KR101796081B1 - Method for manufacturing sintered ore and apparatus for sintering - Google Patents
Method for manufacturing sintered ore and apparatus for sintering Download PDFInfo
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- KR101796081B1 KR101796081B1 KR1020150149450A KR20150149450A KR101796081B1 KR 101796081 B1 KR101796081 B1 KR 101796081B1 KR 1020150149450 A KR1020150149450 A KR 1020150149450A KR 20150149450 A KR20150149450 A KR 20150149450A KR 101796081 B1 KR101796081 B1 KR 101796081B1
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- sintering
- sintering process
- natural gas
- bogie
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B21/00—Open or uncovered sintering apparatus; Other heat-treatment apparatus of like construction
- F27B21/06—Endless-strand sintering machines
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/10—Reduction of greenhouse gas [GHG] emissions
- Y02P10/143—Reduction of greenhouse gas [GHG] emissions of methane [CH4]
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- Manufacture And Refinement Of Metals (AREA)
Abstract
The method for producing sintered ores according to the present invention comprises the steps of charging a raw material for sintering for producing sintered ores in a truck, moving the truck in which the sintered raw material is charged to the direction of ignition, igniting the flame on the surface layer, And a sintering reaction is carried out while moving the bogie on the upper side of the plurality of windboxes arranged from the one side to the end point of the sintering process by the ignition to manufacture the sintered ores. When the sludge from the ignition furnace to the end point of the sintering process is referred to as sintering process section, synthetic natural gas (SNG) is supplied to the sludge during the movement of the sludge during the early stage of the sintering process ≪ / RTI >
Therefore, according to the embodiment of the present invention, temperature fluctuations of the upper and lower portions of the raw material layer can be reduced by supplying the heat source gas as a carrier in the early stage of the sintering process and supplementing the heat source. Thus, the sintered ores having uniform temperature distribution in the height direction of the raw material layer and having uniform strength and reductivity can be produced.
Description
More particularly, the present invention relates to a sintering apparatus capable of improving the quality and productivity of sintered ores and reducing pollutant emissions, and a method of manufacturing sintered ores.
The sinter ore used as a raw material in the blast furnace is produced by mixing iron ore and a binder which is a partial coke (or anthracite), then burning the coke and sintering the iron ore with the heat of combustion.
A general sintering plant for producing sintered ores is composed of a top light hopper in which upper light is stored, a surge hopper in which a mixed raw material is mixed after an iron ore raw material and a heat source coke are mixed, A plurality of bogies to be delivered in the process advancing direction, a conveyor for transferring a plurality of bogies in the process advancing direction, and a plurality of bogies disposed in the upper side of the bogie conveyed by the conveyor in the process advancing direction, A plurality of windboxes arranged in a line along which a plurality of bogies are arranged in one direction and are transported in a process advancing direction in a sparking ignition, the ducts being connected to the ends of the plurality of windboxes, And a blower (not shown) connected to the duct to generate a suction force.
On the other hand, the productivity (t / d / m 2 ) of the sintered ores in the sintering machine expresses the sintered ores generated in one day according to the unit area. At this time, the productivity of the sintering machine is determined by the width or length of the sintering machine, the height (or thickness) of the raw material layer to be charged into the conveyer, the charging density of the raw material layer, and the sintering time. In order to increase the production of sintered ore, the height of the raw material layer to be charged to the single rail is important, and the height of 800mm or less has been increased to 800mm or more. However, the increase in the height of the raw material layer lowers the air permeability of the raw material layer and causes a temperature deviation in the height direction of the raw material layer, which is a cause of deterioration in quality.
Further, generally, in the initial stage of sintering, since the width of the combustion layer in the raw material layer is narrow and the outside air at room temperature is directly introduced, the cooling progresses simultaneously with the sintering reaction. Thus, the amount of heat required for forming the sintered ores is insufficient at the initial stage of sintering. As the sintering process time elapses, the sucked outer product is heated and passes through the sintered high temperature layer to increase the temperature. This heat transfers sensible heat to the lower portion of the raw material layer, thereby causing an excessive heat phenomenon in the lower portion of the raw material layer .
The temperature deviation of the upper and lower portions of the raw material layer tends to become worse as the height of the raw material layer increases.
