KR101382038B1 - Process Of Producing GlassPannel For Home Electronics Using UltraViolet Curing And The GlassPannel For Home Electronics - Google Patents
Process Of Producing GlassPannel For Home Electronics Using UltraViolet Curing And The GlassPannel For Home Electronics Download PDFInfo
- Publication number
- KR101382038B1 KR101382038B1 KR1020120058127A KR20120058127A KR101382038B1 KR 101382038 B1 KR101382038 B1 KR 101382038B1 KR 1020120058127 A KR1020120058127 A KR 1020120058127A KR 20120058127 A KR20120058127 A KR 20120058127A KR 101382038 B1 KR101382038 B1 KR 101382038B1
- Authority
- KR
- South Korea
- Prior art keywords
- glass
- acrylate
- fabric
- curable resin
- film
- Prior art date
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/067—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of fibres or filaments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10247—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10559—Shape of the cross-section
- B32B17/10577—Surface roughness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10743—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing acrylate (co)polymers or salts thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10807—Making laminated safety glass or glazing; Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B2038/0052—Other operations not otherwise provided for
- B32B2038/0076—Curing, vulcanising, cross-linking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2310/00—Treatment by energy or chemical effects
- B32B2310/08—Treatment by energy or chemical effects by wave energy or particle radiation
- B32B2310/0806—Treatment by energy or chemical effects by wave energy or particle radiation using electromagnetic radiation
- B32B2310/0831—Treatment by energy or chemical effects by wave energy or particle radiation using electromagnetic radiation using UV radiation
Abstract
본 발명은 자외선 경화접착방식을 이용한 가전제품용 유리판넬의 제조방법에 관한 것으로서 본 발명에 의해 컬러도수의 제한이 적으며, 선택적인 고해상도의 입체패턴을 제공할 수 있으며, 열경화 방식에서 가공 후 컬링(필름이 수축하는 현상)이 발생하는 문제점을 해결하여 접착강도, 박리강도, 내수성, 내열성이 우수한 가전제품용 유리판넬을 제공할 수 있다. The present invention relates to a method for manufacturing a glass panel for home appliances using an ultraviolet curing adhesive method, and the present invention is less limited in color frequency and can provide an optional high-resolution three-dimensional pattern, which is processed in a thermosetting method. After solving the problem of curling (film shrinkage phenomenon) occurs can provide a glass panel for home appliances excellent in adhesive strength, peel strength, water resistance, heat resistance.
Description
본 발명은 자외선 경화접착방식을 이용한 가전제품용 유리판넬의 제조방법에 관한 것으로서 가전제품의 인테리어용으로 사용할 수 있는 유리판넬의 제조방법에 관한 것이다.The present invention relates to a method for manufacturing a glass panel for home appliances using an ultraviolet curing adhesive method, and a method for manufacturing a glass panel that can be used for interiors of home appliances.
국내 가전업체는 생산성만을 추구하던 70, 80년대를 지나 감성의 시대인 2000년대로 진입하였는데, 이러한 트랜드의 변화는 백색가전제품의 표면에 유리소재를 적용함으로써 전환점이 되었다.Domestic home appliance companies entered the 2000s, the age of emotion, after the 70s and 80s, when they pursued only productivity, and this trend was a turning point by applying glass materials to the surface of white goods.
무채색 일변도였던 백색가전제품에 유리소재의 적용으로 인해 자유로운 패턴과 컬러를 사용할 수 있게 되었으며 이로 인해 다양한 소비자의 감성적 욕구에 부응할 수 있게 되었다. 또한 유리소재의 사용은 소비자의 감성적 요구에 따라 패턴 및 인쇄 기법의 다양함으로 인해 얼마든지 새로운 제품의 분위기를 연출 할 수 있었다.The application of glass materials to white home appliances, which was a one-sided achromatic one, allowed the use of free patterns and colors, which could meet the emotional needs of various consumers. In addition, the use of glass materials was able to create a new product atmosphere due to the variety of patterns and printing techniques according to the emotional needs of consumers.
가전제품에 이러한 유리 소재의 확대 적용을 위해서는 다른 소재와의 접목을 통해 새로운 표현기법을 지속적으로 개발해야 하는데, 최근에는 유리에 다양한 디자인 패턴의 필름이 부착된 판넬이 연구개발되고 있는 추세이다. 유리표면의 다양한 처리기술이 연구개발되어 이른바 UV 몰딩, UV 실크스크린, 증착 등의 표면처리 기술 적용되어 유리표면에 입체패턴을 발현하고 있다. In order to apply such glass materials to home appliances, new expression techniques must be continuously developed by grafting with other materials. Recently, panels with various design patterns on glass are being researched and developed. Various treatment technologies for glass surfaces have been researched and developed, and surface treatment technologies such as UV molding, UV silk screen, and deposition are applied to express three-dimensional patterns on the glass surface.
