KR101809038B1 - Method for manufacturing gel typed car air purification material - Google Patents

Method for manufacturing gel typed car air purification material Download PDF

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KR101809038B1
KR101809038B1 KR1020160057557A KR20160057557A KR101809038B1 KR 101809038 B1 KR101809038 B1 KR 101809038B1 KR 1020160057557 A KR1020160057557 A KR 1020160057557A KR 20160057557 A KR20160057557 A KR 20160057557A KR 101809038 B1 KR101809038 B1 KR 101809038B1
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/32Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/32Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244Non-macromolecular compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16Clays or other mineral silicates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0205Impregnation in several steps
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00Adding substances to exhaust gases
    • F01N2610/01Adding substances to exhaust gases the substance being catalytic material in liquid form

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

본 발명은 젤타입 차량용 공기정화 물질의 제조방법에 관한 것으로서, 자동차 연료가 연소되면서 배기가스가 발생하게 되는데, 본 발명에 따라 제조된 공기정화 물질을 엔진과 엔진 클리너 사이에 주입하게 되면 배기가스에서 발생하는 유해성분의 비율을 효과적으로 감소시킬 수 있다.The present invention relates to a method of manufacturing an air purification material for a gel type vehicle, in which an automobile fuel is burned and an exhaust gas is generated. When the air purification material manufactured according to the present invention is injected between an engine and an engine cleaner, It is possible to effectively reduce the proportion of harmful components that are generated.

Description

젤타입 차량용 공기정화 물질의 제조방법{Method for manufacturing gel typed car air purification material}TECHNICAL FIELD [0001] The present invention relates to a method of manufacturing a gel-type air purifying material,

본 발명은 젤타입 차량용 공기정화 물질의 제조방법에 관한 것으로서, 자동차 연료가 연소되면서 발생하는 배기가스의 유해성분을 저감시키기 위한 공기정화 물질에 대한 것이다.The present invention relates to a method of manufacturing an air purification material for a gel type vehicle, and more particularly, to an air purification material for reducing harmful components of exhaust gas generated when a vehicle fuel is burned.

일반적으로 내연기관이 배출하는 기체를 배기가스라 하며, 이산화탄소, 일산화탄소, 탄화수소, 황산화물, 황화수소, 질소산화물, 암모니아 등 무수히 많은 유해물질이 포함되어 있다. 일산화탄소는 연소하는 동안의 산소 부족에서 생기므로, 혼합기를 가솔린 기관의 이론공연비(혼합기가 완전연소하는 공기와 가솔린의 비율)인 14.8% 이상으로 묽게 하면 발생하지 않으며, 탄화수소는 혼합기가 이론공연비 전후에서는 탄화수소의 발생이 가장 적으나, 이론공연비를 넘어서 묽어지면 불꽃의 전파가 중단되어 불완전연소를 일으켜 일산화탄소는 증가한다. 질소산화물은 공기 중의 산소와 질소가 고온에서 반응하여 생성되는 것이므로 이론공연비 전후에서 최대가 된다.Generally, the gas discharged from the internal combustion engine is called exhaust gas and includes a large number of harmful substances such as carbon dioxide, carbon monoxide, hydrocarbons, sulfur oxides, hydrogen sulfide, nitrogen oxides and ammonia. Since carbon monoxide arises from lack of oxygen during combustion, it does not occur when the mixture is diluted to the theoretical air-fuel ratio of the gasoline engine (the ratio of air and gasoline that the mixture is completely burning) to 14.8% or more. Hydrocarbons are the least generated, but if they exceed the stoichiometric air-fuel ratio, the flame propagation is stopped, resulting in incomplete combustion, and carbon monoxide increases. Since nitrogen oxides are produced by the reaction of oxygen and nitrogen in the air at high temperatures, they become maximum at around the theoretical air-fuel ratio.

