KR100942213B1 - Scrubber with absorbent liquid flowing along the structure, Absorption treatment method of harmful gas, Absorption liquid stripping treatment method and harmful gas absorption and stripping treatment method using the same - Google Patents

Scrubber with absorbent liquid flowing along the structure, Absorption treatment method of harmful gas, Absorption liquid stripping treatment method and harmful gas absorption and stripping treatment method using the same Download PDF

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KR100942213B1
KR100942213B1 KR1020080007423A KR20080007423A KR100942213B1 KR 100942213 B1 KR100942213 B1 KR 100942213B1 KR 1020080007423 A KR1020080007423 A KR 1020080007423A KR 20080007423 A KR20080007423 A KR 20080007423A KR 100942213 B1 KR100942213 B1 KR 100942213B1
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absorbent liquid
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문승현
현주수
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한국에너지기술연구원
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1425Regeneration of liquid absorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/96Regeneration, reactivation or recycling of reactants
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
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Abstract

본 발명은 구조체를 따라 흐르는 흡수액이 구비된 스크러버, 이를 이용한 유해가스의 흡수처리방법, 흡수액 탈거처리방법 및 유해가스 흡수와 탈거 처리방법에 관한 것으로, 그 목적은 세탁소, 도장공장, 인쇄업 등과 같이 휘발성 유기화합물이 발생되는 곳이나 온실가스인 이산화탄소를 흡수 제거하는 공정과 같은 곳에서 흡수액을 일정한 간격과 속도로 공급하도록 내부에 실과 같은 수직의 구조체를 따라 흡수액이 흐르도록 하여 유해가스를 흡수처리하는 장치 및 방법을 제공하는 데 있다.The present invention relates to a scrubber having an absorbent liquid flowing along a structure, a method for treating harmful gases using the same, a method for removing absorbed liquids, and a method for absorbing and removing harmful gases, the purpose of which is volatile such as a laundry, a painting factory, a printing industry, and the like. Absorption treatment of harmful gases by allowing absorbent liquid to flow along a vertical structure such as a seal to supply absorbent liquid at regular intervals and speeds, such as where organic compounds are generated or in the process of absorbing and removing carbon dioxide, a greenhouse gas. And a method.

본 발명의 구성은 흡수탑에 공급되는 흡수액을 사용하여, 유입되는 휘발성 유기화합물을 포함한 유해가스를 흡수처리하는 스크러버에 있어서, 흡수탑본체(20)의 내부 상부쪽에 설치된 흡수탑 상부다공판(27)에 의해 공간부가 형성되어 흡수액이 저장되고, 저장된 흡수액은 흡수탑 상부다공판(27)에 형성된 구조체 관통구를 통해 공급되도록 구성된 상부흡수액 공급조(25)와; 흡수탑본체(20)의 내부 하부쪽에 설치된 흡수탑 하부다공판(28)에 의해 공간부가 형성되어, 흡수탑 하부다공판(28)에 형성된 구조체 관통구를 통해 오염물 가스 성분을 흡수한 흡수액이 유입되도록 구성된 하부흡수액 포집조(26)와; 상기 흡수탑 상부다공판(27)과 흡수탑 하부다공판(28)의 구조체 관통구간을 연결하여 흡수액이 흐르면서 휘발성 유기화합물을 포함한 유해가스를 흡수토록 구성한 구조체(21);를 포함하여 구성된 것을 특징으로 하는 구조체를 따라 흐르는 흡수액이 구비된 스크러버 및 이를 이용한 유해가스 및 염의 흡수 및 탈거방법을 그 기술적 사상의 특징으로 한다.According to the present invention, in the scrubber for absorbing harmful gases including volatile organic compounds introduced therein, the absorption tower upper porous plate 27 provided on the upper side of the absorption tower body 20 is used. An upper absorbent liquid supply tank 25 configured to supply a space through the structure through hole formed in the absorption tower upper perforated plate 27, and the absorbent liquid is stored therein; A space portion is formed by the absorption tower lower perforated plate 28 installed in the lower portion of the absorption tower body 20, and the absorbent liquid that absorbs the contaminant gas component is introduced through the structure through hole formed in the absorption tower lower porous plate 28. A lower absorbent liquid collection tank 26 configured to be; And a structure 21 configured to absorb the harmful gas including the volatile organic compound while the absorption liquid flows by connecting the structure through section of the absorption tower upper porous plate 27 and the absorption tower lower porous plate 28. The scrubber is provided with an absorbent liquid flowing along the structure and the method of absorbing and removing the harmful gas and salt using the same as the characteristics of the technical idea.

