : 광촉매 용액 방울55: droplet of photocatalyst solution
상기와 같은 목적을 달성하기 위한 본 고안의 특징은, 쏠라 필름에 있어서, 폴리에스터(PET) 층(10)과; 상기 폴리에스터 층(10)의 일측면에 형성된 열차단 접착제 층(20)과; 상기 폴리에스터 층(10)의 타측면에 형성된 실리콘(실리카) 코팅 층(40)과; 상기 실리콘(실리카) 코팅 층(40) 위에 광촉매 용액으로 형성된 광촉매 층(50)을 포함하는데, 상기 실리콘(실리카) 코팅 층(40)의 빈공간(45) 사이로 상기 광촉매 용액(55)이 일부 스며들어가면서 광촉매 층이 형성된 데에 있다.Features of the present invention for achieving the above object, in the solar film, polyester (PET) layer (10); A thermal barrier adhesive layer (20) formed on one side of the polyester layer (10); A silicon (silica) coating layer 40 formed on the other side of the polyester layer 10; And a photocatalyst layer 50 formed of a photocatalyst solution on the silicon (silica) coating layer 40, wherein the photocatalyst solution 55 partially penetrates between the voids 45 of the silicon (silica) coating layer 40. As it enters, the photocatalyst layer is formed.
이하, 첨부한 도면을 참조하여, 본 고안에 따른 구성의 실시 예들을 상세히 설명하기로 한다.Hereinafter, with reference to the accompanying drawings, it will be described embodiments of the configuration according to the present invention in detail.
도 1은 본 고안에 따른 광촉매 쏠라 필름의 구조를 나타낸 도면으로서, 폴리에스터 층(10), 점착제 층(20), 이면지 보호막(30), 실리콘(실리카) 코팅 층(40), 및 광촉매 층(50)이 도시되어 있다. 이면지 보호막(30)은 쏠라 필름의 사용 과정에서 벗겨낼 수 있는 것이다. 상기 층 중에서 가장 두껍고 핵심적인 층은 폴리에스터 층(10)인데, 그 두께는 통상 9-50 마이크로미터이다.1 is a view showing the structure of the photocatalyst solar film according to the present invention, a polyester layer 10, pressure-sensitive adhesive layer 20, backing paper protective film 30, a silicon (silica) coating layer 40, and a photocatalyst layer ( 50 is shown. The backing paper protective film 30 can be peeled off during the use of the solar film. The thickest and core of the layers is the polyester layer 10, which is typically 9-50 micrometers thick.
본 고안에 따른 쏠라 필름의 목적 기능으로는 실내 공기의 정화 기능을 포함한다. 그러므로, 본 고안에 따른 쏠라 필름을 유리창에 사용하는 경우에는 유리창의 실내 쪽에서, 상기 이면지 보호막(30)을 벗겨내고, 상기 점착제 층(20)을 유리창에 부착시키도록 한다. 그리고, 상기 광촉매 층(50)은 폴리에스터 층(10)을 중심으로 점착제 층(20)과 반대편에 위치한다. 즉, 광촉매 층(50)이 가장 실내 쪽으로 위치하도록, 쏠라 필름의 구조를 형성한다.The objective function of the solar film according to the present invention includes a purification function of indoor air. Therefore, when the solar film according to the present invention is used for the glass window, the back surface protective film 30 is peeled off from the interior side of the glass window, and the adhesive layer 20 is attached to the glass window. In addition, the photocatalyst layer 50 is positioned opposite to the pressure-sensitive adhesive layer 20 with respect to the polyester layer 10. That is, the structure of the film is formed so that the photocatalytic layer 50 is located most toward the interior.
도 2는 본 고안의 쏠라 필름의 광촉매 층의 형성과정을 설명하기 위해 나타낸 도면이다. 실리콘(실리카) 코팅(40) 층의 평면을 나타내었고, 육안으로는 보이지 않은 실리콘(실리카) 코팅의 구멍 공간(45)을 도시하였다.Figure 2 is a view showing for explaining the formation process of the photocatalyst layer of the solar film of the present invention. The plane of the layer of silicon (silica) coating 40 is shown and the pore space 45 of the silicon (silica) coating is not visible to the naked eye.