내연기관은 밀폐된 실린더 속에 연료와 공기의 혼합기를 가두고, 압축·점화하여 연료 속의 탄소를 급속히 연소시킨다. 연소 후 가스는 외부로 배출하고, 다시 신선한 혼합기를 홉입하는데 이 외부로 버리는 기체가 배기가스이다. 배출되는 가스의 양이 많은 것은 자동차의 가솔린 기관이다. 자동차 배기가스 속에는 대기를 오염시키고 인체에도 해로운 성분이 포함되어 있어 새로운 공해로 사회문제가 되었다. The internal combustion engine confines a mixture of fuel and air in a closed cylinder, compresses and ignites, and rapidly burns carbon in the fuel. After the combustion, the gas is discharged to the outside, and a fresh mixer is again introduced, and the gas which is discharged to the outside is exhaust gas. It is the gasoline engine of a car that has a large amount of gas to be discharged. The pollution of the atmosphere in automobile exhaust gas contains harmful substances to the human body, and it became a social problem with the new pollution.

환경오염 및 자원고갈의 문제가 대두됨에 따라, 매연 저감제 또는 매연 저감 장치 등의 연비 개선제 등이 계속 개발되고 있다. 그러나 최근 개발된 매연 저감 조성물도 매연의 감소 정도가 30 내지 40%에 머물며, 연비 개선 효과는 5 내지 10%에 불과하다. 연비 개선 차량의 개발이 되고 있으나, 이에 비해 환경 오염과 자원 고갈의 진행 속도가 현저히 빨라 매연 감소 효과가 탁월한 조성물의 개발이 시급한 실정이다.As environmental pollution and depletion of resources have come to the fore, there has been a continuing development of a fuel economy improving agent such as a soot reducing agent or a soot reducing agent. However, the recently developed soot reducing composition also has a degree of reduction of soot of 30 to 40%, and a fuel economy improvement effect of only 5 to 10%. Development of fuel efficiency improvement vehicles has been developed, but it is urgent to develop a composition which is remarkably faster in environmental pollution and resource depletion and is excellent in smoke reduction effect.

한국공개특허 제10-2011-0130625호(2011.12.06)Korean Patent Laid-Open No. 10-2011-0130625 (2011.12.06)

본 발명의 목적은 자동차 연료가 연소되면서 발생하게 되는 배기가스 유해성분의 비율을 효과적으로 감소시킬 수 있는 젤타입 차량용 공기정화 물질의 제조방법을 제공하는데에 있다.It is an object of the present invention to provide a method of manufacturing an air purification material for a gel type vehicle, which can effectively reduce the ratio of harmful components of exhaust gas generated when a vehicle fuel is burned.

본 발명은 실시예에 따른 젤타입 차량용 공기정화 물질의 제조방법은, (1) 지하수 및 백토를 혼합하고 숙성하여 1차수를 제조하는 단계와, (2) 상기 제조된 1차수에 광물질 및 구연산을 혼합하고 숙성하여 2차수를 제조하는 단계와, (3) 상기 제조된 2차수에 목초액 및 광물질을 혼합하고 숙성하여 3차수를 제조하는 단계와, (4) 상기 제조된 3차수에서 슬러지 또는 침전물을 제거하는 단계와, (5) 상기 슬러지 또는 침전물이 제거된 3차수에 광물질을 혼합하고 숙성하여 4차수를 제조하는 단계와, (6) 상기 제조된 4차수에 600℃로 중탕한 폴리비닐알코올(pva)을 혼합하고 숙성하여 5차수를 제조하는 단계와, (7) 상기 제조된 5차수에 백금을 혼합하고 숙성하여 6차수를 제조하는 단계와, (8) 상기 제조된 5차수, 상기 제조된 6차수 및 백토를 혼합하고 숙성하여 7차수를 제조하는 단계와, (9) 상기 제조된 7차수에 글루카메이트, 하이셀, 쟁탄검, 트리메틸 및 글리세린을 가열하여 혼합한 점증제를 교반하여 젤타입의 공기정화 물질을 제조하는 단계를 포함한다.The method of manufacturing an air purification material for a gel-type vehicle according to an embodiment of the present invention comprises the steps of (1) mixing ground water and clay and aging to prepare a first order, and (2) adding mineral and citric acid to the first order Mixing and aging to produce a second order, (3) mixing the second order water with the wood vinegar and minerals and aging to produce a third order, and (4) adding sludge or precipitate to the prepared third order water. (5) mixing the mineral with the third-order water from which the sludge or precipitate has been removed and aging to produce fourth-order water; (6) adding polyvinyl alcohol pVa, and aging to produce a fifth order; (7) mixing the prepared fifth order with platinum and aging to produce a sixth order; and (8) mixing the prepared fifth order, 6th order and white clay are mixed and aged to obtain 7th order And (9) stirring the glutamate, the high-cell, the granule, the trimethyl, and the glycerin in the prepared seventh order to prepare a gel-type air purifying material by stirring the blended enhancer .

