KR101173660B1 - Inorganic Ceramic Reparing Moltar Composition - Google Patents

Inorganic Ceramic Reparing Moltar Composition Download PDF

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KR101173660B1
KR101173660B1 KR1020120024058A KR20120024058A KR101173660B1 KR 101173660 B1 KR101173660 B1 KR 101173660B1 KR 1020120024058 A KR1020120024058 A KR 1020120024058A KR 20120024058 A KR20120024058 A KR 20120024058A KR 101173660 B1 KR101173660 B1 KR 101173660B1
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weight
parts
composition
present
repair mortar
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KR1020120024058A
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Korean (ko)
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연규봉
남원구
송기정
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(주) 에스엠씨드림
(주)에스엠씨테크
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/10Clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/22Natural resins, e.g. rosin
    • C04B26/24Cellulosic waste liquor, e.g. sulfite lye
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/44Thickening, gelling or viscosity increasing agents
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/02Portland cement

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

PURPOSE: An inorganic based ceramic repair mortar composition is provided to drastically increase chemical resistance, durability, and neutralization prevention by adding specific configuration of ceramics. CONSTITUTION: An inorganic based ceramic repair mortar composition comprises 30-50 parts by weight of Portland cement, 40-65.94 parts by weight of silica, 1-10 parts by weight of metakaolin, 3-25 parts by weight of ceramics silica, 0.01-0.3 parts by weight of thickening agent, and 0.05-1.5 parts by weight of admixture based on 100 parts by weight of the composition. A manufacturing method of the metakaolin comprises the following step: reacting kaolin at 1250-1400 deg. Celsius for 7-9 hours.

Description

무기질계 세라믹 보수 몰탈 조성물{Inorganic Ceramic Reparing Moltar Composition} Inorganic Ceramic Reparing Moltar Composition

본 발명은 내구성 및 내화학성을 개선한 무기질계 세라믹 보수 몰탈 조성물에 관한 것이다.
The present invention relates to an inorganic ceramic repair mortar composition having improved durability and chemical resistance.

콘크리트 구조물과 포장 도로 등은 공기 및 물과 오랜 기간 동안 접촉되어 열화되고, 과도한 하중을 받거나 수해 등으로 인하여 파손되는 경우가 많으므로 이들을 부분적으로 보수할 필요성이 있게 된다. 공기와 물에 의한 열화 현상은 중성화, 염해, 기온에 따른 수축팽창 등에 기인하게 되는데 이러한 열화 현상으로 인해 철근부식, 균열, 박리 등을 가져와 구조물을 파괴시키게 된다. 따라서 이들을 보수하지 않으면 안 되는 상황에 처하게 된다. Concrete structures, pavements, and the like are degraded by contact with air and water for a long time, and are often damaged due to excessive load or flooding, so there is a need to partially repair them. The degradation caused by air and water is caused by neutralization, salt damage, shrinkage expansion according to temperature, and the like, which causes reinforcement corrosion, cracking, peeling, etc., and destroys the structure. Therefore, they are in a situation where they must be repaired.

이와 같이 부분적으로 파손된 구조물을 보수하기 위해서 대개 보수용 몰탈을 사용하게 되는 데, 일반적으로 사용되는 보수 몰탈은 시멘트, 규사, 실리카흄(fumed silica) 및 증점제로 이루어져 있어 보수 용도로만 사용되고, 내구성, 염해 방지성, 내화학성에 있어서 미흡한 점이 많이 있었다.
In order to repair such partially damaged structures, repair mortar is usually used. The repair mortar generally used is composed of cement, silica sand, fumed silica, and thickener, and is used only for repair purposes. There were many insufficiency in prevention and chemical resistance.

이러한 몰탈로 보수를 하는 경우 그 수명이 짧고 원 모체 콘크리트를 보호하는 기능이 약한 문제점이 있다.In the case of repairing with such mortar, its life is short and there is a problem in that the function of protecting the raw concrete is weak.