In order to reduce the temperature deviation of the upper and lower portions of the raw material layer as described above, oxygen, gaseous fuel, and liquid fuel are supplied to the upper portion of the raw material layer in the sintering process and the amount of the binder material is decreased in the lower portion, A method for forming a combustion zone has been proposed. However, in the case of liquid fuel, there is a risk of explosion, and in the case of the binder, it is difficult to charge the upper part and the lower part with a deviation, and a problem of insufficient calorie is caused not only in the lower part but also in the middle part.
In another method, a method of preparing blast furnace gas coke oven gas, blast furnace / coke mixture gas, city gas, natural gas, methane gas, ethane gas, propane gas, However, the above-mentioned gases have C, S, and N components, and when they are combined with oxygen, there is a problem of generating CO 2, SO x , and NO x , which are environmental regulation substances.
Therefore, research is needed to reduce temperature variations in the upper and lower portions of the raw material layer without generating environmental regulation components.
The present invention provides a sintered light production method and sintering apparatus capable of improving the quality and productivity of sintered ores and reducing emission of pollutants.
The present invention provides a sintered light producing method and a sintering apparatus capable of reducing a height direction temperature deviation of a raw material layer.
A method for producing sintered ores according to the present invention comprises the steps of charging raw materials for sintering for producing sintered ores; A step of igniting the flame on the surface layer by moving the bogie loaded with the sintering compound material in the direction of ignition; And a step in which the sintering reaction is carried out while moving the bogies with ignited flames on the upper side of the plurality of windboxes arranged from the one side to the end point of the sintering process by the ignition to manufacture the sintered ores, Wherein the sintering process is carried out in the sintering process from the ignition furnace to the end point of the sintering process, ; Synthetic Natural Gas).
During the sintering process, the synthetic gas is supplied to the bogie during the movement of the bogie from the one side to the one-third point of the ignition.
The synthetic gas is supplied to the bogie while the bogie moves from 1/6 to 1/3 of the sintering process.
In supplying the synthetic natural gas, it is supplied together with the outside air, and the ratio of the outside air to the synthetic natural gas is adjusted to 8: 1 to 15: 1.
The sintering blending raw material includes iron ore and a binder, and a heat amount required to produce the sintering blend is supplied from the binder and the synthetic natural gas.
The feed rate per hour of the synthetic natural gas is adjusted to provide a caloric value per hour equal to or less than 5 kg / ts of the binder.
The sintering apparatus according to the present invention is characterized in that each of the sintering material is charged with a plurality of movable bogies; An ignition means for spraying a flame on an upper portion of the sintering raw material charged into the truck; A plurality of windboxes positioned below the plurality of bogies and arranged in one direction to provide a suction force to each of the plurality of bogies on a path along which the plurality of bogies move; A light distribution unit located at one end of the moving path of the bogie and discharging sintered light from the bogie; (SNG) is added to the bogie which is installed in an early stage of the sintering process section and moves downward when the sintering process section is referred to as the sintering process section from one side of the ignition path. Synthetic Natural Gas).
The hood is extended from the one side of the ignition to 1/3 of the sintering process.
The hood is extended from 1/6 to 1/3 of the sintering process.
And a SNG storage unit connected to the hood to supply the synthetic natural gas to the hood. The hood sucks the ambient air and the synthetic natural gas and supplies the natural gas to the vehicle.
Wherein the amount of heat required for producing the sintered ores is supplied from the binder and the synthetic natural gas, and the supply amount of the synthetic natural gas per hour is not more than 5 kg / t · s of the binder Lt; / RTI > to provide a calorie per hour.
According to the embodiment of the present invention, temperature fluctuations in the upper and lower portions of the raw material layer can be reduced by supplying the heat source gas in the early stage of the sintering process and replenishing the heat source. Thus, the sintered ores having uniform temperature distribution in the height direction of the raw material layer and having uniform strength and reductivity can be produced.
In addition, in the present invention, the use of the binder for generating environmental pollutants is reduced compared to the prior art, and SNG gas, which does not cause environmental pollution, is supplied to the heat source gas to supplement the heat source. Accordingly, it is possible to reduce the temperature variation of the raw material layer and the lower layer while reducing the generation of environmental pollutants in the sintering process.