상기 목초액은 나무를 숯으로 만들 때 발생하는 연기가 외부 공기와 접촉하면서 액화되어 떨어지는 것을 채취한 것으로, 목재로 여러 종류의 나무가 사용될 수 있으며, 대나무 목초액, 참나무 목초액 및 은행나무 목초액을 포함하는 것이 바람직하다. 목초액은 약 pH 3.5 정도의 강산성으로, 목초액 내의 높은 농도의 수소이온은 이온화를 활성화시킨다.The wood vinegar is obtained by liquefying the smoke generated when the wood is made into charcoal by contacting with the outside air, and various kinds of wood can be used as the wood. The vine wood vinegar, the oak wood vinegar solution and the ginkgo wood vinegar solution desirable. The vinegar has a strong acidity of about pH 3.5, and the high concentration of hydrogen ions in wood vinegar activates ionization.

바람직하게는, 상기 (1) 단계의 지하수는 pH 5 내지 6이고, 80 내지 100℃에서 가열할 수 있으며, 상기 단계는 지하수 및 백토를 3~5 : 1의 중량비로 혼합하는 것이 효과적이다.Preferably, the groundwater in step (1) is at a pH of 5 to 6 and can be heated at 80 to 100 ° C, and it is effective to mix groundwater and clay at a weight ratio of 3 to 5: 1.

바람직하게는, 상기 (2) 단계는 상기 제조된 1차수 100 중량부에 대하여, 광물질 1 내지 2 중량부 및 구연산 5 내지 10 중량부를 혼합하는 것이 효과적이다.Preferably, in step (2), 1 to 2 parts by weight of the mineral and 5 to 10 parts by weight of citric acid are mixed with 100 parts by weight of the prepared first order water.

바람직하게는, 상기 (3) 단계는 상기 제조된 2차수 100 중량부에 대하여, 목초액 30 내지 50 중량부 및 광물질 1 내지 2 중량부를 혼합하는 것이 효과적이다.Preferably, in step (3), 30 to 50 parts by weight of the vinegar solution and 1 to 2 parts by weight of the mineral are mixed with 100 parts by weight of the second order water.

바람직하게는, 상기 (5) 단계는 상기 제조된 3차수 및 광물질을 50~100 : 1의 중량비로 혼합하는 것이 효과적이다.Preferably, in the step (5), it is effective to mix the produced tertiary ore and the mineral at a weight ratio of 50 to 100: 1.

바람직하게는, 상기 (6) 단계는 상기 제조된 4차수 및 폴리비닐알코올(pva)을 10~20 : 1의 중량비로 혼합하는 것이 효과적이다.Preferably, in the step (6), it is effective to mix the prepared fourth order and polyvinyl alcohol (pva) at a weight ratio of 10 to 20: 1.

바람직하게는, 상기 (7) 단계는 상기 제조된 5차수 100 중량부에 대하여, 백금을 0.03 내지 0.035 중량부를 혼합하는 것이 효과적이다.Preferably, in step (7), it is effective to mix 0.03 to 0.035 parts by weight of platinum with respect to 100 parts by weight of the fifth order water.

바람직하게는, 상기 (8) 단계는 상기 제조된 5차수, 상기 제조된 6차수 및 백토를 1 : 1 : 0.2의 중량비로 혼합하는 것이 효과적이다.Preferably, in the step (8), it is effective to mix the produced fifth order, the prepared sixth order, and clay in a weight ratio of 1: 1: 0.2.

삭제delete

바람직하게는, 상기 광물질은 게르마늄, 토르마린, 일라이트, 흑운모 및 벤토라이트로 이루어진 것이 효과적이며, 상기 숙성은 상온에서 10 내지 20일 동안 보관하는 것이 효과적이다.
Preferably, the mineral is effectively composed of germanium, tourmaline, ilite, biotite and bentrite, and the aging is effectively carried out at room temperature for 10 to 20 days.

