KR20020022364A - Manufacturing method of the manure made from brown seaweed wastes - Google Patents

Manufacturing method of the manure made from brown seaweed wastes Download PDF

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KR20020022364A
KR20020022364A KR1020000055123A KR20000055123A KR20020022364A KR 20020022364 A KR20020022364 A KR 20020022364A KR 1020000055123 A KR1020000055123 A KR 1020000055123A KR 20000055123 A KR20000055123 A KR 20000055123A KR 20020022364 A KR20020022364 A KR 20020022364A
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seaweed
waste
seaweed waste
quicklime
cao
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KR1020000055123A
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Korean (ko)
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이정식
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이정식
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00Other organic fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D3/00Calcareous fertilisers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Fertilizers (AREA)

Abstract

PURPOSE: A manufacturing method of organic fertilizer using seaweed waste as a main material and unslaked lime(CaO) is provided, which reduces harmful bacteria, stabilizes seaweed and enables moist calcium fertilizer due to spontaneous heat generation of CaO. CONSTITUTION: The manufacturing method comprises the steps of: collecting seaweed waste; washing and immersing seaweed to remove salt; crushing to 5-10mm in size; adding 5-25wt.% of unslaked lime(CaO), which slakes CaO to generate heat(50-95deg.C) due to the reaction of water in seaweed and CaO. The resultant organic fertilizer (pH12-14) contains 25-40% of water, which gives convenience in use.

Description

미역폐기물을 주제로한 유기질 비료의 제조방법{MANUFACTURING METHOD OF THE MANURE MADE FROM BROWN SEAWEED WASTES}Manufacturing method of organic fertilizer based on seaweed waste {MANUFACTURING METHOD OF THE MANURE MADE FROM BROWN SEAWEED WASTES}

본발명은 미역폐기물을 유기질비료로 제조하기 위한 방법에 관한 것으로서 특히, 수거과정에서 미역의 줄기,포자엽,뿌리등으로 이루어진 미역폐기물을 수거한뒤 세척과정에 의해 이들을 밀물로 세척하여 미역폐기물에 포함되어 있는 염기를 제거하고 파쇄과정에 의해 상기의 미역폐기물을 잘게 파쇄한 다음 생석회혼합과정에서 상기의 미역폐기물에 생석회를 혼합시키고 소화자연발열과정에서는 미역폐기물과 생석회혼합물을 용기에 투입한 후 생석회의 자연 발열에 의해 미역폐기물에 포함된 유해균을 줄이고 미역폐기물을 안정화시키는 동시에 토양에 뿌리기 좋은 수분 상태의 유기질 비료를 얻을 수 있도록 함으로서 해양 환경의 오염을 차단할 수 있고 농업 생산에 기여할 수 있는 미역폐기물을 주제로 한 유기질 비료의 제조방법에 관한 것이다.The present invention relates to a method for manufacturing seaweed waste as organic fertilizer, and in particular, the collection of seaweed waste consisting of stems, spores, roots, etc. of seaweed in the collection process and wash them with high water by washing process to include them in seaweed waste. Remove the base and crush the above seaweed waste finely by crushing process, and then mix the quicklime with the seaweed waste in the quicklime mixing process and inject the seaweed waste and the quicklime mixture into the container in the natural digestion process. The theme is seaweed waste, which can prevent pollution of the marine environment and contribute to agricultural production by reducing harmful bacteria contained in seaweed waste by natural heat generation, stabilizing seaweed waste, and obtaining organic fertilizers that are good for spraying on soil. Regarding manufacturing method of organic fertilizer .

일반적으로 양식하는 미역은 엽체만을 채취하고 뿌리와 포자엽 그리고 줄기등은 그대로 바다에 투기하고 있다.In general, the cultured seaweed harvests only the leaves and dumps the roots, spores and stems into the sea.

상기의 미역폐기물은 전체 미역 생산량 30만톤의 5-60%인 15-18만톤에 이르며 상기의 미역폐기물들은 미역채취 시기인 2월에서 4월까지의 기간내에 집중 투기되고 있는 실정이다.The seaweed waste reaches 15-180,000 tons, which is 5-60% of the total seaweed production of 300,000 tons, and the seaweed waste is concentrated in the period of February to April.

