KR101793786B1 - Continuous in situ particle depositing circular knitting machine and method therefor - Google Patents

Continuous in situ particle depositing circular knitting machine and method therefor Download PDF

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Publication number
KR101793786B1
KR101793786B1 KR1020150150531A KR20150150531A KR101793786B1 KR 101793786 B1 KR101793786 B1 KR 101793786B1 KR 1020150150531 A KR1020150150531 A KR 1020150150531A KR 20150150531 A KR20150150531 A KR 20150150531A KR 101793786 B1 KR101793786 B1 KR 101793786B1
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KR
South Korea
Prior art keywords
catalyst
cloth
particle
catalyst particle
particles
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KR1020150150531A
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Korean (ko)
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KR20170049790A (en
Inventor
이화조
변정훈
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영남대학교 산학협력단
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Priority to KR1020150150531A priority Critical patent/KR101793786B1/en
Priority to PCT/KR2016/010450 priority patent/WO2017073909A1/en
Publication of KR20170049790A publication Critical patent/KR20170049790A/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B1/00—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means
    • B05B1/02—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to produce a jet, spray, or other discharge of particular shape or nature, e.g. in single drops, or having an outlet of particular shape
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B5/00—Electrostatic spraying apparatus; Spraying apparatus with means for charging the spray electrically; Apparatus for spraying liquids or other fluent materials by other electric means
    • B05B5/025—Discharge apparatus, e.g. electrostatic spray guns
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04B—KNITTING
    • D04B9/00—Circular knitting machines with independently-movable needles
    • D04B9/42—Circular knitting machines with independently-movable needles specially adapted for producing goods of particular configuration
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B1/00—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating
    • D06B1/02—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by spraying or projecting
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B1/00—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating
    • D06B1/10—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by contact with a member carrying the treating material
    • D06B1/14—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by contact with a member carrying the treating material with a roller
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/04—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of yarns, threads or filaments
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/49—Oxides or hydroxides of elements of Groups 8, 9, 10 or 18 of the Periodic System; Ferrates; Cobaltates; Nickelates; Ruthenates; Osmates; Rhodates; Iridates; Palladates; Platinates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles

Abstract

A particle-coated circular knitting machine according to an embodiment of the present invention includes: a catalyst particle supplying part for injecting a catalyst particle solution onto a surface of a woven cloth; A catalyst particle coating unit for pressing the cloth having the catalyst particles attached thereon so as to allow the catalyst particles to adhere thereto; An electroless plating unit for impregnating a plating solution coated with the catalyst particle coating unit 200 in a plating bath for a predetermined time to coat the metal particles on the cloth; And a treatment section for treating the catalyst dispersant and the electroless plating solution residue from the metal particle coated cloth, wherein the catalyst particle supplying section is formed by an electrospray method using a disc-type nozzle The catalyst particles are injected in a circumferential direction and one end of a guide facing the disk-shaped nozzle is grounded so that electrostatically charged catalyst particle droplets move in the guide direction, and the disk- And a conductor is arranged in a manner to look at the guide, and a voltage can be applied to each nozzle constituting the disk-shaped nozzle.

Figure R1020150150531

Description

TECHNICAL FIELD [0001] The present invention relates to a particle coating type circular knitting machine, and a method of coating fibrous particles using the circular knitting machine. BACKGROUND ART < RTI ID = 0.0 >

The present invention relates to a particle coating type circular knitting machine and a method for coating metal particles on a fiber using the particle coating type circular knitting machine, And a method for coating fibrous particles using the same.

A wearable device is an electronic device that is worn or attached to the body, such as glasses, watches, and accessories. It can be carried around like a part of the body and is easy to use, and has the advantage of being able to communicate with the user continuously.

Fiber is the most common human interface, accounting for more than 70% of the materials in contact with the human body. It is flexible and stretchable. In particular, there is an increasing need for development of fibrous coating technology for wearable device applications.

Most conventional fiber coating technology adopts a method of manufacturing a functional material paste using an adhesive material and coating the same on a single fiber.

When a functional fiber-coated fiber strand is subsequently woven to produce a functional cloth, there is a problem that the functional material is detached or the loom is contaminated during the weaving.

In addition, such a method is not suitable for imparting functionality to an already woven fabric, and thus there are limitations in its application.