특히, '토르마린'은 6각 주상형의 결정을 갖는 붕규산염으로 육방정계에 속하는 천연광물로서 음이온, 미약전류 및 원적외선을 방출한다. 토르마린의 지속적인 음이온 발생은 토르마린 원석이나 분말은 수분에 닿으면 순간적으로 수분에 방전을 하게 되고, 이 때 물은 전기분해되고 물분자는 수소이온과 수산이온으로 분리에 의한다. 분리된 수소이온은 마이너스 전극에 끌려서 방출되는 전자와 결합되어 중화되고 수소가스가 되어 증발하고, 수산 이온은 주변의 물 분자와 결합하여 히드록실 음이온이라는 계면활성물질이 된다. 더불어 토르마린은 원적외선 발생량이 높은 수치로 나타내어 강력한 열효과와 높은 침투력을 가진다.In particular, 'tourmaline' is a borosilicate with hexagonal columnar crystals and releases anions, weak currents and far-infrared rays as natural minerals belonging to the hexagonal system. The tourmaline's continuous negative ion generation causes the tourmaline stone or powder to instantaneously discharge water when it comes into contact with water, where the water is electrolyzed and the water molecule is separated by hydrogen ion and hydroxide ion. The separated hydrogen ions are attracted to the negative electrode to be neutralized by being combined with the released electrons, become hydrogen gas and evaporate, and the hydroxide ion binds to the surrounding water molecules to form a surfactant called hydroxyl anion. In addition, tourmaline has a strong thermal effect and high penetration power because it shows a high value of far infrared ray generation.

한편, 게르마늄, 일라이트, 흑운모 또는 벤토라이트에는 붕소 또는 규소 등의 성분이 포함되어 있어, 광물질 혼합물의 음이온 발생효과를 더욱 상승시킨다.On the other hand, germanium, ilite, biotite or bentrite contain components such as boron or silicon, thereby further enhancing the anion generating effect of the mineral mixture.

본 발명은 차량용 공기정화 물질의 제조방법에 관한 것으로서, 자동차 연료가 연소되면서 배기가스가 발생하게 되는데, 본 발명에 따라 제조된 젤타입 공기정화 물질을 엔진과 엔진 클리너 사이에 주입하게 되면 배기가스에서 발생하는 유해성분의 비율을 효과적으로 감소시킬 수 있다. 또한, 공기정화 물질을 젤타입으로 제조함에 따라 고체 상태인 경우에 비해 차량의 이동 중에도 일정한 성능을 유지시킬 수 있다.The present invention relates to a method of manufacturing an air purifying material for a vehicle, wherein an automobile fuel is combusted to generate an exhaust gas. When the gel-type air purifying material manufactured according to the present invention is injected between an engine and an engine cleaner, It is possible to effectively reduce the proportion of harmful components that are generated. In addition, since the air purifying material is manufactured in the gel type, the performance can be maintained even when the vehicle is moving, as compared with the case of the solid state.

도 1은 본 발명에 따라 제조된 젤타입 차량용 공기정화 물질을 이용한 공기조절시스템의 구성도,
도 2a 및 도 2b는 본 발명에 따른 젤타입 차량용 공기정화 물질을 제조하는 것을 설명하기 위한 흐름도이다.
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a configuration diagram of an air conditioning system using a gel-type vehicle air purifying material manufactured according to the present invention;
2A and 2B are flowcharts for explaining the production of a gel-type vehicle air purification material according to the present invention.

본 발명에 기재된 용어, 기술 등은 특별한 한정이 없는 한, 본 발명이 속하는 기술 분야에서 일반적으로 사용되는 의미로 사용된다. 또한, 본 명세서에 언급된 문헌들은 모두 본 발명을 설명하기 위한 문헌으로 본 명세서에 포함된다.  The terms, techniques, and the like described in the present invention are used in the meaning commonly used in the technical field to which the present invention belongs, unless otherwise specified. In addition, all documents referred to in this specification are included in the present specification as a document for explaining the present invention.

이하, 하기 실시예를 통해 본 발명을 보다 상세하게 설명한다. 다만, 이러한 실시예에 의해 본 발명이 한정되는 것은 아니다.
Hereinafter, the present invention will be described in more detail with reference to the following examples. However, the present invention is not limited by these examples.

도 1은 본 발명에 따라 제조된 차량용 공기정화 물질을 이용한 공기조절시스템의 구성도이다.1 is a configuration diagram of an air conditioning system using an air purifying material for a vehicle manufactured according to the present invention.