1 is a view schematically showing a sintering apparatus according to an embodiment of the present invention;
2 is a schematic view showing a sintering reaction layer in a general sintering machine
Fig. 3 is a view showing the temperature with reference to a plurality of windboxes in order to explain the insufficient amount of heat in the sintering process section
4 is a view for explaining the sintering reaction layer, FFL and FBL in the sintering process, and illustrating the SNG gas supply position by the method according to the embodiment of the present invention
5 is a view for explaining the position of feeding the hood and the SNG gas in the sintering apparatus according to the embodiment of the present invention;
Hereinafter, embodiments of the present invention will be described in detail. It should be understood, however, that the invention is not limited to the disclosed embodiments, but is capable of other various forms of implementation, and that these embodiments are provided so that this disclosure will be thorough and complete, It is provided to let you know completely.
1 is a view schematically showing a sintering apparatus according to an embodiment of the present invention. 2 is a schematic view showing a sintering reaction layer in a general sintering machine. Fig. 3 is a graph showing the temperatures based on a plurality of windboxes in order to explain the lack of heat in the sintering process section. Fig. 4 is a view for explaining the sintering reaction layer, FFL and FBL in the sintering process, and explaining the SNG gas supply position by the method according to the embodiment of the present invention. 5 is a view for explaining a supply position of the hood and the SNG gas in the sintering apparatus according to the embodiment of the present invention.
Referring to FIG. 1, a sintering apparatus according to an embodiment of the present invention includes a
The sintering apparatus according to an embodiment of the present invention includes a
The raw material for producing sintered ores, that is, the sintered raw materials to be charged into the
The
The
When the flame is sprayed onto the sintered blend material (hereinafter referred to as the raw material layer) charged into the
As described above, when the flame is injected from the
That is, as shown in FIG. 2, the region in which the sintering is performed from the
On the other hand, at the initial stage of sintering which passes through the
To explain more specifically, the sintering process section from the
This temperature deviation can be explained with reference to a plurality of
The temperature difference between the top and bottom of the raw material layer can also be found from the slope difference between FFL and FBL shown in Figs. In order to improve the quality of the sintered ore and the productivity of the sintered ores, it is preferable that the sintering reaction layer in the section between FFL and FBL has a uniform width. To do this, the slope of the FBL must be made parallel or as close as possible to the slope of the FFL, which can be overcome by solving the lack of heat in the upper layer of the feedstock.
A graph showing FFL and FBL according to the movement direction of the
When FBL and IFBL are shown on one graph as shown in FIG. 4, a contact point where FBL and IFBL meet occurs, and the position of the contact in the X axis direction is one third (P2) of the sintering process section. On the basis of the 1/3 point (P2) of the sintering process section, there is a phenomenon that the amount of heat in the upper part of the raw material layer is insufficient in the section before the 1/3 point (P2) A phenomenon that the amount of heat in the lower part of the layer becomes excessive occurs. More specifically, from the 1/6 point (P1) to the 1/3 point (P2) of the sintering process section, the amount of heat in the upper part of the raw material layer is insufficient, and after the 1/3 point (P2) In the latter part of the process, the excessive amount of heat is generated in the lower part of the raw material layer.
In the present invention, a
At this time, the gas for the heat source may be supplied from one side of the
For example, suppose that thirty windboxes are arranged from just below the
In the present invention, as shown in FIG. 1, a
When the gas for the heat source is supplied from the first side to the third side (P2) of the
As another example, when the gas for the heat source is supplied from the 1/6 point (P1) to the 1/3 point (P2) of the sintering process section, the
In the present invention, by supplying the gas for the heat source in the early stage of sintering, the problem of insufficient heat of the upper portion of the raw material layer is solved, and the temperature deviation between the upper and lower layers of the raw material layer is reduced or the temperature is made uniform. Therefore, it is possible to reduce the difference in the reducing property and the strength in accordance with the temperature variation in the height direction of the raw material layer.
As described above, in the embodiment of the present invention, synthetic natural gas (hereinafter referred to as SNG (Synthetic Natural Gas)) is used as the heat source gas for supplying the heat source gas at the beginning of the sintering.
SNG is a gas obtained by refining and gasifying solid coal, which is mainly composed of methane (CH 4 ), called synthetic natural gas or alternative natural gas. On the other hand, LNG is liquefied by cooling methane obtained by refining natural gas, and its production method, composition and composition are different from SNG.
Table 1 shows the general composition of SNG. Referring to Table 1, the SNG includes elements CH 4 , CO 2 , CO, H 2 and H 2 O that generate heat by reaction with oxygen, and CH 4 is the most abundant, .