Also, there is a problem in that there is no technique for coating a functional material and a dry / semipurpose eco-friendly technique for coating a particle such as a metal on a fiber when continuous or woven cloth is woven or stretched.

Patent Publication No. 10-2015-0007681

A particle-coated circular knitting machine according to an embodiment of the present invention and a method of coating a fibrous particle using the circular knitting machine according to an embodiment of the present invention aim at solving the above-mentioned problems.

A particle coating type circular knitting machine capable of instantly continuously coating fine particles such as fibrous metal through a particle coating system in a circular knitting machine to produce functional fibers, and a method of coating fibrous particles using the circular knitting machine.

The present invention has been made in view of the above problems, and it is an object of the present invention to provide an apparatus and method for controlling the same.

A particle-coated circular knitting machine according to an embodiment of the present invention includes: a catalyst particle supplying part for injecting a catalyst particle solution onto a surface of a woven cloth; A catalyst particle coating unit for pressing the cloth having the catalyst particles attached thereon so as to allow the catalyst particles to adhere thereto; An electroless plating unit for impregnating a plating solution coated with the catalyst particle coating unit 200 in a plating bath for a predetermined time to coat the metal particles on the cloth; And a treatment section for treating the catalyst dispersant and the electroless plating solution residue from the metal particle coated cloth, wherein the catalyst particle supplying section is formed by an electrospray method using a disc-type nozzle The catalyst particles are injected in a circumferential direction and one end of a guide facing the disk-shaped nozzle is grounded so that electrostatically charged catalyst particle droplets move in the guide direction, and the disk- And a conductor is arranged in a manner to look at the guide, and a voltage can be applied to each nozzle constituting the disk-shaped nozzle.

delete

The catalyst particle supplying unit may inject the catalyst particles in a colloidal state onto the surface of the cloth.

The catalyst particle supplying unit may inject the catalyst particles through the ultrasonic reducing unit in an ionic state or spray a reducing agent onto the surface of the cloth.

The catalyst particle supply unit may spray the catalyst particles onto the surface of the cloth with metal nanoparticles.

The catalyst particle coating unit may heat-press the cloth to which the catalyst particles are attached to allow the catalyst particles to adhere to the cloth.

A method of coating a fibrous particle using a particle coated circular knitting machine according to an embodiment of the present invention includes: spraying a catalyst particle solution onto a surface of a cloth to which the catalyst particle supplying section is woven; A catalyst particle coating section for pressing the catalyst particle-attached cloth to adhere the catalyst particle to the cloth; Coating the metal particles on the cloth by impregnating a plating solution coated with the catalyst particle coating portion on the plating bath for a predetermined time after electroless plating; And treating the catalyst dispersant and the electroless plating solution residue from the cloth coated with the metal particles, wherein the step of spraying the catalyst particle solution includes a step of supplying the catalyst particle supply part with a plurality of conductors Type nozzles 150 are arranged in such a manner that they are arranged in a manner of looking at a guide and are capable of applying a voltage to each of the nozzles, the catalyst particles are injected in a circumferential direction, The one end of the guide facing the guide 150 is grounded so that the electrostatically charged catalyst particle droplet moves in the guide direction and the catalyst particle solution is sprayed onto the surface of the cloth in an electrospray manner.

delete

In the step of spraying the catalyst particle solution, the catalyst particle supplying section may inject the catalyst particle in a colloidal state onto the surface of the cloth.

In the step of spraying the catalyst particle solution, the catalyst particle supplying section may spray the catalyst particle in the ion state through the ultrasonic reducing section or by adding a reducing agent to the surface of the cloth.

In the step of spraying the catalyst particle solution, the catalyst particle supplying section may spray the catalyst particle onto the surface of the cloth with metal nanoparticles.

In the step of attaching the catalyst particles to the cloth, the catalyst particle coating unit may heat-press the cloth to which the catalyst particles are attached to attach the catalyst particles to the cloth.

The particle-coated type circular knitting machine according to an embodiment of the present invention and the method of coating the fibrous particles using the particle knitting machine according to the present invention have the effect of instantly coating the fine particles such as fibrous metal through the particle coating system in the circular knitting machine to produce functional fibers have.

Also, it can be expected to solve the problems such as deterioration of physical properties and contamination of circular knitting machine due to use of pressure-sensitive adhesive, which is a technical limitation of conventional fiber coating technology.