이에 본 발명자들은 상기한 문제점들을 해결할 수 있는 보수 몰탈을 개발하기 위해 계속 연구를 진행하던 중 특정 구성의 세라믹을 첨가함으로써 종래의 보수 몰탈의 성질을 유지하면서 내구성, 염해 방지성, 내화학성을 증진시킬 수 있다는 사실을 알아내고 본 발명을 완성하기에 이르렀다.Therefore, the present inventors continue to research to develop a repair mortar that can solve the above problems, while adding a ceramic of a specific configuration to improve the durability, salt resistance and chemical resistance while maintaining the properties of the conventional repair mortar It has been found that the invention can be completed and the present invention has been completed.

따라서 본 발명의 목적은 내구성, 중성화 방지성, 염해 방지성, 내화학성을 증진시킨 무기질계 세라믹 보수 몰탈을 제공하는 데 있다.
Accordingly, it is an object of the present invention to provide an inorganic ceramic repair mortar having improved durability, anti-neutralization, anti-salt and chemical resistance.

상기한 목적을 달성하기 위하여, 본 발명에서는 조성물 총 100 중량부를 기준으로, 다음 성분을 포함하는 무기질계 세라믹 보수 몰탈을 제공한다:In order to achieve the above object, the present invention provides an inorganic ceramic repair mortar comprising the following components, based on a total of 100 parts by weight of the composition:

- 포틀랜드 시멘트 30 내지 50 중량부,30 to 50 parts by weight of Portland cement,

- 규사 40 내지 65.94 중량부,-Silica sand 40 to 65.94 parts by weight,

- 메타카올린 1 내지 10 중량부,1 to 10 parts by weight of metakaolin,

- 세라믹 규사 3 내지 25 중량부,3 to 25 parts by weight of ceramic silica sand,

- 증점제 0.01 내지 0.3 중량부, 및0.01 to 0.3 parts by weight of thickener, and

- 혼화제 0.05 내지 1.5 중량부.
0.05 to 1.5 parts by weight of admixture.

본 발명의 무기질계 세라믹 보수 몰탈은 종래의 보수 몰탈의 성질을 유지하면서 내구성, 중성화 방지성, 염해 방지성, 내화학성을 크게 증진시켰다. 가격 면에서도, 종래의 수입품보다 5 내지 10배 정도 저렴하여 경제적 효과도 매우 높다.
The inorganic ceramic repair mortar of the present invention greatly improved durability, anti-neutralization, salt prevention, and chemical resistance while maintaining the properties of the conventional repair mortar. In terms of price, it is also about 5 to 10 times cheaper than conventional imports, and the economic effect is also very high.

본 발명에서 사용되는 기술 용어 및 과학 용어에 있어서 다른 정의가 없다면, 이 발명이 속하는 기술 분야에서 통상의 지식을 가진 자가 통상적으로 이해하고 있는 의미를 갖는 것으로 해석될 수 있다.The technical terms and scientific terms used in the present invention can be construed as meaning ordinary meanings understood by those of ordinary skill in the art without departing from the scope of the present invention.

본 발명에서 사용되는 포틀랜드 시멘트는, 조성물 총 100 중량부를 기준으로, 30 내지 50 중량부의 양으로 사용된다. 30 중량부 미만의 양으로 사용하면 요구되는 강도가 저하되는 문제점이 있으며, 50 중량부를 초과하면 몰탈에 크랙이 발생되는 문제점이 있다. Portland cement used in the present invention is used in an amount of 30 to 50 parts by weight, based on 100 parts by weight of the total composition. When used in an amount less than 30 parts by weight, there is a problem that the required strength is lowered, and when it exceeds 50 parts by weight, there is a problem that cracks occur in mortar.

본 발명에서 사용되는 규사는, 조성물 총 100 중량부를 기준으로, 40 내지 65.94 중량부의 양으로 사용된다. 40 중량부 미만의 양으로 사용하면 몰탈에 크랙이 발생되는 문제점이 있으며, 65.94 중량부를 초과하면 요구하는 강도가 저하되는 문제점이 있다. The silica sand used in the present invention is used in an amount of 40 to 65.94 parts by weight based on 100 parts by weight of the total composition. When used in an amount of less than 40 parts by weight, there is a problem that cracks occur in mortar, and when it exceeds 65.94 parts by weight, there is a problem that the required strength is lowered.