Table 2 shows the composition of anthracite coal, which is generally used as a raw material for binders in sintered blend materials, by product.
weight%
weight%
weight%
weight%
weight%
weight%
Content (% by weight)
(weight%)
(weight%)
(weight%)
(weight%)
As shown in Table 1 and Table 2, SNG does not include sulfur (S), which is a problem in environmental pollution, and N content is extremely low (Table 1). However, in case of anthracite coal, it is the main cause of environmental pollution. Regulated material contains sulfur (S), and nitrogen (N) is also contained in a larger amount than SNG. That is, the coal the sulfur (S) and nitrogen (N) when there is a reaction with oxygen, SO X, NO X occurs, which is a substance for SO X, NO X is caused environmental pollution. However, the SO X, it sulfur (S) and nitrogen (N) for generating a large amount of NO X is contained in the coal, the use of the hard coal is causing environmental pollution.
Accordingly, in the present invention, the ratio of the binder used as a binder for the purpose of providing a heat source for combustion is reduced, and SNG gas is supplemented, thereby minimizing or preventing generation of environmental pollutants and solving the problem of insufficient heat source.
Table 3 shows the calorific value of general binder composed of coke and anthracite, and Table 4 shows calorific value according to binder and SNG usage.
(kg / t · s)
(kcal / kg)
Usage (t / hr)
(Gcal / hr)
(Coke + anthracite)
Generally, the binder has a calorific value of 6000 to 7000 kcal / kg (see Table 3), and the SNG gas has a caloric value of 9000 to 10000 kcal / Nm 3 , although the binder depends on the completion and proportion of coke and anthracite coal to be.
Referring to Table 4, when the amount of binder used is 1 kg / t · s, the amount of heat per hour is 4.69 Gcal / hr. When the amount of SNG gas used is 100 Nm 3 / hr, the amount of heat per hour is 1 Gcal / hr. In the present invention, SNG gas is supplied in order to compensate for the decrease in heat quantity due to the decrease in the amount of binder used. That is, when the amount of binder used is decreased by 1 kg / t · s, the amount of heat of 4.69 Gcal / hr per hour decreases. Therefore, it is true that the SNG is supplied at 469 Nm 3 / hr from the viewpoint of heat quantity conservation. 30% to 100% of 469 Nm 3 / hr is supplied. In other words, the quantity of heat loss is determined according to the amount of use of the binder, and the quantity of heat loss is the maximum (100%) quantity to be supplemented by the supply of SNG. In the present invention, the SNG gas is supplied to compensate for the amount of heat of 30% to 100% of the amount of decrease in the amount of heat.
For example, when the binder is reduced to 1 kg / t · s, the calorie reduction amount is 4.69 Gcal / hr. In order to compensate for this, in the present invention, 30 to 100% of the calorie of 4.69 Gcal / hr is supplemented. That is, when the binder is reduced by 1 kg / ts, the amount of heat decrease is 4.69 Gcal / hr, so SNG gas is supplied at 140 Nm 3 / hr to 469 Nm 3 / hr.
In this way, the adjustment of between 30% and 100% without compensating for 100% of the unconditional reduction in the amount of heat is intended to prevent overheating of the lower layer.
Further, in the present invention, when the amount of binder used is reduced compared to the conventional method, and the amount of decrease of the binder is 5 kg / ts or less, more preferably 5 kg / ts or less .
Even if the SNG gas is supplied, if oxygen is insufficient, incomplete combustion may occur. Therefore, sufficient outside air must be sucked together with the SNG gas, and the ratio of the outside air to the SNG is set to 8: 1 to 15: 1. When the ratio of the outside air to the SNG is less than 8: 1, there is a problem that the oxygen is not sufficient and the combustion can not be complete, resulting in incomplete combustion.
As described above, limiting the amount of decrease of the binder to 5 kg / t · s or less and limiting the outside-air-to-SNG ratio to 15: 1 or less is due to the limit of the air volume that can be sucked in the
This is because, when the amount of decrease of the binder is decreased to exceed 5 kg / ts, the SNG gas must be supplied by the amount of the reduced binder, and the amount of outdoor air supplied to the
Accordingly, in the present invention, 23.45 Gcal / hr of heat of 5 kg / ts of the binder is supplied at the maximum (100%) and at least 30% in supplementing the heat source by supplying the gas SNG for the heat source. That is, the supply amount (100%) of the SNG is 703.5 Nm 3 / hr (30%) to 2,345 Nm 3 / hr (100%), and the outer space to SNG ratio is 8: 1 to 15: 1.