Furthermore, wet process technology can be replaced and improved by implementing environmentally friendly dry / semi-dry coating technology.

The effects of the present invention are not limited to those mentioned above, and other effects not mentioned can be clearly understood by those skilled in the art from the following description.

1 is a schematic view of a particle coated circular knitting machine according to an embodiment of the present invention.
2 is a block diagram of a particle-coated circular knitting machine according to an embodiment of the present invention.
3 is a schematic view illustrating a process of attaching metal particles in an electroless plating portion of a particle-coated ring knitting machine according to an embodiment of the present invention.
4 is a flowchart illustrating a method of coating fibrous particles using a particle-coated circular knitting machine according to an embodiment of the present invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Reference will now be made in detail to the preferred embodiments of the present invention, examples of which are illustrated in the accompanying drawings, wherein like reference numerals refer to the like elements throughout.

In the following description, well-known functions or constructions are not described in detail since they would obscure the invention in unnecessary detail. It is to be noted that the accompanying drawings are only for the purpose of facilitating understanding of the present invention, and should not be construed as limiting the scope of the present invention with reference to the accompanying drawings.

Hereinafter, a particle-coated circular knitting machine according to an embodiment of the present invention will be described with reference to FIGS. 1 and 2. FIG.

FIG. 1 is a schematic view of a particle coating type circular knitting machine according to an embodiment of the present invention, and FIG. 2 is a configuration diagram of a particle coating type circular knitting machine according to an embodiment of the present invention.

1 and 2, a particle coating type circular knitting machine according to an embodiment of the present invention includes a catalyst particle supplying unit 100, a catalyst particle coating unit 200, an electroless plating unit 300, and a treatment unit 400 .

The catalytic particle coating unit 200 is disposed at the center of the circular knitting machine and the electroless plating unit 300 is provided at the bottom of the circular knitting machine. So that the coating of the particles can be continuously performed without affecting the operation of the circular knitting machine.

The catalyst particle feeder 100 injects the catalyst particle solution onto the surface of the woven cloth, which is located on top of the particle-coated circular knitting machine according to an embodiment of the present invention. In particular, the catalyst particles can be sprayed onto the surface of the woven cloth by an electrospray method using a disc-type nozzle (150).

At this time, the catalyst particles are injected in the circumferential direction through an electrospray method through a disc-type nozzle (150). In addition, one end of the second guide 120 facing the disc-type nozzle is grounded so that the electrostatically charged catalyst particle droplet is moved in the direction of the second guide 120.

 The circular flow path to which the catalyst particle colloid solution is supplied is formed of a dielectric material such as Teflon, plastic, or glass.

 A disc-type nozzle 150 made of a plurality of conductors is arranged at a predetermined interval in the circular path so as to face the second guide 120 which is grounded, and at the same time, The same voltage can be applied to the nozzles in a form electrically connected to each nozzle constituting the nozzle 150.

In this case, an applied voltage range applied to the disc-type nozzle 150 is 0.5 to 60 kV, a gap between the disc-type nozzle 150 and the grounded second guide 120 The distance is from 2 to 300 mm, the inner diameter of the nozzle is 0.1 to 1.5 mm, and the colloid solution supply flow rate is 2 to 200 μL / min per nozzle.

When the second guide 120 is grounded during the injection of the catalyst particles by an electrospray method

First, there is an effect that the droplets of the catalyst particles adhere to the target position.

Second, the droplets of the catalyst particles are charged to the same polarity, and the force of pushing each other between the droplets becomes strong, so that the size of the droplet becomes smaller. In this case, the surface area of the droplet becomes wider, and the droplet is dried faster at the time of adhering to the woven fabric.

In addition, the catalyst particle supplying section 100 can inject the catalyst particles in a colloidal state onto the surface of the cloth. That is, the catalyst particle colloid prepared by dispersing the prepared catalyst particles in a solution containing a dispersant can be sprayed onto the surface of the cloth.

In addition, the catalyst particle supplying unit 100 may inject the catalyst particles through the ultrasonic reducing unit in the ion state or add a reducing agent to the surface of the cloth. In this case, the catalyst particle supplying unit 100 can overcome the instability of the dispersion of the colloid solution (the problem of precipitation or aggregation of the catalyst particles), and at the same time, supersonic waves are added to the pre- And the catalytic metal ions are reduced by anionic or anionic radicals to be granulated and then injected.