흡수, 실, 스크러버, 휘발성유기화합물, 이산화탄소 Absorption, seal, scrubber, volatile organic compounds, carbon dioxide

Description

구조체를 따라 흐르는 흡수액이 구비된 스크러버, 이를 이용한 유해가스의 흡수처리방법, 흡수액 탈거처리방법 및 유해가스 흡수와 탈거 처리방법{Scrubber with internal structure for absorbing agent flor and methods of separating gaseous pollutants and regenerating absorbing agent using the same} Scrubber with absorbent liquid flowing along the structure, Absorption treatment method of harmful gas, Absorption liquid stripping treatment method and harmful gas absorption and stripping treatment method {Scrubber with internal structure for absorbing agent flor and methods of separating gaseous pollutants and regenerating absorbing agent using the same}

본 발명은 휘발성유기화합물 또는 이산화탄소와 같이 제거를 목적으로 하는 가스를 흡수액에 흡수시켜 분리, 제거하기 위하여 구조체를 따라 흐르는 흡수액이 구비된 스크러버, 이를 이용한 유해가스의 흡수처리방법, 흡수액 탈거처리방법 및 유해가스 흡수와 탈거 처리방법에 관한 것으로, 자세하게는 하부 또는 측면에서 유입되는 가스의 흐름방향과 반대 방향으로 흡수액을 흘릴 때 실과 같은 구조체 주위로 흡수액을 흘리는 방법과 흡수 반응 생성물로 발생하는 케이크 등을 연속 제거하는 장치 및 방법, 그리고 흡수액을 회수, 재사용하는 장치 및 방법, 배출되는 청정가스로부터 흡수액을 회수하여 저장탱크로 되돌리는 장치 및 방법에 관한 것이다. The present invention provides a scrubber having an absorbent liquid flowing along a structure for absorbing, separating and removing a gas intended for removal in an absorbent liquid, such as a volatile organic compound or carbon dioxide, a method for treating harmful gases using the same, an absorbent liquid stripping treatment method, and The present invention relates to a method for absorbing and removing harmful gases, and more particularly, a method of flowing an absorbent liquid around a structure such as a seal when the absorbent liquid flows in a direction opposite to the flow direction of the gas flowing from the lower side or the side, and a cake generated from the absorbent reaction product. Apparatus and method for continuous removal, and apparatus and method for recovering and reusing absorbent liquid, and apparatus and method for recovering absorbent liquid from discharged clean gas and returning to storage tank.

스크러버는 액적을 이용하여 오염가스의 흡수가 효과적으로 이루어지게 하기 위하여, 액적, 액막 등의 형성과 세정방법을 여러 가지로 연구하여, 다양한 것이 시판되고 있다. In order to effectively absorb the polluting gas by using the droplets, the scrubber has been researched into various methods of forming and cleaning liquid droplets, liquid films, and the like, and various ones are commercially available.

현재 일반적으로 사용되고 있는 스크러버 장치는 분무탑, 충전식 세정탑, 원심력 세정장치, 벤츄리식, 선회류 식을 들 수 있으며 모든 장치가 흡수액과 오염가스의 접촉을 최대로 하기 위하여 고안되어 있다. The scrubber apparatus currently used generally includes a spray tower, a packed scrubber, a centrifugal force scrubber, a venturi type, a swirl flow type, and all the apparatuses are designed to maximize the contact between the absorbing liquid and the pollutant gas.

종래의 스크러버 장치는 노즐을 통하여 상부에서 분사되는 흡수액과 반대방향인 하부에서 오염 가스를 유입시킴으로써 흡수탑내에서 오염 가스가 정화되는 기술이 대표적으로 활용되고 있다. 이 기술은 분사된 흡수액이 빠르게 하부로 이동하므로 체류시간이 매우 짧으며 액적과 액적이 서로 충돌하여 큰 액적으로 되므로 흡수효율이 낮을 뿐 만 아니라 벽면에 접촉한 액적은 벽면을 타고 내려가므로 오염 가스의 흡수에 크게 기여하지 못하는 단점이 있다. 또한 노즐을 통하여 분사되는 흡수액 중에 입자나 염이 포함되어 있을 경우에는 노즐의 막힘이 발생할 소지가 매우 크다. The conventional scrubber device is typically utilized a technology in which the contaminated gas is purified in the absorption tower by introducing the contaminated gas from the lower side opposite to the absorbing liquid injected from the upper through the nozzle. This technique has a very short residence time because the injected absorbent liquid moves to the lower part rapidly. As the droplets and droplets collide with each other, they become large droplets. As a result, the absorption efficiency is not only low. The disadvantage is that it does not contribute significantly to absorption. In addition, when particles or salts are contained in the absorbent liquid sprayed through the nozzle, the nozzle may be clogged very much.