본 발명에서는 종래에 사용되던 실리카흄을 사용하지 않고, 그 대신 고령토를 소성온도 1250 ℃ 내지 1400 ℃에서 7 내지 9 시간 동안 반응시켜 얻은 메타카올린을 사용한다. 이때 고령토를 상기와 같이 고온에서 소성시켜 얻는 메타카올린으로 만들어 사용하지 않으면, 본 발명에서 목적으로 하는 효과를 얻을 수가 없다. 그런데 여기서 단기적으로는 에트린자이트(ettringite)의 생성과 시멘트 중의 C3S의 활성화로 인해 초기 강도가 증가되며, 중장기적으로는 시멘트의 수산화칼슘과 포졸란 반응(수경성을 가지는 실리케이트 또는 알루미네이트 성분을 생성하는 반응)을 일으킨다. In the present invention, the silica fume used in the prior art is not used. Instead, metakaolin obtained by reacting kaolin at a firing temperature of 1250 ° C to 1400 ° C for 7 to 9 hours is used. In this case, if the kaolin is not made of metakaolin obtained by calcining at a high temperature as described above and not used, the effect desired in the present invention cannot be obtained. However, in the short term, the initial strength is increased due to the formation of ettringite and the activation of C 3 S in cement. Reaction to produce).

포졸란 물질의 직접적인 반응 참여는 수화반응이 시작되고 나서 3일 내지 14일 경과한 다음에 본격적으로 시작된다. 포졸란 물질부터 용출된 Si 이온 과 Al 이온은 공극에 존재하는 세공액에 포함된 Ca 이온과 반응하여 CSH 상 및 칼슘 알루미늄 수화물을 형성하여 경화체의 조직을 치밀하게 만들어 준다.Participation in the direct reaction of pozzolanic material begins in earnest three to fourteen days after the hydration reaction begins. Si ions and Al ions eluted from the pozzolanic material react with Ca ions in the pore solution present in the pores to form CSH phase and calcium aluminum hydrate to make the structure of the cured body dense.

본 발명에서 사용되는 메타카올린은 비표면적이 11,000 내지 13,000 g/cm2이어야 한다. 비표면적이 11,000 g/cm2 미만이면, 몰탈 밀도가 떨어지므로 중성화 염해 방지 성능과 같은 몰탈의 기능성이 떨어지는 문제점이 있으며, 13,000 g/cm2를 초과하면 상기와 같은 몰탈의 기능성은 상승하지만 고 분말로 인하여 원가 상승 이라는 문제점이 발생한다.The metakaolin used in the present invention should have a specific surface area of 11,000 to 13,000 g / cm 2 . If the specific surface area is less than 11,000 g / cm 2 , there is a problem that the mortar density, such as the neutralization salt prevention performance is inferior because the mortar density is lowered, and if the specific surface area exceeds 13,000 g / cm 2 , but the functionality of the mortar as mentioned above is high powder This raises the problem of cost increase.

본 발명에서 사용되는 메타카올린은, 다음과 같은 구성 성분과 조성비(중량비)를 갖는다:Metakaolin used in the present invention has the following components and composition ratio (weight ratio):

SiO2 58%, Al2O3 37%, Fe2O3 2.4 %, CaO 0.2%, MgO 0.3%, K20 0.8%, SiO 2 58%, Al 2 O 3 37%, Fe 2 O 3 2.4%, CaO 0.2%, MgO 0.3%, K 2 0 0.8%,

Na2O 0.2%.Na 2 O 0.2%.

본 발명에서 사용되는 세라믹 규사는 분말형이며, 카올리나이트와 할로이사이트가 있다. 카올리나이트는 Al2O3.2SiO2.2H2O로 구성되어 있으며, 할로이사이트는 Al2O3ㆍSiO2ㆍ4H2O로 구성되어 있다. Ceramic silica sand used in the present invention is powder type, and there are kaolinite and halosite. Kaolinite is composed of Al 2 O 3 .2SiO 2 .2H 2 O , and halloysite is composed of Al 2 O 3 and SiO 2 and 4H 2 O.