그러나, 상기와 같이 바다로 투기되는 미역폐기물들은 바다의 바닥면에 퇴적되어 뻘의 산소 유입을 차단함으로서 해저 식물이나 생물들을 사멸시키는 문제점을 발생시키고 있다.However, the seaweed wastes dumped into the sea as described above is deposited on the bottom of the sea to block the oxygen inflow of water, causing the problem of killing marine plants and organisms.

또한, 상기 미역폐기물에서 분해된 부유물들은 바닷물의 투과광을 감소시키는 동시에 양식중인 미역 엽체에 가라 앉아 미역의 생리 저하뿐만 아니라 병충해를 유발시켜 양식 어장을 황폐화시키게 되는 중대한 문제점도 가지고 있었다.In addition, the suspended matters decomposed in the seaweed waste had a significant problem of reducing the transmitted light of the sea water and at the same time sinking in the seaweed leaf in culture, causing not only the physiology of the seaweed but also causing pests to ravage the fishery.

상기와 같은 심각한 상황임에도 불구하고 미역폐기물들을 그대로 바다에 투기해 버리는 이유는 상기의 미역폐기물들을 수거해 봐도 그 많은량을 처리할 방법이 없고 오히려 육상에서 또다른 환경오염을 만들어 내기 때문에 미역의 채취시에 그냥 바다로 투기해 버리는 것이었다.Despite the above serious situation, the reason for dumping seaweed waste into the sea as it is is because there is no way to treat the large amount of seaweed waste, but rather it creates another environmental pollution on land. The city just dumped into the sea.

또한, 상기 미역폐기물은 25%가 넘는 다당류인 알긴산과 미역귀에 많이 포함되어 있는 점액질과 80%이상의 수분등으로 이루어져 있기 때문에 육상에서는 죽(겔)상의 형태로 빠르게 부패되버리므로 폐기물을 수거 처리한다는 것은 불가능하게 된다.In addition, since the seaweed waste is composed of more than 25% of the polysaccharide alginic acid and mucosa and more than 80% of the water contained in seaweed ears, it is quickly decayed in the form of porridge (gel) on land, so the waste is collected It becomes impossible.

따라서, 상기 미역폐기물의 활용 방법이 우선적으로 개발되어야 미역폐기물에 의한 해양 오염을 막을 수 있을 것이다.Therefore, the method of utilizing the seaweed waste should be developed first to prevent the marine pollution by seaweed waste.

이러한 종래의 문제점등을 해결 보완하기 위한 본발명의 목적은,The purpose of the present invention for solving and solving these conventional problems,

해양오염의 차단은 물론이고 궁극적으로는 미역폐기물을 자원화하여 유기질비료를 제조함으로서 농업생산에 기여할 수 있도록 하는 목적을 제공한다.It provides the purpose of contributing to agricultural production by blocking marine pollution and ultimately by making seaweed waste into organic fertilizer.

상기의 목적을 달성하기 위하여 본발명은,In order to achieve the above object, the present invention,

수거과정에서 미역의 줄기,포자엽,뿌리등으로 이루어진 미역폐기물을 수거한뒤 세척과정에 의해 이들을 밀물로 세척하여 미역폐기물에 포함되어 있는 염기를 제거하고 파쇄과정에 의해 상기의 미역폐기물을 잘게 파쇄한 다음 생석회혼합과정에서 상기의 미역폐기물에 생석회를 혼합시키고 소화자연발열과정에서는 미역폐기물과 생석회혼합물을 용기에 투입한 후 생석회의 자연 발열에 의해 미역폐기물에 포함된 유해균을 줄이고 미역폐기물을 안정화시키는 동시에 토양에 뿌리기 좋은 수분 상태의 유기비료를 얻을 수 있도록 하면 본발명의 목적을 달성할 수 있게 된다.In the collection process, the seaweed waste consisting of stems, spores and roots of seaweed is collected and washed with high water by the washing process to remove the bases contained in the seaweed waste and finely shredded the seaweed waste by crushing process. In the next quick-lime mixing process, the quick-waste is mixed with the seaweed waste, and in the natural digestion process, the sea-weed waste and the quick-lime mixture are put into the container, and the natural heat of the quick-lime reduces the harmful bacteria contained in the sea-waste waste and stabilizes the seaweed waste. It is possible to achieve the purpose of the present invention by obtaining a water-soluble organic fertilizer to the soil.