도 1을 참조하면, 본 발명에 따라 제조된 차량용 공기정화 물질을 이용한 공기조절시스템(100)은 정화물질통(110) 및 연결관(130)을 포함한다.Referring to FIG. 1, an air conditioning system 100 using a vehicle air purifying material manufactured in accordance with the present invention includes a purifying material container 110 and a connection pipe 130.

정화물질통(110)은 차량용 공기정화 물질을 수용한다. 정화물질통(110)에는 젤타입의 공기정화 물질이 수용되고, 이로부터 발생하는 기체 상태의 정화물질들이 후술하는 연결관(130)으로 공급된다. 이 경우, 차량용 공기정화 물질은 친환경 소재로 구성되는 물질로 차량의 배기가스 중 유해물질을 저감시킬 수 있는 물질로 구성되는 것이 바람직하다. 정화물질통(110)의 개수 및 차량용 공기정화 물질의 종류는 사용자 설정에 의해 달라질 수 있다.The purge cylinder 110 receives the air purifying material for a vehicle. In the purifying material container 110, a gel-type air cleaning material is accommodated, and gaseous purifying materials generated therefrom are supplied to a connection pipe 130, which will be described later. In this case, the air purifying material for a vehicle is preferably made of an eco-friendly material, and is preferably made of a material capable of reducing harmful substances in the exhaust gas of the vehicle. The number of the purifying material cylinders 110 and the type of the air purifying material for a vehicle may vary depending on user settings.

연결관(130)은 일측이 차량의 엔진과 연결되고, 타측이 차량의 에어클리너와 연결되어 배기가스를 배출하는 통로이다. 연결관(130)의 중앙은 튜브를 통해 정화물질통(110)에 연결된다. 이러한 차량용 공기정화 물질이 배기가스 내에 존재하는 유해물질을 제거하는 효과를 가진다.The connection pipe 130 is a passage through which one side is connected to the engine of the vehicle and the other side is connected to the air cleaner of the vehicle to discharge the exhaust gas. The center of the connector tube 130 is connected to the purifier tube 110 through a tube. Such an air purifying material for vehicles has the effect of removing harmful substances present in the exhaust gas.

이하, 정화물질통(110)에 수용되는 젤타입 차량용 공기정화 물질을 제조하기 위한 실시예를 도 2a 및 도 2b를 참조하여 설명하도록 한다.
Hereinafter, an embodiment for manufacturing a gel type vehicle air purification material accommodated in the purifying material container 110 will be described with reference to FIGS. 2A and 2B.

도 2a 및 도 2b는 본 발명에 따른 차량용 공기정화 물질을 제조하는 것을 설명하기 위한 흐름도이다.
2A and 2B are flowcharts for explaining the production of the air purifying material for a vehicle according to the present invention.

<< 실시예Example > >

1. 1차수 제조1. 1st order manufacturing

지하수(철분함량 pH 5~6)를 90℃에서 가열 후, 지하수(1ℓ)에 백토(250g) 비율로 회전교반시킨 후, 15일 정도 상온에서 숙성하여 1차수를 제조한다(S110).
After the ground water (iron content pH 5 ~ 6) is heated at 90 ° C, the ground water (1 l) is agitated at a rate of 250 g of white clay and then aged at room temperature for about 15 days to produce a first order water.

2. 2차수 제조2. 2nd order manufacturing

상기 1차수(1ℓ) + 광물질[게르마늄(4g), 토르마린, 일라이트, 흑운모 및 벤토라이트 각 2.5g 씩] + 구연산(80g, pH 3.15~3.5)을 섞은 후 15일 정도 상온에서 숙성하여 2차수를 제조한다(S120).
After mixing the above first order (1 L) + mineral (germanium (4 g), tourmaline, ilite, biotite and bentrite in an amount of 2.5 g each) + citric acid (80 g, pH 3.15 to 3.5), aged at room temperature for about 15 days, (S120).

3. 3차수 제조3. Third order manufacturing

상기 2차수(1ℓ) + 목초액(400ml) + 광물질[게르마늄(4g), 토르마린, 일라이트, 흑운모 및 벤토라이트 각 2.5g 씩]을 추가로 섞은 후 15일 정도 상온에서 숙성하여 3차수를 제조하고, 슬러지(침전물)를 제거한다(S130).
The second order (1 liter) + wood vinegar (400 ml) + mineral matter (germanium (4 g), tourmaline, ilite, biotite and bentonite each 2.5 g each) were further mixed and aged at room temperature for about 15 days to prepare a third order , And the sludge (precipitate) is removed (S130).