광촉매 용액의 방울(55)들은 스프레이를 이용하여 뿌릴 수도 있으나, 그럴 경우에는 광촉매 용액이 응결되어 뿌옇게 될 수도 있다. 그래서, 바람직하게는 콤프레샤를 이용하여 광촉매 용액 입자(55)가 실리콘(실리카) 코팅 층(40)의 표면에 고르게 코팅하면, 단층처럼 형성된다.Drops 55 of the photocatalyst solution may be sprayed using a spray, but in this case, the photocatalyst solution may be condensed and cloudy. Thus, when the photocatalyst solution particles 55 are preferably evenly coated on the surface of the silicon (silica) coating layer 40 using a compressor, they are formed like a single layer.
도 3은 본 고안에 따른 쏠라 필름의 실리콘(실리카) 코팅 층의 단면 구조를 나타낸 것이다. 광촉매 용액 입자(55)가 실리콘(실리카) 코팅 층(40)의 빈공간(45)에 어떤 상태로 스며들어가 있는 지를 나타내고 있다. 광촉매 용액 입자(55)는 각각의 빈공간(45)에서 실리카 처리가 되면서, 광촉매 층(50)이 실리콘(실리카) 코팅 층(40) 위에 형성된다.Figure 3 shows a cross-sectional structure of the silicon (silica) coating layer of the solar film according to the present invention. The photocatalyst solution particles 55 are shown in the state where they enter the empty space 45 of the silicon (silica) coating layer 40. The photocatalyst solution particles 55 are silica treated in each void 45, so that the photocatalyst layer 50 is formed over the silicon (silica) coating layer 40.
위와 같은 구조의 광촉매 쏠라 필름에서 광촉매 용액 성분의 일 예로 TiO2용액 입자가 있다. 이산화 티타늄을 주 원료로 한 광촉매제가 바람직한 데, 실내 공기를 쾌적하게 하려는 목적에 맞게 다른 것을 선택할 수도 있다.An example of the photocatalyst solution component in the photocatalyst solar film having the above structure is TiO 2 solution particles. A photocatalyst mainly composed of titanium dioxide is preferable, but another may be selected for the purpose of making room air comfortable.
광촉매 중에서 이산화티타늄이 내산성, 내알카리성 등이 좋으며 인체에 무해하다. 이산화티타늄 광촉매는 n형 반도체로서 자외선(400nm)을 받으면 전자(Electron), 전공대(Electron Hole)가 형성되어 강한 산화력을 가진 하이드록시 라티칼(-OH)과 슈퍼 옥사이드를 생성한다.Among photocatalysts, titanium dioxide has good acid resistance and alkali resistance and is harmless to human body. Titanium dioxide photocatalysts are n-type semiconductors that, when subjected to ultraviolet light (400 nm), form electrons and electron holes to form hydroxy radicals (-OH) and super oxides with strong oxidizing power.
본 고안의 특징적인 사항 중 하나는, 광촉매의 기능에는 광원이 필요하므로, 유리창 밖의 자연광원을 이용하는 경우에, 햇빛의 일부가 통과되는 투명소재, 즉 폴리에스터 필름을 사용함이 바람직하다는 것이다. 즉, 일부의 자외선이 폴리에스터 층(10)을 통과하여 광촉매 층(50)에 닿으면, 광촉매의 탈취, 항균 효과가 나타날 수 있다. 한편, 폴리에스터 층(10) 위에 곧바로 광촉매 층(50)을 형성할 수는 없고, 실리콘(실리카) 코팅 층(40)이 중간에 있을 필요가 있다. 투명성, 단열성, 광촉매의 기능성을 모두 갖을 수 있는 필름의 구조를 위한 것이다.One of the characteristic features of the present invention is that, since a light source is required for the function of the photocatalyst, it is preferable to use a transparent material, ie, a polyester film, through which a part of sunlight passes when using a natural light source outside the glass window. That is, when some ultraviolet rays pass through the polyester layer 10 and reach the photocatalytic layer 50, deodorization and antibacterial effects of the photocatalyst may be exhibited. On the other hand, it is not possible to form the photocatalytic layer 50 directly on the polyester layer 10, and the silicon (silica) coating layer 40 needs to be in the middle. It is for the structure of the film which can have all transparency, heat insulation, and the functionality of the photocatalyst.