실크스크린 제품의 경우 다양한 색상과 디자인을 구현할 수 있는 장점을 갖고 있으나, 다양한 색상 및 패턴을 나타내기 위해 각 색상 도수에 따라 스크린 및 열고정 공정을 거쳐야 하며, 만약 3도의 색상을 나타내기 위해서는 스크린 공정이 3회가 필요하며, 열고정 공정이 3회가 필요하게 되므로 단가적인 측면과 생산성 문제로 컬러도수에 제한이 있는 문제점을 가진다.Silk screen products have the advantage of realizing various colors and designs, but screens and heat setting processes must be carried out according to the frequency of each color in order to show various colors and patterns. This is required three times, since the heat setting process is required three times, there is a problem in that there is a limit in the color frequency due to the unit cost and productivity problems.
한편, 보다 섬세하고 우아한 무늬패턴을 구현하기 위하여 유리와 필름의 접착형태의 제품이 개발되고 있으며, 이러한 유리와 필름의 접착 가공의 경우에 일반적인 열경화 방식을 적용하고 있으나 내열성 및 내수성이 취약하며, 가공 후 컬링(필름이 수축하는 현상)이 발생하는 물성의 한계성에 봉착하고 있는 실정이다. On the other hand, in order to realize a more delicate and elegant pattern pattern, the product of the adhesive form of glass and film has been developed, and in the case of the adhesive processing of the glass and film is applied a general thermosetting method, but heat resistance and water resistance is weak, It is a situation that the limit of the physical property which curling (film shrinkage) after processing occurs.
그러므로 본 발명에 의하면 기존의 종래기술의 문제점을 극복하여 컬러도수에 제한이 없고 열경화 방식에서 가공 후 컬링(필름이 수축하는 현상)이 발생하는 문제점을 해결하여 내열성 및 내수성이 우수하며, 연속공정이 가능하여 생산성향상을 가져올 수 있으며, 환경 친화적이고 에너지절감효과가 우수한 가전제품용 유리판넬의 제조방법을 제공하는 것을 기술적과제로 한다. Therefore, according to the present invention, there is no limitation on the color frequency by overcoming the problems of the prior art and solving the problem of curling (film shrinkage) after processing in the thermosetting method, which is excellent in heat resistance and water resistance, and continuous It is a technical task to provide a method for manufacturing glass panels for home appliances, which is environmentally friendly and has excellent energy saving effect due to possible processes.
그러므로 본 발명에 의하면, 필름표면에 입체형 엠보싱 또는 입체형 무늬패턴을 가지는 것으로서 두께가 0.1~0.3mm로 제조된 필름 또는 직물을 준비하는 단계;
상기 필름 또는 직물에 우레탄 아크릴레이트와 에폭시 아크릴레이트를 혼합한 올리고머 10~60중량%와 데실아크릴레이트(Decyl acrylate), 세틸아크릴레이트(Cetyl acrylate), 시클릭트리메티롤프로판아크릴레이트(Cyclic Trimetylolpropane Formal Acrylate) 중 어느 하나 이상인 모노머 37~89중량%와 α-히드록시알킬페논(α-Hydroxyalkylphenone)계 또는 벤조인에테르(benzoinether)계 광개시제 1~10중량%로 이루어진 자외선 경화형 수지를 도포하는 단계;
상기 자외선 경화형 수지를 도포한 직물을 유리에 부착시키는 단계;
상기 유리에 부착된 직물에 자외선을 조사하여 직물과 유리 사이에 위치한 자외선 경화형 수지를 경화시켜 직물과 유리를 접착시키는 단계로 이루어진 것을 특징으로 하는 자외선 경화접착방식을 이용한 가전제품용 유리판넬의 제조방법이 제공된다.Therefore, according to the present invention, the step of preparing a film or fabric having a three-dimensional embossing or three-dimensional pattern on the surface of the film made of 0.1 ~ 0.3mm thick;
10 to 60% by weight of oligomer mixed with urethane acrylate and epoxy acrylate to the film or fabric, decyl acrylate, cetyl acrylate, cyclic trimethyrolpropane acrylate (Cyclic Trimetylolpropane Formal) Applying an ultraviolet curable resin comprising 37 to 89% by weight of any one or more monomers and 1 to 10% by weight of an α-Hydroxyalkylphenone-based or a benzoinether-based photoinitiator;
Attaching the fabric coated with the ultraviolet curable resin to glass;
Method of manufacturing a glass panel for home appliances using UV-curable adhesive method characterized in that the step of irradiating UV light to the fabric attached to the glass to cure the UV-curable resin located between the fabric and glass to bond the fabric and glass. This is provided.