4. 4차수 제조4. Fourth order manufacturing

상기 슬러지(침전물)가 제거된 3차수(1ℓ) + 광물질[게르마늄(4g), 토르마린, 일라이트, 흑운모 및 벤토라이트 각 2.5g 씩]을 추가로 섞은 후 15일 정도 상온에서 숙성하여 4차수를 제조한다(S140).
After addition of the third order (1 L) + minerals (germanium (4 g), tourmaline, ilite, biotite and bentonite each 2.5 g each) from which the sludge (precipitate) has been removed, the mixture is aged at room temperature for about 15 days, (S140).

5. 5차수 제조5. 5th order manufacturing

상기 4차수(1ℓ)에 중탕으로 6시간 동안 600℃까지 가열한 폴리비닐알코올(pva; 60g)을 섞어서 15일 정도 상온에서 숙성하여 5차수를 제조한다. 상기 pva는 직접가열하지 않고 간접가열방식으로 가열한다. 제조된 5차수는 풀과 같은 점성이 높은 물성을 가지게 된다(S150).
Polyvinyl alcohol (pva; 60 g) heated to 600 ° C. for 6 hours in the fourth order (1 L) is mixed with the mixture and aged at room temperature for about 15 days to prepare a fifth order. The pva is heated by indirect heating without direct heating. The manufactured fifth order water has high viscosity properties such as a paste (S150).

6. 6차수 제조6. Sixth order manufacturing

상기 5차수(1ℓ) + 백금(0.33g/ 0.30~0.35g)을 섞어서 15일 정도 상온에서 숙성하여 6차수를 제조한다(S160).
The fifth order (1 L) + platinum (0.33 g / 0.30-0.35 g) are mixed and aged at room temperature for about 15 days to prepare a sixth order (S160).

7. 7차수 제조7. 7th order manufacturing

상기 5차수(1ℓ) + 상기 6차수(1ℓ) + 백토(200g)를 섞어서 15일 정도 상온에서 숙성하여 7차수를 제조한다(S170).
The fifth order (1 L) + the sixth order (1 L) + white clay (200 g) are mixed and aged at room temperature for about 15 days to produce a seventh order (S170).

8. 공기정화 물질 완성8. Completion of air purification material

글루카메이트(50g) + 하이셀(15g) + 쟁탄검(15g) + 트리메틸(15g) + 글리세린(10g)을 섞어서 60~70℃로 가열한 점증제를 생성한 후, 상기 점증제에 상기 7차수(0.2ℓ)를 교반하여 젤타입의 공기정화 물질이 완성된다(S180). 점증제 중 트리메틸은 트리메틸아민 또는 트리메틸암모니아로부터 획득할 수 있다. 기화작용에 의해 공기정화 물질이 기체상태로 차량의 엔진 클리너 측에 유입된다.
After adding the glucamate (50 g) + high cell (15 g) + slugging gum (15 g) + trimethyl (15 g) + glycerin (10 g) to the agitator heated to 60-70 ° C, And the order (0.2 L) is stirred to complete the gel-type air cleaning material (S180). Trimethyl in the gradual phase can be obtained from trimethylamine or trimethylammonia. The air purifying material flows into the engine cleaner side of the vehicle in a gaseous state by the vaporizing action.

이상으로 본 발명 내용의 특정한 부분을 상세히 기술하였는 바, 당업계의 통상의 지식을 가진 자에게 있어서, 이러한 구체적 기술은 단지 바람직한 실시양태일 뿐이며, 이에 의해 본 발명의 범위가 제한되는 것이 아닌 점은 명백할 것이다. 따라서 본 발명의 실질적인 범위는 첨부된 청구항들과 그것들의 등가물에 의하여 정의된다고 할 것이다.While the present invention has been particularly shown and described with reference to specific embodiments thereof, those skilled in the art will appreciate that such specific embodiments are merely preferred embodiments and that the scope of the present invention is not limited thereby. something to do. It is therefore intended that the scope of the invention be defined by the claims appended hereto and their equivalents.