In addition, the catalyst particle supplying unit 100 can inject the catalyst particles onto the surface of the cloth with metal nanoparticles.

The catalytic particle feeder (100) presses the cloth attached with the catalyst particles to allow the catalyst particles to adhere thereto.

In particular, referring to FIG. 1, the catalyst particle coating unit 200 may heat-press the catalyst particle-attached cloth so that the catalyst particles adhere to the cloth.

In the case of heat pressing using a heating roller in the catalyst particle coating unit 200, since the catalyst particles are metal, they are melted into heat and are more likely to adhere to the cloth, The adhesive force to be coated on the cloth can be increased.

3 is a schematic view illustrating a process of attaching metal particles in an electroless plating portion of a particle-coated ring knitting machine according to an embodiment of the present invention.

Referring to FIG. 3, in the electroless plating part 300, a cloth to which catalyst particles are attached by a catalyst particle coating part 200 is impregnated into a plating bath for a preset time to coat the cloth with metal particles.

When the cloth having the catalyst particles adhered in the plating bath is impregnated for about 5 to 10 minutes, the metal cations existing in the plating tank are reduced and the metal particles are coated on the cloth.

For example, the electroless plating reaction scheme using palladium (Pd) catalyst of nickel (Ni) is as follows.

Figure 112015104997123-pat00001

When impregnating a cloth with palladium (Pd) catalyst particles, the nickel cation (Ni 2+ ) inside the plating tank is reduced and the metal particles start to adhere to the cloth. The resulting metal particles are subjected to autocatalysis As the metal ions are continuously reduced, the adhesion of the metal particles continues.

 In the treatment unit 400, the catalyst dispersant and the electroless plating solution residue are treated from the metal particle coated cloth, and are generally washed and dried to be wound on the transition roller unit coated with the metal particles.

Hereinafter, with reference to FIG. 4, a method of coating fibrous particles using a particle-coated circular knitting machine according to an embodiment of the present invention will be described, and the same contents as those of the particle-coated circular knitting machine described above will be omitted.

      Referring to FIG. 4, a method of coating a fibrous particle using a particle coating type circular knitting machine according to an embodiment of the present invention includes a step S100 of spraying a catalyst particle solution on a surface of a cloth, (S200), the electroless plating unit (300) applies a cloth coated with the catalyst particle coating unit to a predetermined time (S300) of coating the metal particles on the cloth by impregnating the plating bath while the treatment unit (400) processes the catalyst dispersant and the electroless plating solution residue on the metal particle coated cloth (S400).

In the step S100 of spraying the catalyst particle solution, the catalyst particle supplying unit 100 applies the catalyst particle solution to the surface of the cloth in an electrospray manner using a disc-type nozzle 150 It can be sprayed.

     In the step S100 of injecting the catalyst particle solution, the catalyst particle supplying unit 100 may inject the catalyst particles in a colloidal state onto the surface of the cloth. Further, the catalyst particles may be sprayed onto the surface of the cloth by passing through the ultrasonic reducing unit in an ionic state or by adding a reducing agent, and the catalyst particles may be sprayed onto the surface of the cloth with metal nanoparticles.

In the step of attaching the catalyst particles to the cloth (S200), the catalyst particle coating unit 200 may heat-press the cloth having the catalyst particles attached thereto so that the catalyst particles adhere to the cloth .

The embodiments and the accompanying drawings described in the present specification are merely illustrative of some of the technical ideas included in the present invention. Therefore, it is to be understood that the embodiments disclosed herein are not intended to limit the scope of the present invention but to limit the scope of the present invention. It will be understood by those of ordinary skill in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims and their equivalents. It should be interpreted.