삭제delete
삭제delete
삭제delete
삭제delete
삭제delete
삭제delete
삭제delete
삭제delete
상기 자외선 경화형 수지는 점도 1,000~3,000cps 인 것이 바람직하다.It is preferable that the said ultraviolet curable resin is viscosity 1000-3,000cps.
또한, 본 발명에서는 입체패턴을 가지는 필름 또는 직물, 우레탄 아크릴레이트와 에폭시 아크릴레이트를 혼합한 올리고머 10~60중량%와 데실아크릴레이트(Decyl acrylate), 세틸아크릴레이트(Cetyl acrylate), 시클릭트리메티롤프로판아크릴레이트(Cyclic Trimetylolpropane Formal Acrylate) 중 어느 하나 이상인 모노머37~89중량%와 α-히드록시알킬페논(α-Hydroxyalkylphenone)계 또는 벤조인에테르(benzoinether)계 광개시제 1~10중량%로 이루어진 자외선 경화형 수지층 및 유리가 순차적으로 적층되고 접착된 것을 특징으로 하는 자외선 경화접착방식을 이용한 가전제품용 유리판넬이 제공된다.In addition, in the present invention, a film or fabric having a three-dimensional pattern, 10 to 60% by weight of oligomers mixed with urethane acrylate and epoxy acrylate, decyl acrylate, cetyl acrylate and cyclic trimes UV light consisting of 37 to 89% by weight of monomers of at least one of tyryl propane acrylate (Cyclic Trimetylolpropane Formal Acrylate) and 1 to 10% by weight of α-Hydroxyalkylphenone-based or benzoinether-based photoinitiators Provided is a glass panel for home appliances using an ultraviolet curable adhesive method, wherein the curable resin layer and the glass are sequentially laminated and bonded.
삭제delete
그러므로 본 발명에 의해 입체패턴을 가지는 필름 또는 직물을 유리에 접착시킴으로써 컬러도수의 제한이 적으며, 선택적인 고해상도의 입체패턴을 제공할 수 있으며, 열경화 방식에서 가공 후 컬링(필름이 수축하는 현상)이 발생하는 문제점을 해결하여 접착강도, 박리강도, 내수성, 내열성이 우수한 가전제품용 유리판넬을 제공할 수 있다. 또한 연속공정이 가능하여 생산성향상을 가져올 수 있으며, 수지층의 열경화방법에 비해 경화속도와 경화도가 월등히 높으므로 미반응물 배출에 따른 환경오염, 연소에 의한 이산화탄소 무배출 등 환경 친화적이고 에너지절감효과가 우수하다.Therefore, according to the present invention, the film or fabric having a three-dimensional pattern is adhered to glass, thereby limiting the number of colors and providing an optional high-resolution three-dimensional pattern, and curling after processing in a thermosetting method (the film shrinks) It is possible to provide a glass panel for home appliances excellent in adhesive strength, peeling strength, water resistance, heat resistance by solving the problem that occurs). In addition, continuous process is possible, resulting in improved productivity. Since the curing rate and degree of curing are much higher than the thermal curing method of the resin layer, environmentally friendly and energy-saving effects such as environmental pollution due to the discharge of unreacted substances and no carbon dioxide emission by combustion Is excellent.
도 1은 본 발명의 가전제품용 유리판넬의 구조를 나타낸 사시분해도이며,
도 2는 본 발명의 가전제품용 유리판넬의 구조를 나타낸 단면도이며,
도 3은 본 발명의 가전제품용 유리판넬의 제조방법에 사용되는 부착장치의 정면도이다.1 is a perspective exploded view showing the structure of a glass panel for home appliances of the present invention,
Figure 2 is a cross-sectional view showing the structure of a glass panel for home appliances of the present invention,
Figure 3 is a front view of the attachment device used in the manufacturing method of the glass panel for home appliances of the present invention.
이하 본 발명의 가전제품용 유리판넬의 제조방법을 첨부도면을 참조하여 보다 상세히 설명하기로 한다.Hereinafter, a method for manufacturing a glass panel for home appliances according to the present invention will be described in detail with reference to the accompanying drawings.