100 : 공기조절시스템 110 : 정화물질통
130 : 연결관
100: air conditioning system 110: purge tank
130: connector

Claims (5)

(1) 지하수 및 백토를 혼합하고 숙성하여 1차수를 제조하는 단계;
(2) 상기 제조된 1차수에 광물질 및 구연산을 혼합하고 숙성하여 2차수를 제조하는 단계;
(3) 상기 제조된 2차수에 목초액 및 광물질을 혼합하고 숙성하여 3차수를 제조하는 단계;
(4) 상기 제조된 3차수에서 슬러지 또는 침전물을 제거하는 단계;
(5) 상기 슬러지 또는 침전물이 제거된 3차수에 광물질을 혼합하고 숙성하여 4차수를 제조하는 단계;
(6) 상기 제조된 4차수에 600℃로 중탕한 폴리비닐알코올(pva)을 혼합하고 숙성하여 5차수를 제조하는 단계;
(7) 상기 제조된 5차수에 백금을 혼합하고 숙성하여 6차수를 제조하는 단계;
(8) 상기 제조된 5차수, 상기 제조된 6차수 및 백토를 혼합하고 숙성하여 7차수를 제조하는 단계; 및
(9) 상기 제조된 7차수에 글루카메이트, 하이셀, 쟁탄검, 트리메틸 및 글리세린을 가열하여 혼합한 점증제를 교반하여 젤타입의 공기정화 물질을 제조하는 단계를 포함하는 젤타입 차량용 공기정화 물질의 제조방법.
(1) mixing ground water and clay and aging to produce first order water;
(2) Mixing the mineral and citric acid in the prepared primary water and aging to prepare a secondary water;
(3) mixing the vinegar liquid and the mineral to the prepared second water and aging to prepare a third water;
(4) removing sludge or sediment from the prepared tertiary water;
(5) mixing the mineral with the third order water from which the sludge or precipitate has been removed and aging to produce fourth order water;
(6) Mixing polyvinyl alcohol (pva), which has been heated at 600 ° C., with the above-prepared quaternary water and aging to prepare a fifth order water;
(7) mixing the prepared fifth order with platinum and aging to prepare sixth order;
(8) mixing the prepared fifth order, the prepared sixth order and white clay and aging to produce a seventh order; And
(9) A method of manufacturing a gel-type vehicle air purification apparatus, comprising the steps of: (1) preparing a gel-type air-cleaning material by stirring glucakamate, high-cell, zirconium, trimethyl, &Lt; / RTI &gt;
제1항에 있어서, 상기 (1) 단계의 지하수는 pH 5 내지 6이고, 80 내지 100℃에서 가열한 것을 특징으로 하는 젤타입 차량용 공기정화 물질의 제조방법.The method according to claim 1, wherein the groundwater in step (1) is heated at a temperature of 80 to 100 ° C at a pH of 5 to 6. 제1항에 있어서, 상기 (1) 단계는 지하수 및 백토를 3~5 : 1의 중량비로 혼합하는 것을 특징으로 하는 젤타입 차량용 공기정화 물질의 제조방법.The method of claim 1, wherein the step (1) comprises mixing groundwater and clay at a weight ratio of 3 to 5: 1. 제1항에 있어서, 상기 (2) 단계는 상기 제조된 1차수 100 중량부에 대하여, 광물질 1 내지 2 중량부 및 구연산 5 내지 10 중량부를 혼합하는 것을 특징으로 하는 젤타입 차량용 공기정화 물질의 제조방법.The method according to claim 1, wherein in step (2), 1 to 2 parts by weight of mineral and 5 to 10 parts by weight of citric acid are mixed with 100 parts by weight of the prepared first order water. Way. 제1항에 있어서, 상기 (9) 단계는 상기 제조된 7차수 100 중량부에 대하여, 글루카메이트 20 내지 30 중량부, 하이셀, 쟁탄검, 트리메틸 및 글리세린은 각각 5 내지 10 중량부를 60 내지 70℃로 가열 혼합한 점증제를 혼합하는 것을 특징으로 하는 젤타입 차량용 공기정화 물질의 제조방법.[7] The method of claim 1, wherein the step (9) comprises: 20 to 30 parts by weight of glucamate, 5 to 10 parts by weight of high-cellulose, glutaraldehyde, trimethyl and glycerin, And mixing the viscous agent heated and mixed at 70 占 폚.
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