KR102629634B1 - 디아릴 술폰들을 제조하기 위한 개선된 프로세스 - Google Patents

디아릴 술폰들을 제조하기 위한 개선된 프로세스 Download PDF

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KR102629634B1
KR102629634B1 KR1020177037284A KR20177037284A KR102629634B1 KR 102629634 B1 KR102629634 B1 KR 102629634B1 KR 1020177037284 A KR1020177037284 A KR 1020177037284A KR 20177037284 A KR20177037284 A KR 20177037284A KR 102629634 B1 KR102629634 B1 KR 102629634B1
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coupling step
sulfonic acid
aryl
sulfone
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KR20180016425A (ko
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라미아흐 무루간
데이비드 에이. 해이
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오로리움 홀딩스 엘엘씨
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C315/00—Preparation of sulfones; Preparation of sulfoxides
    • C07C315/04—Preparation of sulfones; Preparation of sulfoxides by reactions not involving the formation of sulfone or sulfoxide groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C315/00—Preparation of sulfones; Preparation of sulfoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/18—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0257—Phosphorus acids or phosphorus acid esters
    • B01J31/0258—Phosphoric acid mono-, di- or triesters ((RO)(R'O)2P=O), i.e. R= C, R'= C, H
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
    • C07C303/04—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups
    • C07C303/06—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups by reaction with sulfuric acid or sulfur trioxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C315/00—Preparation of sulfones; Preparation of sulfoxides
    • C07C315/06—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
    • C07C317/14—Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020177037284A 2015-06-09 2016-06-09 디아릴 술폰들을 제조하기 위한 개선된 프로세스 Active KR102629634B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562173283P 2015-06-09 2015-06-09
US62/173,283 2015-06-09
PCT/US2016/036587 WO2016201039A1 (en) 2015-06-09 2016-06-09 Improved process for making diaryl sulfones

Publications (2)

Publication Number Publication Date
KR20180016425A KR20180016425A (ko) 2018-02-14
KR102629634B1 true KR102629634B1 (ko) 2024-01-25

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Country Link
US (2) US10745348B2 (https=)
EP (2) EP3307710B1 (https=)
JP (2) JP2018516952A (https=)
KR (1) KR102629634B1 (https=)
CN (1) CN107922325B (https=)
WO (1) WO2016201039A1 (https=)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017177030A1 (en) * 2016-04-06 2017-10-12 Emerge Print Management, Llc Apparatus and method for metering and monitoring printer related data on-networked printers
EP3441393B1 (en) * 2017-08-07 2020-03-18 Rhodia Operations New cycloadduct precursors of dihalodiphenylsulfones and preparations thereof
KR20220050996A (ko) * 2019-08-27 2022-04-25 바스프 에스이 4,4'-디클로로디페닐설폰 결정(c)을 포함하는 (c)결정 조성물(cc)
CN114728818A (zh) 2019-11-13 2022-07-08 巴斯夫欧洲公司 处理含有4,4’-二氯二苯亚砜和/或4,4’-二氯二苯砜作为杂质的水的方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102351759A (zh) * 2011-08-25 2012-02-15 吴江市北厍盛源纺织品助剂厂 改进的制备4.4-二氯二苯砜的三氧化硫方法