100: catalyst particle supply part
110: First guide
120: Second Guide
150: Disc-type nozzle
200: catalyst particle coating part
300: electroless plating part
400:

Claims (12)

A catalyst particle supply part (100) for injecting a catalyst particle solution onto the surface of the woven cloth;
A catalyst particle coating unit 200 for pressing the cloth having the catalyst particles thereon so as to allow the catalyst particles to adhere thereto;
An electroless plating unit 300 for impregnating a cloth coated with the catalyst particle coating unit 200 in a plating bath for a preset time to coat the cloth with metal particles; And
A treatment unit 400 for treating the catalyst dispersant and the electroless plating solution residue from the metal particle coated cloth;
Lt; / RTI >
The catalyst particle supplying unit 100 includes:
The catalyst particles are injected in a circumferential direction in an electrospray manner using a disk-type nozzle 150, one end of a guide facing the disk-shaped nozzle 150 is grounded, The electrostatically charged catalyst particle droplet is caused to move in the guide direction,
The disk-shaped nozzle 150 is formed of a plurality of conductors and arranged in a manner to look at the guide,
And a voltage is applied to each of the nozzles constituting the disk-shaped nozzle (150). delete The method according to claim 1,
Wherein the catalyst particle supplying unit (100) injects the catalyst particles in a colloidal state onto the surface of the cloth. The method according to claim 1,
Wherein the catalyst particle supplying unit (100) passes the catalyst particles through the ultrasonic reducing unit in the ion state or adds a reducing agent to spray the catalyst particles onto the surface of the cloth. The method according to claim 1,
The catalyst particle supplying unit (100) injects the catalyst particles onto metal surfaces with metal nanoparticles. The method according to claim 1,
The catalyst particle coating unit 200 may heat-press the cloth having the catalyst particles attached thereto to allow the catalyst particles to adhere to the cloth. (S100) spraying a catalyst particle solution on the surface of the cloth woven by the catalyst particle supplying part (100);
(S200) the catalyst particle coating unit 200 presses the cloth to which the catalyst particles are adhered to attach the catalyst particles to the cloth;
(S300) of coating the metal particles on the cloth by impregnating the electroless plating unit (300) with a cloth coated by the catalyst particle coating unit (200) for a predetermined time; And
Treating the catalyst dispersant and the electroless plating solution residue from the metal particle coated cloth (S400);
Lt; / RTI >
The step (S100) of spraying the catalyst particle solution includes:
The catalyst particle supplying unit 100 includes a plurality of conductors arranged in a manner of looking at a guide and a disc-type nozzle 150 configured to apply a voltage to each of the nozzles. The catalyst particles are sprayed in the circumferential direction and one end of the guide facing the disk-shaped nozzle 150 is grounded so that the electrostatically charged catalyst particle droplet is moved in the guide direction, and an electrospray ) Method for spraying the catalyst particle solution onto the surface of a cloth. delete 8. The method of claim 7,
(S100) of spraying the catalyst particle solution is a particle coating type circular knitting machine in which the catalyst particle supplying unit (100) injects the catalyst particles in a colloidal state onto a cloth surface. 8. The method of claim 7,
The step S100 of spraying the catalyst particle solution may be performed by using a particle coating type circular knitting machine in which the catalyst particle supplying unit 100 injects the catalyst particles in an ionic state through the ultrasonic reducing unit or injects a reducing agent onto the surface of the cloth A method of coating fibrous particles. 8. The method of claim 7,
In the step (S100) of spraying the catalyst particle solution, the particle-coated type circular knitting machine in which the catalyst particle supplying section (100) injects the catalyst particles onto the surface of the cloth with metal nanoparticles is used. 8. The method of claim 7,
The step of attaching the catalyst particles to the cloth (S200) may include a step (S200) of allowing the catalyst particle coating unit 200 to heat-press the cloth to which the catalyst particles are attached to attach the catalyst particles to the cloth A method of coating fibrous particles using a coated circular knitting machine.




KR1020150150531A 2015-10-28 2015-10-28 Continuous in situ particle depositing circular knitting machine and method therefor KR101793786B1 (en)

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KR1020150150531A KR101793786B1 (en) 2015-10-28 2015-10-28 Continuous in situ particle depositing circular knitting machine and method therefor
PCT/KR2016/010450 WO2017073909A1 (en) 2015-10-28 2016-09-20 Particle coating-type circular knitting machine and method for coating fibrous particles by using same

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JP2001003264A (en) * 1999-06-21 2001-01-09 Suminoe Textile Co Ltd Magnetic wave-insulating three-dimensional structural body and its production
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KR100434444B1 (en) * 2001-05-26 2004-06-04 (주)메디텍스 Graded plating method of metal to textile
KR20090046385A (en) * 2007-11-06 2009-05-11 한국 고덴시 주식회사 Electroless plateing method and electroless plate using thereof
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