도면은 본발명 미역폐기물이 유기질 비료화되는 과정을 설명하기 위해 나타낸 플루우챠트Figure is a flute chart shown to explain the process of the invention seaweed waste organic fertilizer

본발명의 미역폐기물을 석회질비료로 제조하기 위한 방법을 첨부된 도면에 의해 과정별로 상세히 설명하면 다음과 같다.The method for producing seaweed waste of the present invention as a calcined fertilizer will be described in detail by process by the accompanying drawings as follows.

미역의 줄기,포자엽,뿌리등으로 이루어진 미역폐기물을 수거하기 위한 수거과정과,A collection process for collecting seaweed waste consisting of stems, spores and roots of seaweed,

상기 수거과정에서 수거된 미역폐기물에 포함된 염기를 제거하기 위해 미역폐기물들을 밀물에 의해 세척 또는 침적시키는 세척과정과,Washing process of washing or depositing seaweed wastes by high water to remove the base contained in the seaweed waste collected in the collection process,

상기 세척과정에서 세척된 미역폐기물을 파쇄기에서 잘게 파쇄하기 위한 파쇄과정과,Shredding process for finely crushing the seaweed waste washed in the washing process in the crusher,

상기 파쇄과정에서 잘게 파쇄된 미역폐기물에 생석회를 약 5-25중량%를 투입하여 혼합시키는 혼합과정과,A mixing process of mixing about 5-25% by weight of quicklime with finely crushed seaweed waste in the crushing process;

상기 혼합과정을 거친 미역폐기물 및 생석회혼합물을 용기에 투입한후 밀봉하여 생석회에서 발열되는 약50-95℃의 자연 발열에 의해 미역폐기물에 포함된 유해균을 죽이고 미역폐기물을 안정화시키는 동시에 산도pH12-14, 수분율25-40%로 토양에 뿌리기 좋은 수분 상태의 유기비료를 얻기 위한 소화자연발열과정으로 이루어진 것이다.The seaweed waste and quicklime mixture, which have undergone the mixing process, are put into a container and sealed to kill harmful bacteria contained in the seaweed waste by natural heat of about 50-95 ° C. generated from quicklime and stabilize the seaweed waste at the same time. It is composed of digestive spontaneous pyrogenic process to obtain organic fertilizers in water with good moisture content of 25-40%.

이와같이된 본발명을 실시하기 위한 일실시예를 설명하면 다음과 같다.When explaining an embodiment for carrying out the present invention as described above is as follows.

먼저, 수거과정에서는 미역양식장에서 양식로우프에 매달린 미역의 엽체만을 채취하고 로우프에 매달려 남아 있는 미역의 줄기,포자엽,뿌리등으로 이루어진 미역폐기물들은 분리형틀을 통과시켜 분리를 하게 된다.First, in the collection process, only the seaweed leaves hanging from the seaweed rope are collected from the seaweed farm, and the seaweed waste consisting of stems, spores and roots of seaweed remaining on the rope is separated through a separate mold.

즉, 상기 로우프 일단부를 분리형틀에 삽입하여 로우프만을 뽑아내는 작업과정에 의해 로우프로 부터 상기의 미역폐기물들을 분리시킬 수 있게 된다.That is, the seaweed wastes can be separated from the rope by inserting one end of the rope into the separating mold and extracting only the rope.

그리고, 상기 로우프로 부터 분리된 미역폐기물들은 어망 또는 수거선에 담아 운반을 하게 된다.And, the seaweed waste separated from the rope is transported in a fishing net or a collection ship.

상기와 같이 수거과정에 의해 수거된 미역폐기물에는 많은 염기를 포함하고 있으므로 세척과정에 의해 염기를 제거하게 된다.As described above, the seaweed waste collected by the collection process contains many bases, thereby removing the bases by washing.