본 발명에 따른 세라믹 규사는, 조성물 총 100 중량부를 기준으로, 3 내지 25 중량부의 양으로 사용된다. 3 중량부 미만의 양으로 사용하면 기능성이 저하되는 문제점이 있으며, 25 중량부를 초과하면 요구되는 강도가 저하되는 문제점이 있다. Ceramic silica sand according to the present invention is used in an amount of 3 to 25 parts by weight, based on 100 parts by weight of the total composition. When used in an amount less than 3 parts by weight, there is a problem that the functionality is lowered, and when it exceeds 25 parts by weight, there is a problem that the required strength is lowered.

본 발명에서 사용되는 증점제로는 폴리메틸셀룰로스(PMC)가 있으며, 그 예로는 에틸셀룰로스(EC), 하이드로 에틸셀룰로스(HEC), 메틸셀룰로스(MC), 하이드로 폴리메틸셀룰로스(HPMC) 등이 있고, 이들은 단독으로 사용되거나 조합하여 사용될 수 있다. Thickeners used in the present invention include polymethyl cellulose (PMC), and examples thereof include ethyl cellulose (EC), hydro ethyl cellulose (HEC), methyl cellulose (MC), hydro polymethyl cellulose (HPMC), These may be used alone or in combination.

본 발명에서 사용되는 증점제의 양은, 조성물 총 100 중량부를 기준으로, 0.01 내지 0.3 중량부의 양으로 사용된다. 0.01 중량부 미만의 양으로 사용하면 증점 효과가 떨어져 부착강도가 약해지는 문제점이 있으며, 0.3 중량부를 초과하면 몰탈의 압축 강도 및 휨 강도가 저하되는 문제점이 있다. The amount of thickener used in the present invention is used in an amount of 0.01 to 0.3 parts by weight based on 100 parts by weight of the total composition. If the amount is less than 0.01 parts by weight, there is a problem that the thickening effect is reduced and the adhesion strength is weakened. If the amount is less than 0.3 parts by weight, the compressive strength and the bending strength of the mortar decrease.

본 발명에서 사용되는 혼화제는 멜라민류이며, 그 예로는 멜멘트(바스프, 독일제품), MM-2000P(이코넥스, 한국제품) 등이 있고, 이들은 단독으로 사용되거나 혼합 사용될 수 있다. The admixtures used in the present invention are melamines, and examples thereof include melment (BASF, Germany), MM-2000P (Econex, Korea), and the like, which may be used alone or in combination.

본 발명에서 사용되는 혼화제의 양은, 조성물 총 100 중량부를 기준으로, 0.05 내지 1.5 중량부의 양으로 사용된다. 0.05 중량부 미만의 양으로 사용하면 분산성이 낮아지는 문제점이 있으며, 1.5 중량부를 초과하면 유동성이 증가되어 몰탈을 스프레이(뿜칠)할 수 없는 문제점이 생긴다. The amount of admixture used in the present invention is used in an amount of 0.05 to 1.5 parts by weight based on 100 parts by weight of the total composition. When used in an amount of less than 0.05 parts by weight, there is a problem that the dispersibility is lowered, and when it exceeds 1.5 parts by weight, the fluidity is increased to cause a problem that can not spray (spray) mortar.

본 발명에 따라 얻어진 무기질계 세라믹 보수 몰탈 조성물은 비중이 2.0인 분말로서, 몰탈 100 중량%를 기준으로 할 때 물 16 내지 20 중량%의 비로 사용한다. The inorganic ceramic repair mortar composition obtained according to the present invention is a powder having a specific gravity of 2.0, and is used in a ratio of 16 to 20% by weight of water based on 100% by weight of mortar.