본 발명의 가전제품용 유리판넬은 도 1에 도시된 바와 같이 유리판(1)에 입체패턴을 가지는 필름 또는 직물(2)이 자외선 경화형 수지(3)에 의해 접착된 유리판넬이다. As shown in FIG. 1, the glass panel for home appliances of the present invention is a glass panel in which a film or
본 발명의 가전제품용 유리판넬의 제조방법을 설명하면, 먼저 입체패턴을 가지는 필름 또는 직물을 준비하는 단계를 행하는데, 상기 입체패턴을 가지는 필름은 합성수지로 된 필름의 표면에 입체적인 엠보싱이나 입체형 무늬패턴을 가지는 것으로서 두께를 0.1~0.3mm 제조된 것으로서 재질은 폴리염화비닐, 폴리에틸렌, 폴리프로필렌, 폴리에스테르, 폴리우레탄등의 어느 재질로 된 필름을 선택하여 사용할 수 있다. 또한, 상기 직물은 합성섬유 또는 천연섬유로된 직물로서 그 조직형태는 평직, 능직, 쟈카드직 어느 것이라도 무방하며 직물표면에 다양한 무늬가 형성되도록 한 것을 사용할 수 있다. Referring to the manufacturing method of the glass panel for home appliances of the present invention, the first step is to prepare a film or fabric having a three-dimensional pattern, the film having a three-dimensional pattern is a three-dimensional embossing or three-dimensional pattern on the surface of the film made of synthetic resin As a pattern having a thickness of 0.1 ~ 0.3mm manufactured as a material can be used to select a film made of any material, such as polyvinyl chloride, polyethylene, polypropylene, polyester, polyurethane. In addition, the fabric is a fabric made of synthetic fibers or natural fibers, the tissue form may be any of plain weave, twill, jacquard weave can be used to form a variety of patterns on the surface of the fabric.
이후 상기 준비된 필름 또는 직물에 자외선 경화형 수지를 도포하는 단계를 행하는데, 상기 자외선 경화형 수지는 우레탄 아크릴레이트와 에폭시 아크릴레이트를 혼합한 올리고머 10~60중량%와 데실아크릴레이트(Decyl acrylate), 세틸아크릴레이트(Cetyl acrylate), 시클릭트리메티롤프로판아크릴레이트(Cyclic Trimetylolpropane Formal Acrylate) 중 어느 하나 이상인 모노머37~89중량%와 α-히드록시알킬페논(α-Hydroxyalkylphenone)계 또는 벤조인에테르(benzoinether)계 광개시제 1~10중량%로 이루어진 것을 사용할 수 있는데, 상기 자외선 경화형 수지를 나이프코팅, 롤러코팅, 스프레이코팅 방법 등으로 상기 필름 또는 직물에 도포를 하게 된다.Thereafter, the step of applying a UV curable resin to the prepared film or fabric, wherein the UV curable resin is 10 to 60% by weight of oligomer mixed with urethane acrylate and epoxy acrylate, decyl acrylate (decyl acrylate), cetyl acryl 37 to 89% by weight of monomer or any one of at least one of Cetyl acrylate and Cyclic Trimetylolpropane Formal Acrylate and α-Hydroxyalkylphenone-based or benzoinether The photo-initiator may be made of 1 to 10% by weight, the ultraviolet curable resin is applied to the film or fabric by knife coating, roller coating, spray coating method or the like.
본 발명에서는 상기 자외선 경화형 수지를 필름 또는 직물에 도포함으로써 자외선조사에 의해 빠른 경화속도로 필름 또는 직물과 유리사이에서 경화될 수 있도록 하여 생산속도를 단축시킬 뿐만 아니라 입체적인 무늬패턴을 가진 필름 또는 직물이 유리에 우수한 물성으로 접착되도록 함으로써 유리에 대한 접착강도가 우수하고 내수성, 박리강도가 우수하다. 이렇게 본 발명의 상기 수지층의 조성에 의해 우수한 투과도, 우수한 접착력을 부여하여 유리층이 박리가 되지 않도록 하며, 유리파손시 비산을 방지할 수 있다. 경우에 따라서는 반응성 희석제(reactive diluent)인 저분자량의 폴리에스테르나 펄리에테르 아크릴레이트가 첨가될 수 있으며, 첨가제로 계면활성체, 산화/광분해 안정제등이 첨가될수 있다. 또한, 무기계 안료를 첨가하여 수지층내에 분산을 시켜 다양한 색상을 구현할 수도 있다. In the present invention, by applying the UV-curable resin to the film or fabric to be cured between the film or the fabric and glass at a high curing speed by ultraviolet irradiation not only shorten the production speed but also a film or fabric having a three-dimensional pattern pattern By bonding to glass with excellent physical properties, the adhesive strength to glass is excellent, and the water resistance and peel strength are excellent. Thus, the composition of the resin layer of the present invention provides excellent permeability and excellent adhesion to prevent the glass layer from being peeled off and to prevent scattering during glass breakage. In some cases, low molecular weight polyesters or perlyether acrylates, which are reactive diluents, may be added. Surfactants, oxidation / photolysis stabilizers and the like can be added. In addition, the inorganic pigment may be added to disperse in the resin layer to implement various colors.
상기 자외선 경화형 수지는 점도가 1,000~3,000cps인 것을 사용하는 것이 필름과 섬유의 자외선 경화형 수지의 균일한 도포층 형성 측면에서 바람직하다.It is preferable to use the thing whose viscosity is 1,000-3,000 cps for the said ultraviolet curable resin from the surface of uniform coating layer formation of the ultraviolet curable resin of a film and a fiber.