즉, 상기 미역폐기물들을 콘베이어로 이송 도중 스프레이로 민물을 분사하여염기를 제거하거나 민물이 담겨 있는 수조에 미역폐기물을 침적시켜 염기를 제거하게 된다.In other words, during the transfer of the seaweed waste to the conveyor to remove the base by spraying fresh water with a spray or to remove the base by depositing the seaweed waste in a tank containing fresh water.

또한, 상기 세척과정에서 세척된 미역폐기물은 파쇄과정의 파쇄기로 옮겨져 가로 세로 약 5-10mm정도의 크기로 잘게 파쇄한다.In addition, the seaweed waste washed in the washing process is transferred to the crusher of the crushing process to be finely crushed to a size of about 5-10mm horizontally.

그리고, 상기 파쇄과정에서 잘게 파쇄된 미역폐기물은 혼합과정에서 미역폐기물에 생석회 약5-25중량%를 투입하여 혼합시키게 된다.And, finely crushed seaweed waste in the shredding process is mixed by adding about 5-25% by weight of quicklime to the seaweed waste in the mixing process.

또한, 상기 혼합과정을 거친 미역폐기물 및 생석회혼합물은 소화자연발열과정에서 용기에 투입한후 생석회에서 발열되는 약50-95℃의 자연 발열에 의해 미역폐기물에 포함된 유해균을 죽이고 미역폐기물을 안정화시키는 동시에 산도pH12-14, 수분율25-40%로 토양에 뿌리기 좋은 수분 상태의 유기비료를 얻을 수 있게 된다.In addition, the seaweed waste and quicklime mixture after the mixing process is put into the container in the natural heat of digestion process by killing harmful bacteria contained in seaweed waste by the natural exotherm of about 50-95 ℃ that is generated from the quicklime to stabilize the seaweed waste At the same time, it is possible to obtain organic fertilizers with good water solubility in soil with acidity pH 12-14 and moisture content 25-40%.

그리고, 상기 소화자연발열과정에서 생석회는 농산물재배에 있어서 화학비료 남용으로 산성화된 토양을 중화개량시키기 위해 패회(貝灰)와 함께 사용하고 있는바, 석회는 소석회를 말하고 소석회는 소화과정을 거쳐 만들어진다.In the digestive natural heating process, quicklime is used together with shellfish to neutralize soil acidified by chemical fertilizer abuse in agricultural production. Lime refers to hydrated lime and hydrated lime is made through digestion. .

또한, 상기의 소화는 건식소화와 습식소화가 있으나 본발명의 소화자연발열과정에서는 습식소화시에 사용되는 물 대신에 수분함량이 80-90%인 미역폐기물에 함유된 수분에 의해 생석회를 소화시키고 그 소화과정에서 발생하는 열을 이용하여 유해균을 죽이고 미역폐기물을 안정화시키는 것이다.In addition, the above digestion is dry digestion and wet digestion, but in the natural exothermic process of the present invention, the quicklime is digested by moisture contained in seaweed waste having water content of 80-90% instead of water used for wet digestion. The heat generated during the digestion process is used to kill harmful bacteria and stabilize seaweed waste.

따라서, 상기와 같이 혼합 소화된 미역 폐기물 유기 비료는 건조할 필요 없이 적당한 수분을 함유하기 때문에 바람에 비산되지 않고 덩어리도 없게 되므로 사용하기에 매우 좋은 상태로 만들어진다.Therefore, the mixed and digested seaweed waste organic fertilizer as described above is made in a very good state to use because it does not need to be dried, so it does not scatter in the wind and there is no lump.