이상에서와 같은 구성을 갖는 본 고안에 따른 광촉매 쏠라 필름을 내벽재로 사용하면 다음과 같은 효과가 있다. 즉, 사무실 등의 실내공간 인테리어용으로 사용하면 광촉매 층의 유기물 산화분해 작용으로 사무실 공기를 쾌적하게 유지시켜 줄 수 있다. 특히, 흡연실 등에 사용하면 흡연실의 담배 냄새를 제거하여 줄 수 있으며, 신축 아파트에서는 인체 유해가스인 휘발성 화합물(VOCs)과 포름알데히드 등을 제거할 수 있다.When the photocatalyst solar film according to the present invention having the configuration as described above is used as an inner wall material, the following effects are obtained. That is, when used for the interior of the interior space, such as offices can keep the office air comfortable by oxidative decomposition of organic matter of the photocatalyst layer. In particular, when used in a smoking room, such as can remove the smell of tobacco in the smoking room, new apartments can remove volatile compounds (VOCs) and formaldehyde, which are harmful gases.
또한, 광촉매 층 자체도 자외선 차단 기능이 있으므로, 전체적으로 광촉매 쏠라 필름은 일부 자외선에 의한 광촉매 기능을 활용하면서도, 더 나은 자외선 차단 역할도 하는 효과가 있다.In addition, since the photocatalyst layer itself also has a UV blocking function, the photocatalytic solar film as a whole utilizes the photocatalytic function of some ultraviolet rays, but also has a role of better UV blocking.
본 고안에 따른 광촉매 쏠라 필름을 시공하기 전후의 냉,난방 효과를 비교 측정한 결과는 다음과 같다. 본 결과는 냉,온방 장치를 가동하지 않은 상태에서 측정한 것이다.Comparative results of the cooling and heating effects before and after construction of the photocatalyst solar film according to the present invention are as follows. The results were measured without the cooling and heating units running.
측정 결과, 본 고안의 필름을 시공하기 전에 외기온도(평균)는 29℃ 기준으로, 오전 9시에 실내온도는 30도, 10시에 31도, 11시에 32도, 12시에 33도, 13시에 34도, 14시에 32도, 15시에 32도, 그리고 16시에 31도 이었다.As a result of the measurement, before constructing the film of the present invention, the outside air temperature (average) is based on 29 ° C, and the room temperature is 30 °, 10 ° 31 °, 11 ° 32 °, 12 ° 33 °, It was 34 degrees at 13, 32 degrees at 14, 32 degrees at 15, and 31 degrees at 16.
본 고안의 필름을 시공한 후에는 외기온도(평균)가 29.8℃ 기준으로, 오전 9시 30분에 31.2도, 10시 30분에 31.8도, 11시 30분에 32.5도, 12시 30분에 33도, 13시 30분에 34.9도, 14시 30분에 33도, 15시 30분에 32.8도, 16시 30분에 31도 이었다.After constructing the film of the present invention, the outside air temperature (average) is 21.2 ° C, at 31.2 degrees at 9:30 am, 31.8 degrees at 10:30, 32.5 degrees at 11:30, and 12:30. It was 33 degrees, 34.9 degrees at 13:30, 33 degrees at 14:30, 32.8 degrees at 15:30, and 31 degrees at 16:30.
즉, 측정의 오차나 조건에 대한 보정 등을 하면, 광촉매 쏠라 필름의 시공 전보다 시공 후에 하절기 냉방부차 절감량이 35% 향상되는 결과를 얻을 수 있다. 비슷하게, 태양열 감소율은 68%, 눈부심 감소율은 71%, 자외선 차단율은 99%의 효과를 나타내었다.That is, the correction of the error or condition of the measurement, the result can be improved by 35% the amount of cooling secondary summer savings after construction than before the photocatalytic solar film. Similarly, sun reduction was 68%, glare reduction was 71%, and sun protection was 99%.
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