이렇게 자외선 경화형 수지를 도포한 필름 또는 직물을 유리에 부착시키는 단계를 거친 후, 상기 유리에 부착된 필름 또는 직물에 자외선을 조사하여 필름 또는 직물과 유리 사이에 위치한 자외선 경화형 수지를 경화시켜 필름 또는 직물과 유리를 접착시켜 본 발명의 자외선 경화접착방식을 이용한 가전제품용 유리판넬을 제조하게 된다.After attaching the UV-curable resin-coated film or fabric to the glass, the UV-curable resin located between the film or the fabric and the glass is cured by irradiating ultraviolet rays to the film or the fabric attached to the glass. By bonding the glass and the glass panel for home appliances using the ultraviolet curing adhesive method of the present invention.
본 발명에서 상기 필름 또는 직물에 자외선 경화형 수지를 도포하는 단계; 상기 자외선 경화형 수지를 도포한 필름 또는 직물을 유리에 부착시키는 단계; 상기 유리에 부착된 필름 또는 직물에 자외선을 조사하여 필름 또는 직물과 유리 사이에 위치한 자외선 경화형 수지를 경화시켜 필름 또는 직물과 유리를 접착시키는 단계는 도 3의 정면도를 가지는 부착장치에서 행하는 것이 바람직하다.Applying an ultraviolet curable resin to the film or fabric in the present invention; Attaching the UV-curable resin-coated film or fabric to glass; Irradiating the film or fabric attached to the glass with ultraviolet rays to cure the ultraviolet curable resin located between the film or the fabric and the glass to bond the film or the fabric to the glass is preferably performed in the attachment device having the front view of FIG. 3. .
도 3에서 도시된 부착장치는 콘베어벨트, 노즐, 나이프, 수지저장탱크, 자외선램프, 텐션롤러, 히팅롤러 및 필름공급롤러를 구비하는 것으로서 콘베어벨트(100)으로 유리(1)를 이송한다. 이때 별도로 텐션롤러(140)에 감긴 필름 또는 직물(2)은 히팅롤러(150)에 의해 예열된 후, 수지저장탱크(110)으로부터 공급되어 노즐(120)로 토출 내지는 분사되는 자외선 경화형 수지(3)가 필름 또는 직물(2)의 일면에 도포되고 노즐(120)과 인접한 나이프(130)에 의해 도포된 자외선 경화형 수지(3)의 두께가 일정하게 조절된다. 필름공급롤러(160)에 의해 상기 자외선 경화형 수지(3)가 도포된 필름 또는 직물은 유리위로 밀착되면서 공급되어 유리와 적층된다. 이렇게 적층된 유리, 자외선 경화형 수지 및 필름(또는 직물)은 자외선램프(170)에 의해 자외선을 조사받아 자외선 경화형 수지가 경화되면서 입체패턴을 가지는 필름 또는 직물, 자외선 경화형 수지층 및 유리가 순차적으로 적층되고 접착된 본 발명의 유리판넬이 제조된다.The attachment apparatus shown in FIG. 3 includes a conveyor belt, a nozzle, a knife, a resin storage tank, an ultraviolet lamp, a tension roller, a heating roller, and a film supply roller to convey the
상기 조사되는 자외선은 260~450㎚인 것이 경화속도를 빠르게 할 수 있어 바람직하다. 자외선 조사폭은 100 ~ 1,500mm로 수평식의 UV LED 램프, 수은램프 및 메탈램프등을 설치하여 유리판의 상부에서 조사하여 경화하는 방식을 이용할 수 있다.The irradiated ultraviolet rays are preferably 260 to 450 nm because the curing speed can be increased. UV irradiation width is 100 ~ 1,500mm, horizontal UV LED lamps, mercury lamps and metal lamps can be installed to irradiate and harden the top of the glass plate.
이하 다음의 실시 예에서는 본 발명의 유리판넬에 대한 비한정적인 예시를 하고 있다.
The following examples are given as non-limiting examples of the glass panel of the present invention.