(세라믹 보수 몰탈 조성물의 제조)(Production of Ceramic Repair Mortar Composition)

실시예Example 1 One

포틀랜드 시멘트 30 kg, 시중에서 구입한 5호 규사 50 kg, 본 발명에 따른 메타카올린 5 kg, 세라믹 규사로서 카올리나이트 19.4 kg, 증점제로서 에틸셀룰로스 100 g, 혼화제로서 멜멘트(바스프, 독일제품) 500 g을 상온에서 300 리터 용기에 넣고 균일하게 혼합하여 본 발명에 따른 무기계 세라믹 보수 몰탈 조성물 100 kg을 제조하였다. Portland cement 30 kg, commercially available No. 5 silica sand 50 kg, 5 kg metakaolin according to the present invention, kaolinite 19.4 kg as ceramic silica sand, 100 g of ethylcellulose as a thickener, 500 g of mement as a blending agent (BASF, Germany) 100 kg of an inorganic ceramic repair mortar composition according to the present invention was prepared by uniformly mixing the mixture into a 300 liter container at room temperature.

실시예Example 2 내지 10 2 to 10

성분비를 하기 표 1에서 나타낸 것을 제외하고는 실시예 1에서와 동일하게 실시하여 본 발명에 따른 무기계 세라믹 보수 몰탈 조성물 100 kg을 제조하였다.100 kg of the inorganic ceramic repair mortar composition according to the present invention was prepared in the same manner as in Example 1 except that the component ratios are shown in Table 1 below.

(단위 kg)(Unit kg) 실 시 예Example 1One 22 33 44 55 66 77 88 99 1010 포틀랜드 시멘트Portland cement 3535 4040 3535 4040 3535 4040 3535 3535 3535 3535 규사 Quartz sand 4040 3535 4040 3535 4545 4040 4040 4040 4040 4040 메타카올린Metakaolin 55 55 33 33 55 55 55 55 55 55 세라믹 규사
(카올리나이트)
Ceramic silica sand
(Kaolinite)
19.419.4 19.419.4 21.421.4 21.421.4 14.414.4 14.414.4 19.319.3 19.219.2 18.918.9 18.418.4
증점제
(에틸셀룰로스)
Thickener
(Ethylcellulose)
0.10.1 0.10.1 0.10.1 0.10.1 0.10.1 0.10.1 0.20.2 0.30.3 0.10.1 0.10.1
혼화제
(멜멘트)
Admixture
(Melment)
0.50.5 0.50.5 0.50.5 0.50.5 0.50.5 0.50.5 0.50.5 0.50.5 1.01.0 1.51.5
합계Sum 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100

(보수 몰탈 시료의 제조)(Production of Repair Mortar Sample)

실시예 11 내지 20Examples 11-20

상기 실시예 1 내지 10에서 제조된 본 발명에 따른 무기계 세라믹 보수 몰탈 조성물과 물을 하기 표2에 나타낸 비율로 혼합하여 보수 몰탈 시료 100 kg을 얻었다. 실시예 2의 조성물을 사용하는 경우는 실시예 12이고, 동일한 방식으로 실시예 10의 조성물을 사용하는 경우는 실시예 20이다.The inorganic ceramic repair mortar composition according to the present invention prepared in Examples 1 to 10 and water were mixed at a ratio shown in Table 2 below to obtain 100 kg of a repair mortar sample. Example 12 is the case when using the composition of Example 2, and Example 20 when the composition of Example 10 is used in the same manner.

(단위 kg)                                                          (Unit kg) 실 시 예Example 1111 1212 1313 1414 1515 1616 1717 1818 1919 2020 본 발명의 조성물Compositions of the Invention 8484 8383 8282 8181 8080 8484 8383 8282 8181 8080 water 1616 1717 1818 1919 2020 1616 1717 1818 1919 2020 합계Sum 100100 100100 100100 100100 100100 100100 100100 100100 100100 100100

(압축강도 시험)(Compressive strength test)

본 발명에 따른 실시예 11 내지 20에서 얻어진 보수 몰탈 시료에 대한 압축강도 시험을 KS L 5105에 따라 실시하여 재령 3일, 7일 및 28일로 하여 압축강도를 측정하였다. 측정 결과를 하기 표 3에 나타냈다.The compressive strength test of the repair mortar sample obtained in Examples 11 to 20 according to the present invention was carried out in accordance with KS L 5105 to measure the compressive strength at ages 3, 7 and 28 days. The measurement results are shown in Table 3 below.

