KR102157915B1 - 에틸렌의 하이드로포밀화를 위한 두자리 리간드 - Google Patents

에틸렌의 하이드로포밀화를 위한 두자리 리간드 Download PDF

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KR102157915B1
KR102157915B1 KR1020157014700A KR20157014700A KR102157915B1 KR 102157915 B1 KR102157915 B1 KR 102157915B1 KR 1020157014700 A KR1020157014700 A KR 1020157014700A KR 20157014700 A KR20157014700 A KR 20157014700A KR 102157915 B1 KR102157915 B1 KR 102157915B1
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ligand
hydroformylation
reaction
rhodium
catalyst
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KR20150092144A (ko
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올리비에 다이볼트
휴고 트리카스
리우웬 퍼트루스 더블유엔엠 반
헤더 앤 스피니
로버트 데이비드 존 프로에세
마이클 에이 브라머
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다우 테크놀로지 인베스트먼츠 엘엘씨.
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B01J31/186—Mono- or diamide derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
    • B01J31/187—Amide derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
KR1020157014700A 2012-12-04 2013-11-19 에틸렌의 하이드로포밀화를 위한 두자리 리간드 Active KR102157915B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12382481.5A EP2740535A1 (en) 2012-12-04 2012-12-04 Bidentate ligands for hydroformylation of ethylene
EP12382481.5 2012-12-04
PCT/US2013/070753 WO2014088800A1 (en) 2012-12-04 2013-11-19 Bidentate ligands for hydroformylation of ethylene

Publications (2)

Publication Number Publication Date
KR20150092144A KR20150092144A (ko) 2015-08-12
KR102157915B1 true KR102157915B1 (ko) 2020-09-21

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Country Status (7)

Country Link
US (1) US9795952B2 (https=)
EP (1) EP2740535A1 (https=)
JP (1) JP6360067B2 (https=)
KR (1) KR102157915B1 (https=)
CN (2) CN109364997A (https=)
WO (1) WO2014088800A1 (https=)
ZA (1) ZA201503184B (https=)

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TW201840362A (zh) * 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
TWI758353B (zh) * 2016-11-08 2022-03-21 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
TW201840363A (zh) * 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 處理氫甲醯化催化劑溶液之方法
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US11123723B2 (en) 2018-02-26 2021-09-21 The Regents Of The University Of California Oxidative dehydroxymethylation of alcohols to produce olefins
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CN110327975B (zh) * 2019-06-06 2020-05-19 浙江新和成股份有限公司 氢甲酰化催化剂及其制备方法和应用
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CN116685401B (zh) 2020-09-25 2025-10-03 利安德化学技术有限公司 在加氢甲酰化中将乙烯与烯丙醇共进料以制备1,4-丁二醇和正丙醇
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CN113385236B (zh) * 2021-06-16 2023-02-03 上海华谊（集团）公司 烯烃氢甲酰化催化剂组合物和氢甲酰化方法
CN115536698B (zh) * 2021-06-30 2026-02-06 中国石油化工股份有限公司 膦配体化合物、用于均相氢甲酰化反应的催化剂组合物及方法
CN115536695B (zh) * 2021-06-30 2025-10-14 中国石油化工股份有限公司 一种含有聚乙二醇氨基的非对称膦配体及其应用
CN115536697A (zh) * 2021-06-30 2022-12-30 中国石油化工股份有限公司 膦配体化合物、用于催化氢甲酰化制备醛的催化剂组合物及方法
CN113583046B (zh) * 2021-09-02 2023-08-25 成都欣华源科技有限责任公司 双齿膦配体及其制备方法、应用
US12151993B2 (en) 2021-09-10 2024-11-26 Chevron Phillips Chemical Company Lp Selective 1-hexene/1-octene production with 1-decene
CN118019747A (zh) 2021-10-06 2024-05-10 陶氏环球技术有限责任公司 丙基亚胺官能化有机硅化合物和伯氨基丙基官能化有机硅化合物的制备
WO2023060155A1 (en) 2021-10-06 2023-04-13 Dow Global Technologies Llc Preparation of propylimine-functional organosilicon compounds and primary aminopropyl-functional organosilicon compounds
CN114163476B (zh) * 2021-12-02 2023-09-19 万华化学集团股份有限公司 一种单齿膦型配体、氢甲酰化催化剂，一种烯烃氢甲酰化制备线性醛的方法
CN114736239B (zh) * 2022-05-26 2024-01-16 重庆理工大学 一种双齿膦配体及其制备方法、应用

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KR20150092144A (ko) 2015-08-12
JP6360067B2 (ja) 2018-07-18
WO2014088800A1 (en) 2014-06-12
CN109364997A (zh) 2019-02-22
EP2740535A1 (en) 2014-06-11
US20150328628A1 (en) 2015-11-19
CN104822456A (zh) 2015-08-05
US9795952B2 (en) 2017-10-24
JP2016500123A (ja) 2016-01-07
ZA201503184B (en) 2017-07-26

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