[실시예 1][Example 1]
쟈카드직물을 준비하여 도 3에서 도시된 부착장치의 텐션롤러에 감은 후 텐션롤러로부터 쟈카드직물을 풀어 히팅롤러를 통과시켜 예열한 후, 수지저장탱크로부터 공급되어 노즐로 토출되는 자외선 경화형 수지를 상기 직물의 일면에 도포하고 노즐과 인접한 나이프로 의해 도포된 자외선 경화형 수지의 두께를 일정하게 조절한다. 상기 자외선 경화형 수지는 우레탄 아크릴레이트와 에폭시 아크릴레이트를 5: 5로 혼합한 올리고머 40중량%와 데실아크릴레이트(Decyl acrylate), 세틸아크릴레이트(Cetyl acrylate) 모노머 58중량%와 벤조인에테르(benzoinether)계 광개시제 2중량%로 이루어진 것을 사용하였다.After preparing the jacquard fabric and winding it on the tension roller of the attachment device shown in FIG. 3, the jacquard fabric was unwound from the tension roller, passed through a heating roller, and preheated. The ultraviolet curable resin supplied from the resin storage tank and discharged to the nozzle was fabricated. The thickness of the UV curable resin coated on one side of the coated with a knife adjacent to the nozzle is controlled. The UV-curable resin is 40% by weight of the oligomer mixed with urethane acrylate and epoxy acrylate 5: 5, decyl acrylate, cetyl acrylate monomer 58% by weight and benzoinether (benzoinether) The one consisting of 2% by weight of the system photoinitiator was used.
이후 콘베어벨트로 이송된 유리를 필름공급롤러아래로 통과시켜 상기 자외선 경화형 수지가 도포된 직물을 유리위로 밀착시켜 유리와 적층시킨 후 자외선램프에 의해 자외선을 조사시켜 자외선 경화형 수지를 경화하여 쟈카드직물, 자외선 경화형 수지층 및 유리가 순차적으로 적층되고 접착된 본 발명의 유리판넬을 제조하였다. 상기 제조된 유리판넬의 물성실험을 수행하였다.
After passing the glass conveyed by the conveyor belt under the film feed roller, the fabric coated with the UV curable resin is adhered onto the glass, laminated with glass, and then irradiated with UV light by an ultraviolet lamp to cure the UV curable resin. An ultraviolet curable resin layer and glass were sequentially laminated and bonded to prepare a glass panel of the present invention. Physical properties of the glass panel prepared above were performed.
1. 열충격시험1. Thermal Shock Test
영하 30±2℃에서 1시간 방치, 50℃에서 1시간 방치를 1 싸이클로 하여 5싸이클을 실시한 후 제품 변형 여부 및 제품기능을 살펴본 결과 박리/들뜸/수축/결함이 없음을 확인하였다.After 5 cycles of 1 cycle at minus 30 ± 2 ℃ and 1 hour at 50 ℃ for 1 cycle, it was confirmed that there was no peeling / lifting / shrinkage / defect when the product was deformed and the product function was examined.
2. 내열성 시험(KS L 2004:2009)2. Heat resistance test (KS L 2004: 2009)
KSL 2004 : 2009 방법으로 제품 변형 여부 및 제품기능을 살펴본 결과 박리/들뜸/수축/결함이 없음을 확인하였다.As a result of examining whether the product was deformed and functioned by KSL 2004: 2009 method, it was confirmed that there was no peeling / lifting / shrinkage / defect.
3. 밀착성 시험(KS M ISO 2409:2008) 아래내용이 맞는지 확인해주시기 바랍니다.3. Adhesion test (KS M ISO 2409: 2008) Please check the following.
시편(3mm×3mm)의 배면을 예리한 철필로 11개씩 긋고,Draw the back of the specimen (3mm x 3mm) by 11 with a sharp stylus,
시편(편50mm×80mm)에 3M Scotch Tape을 약 500g의 압력으로 5회 문지른 후 표면과 수직방향으로 50cm/sec. 속도로 떼어낸 후 제품 변형 여부 및 제품기능을 살펴본 결과 전혀 이상이 없음을 확인하였다.(0등급)Rub the 3M Scotch Tape on the specimen (50mm × 80mm) five times at a pressure of about 500g and 50cm / sec. After peeling off at the speed, the product was checked for deformation and its function, and it was confirmed that there was no abnormality.
4. 내한성시험4. Cold resistance test
영하 -30±2℃에서 24시간 방치 후 제품 변형 여부 및 제품기능을 살펴본 결과 박리/들뜸/수축/결함이 없음을 확인하였다.After 24 hours at minus -30 ± 2 ℃, the product was examined for deformity and function, and it was confirmed that there was no peeling / lifting / shrinkage / defect.
5. 내수성시험5. Water resistance test
40±2℃의 물속에서 1시간 방치 후 제품 변형 여부 및 제품기능을 살펴본 결과 전혀 이상이 없음을 확인하였다.After leaving for 1 hour in water at 40 ± 2 ℃, the results of the product deformation and the results were confirmed that no abnormality.
6. 내약품성시험6. Chemical resistance test
NaCl 5% 수용액속에 48시간 방치 후 제품 변형 여부 및 제품기능을 살펴본 결과 전혀 이상이 없음을 확인하였다.After 48 hours in NaCl 5% aqueous solution, the result of the product deformation and product function was confirmed to be no abnormality.