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US2971985A (en) 1958-07-05 1961-02-14 Roussel Uclaf Process for the preparation of 4, 4'-dichlorodiphenylsulfone
GB895464A (en) * 1958-07-05 1962-05-02 U C L A F Improvements in or relating to sulphones
US3309409A (en) 1964-04-10 1967-03-14 Stauffer Chemical Co Purification of acidic chlorophenylsulfones
US3355497A (en) 1965-02-01 1967-11-28 Plains Chemical Dev Co Manufacture of 4, 4'-dichlorodiphenyl sulfone
CH497396A (de) 1968-11-06 1970-10-15 Inventa Ag Verfahren zum Reinigen von Halogendiphenylsulfonen
US3855312A (en) * 1970-02-06 1974-12-17 Ici Ltd Production of di-4-chlorophenyl sulphone
JPS5182237A (en) 1975-01-16 1976-07-19 Nippon Soda Co 4*4** jikurofuenirusurupponnoseizojiniokeru jimechiruryusannokaishuhoho
JPS5188938A (en) 1975-01-31 1976-08-04 Kojundo 4*4** jikurorujifuenirusurupponnobunrihoho
JPS5785363A (en) * 1980-11-18 1982-05-28 Mitsui Toatsu Chem Inc Preparation of diaryl sulfone
US4778932A (en) * 1986-07-16 1988-10-18 New Japan Chemical Co., Ltd. Process for preparing diarylsulfones
JPS6368556A (ja) * 1986-09-09 1988-03-28 New Japan Chem Co Ltd ジアリ−ルスルホン類の製造方法
US4937387A (en) 1986-09-05 1990-06-26 Amoco Corporation Processes for preparing diaryl sulfones
DE3704932A1 (de) 1987-02-17 1988-09-01 Basf Ag Verfahren zur herstellung von 4,4'-dichlordiphenylsulfon
US4822916A (en) * 1987-09-21 1989-04-18 Akzo America Inc. Preparation of diaryl sulfones
US4876390A (en) 1988-08-19 1989-10-24 Uop Process for separating dichlorodiphenylsulfone isomers
DE3835562A1 (de) 1988-10-19 1990-05-03 Basf Ag Verfahren zur herstellung von bis-(4-chlorphenyl)-sulfon
DE3902890A1 (de) 1989-02-01 1990-08-02 Basf Ag Verfahren zur herstellung von bis-(4-chlorphenyl)-sulfon
DE3902894A1 (de) * 1989-02-01 1990-08-02 Basf Ag Verfahren zur herstellung von bis-(4-chlorphenyl)-sulfon
GB9007577D0 (en) * 1990-04-04 1990-05-30 Ici Plc Preparation of aromatic compounds
JPH06116231A (ja) * 1992-10-06 1994-04-26 Ube Ind Ltd ４，４’−ジクロロジフェニルスルホンの精製法
JPH09143150A (ja) 1995-11-28 1997-06-03 Tokuyama Corp 芳香族スルホンの製造方法
JPH09157246A (ja) 1995-12-13 1997-06-17 Tokuyama Corp ４，４’−ジクロロジフェニルスルホンの単離方法
JPH09165366A (ja) 1995-12-15 1997-06-24 Tokuyama Corp 芳香族スルホンの製造方法
JP3188173B2 (ja) 1996-01-10 2001-07-16 株式会社トクヤマ 芳香族スルホンの製造方法
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GB0921069D0 (en) * 2009-12-01 2010-01-13 Bandodkar Hemant R Process for the production of a sulfone polymer
KR20130043620A (ko) 2010-03-05 2013-04-30 바스프 에스이 4-클로로벤젠술폰산 및 4,4''-디클로로디페닐술폰의 제조 방법
US20110263902A1 (en) 2010-04-22 2011-10-27 Basf Se Process for preparing 4,4'-dichlorodiphenyl sulfone
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Patent Citations (1)

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CN102351759A (zh) * 2011-08-25 2012-02-15 吴江市北厍盛源纺织品助剂厂 改进的制备4.4-二氯二苯砜的三氧化硫方法

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JP7027509B2 (ja) 2022-03-01
CN107922325A (zh) 2018-04-17
EP3307710A1 (en) 2018-04-18
JP2021042221A (ja) 2021-03-18
KR20180016425A (ko) 2018-02-14
EP3307710B1 (en) 2020-09-30
EP3805202A1 (en) 2021-04-14
EP3307710A4 (en) 2018-12-19
US10745348B2 (en) 2020-08-18
CN107922325B (zh) 2021-09-07
WO2016201039A1 (en) 2016-12-15
US20180179153A1 (en) 2018-06-28
US20210171457A1 (en) 2021-06-10
JP2018516952A (ja) 2018-06-28

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