More preferably, the supply amount (100%) of SNG is 562.8 Nm 3 / hr (30%) to 1,876 Nm 3 / hr (100%) when the binder is the maximum (100%) 4 kg / At this time, the ratio of the outside air to the SNG is 8: 1 to 15: 1.
Hereinafter, a sintering apparatus according to an embodiment of the present invention and a method for manufacturing sintered ores and reduced iron using the same will be described with reference to FIGS. 1 to 6. FIG.
First, prepare an assembly for producing sintered ores. That is, the iron ore raw material, the binder, the minor raw material limestone (CaCO 3 ), and water are mixed in a mixer, and they are assembled and pre-assembled into particles having an average particle size of 2 to 3 mm. Here, the binder includes a mixture of coke and anthracite, and the binder is mixed or blended in a reduced amount of less than 5 kg / t · s. The assembly is then stored in the drum feeder.
Thereafter, a plurality of
The
The sintering reaction proceeds from the surface layer of the raw material layer to the downward direction as the
The bogies from which the flame is ignited move from the
The SNG supply section is not limited to the above-described example, and SNG gas may be supplied from the 1/6 point (P1) to the 1/3 point (P2) of the sintering process section. That is, when the
Here, the supply amount of the SNG gas is determined and supplied according to the decrease amount of the binder as described above. And together with the SNG gas, the outside air is supplied together so that the ambient air to SNG gas is between 8: 1 and 15: 1.
SNG gas and air is fed to the
100: Dream feeder 200: By ignition
300: Bogie 400: Hood
600: Wind Box
Claims (11)
A step of igniting the flame on the surface layer by moving the bogie loaded with the sintering compound material in the direction of ignition;
A step in which the sintering reaction is performed while moving the bogies with ignited flames on the upper side of the plurality of wind boxes arranged from one side to the end point of the sintering process by the ignition to produce sintered ores;
/ RTI >
In moving the bogie from one side to the end of the sintering process by the ignition,
A step of supplying synthetic natural gas (SNG) to the bogie during the movement of the bogie during the initial section of the sintering process section from the ignition furnace to the end point of the sintering process;
/ RTI >
In supplying the synthetic natural gas,
Supplying the synthetic natural gas to the truck while the truck moves from the one side of the ignition to the one-third point during the sintering process,
Wherein the sintering raw material comprises iron ores and a binder,
The amount of heat required to produce the sintered ores is supplied from the binder and the synthetic natural gas,
The feed rate of the synthetic natural gas per hour is controlled to provide more than 30% and less than 100% of the amount of heat per hour corresponding to 5 kg / ts or less of the binder,
Wherein the ratio of the outside air to the synthetic natural gas is adjusted to 8: 1 to 15: 1 in supplying the synthetic natural gas together with the outside air.
Wherein the synthetic gas is supplied to the bogie while the bogie moves from 1/6 to 1/3 of the sintering process.
An ignition means for spraying a flame on an upper portion of the sintering raw material charged into the truck;
A plurality of windboxes positioned below the plurality of bogies and arranged in one direction to provide a suction force to each of the plurality of bogies on a path along which the plurality of bogies move;
A light distribution unit located at one end of the moving path of the bogie and discharging sintered light from the bogie;
(SNG) is added to the bogie which is installed in an early stage of the sintering process section and moves downward when the sintering process section is referred to as the sintering process section from one side of the ignition path. Synthetic Natural Gas);
Lt; / RTI >
The hood is extended from the one side of the ignition to 1/3 of the sintering process, Supplying the synthetic natural gas together with ambient air,
Wherein the sintering raw material comprises iron ores and a binder,
The amount of heat required to produce the sintered ores is supplied from the binder and the synthetic natural gas,
The amount of the synthetic natural gas supplied per hour is not less than 30% and less than 100% of the amount of heat per hour corresponding to 5 kg / t · s or less of the binder Lt; / RTI >
Wherein the ratio of the outside air to the synthetic natural gas is adjusted to 8: 1 to 15: 1.
Wherein the hood extends from 1/6 to 1/3 of the sintering process.
And a SNG storage unit connected to the hood and supplying synthetic natural gas to the hood,
Wherein the hood sucks the outside air and the synthetic natural gas and supplies the air to the car.
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