7. 내자외성 시험(KS M 5982:2008)7. UV resistance test (KS M 5982: 2008)
UV하 48시간 방치 후 색차 변형 여부를 살펴본 결과 △E=0.4로 이상이 없음을 확인하였다.After 48 hours of UV, the color difference was examined and the result was confirmed that ΔE = 0.4.
8. 접착강도시험(KS L 2016:2007)결과 박리불가하였다.8. Adhesion test (KS L 2016: 2007) showed that peeling was impossible.
1 : 유리 2 : 필름 또는 직물
3 : 자외선 경화형 수지 100 : 콘베어벨트
110 : 수지저장탱크 120 : 노즐
130 : 나이프 140 : 텐션롤러
150 : 히팅롤러 160 : 필름공급롤러
170 : 자외선램프1: glass 2: film or fabric
3: ultraviolet curable resin 100: conveyor belt
110: resin storage tank 120: nozzle
130: knife 140: tension roller
150: heating roller 160: film feed roller
170: UV lamp
Claims (7)
상기 필름 또는 직물에 우레탄 아크릴레이트와 에폭시 아크릴레이트를 혼합한 올리고머 10~60중량%와 데실아크릴레이트(Decyl acrylate), 세틸아크릴레이트(Cetyl acrylate), 시클릭트리메티롤프로판아크릴레이트(Cyclic Trimetylolpropane Formal Acrylate) 중 어느 하나 이상인 모노머 37~89중량%와 α-히드록시알킬페논(α-Hydroxyalkylphenone)계 또는 벤조인에테르(benzoinether)계 광개시제 1~10중량%로 이루어진 자외선 경화형 수지를 도포하는 단계;
상기 자외선 경화형 수지를 도포한 직물을 유리에 부착시키는 단계;
상기 유리에 부착된 직물에 자외선을 조사하여 직물과 유리 사이에 위치한 자외선 경화형 수지를 경화시켜 직물과 유리를 접착시키는 단계로 이루어진 것을 특징으로 하는 자외선 경화접착방식을 이용한 가전제품용 유리판넬의 제조방법.Preparing a film or fabric having a three-dimensional embossing or three-dimensional pattern on the surface of the film, the thickness of which is 0.1-0.3 mm;
10 to 60% by weight of oligomer mixed with urethane acrylate and epoxy acrylate to the film or fabric, decyl acrylate, cetyl acrylate, cyclic trimethyrolpropane acrylate (Cyclic Trimetylolpropane Formal) Applying an ultraviolet curable resin comprising 37 to 89% by weight of any one or more monomers and 1 to 10% by weight of an α-Hydroxyalkylphenone-based or a benzoinether-based photoinitiator;
Attaching the fabric coated with the ultraviolet curable resin to glass;
Method of manufacturing a glass panel for home appliances using UV-curable adhesive method characterized in that the step of irradiating UV light to the fabric attached to the glass to cure the UV-curable resin located between the fabric and glass to bond the fabric and glass. .
상기 자외선 경화형 수지는 점도 1,000~3,000cps 인 것을 특징으로 하는 자외선 경화접착방식을 이용한 가전제품용 유리판넬의 제조방법. The method according to claim 1,
The UV curable resin is a manufacturing method of a glass panel for home appliances using a UV curable adhesive method, characterized in that the viscosity of 1,000 ~ 3,000cps.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020120058127A KR101382038B1 (en) | 2012-05-31 | 2012-05-31 | Process Of Producing GlassPannel For Home Electronics Using UltraViolet Curing And The GlassPannel For Home Electronics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020120058127A KR101382038B1 (en) | 2012-05-31 | 2012-05-31 | Process Of Producing GlassPannel For Home Electronics Using UltraViolet Curing And The GlassPannel For Home Electronics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20130134540A KR20130134540A (en) | 2013-12-10 |
| KR101382038B1 true KR101382038B1 (en) | 2014-04-04 |
Family
ID=49982155
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020120058127A KR101382038B1 (en) | 2012-05-31 | 2012-05-31 | Process Of Producing GlassPannel For Home Electronics Using UltraViolet Curing And The GlassPannel For Home Electronics |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR101382038B1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101544358B1 (en) | 2015-06-16 | 2015-08-13 | 주식회사 지앤윈 | A continuous coating apparatus of a glass |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101664353B1 (en) | 2015-01-19 | 2016-10-12 | 주식회사 소포스 | Process Of Producing Nonmetalic Solid Pattern Material Using 3D Metalic Texture Film |
| ES2629062B1 (en) * | 2015-12-22 | 2018-06-08 | Bsh Electrodomésticos España, S.A. | Process for manufacturing a household appliance component |
| KR101867287B1 (en) * | 2016-08-08 | 2018-08-02 | 주식회사 소포스 | Process Of Producing The MetalPannel Using UltraViolet Curing |
| KR102307896B1 (en) * | 2019-12-10 | 2021-09-30 | 주식회사 포스코 | Thin glass laminated printed steel plate having excellent flammability and manufacturing method thereof |
| KR102529330B1 (en) | 2021-05-13 | 2023-05-08 | 주식회사 소포스 | Process Of Producing FiberBased Composite Material Using UV Curing |