(휨강도 시험)(Bending Strength Test)

본 발명에 따른 실시예 11 내지 20에서 얻어진 보수 몰탈 시료에 대한 휨 강도 시험을 KS F 2477에 따라 실시하여 재령 3일, 7일 및 28일로 하여 휨 강도를 측정하였다. 측정 결과를 하기 표 3에 나타냈다.The flexural strength test on the repair mortar samples obtained in Examples 11 to 20 according to the present invention was carried out in accordance with KS F 2477 to determine the flexural strength at ages 3, 7 and 28 days. The measurement results are shown in Table 3 below.

(부착강도 시험)(Adhesive Strength Test)

본 발명에 따른 실시예 11 내지 20에서 얻어진 보수 몰탈 시료에 대한 부착강도 시험을 KS F 4918에 따라 실시하여 재령 3일, 7일 및 28일로 하여 부착강도를 측정하였다. 측정 결과를 하기 표 3에 나타냈다.The adhesion strength test on the repair mortar sample obtained in Examples 11 to 20 according to the present invention was carried out in accordance with KS F 4918 to measure the adhesion strength at ages 3, 7 and 28 days. The measurement results are shown in Table 3 below.

(응결시간 시험)(Condensation time test)

본 발명에 따른 실시예 11 내지 20에서 얻어진 보수 몰탈 시료에 대한 응결시간을 KS F 2560에 따라 실시하여 ‘초결‘과 ’종결‘로 하여 응결시간을 측정하였다. 측정 결과를 하기 표 3에 나타냈다.The setting time for the repair mortar sample obtained in Examples 11 to 20 according to the present invention was carried out in accordance with KS F 2560, and the setting time was measured as 'first' and 'terminated'. The measurement results are shown in Table 3 below.

비교예 1 내지 3Comparative Examples 1 to 3

A사, B사 및 C사 제품을 동일한 조건 하에서 실시하여 하기 표 3에 나타냈다.A company, B company, and C company products were implemented under the same conditions, and are shown in Table 3 below.

실 시 예Example 비 교 예Comparative Example 1111 1212 1313 1414 1515 1616 1717 1818 1919 2020 1One 22 33 압축강도
(kgf/cm2)
Compressive strength
(kgf / cm 2 )
3일3 days 272272 294294 248248 268268 226226 292292 256256 236236 240240 216216 196196 190190 184184
7일7 days 456456 462462 426426 432432 396396 466466 418418 382382 386386 362362 355355 331331 324324 28일28 days 534534 538538 492492 486486 434434 520520 484484 442442 416416 402402 368368 360360 361361 휨강도
(kgf/cm2)
Flexural strength
(kgf / cm 2 )
3일3 days 5656 6363 5252 5454 4848 6262 5252 4848 5050 5252 3939 3737 3535
7일7 days 8888 9292 7878 8686 7272 9494 7474 7272 6868 6868 5555 5353 5050 28일28 days 104104 108108 7676 102102 8888 106106 8686 8888 7878 7676 6767 6969 6868 부착강도
(kgf/cm2)
Adhesion strength
(kgf / cm 2 )
3일3 days 10.210.2 12.412.4 9.69.6 10.410.4 9.69.6 12.012.0 9.89.8 8.48.4 9.89.8 9.49.4 7.07.0 6.96.9 6.36.3
7일7 days 17.617.6 18.618.6 15.415.4 16.216.2 12.412.4 16.616.6 12.612.6 9.89.8 12.612.6 11.211.2 8.28.2 7.87.8 7.37.3 28일28 days 21.321.3 23.323.3 18.218.2 18.618.6 16.616.6 19.219.2 15.215.2 12.412.4 14.414.4 14.014.0 10.210.2 10.510.5 9.89.8 응결시간
(시:분)
Setting time
(hour minute)
초결First 3:103:10 2:002:00 3:403:40 3:353:35 3:203:20 3:503:50 4:204:20 5:105:10 4:504:50 5;205; 20 4:504:50 3:003:00 3:403:40
종결closing 4:504:50 4:204:20 5:105:10 5:005:00 4:504:50 5:105:10 6:306:30 7:407:40 6:106:10 6:306:30 9:209:20 9:509:50 9:209:20