이와같이된 본발명은 수거과정에서 미역의 줄기,포자엽,뿌리등으로 이루어진 미역폐기물을 수거한뒤 세척과정에 의해 이들을 밀물로 세척하여 미역폐기물에 포함되어 있는 염기를 제거하고 파쇄과정에 의해 상기의 미역폐기물을 잘게 파쇄한 다음 생석회혼합과정에서 상기의 미역폐기물에 생석회를 혼합시키고 소화자연발열과정에서는 미역폐기물과 생석회혼합물을 용기에 투입한 후 생석회의 자연 발열에 의해 미역폐기물에 포함된 유해균을 줄이고 미역폐기물을 안정화시키는 동시에 토양에 뿌리기 좋은 수분 상태의 유기비료를 얻을 수 있도록 된것으로, 상기의 미역폐기물에는 다량의 미량원소들을 함유되어 있고 상기 미역 폐기물 자체의 유기물질도 좋지만 특히, 작물에서 결핍되어 나타나는 미량원소 결핍증의 장애를 치유하는 절대적 성분(마그네슘,인,칼륨,망간)이 아래의 표1에 나타낸 바와같이 미역폐기물에 다량 함유되어 있다.Thus, the present invention collects seaweed waste consisting of stems, spores and roots of seaweed in the collection process and washes them with high water by washing process to remove the bases contained in the seaweed waste and crushed seaweed Finely crush the waste and then mix the quicklime with the seaweed waste in the quicklime mixing process, and in the natural digestion process, put the seaweed waste and the quicklime mixture into the container and reduce the harmful bacteria contained in the seaweed waste by the natural heat of quicklime It is possible to stabilize the wastes and to obtain organic fertilizers that are good to be sprayed on the soil. The seaweed wastes contain a large amount of trace elements and the organic matters of the seaweed wastes themselves are good, but are deficient in crops. Absolute ingredient that cures disorders of microelement deficiency (Magnesium, phosphorus, potassium and manganese) are contained in seaweed waste as shown in Table 1 below.

미역 폐기물에 포함된 미네랄 성분(100g 중 mg)Mineral content in seaweed waste (mg in 100 g) 칼슘calcium 마그네슘magnesium sign 칼륨potassium iron 요드Yod copper 망간manganese 아연zinc 니켈nickel 크롬chrome 세렌Seren CaCa MgMg PP KK FeFe II CuCu MnMn ZnZn NiNi CrCr SeSe 1,3001,300 1,1701,170 420420 5,5005,500 77 3636 3434 9.59.5 3.13.1 2.42.4 77 33

따라서, 상기 미역폐기물을 본발명에 의해 비료로 이용함으로서 원천적으로 환경오염원을 차단할 수 있고 양식어장을 보존하여 어민에게 안정적인 양식 환경을 제공할 뿐만 아니라 양질의 유기질 비료는 농업생산에도 크게 기여할 수 있게 된다.Therefore, by using the seaweed waste as a fertilizer by the present invention, it is possible to fundamentally block the environmental pollution source, to preserve fish farms to provide a stable farming environment to fishermen, and high quality organic fertilizers can greatly contribute to agricultural production. .

특히, 지금 까지 유기질 비료로 이용되고 있는 음식쓰레기,하수쓰레기,해저퇴적물들은 염분을 함유하고 있어 상기의 염분 피해 때문에 노천 재배 작물에 한정적으로 사용될 수 밖에 없는 단점을 가지고 있었으나 본발명에 의한 미역 유기질 비료는 염분이 완전히 제거된 상태로 계속적이고 안정적으로 다량을 사용할 수 있게 되므로 자원으로서의 활용도가 높아지게 된다.In particular, food waste, sewage waste, and sea sediment, which have been used as organic fertilizers until now, contain salts, so they have limited disadvantages in open-air crops due to the salt damage. Since the salt can be used continuously and stably in large amounts with the salt completely removed, the utilization as a resource increases.

그리고, 상기의 미역폐기물을 이용한 유기질 비료는 그 양이 매우 많기 때문에 산업화가 보장되고 높은 수익성과 부가 가치를 얻을 수 있는 유용한 효과를 가진다.In addition, the organic fertilizer using the seaweed waste has a useful effect that the industrialization is guaranteed and high profitability and added value can be obtained because the amount of the organic fertilizer is very large.