| KR102630043B1 (en) * | 2023-09-12 | 2024-01-25 | 강대선 | Manufacturing method of interior composite material using ultraviolet curing method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20080037872A (en) * | 2006-10-27 | 2008-05-02 | 엘지전자 주식회사 | Uv cured adhesive, keypad structure for mobole phone and method for bonding key to keypad |
| KR20090069136A (en) * | 2007-12-24 | 2009-06-29 | 동우 화인켐 주식회사 | Curable resin composition, image display and method of manufacturing image display using the same |
| KR100949991B1 (en) | 2008-11-21 | 2010-03-26 | 주식회사 소포스 | Adhesion method for glass and film |
| KR20110041794A (en) * | 2009-10-16 | 2011-04-22 | 나투라미디어 주식회사 | Tranparent decoration panels with metallic feel having digital printing layer |
-
2012
- 2012-05-31 KR KR1020120058127A patent/KR101382038B1/en active IP Right Grant
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20080037872A (en) * | 2006-10-27 | 2008-05-02 | 엘지전자 주식회사 | Uv cured adhesive, keypad structure for mobole phone and method for bonding key to keypad |
| KR20090069136A (en) * | 2007-12-24 | 2009-06-29 | 동우 화인켐 주식회사 | Curable resin composition, image display and method of manufacturing image display using the same |
| KR100949991B1 (en) | 2008-11-21 | 2010-03-26 | 주식회사 소포스 | Adhesion method for glass and film |
| KR20110041794A (en) * | 2009-10-16 | 2011-04-22 | 나투라미디어 주식회사 | Tranparent decoration panels with metallic feel having digital printing layer |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101544358B1 (en) | 2015-06-16 | 2015-08-13 | 주식회사 지앤윈 | A continuous coating apparatus of a glass |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20130134540A (en) | 2013-12-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101382038B1 (en) | Process Of Producing GlassPannel For Home Electronics Using UltraViolet Curing And The GlassPannel For Home Electronics | |
| EP2146805B1 (en) | Materials having a textured surface and methods for producing same | |
| KR101615315B1 (en) | Thin Film Color Coating Method For HardtoDye Yarn | |
| KR101437784B1 (en) | Interior Film having longitudinal hair line of various lengths and the manufacturing method thereof | |
| US3661673A (en) | Method of making plastic laminate having high abrasion resistance | |
| JP2018516780A (en) | Method for generating a structured surface and article structured in such a manner | |
| CN1840301B (en) | Composite plate and decorative composite plate | |
| KR20140058762A (en) | Hard coating film and cover window using the same | |
| JP6414496B2 (en) | Transfer film for 3D molding | |
| KR101867287B1 (en) | Process Of Producing The MetalPannel Using UltraViolet Curing | |
| JP7243933B2 (en) | Transfer sheet and method for manufacturing resin molded product using the same | |
| KR20130120204A (en) | Uv coating composition and the membrane decosheet using the same material and its manufacturing method | |
| KR101621214B1 (en) | Method of high-fastness dying yarn using ultraviolet ray hardning | |
| JP6455269B2 (en) | Transfer film for 3D molding | |
| JP4498548B2 (en) | Manufacturing method of decorative board | |
| KR102005214B1 (en) | Fabric with glitter material and manufacturing method thereof | |
| KR101622301B1 (en) | High performance laminar color steel sheet and method of the same | |
| KR101725407B1 (en) | UV Curing Coating Process Of High Brightness Retroreflective Textile Articles | |
| KR102529330B1 (en) | Process Of Producing FiberBased Composite Material Using UV Curing | |
| KR101737511B1 (en) | Process Of Producing Retroreflective Textile Articles Using UV Curing | |
| KR101247466B1 (en) | Eco-friendly uv high-glossy method for manufacturing plywood for interior material including a-pet film | |
| CN101549578A (en) | Decorative sheet for floor material and production method thereof | |
| KR100855607B1 (en) | Apparatus of decoration glass lamination using uv cured resin and menufacturing method thereof | |
| KR20110004970A (en) | A process for preparing high glossy board decorated with a pattern | |
| JPWO2018168284A1 (en) | Optical film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| E902 | Notification of reason for refusal | ||
| E701 | Decision to grant or registration of patent right | ||
| FPAY | Annual fee payment |
Payment date: 20180411 Year of fee payment: 5 |
|
| FPAY | Annual fee payment |
Payment date: 20190401 Year of fee payment: 6 |
|
| FPAY | Annual fee payment |
Payment date: 20200311 Year of fee payment: 7 |