상기 표 3에서 알 수 있는 바와 같이, 압축강도는 본 발명의 조성물이 비교예의 것보다 최저 12%, 최고 60% 증가하였고, 휨강도는 본 발명의 조성물이 비교예의 것보다 최저 12%, 최고 180% 증가하였고, 부착강도는 본 발명의 조성물이 비교예의 것보다 최저 27%, 최고 97%까지 상승하였고, 그리고 응결시간은 본 발명의 조성물이 초결에는 비슷하다가 종결에는 비교예의 것보다 2배 이상 단축되었다. As can be seen in Table 3, the compressive strength of the composition of the present invention is increased by at least 12%, up to 60% than that of the comparative example, the flexural strength of the composition of the present invention is at least 12%, up to 180% than that of the comparative example Adhesion strength was increased by 27% and 97% of the composition of the present invention as compared to that of the comparative example, and the setting time was similar to that of the composition of the present invention, but at least 2 times shorter than that of the comparative example. It became.

따라서, 본 발명의 조성물은 종래의 것보다 압축강도, 휨강도, 부착강도 및 응결시간에 있어 매우 탁월한 것으로 밝혀졌다.Therefore, the composition of the present invention was found to be very superior in compressive strength, flexural strength, adhesion strength and setting time than the conventional one.

Claims (5)

조성물 총 100 중량부를 기준으로, 포틀랜드 시멘트 30 내지 50 중량부, 규사 40 내지 65.94 중량부, 메타카올린 1 내지 10 중량부, 세라믹 규사 3 내지 25 중량부, 증점제 0.01 내지 0.3 중량부, 및 혼화제 0.05 내지 1.5 중량부를 포함하는 무기질계 세라믹 보수 몰탈 조성물에 있어서, 메타카올은 고령토를 1250 ℃ 내지 1400 ℃에서 7 내지 9 시간 동안 반응시켜 얻어지는 것을 특징으로 하는 무기질계 세라믹 보수 몰탈 조성물.
30 to 50 parts by weight of Portland cement, 40 to 65.94 parts of silica sand, 1 to 10 parts by weight of metakaolin, 3 to 25 parts by weight of ceramic silica sand, 0.01 to 0.3 parts by weight of thickener, and 0.05 to 3 weight parts of admixture based on 100 parts by weight of the total composition. An inorganic ceramic repair mortar composition comprising 1.5 parts by weight, wherein the metakaol is obtained by reacting kaolin at 1250 ° C. to 1400 ° C. for 7 to 9 hours.
삭제delete 삭제delete 삭제delete 삭제delete
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20180135401A (en) 2017-06-12 2018-12-20 (주)태상건설 the rapid hardening repairing mortar composite with chemical resistance
KR102289253B1 (en) * 2020-08-28 2021-08-11 장용옥 Mortar composition for eco-friendly artificial rock

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100880908B1 (en) 2008-11-27 2009-02-04 임원순 Cement concrete composite and pavement method for concrete bridge using the same
KR100932890B1 (en) 2009-07-20 2009-12-21 주식회사 한국종합기술 Construction method of non-slip ground surface using a inorganic-based aqueous polymer mortar
KR101105490B1 (en) 2011-10-12 2012-01-13 토정건설(주) The construction method of concrete surface's reinforce

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100880908B1 (en) 2008-11-27 2009-02-04 임원순 Cement concrete composite and pavement method for concrete bridge using the same
KR100932890B1 (en) 2009-07-20 2009-12-21 주식회사 한국종합기술 Construction method of non-slip ground surface using a inorganic-based aqueous polymer mortar
KR101105490B1 (en) 2011-10-12 2012-01-13 토정건설(주) The construction method of concrete surface's reinforce

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20180135401A (en) 2017-06-12 2018-12-20 (주)태상건설 the rapid hardening repairing mortar composite with chemical resistance
KR101972775B1 (en) 2017-06-12 2019-04-29 (주)태상건설 the rapid hardening repairing mortar composite with chemical resistance
KR102289253B1 (en) * 2020-08-28 2021-08-11 장용옥 Mortar composition for eco-friendly artificial rock

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