Claims (1)

미역의 줄기,포자엽,뿌리등으로 이루어진 미역폐기물을 수거하기 위한 수거과정과,A collection process for collecting seaweed waste consisting of stems, spores and roots of seaweed, 상기 수거과정에서 수거된 미역폐기물에 포함된 염기를 제거하기 위해 미역폐기물들을 밀물에 의해 세척 또는 침적시키는 세척과정과,Washing process of washing or depositing seaweed wastes by high water to remove the base contained in the seaweed waste collected in the collection process, 상기 세척과정에서 세척된 미역폐기물을 파쇄기에서 잘게 파쇄하기 위한 파쇄과정과,Shredding process for finely crushing the seaweed waste washed in the washing process in the crusher, 상기 파쇄과정에서 잘게 파쇄된 미역폐기물에 생석회 약5-25중량%를 투입하여 혼합시키는 혼합과정과,Mixing and mixing about 5-25% by weight of quicklime with finely crushed seaweed waste in the crushing process; 상기 혼합과정을 거친 미역폐기물 및 생석회혼합물을 용기에 투입한후 생석회에서 발열되는 약50-95℃의 자연 발열에 의해 미역폐기물에 포함된 유해균을 죽이고 미역폐기물을 안정화시키는 동시에 산도pH12-14, 수분율25-40%로 토양에 뿌리기 좋은 수분 상태의 유기비료를 얻기 위한 소화자연발열과정으로 이루어진 것을 특징으로 하는 미역폐기물을 주제로 한 유기질 비료의 제조방법.Put the seaweed waste and quicklime mixture after the mixing process into the container and kill the harmful bacteria contained in the seaweed waste by the natural exotherm of about 50-95 ℃ heat generated from the quicklime and stabilize the seaweed waste at the same time pH pH12-14, moisture content A method for producing organic fertilizers based on seaweed waste, characterized in that it consists of digestive spontaneous heat generation to obtain organic fertilizers in a good state of water sprayed to the soil at 25-40%.
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040031422A (en) * 2002-10-07 2004-04-13 유용숙 The addition and method for manufacturing of starfish lime treatment fertilizer
WO2005080297A1 (en) * 2004-01-23 2005-09-01 Simon Njoroge Mwaura Method of converting aquatic plants especially hyacinth into useful products
FR2983852A1 (en) * 2011-12-09 2013-06-14 Droff Yves Le Treating and recovering green algae by exothermic treatment with calcium oxide delayed reaction, comprises pretreating, exothermic treating and/or post treating green algae to obtain organic fertilizer and natural mineral product
CN104291899A (en) * 2013-07-18 2015-01-21 张文举 Novel composite fertilizer
CN108863461A (en) * 2018-03-01 2018-11-23 安徽金敦福农业科技有限公司 It is a kind of using yellow tang as the microbial-bacterial fertilizer of matrix

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Publication number Priority date Publication date Assignee Title
EP0012670A1 (en) * 1978-12-07 1980-06-25 Jean-François Lemaire Fertilizer composed of natural products
KR910004866A (en) * 1989-08-22 1991-03-29 제임스 제이. 플린 Blend of cotton, nylon and heat resistant fiber
KR19980035281A (en) * 1996-11-11 1998-08-05 양대윤 Manufacturing method of fertilizer using waste
CN1229778A (en) * 1998-03-20 1999-09-29 汤洁 Method for prodn. of functional marine alga fertilizer

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0012670A1 (en) * 1978-12-07 1980-06-25 Jean-François Lemaire Fertilizer composed of natural products
KR910004866A (en) * 1989-08-22 1991-03-29 제임스 제이. 플린 Blend of cotton, nylon and heat resistant fiber
KR19980035281A (en) * 1996-11-11 1998-08-05 양대윤 Manufacturing method of fertilizer using waste
CN1229778A (en) * 1998-03-20 1999-09-29 汤洁 Method for prodn. of functional marine alga fertilizer

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040031422A (en) * 2002-10-07 2004-04-13 유용숙 The addition and method for manufacturing of starfish lime treatment fertilizer
WO2005080297A1 (en) * 2004-01-23 2005-09-01 Simon Njoroge Mwaura Method of converting aquatic plants especially hyacinth into useful products
FR2983852A1 (en) * 2011-12-09 2013-06-14 Droff Yves Le Treating and recovering green algae by exothermic treatment with calcium oxide delayed reaction, comprises pretreating, exothermic treating and/or post treating green algae to obtain organic fertilizer and natural mineral product
CN104291899A (en) * 2013-07-18 2015-01-21 张文举 Novel composite fertilizer
CN108863461A (en) * 2018-03-01 2018-11-23 安徽金敦福农业科技有限公司 It is a kind of using yellow tang as the microbial-bacterial fertilizer of matrix

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