그 외 종래기술로는 대한민국 특허(등록번호 1002804200000호 2003년 11월 5일)에 이중 다공판 세트 부착형 다공판식 스크러버 방법이 개시되어 있으나 증류탑과 유사한 방식으로서 압력강하와 염 또는 입자의 존재에 따른 막힘 현상이 쉽게 발생한다는 문제점을 가지고 있다. In addition, the prior art is disclosed in the Republic of Korea Patent (Registration No. 1002804200000 No. 5, 2003) is a double-plate plate-attached porous plate scrubber method, but similar to the distillation column due to the pressure drop and the presence of salt or particles The problem is that clogging occurs easily.

또한 대한민국 특허 제 0536547호(2005년 12월 7일 등록) "멀티선 회류를 이용한 흡수 세정장치"에서 활용하는 스크류(Screw) 형태의 안내 깃(Guide Vane)에 의하여 가스의 흐름이 선회류로 전환되게 하고, 선회류의 중심부에 스프레이 노즐(Spray nozzle)을 설치하여 세정액을 분무함으로써 원심력에 의한 분진의 비중차 분리와 회전 유체의 균일한 혼합에 의하여 흡수와 세정 효과를 극대화하는 것을 특징으로 하고 있으나 여전히 상기의 문제점들을 여전히 해소하지 못하고 있다.In addition, the Republic of Korea Patent No. 0536547 (registered on December 7, 2005), the flow of gas to the swirl flow by the screw guide guide vane used in the "absorption cleaning device using multi-wire circulation" By spraying the cleaning liquid by installing a spray nozzle in the center of the swirl flow, it is characterized by maximizing the absorption and cleaning effect by separating the specific gravity of the dust by centrifugal force and uniform mixing of the rotating fluid. Still, the above problems are still not solved.

상기와 같은 문제점을 해결하기 위한 본 발명의 목적은 세탁소, 도장공장, 인쇄업 등과 같이 휘발성 유기화합물이 발생되는 곳이나 온실가스인 이산화탄소를 흡수 제거하는 공정과 같은 곳에서 흡수액을 일정한 간격과 속도로 공급하도록 내부에 실과 같은 수직의 구조체를 따라 흡수액이 흐르도록 하여 유해가스를 흡수처리하는 장치 및 방법을 제공하는 데 있다.An object of the present invention for solving the above problems is to supply the absorbent liquid at regular intervals and speed, such as where the volatile organic compounds are generated, such as laundry, paint shop, printing industry, or the process of absorbing and removing carbon dioxide, which is a greenhouse gas. The present invention provides an apparatus and method for absorbing harmful gases by allowing an absorbent liquid to flow along a vertical structure such as a seal.

또한 본 발명의 다른 목적은 세탁소, 도장공장, 인쇄업 등에서 발생되는 휘발성 유기화합물이나 온실가스인 이산화탄소를 흡수 제거하는 공정에서 흡수액을 연속적으로 재순환시키기 위하여 흡수액에 흡수된 휘발성유기화합물이나 이산화탄소 등을 연속적으로 제거하는 탈거장치 및 방법을 제공하는 데 있다. In addition, another object of the present invention is to continuously volatile organic compounds or carbon dioxide absorbed in the absorbent liquid in order to continuously recycle the absorbent liquid in the process of absorbing and removing carbon dioxide which is a volatile organic compound or greenhouse gas generated in a laundry, painting factory, printing industry, etc. It is to provide a removal apparatus and method for removing.

또한 본 발명의 다른 목적은 세탁소, 도장공장, 인쇄업 등과 같이 휘발성 유기화합물이 발생되는 곳이나 온실가스인 이산화탄소를 흡수 제거하는 공정과 같은 곳에서 휘발성유기화합물이나 이산화탄소의 흡수와 탈거를 동시에 연속처리하는 장치 및 방법을 제공함에 있다.In addition, another object of the present invention is to continuously process the absorption and removal of volatile organic compounds or carbon dioxide at the same time, such as the process of absorbing and removing carbon dioxide, which is a volatile organic compound is generated, such as laundry, paint shop, printing industry, etc. An apparatus and method are provided.

상기한 바와 같은 목적을 달성하고 종래의 결점을 제거하기 위한 과제를 수 행하는 본 발명은 흡수탑에 공급되는 흡수액을 사용하여, 유입되는 휘발성 유기화합물이나 이산화탄소 등과 같은 유해가스를 흡수처리하는 스크러버에 있어서, The present invention which achieves the object as described above and the problem to remove the conventional defects in the scrubber for absorbing harmful gases such as volatile organic compounds, carbon dioxide and the like introduced by using the absorption liquid supplied to the absorption tower. ,

흡수탑본체의 내부 상부쪽에 설치된 흡수탑 상부다공판에 의해 공간부가 형성되어 흡수액이 저장되고, 저장된 흡수액은 흡수탑 상부다공판에 형성된 구조체 관통구를 통해 공급되도록 구성된 상부흡수액 공급조와;An upper absorption liquid supplying tank configured to have a space formed by an absorption tower upper perforated plate installed at an upper side of the absorption tower body so that the absorption liquid is stored, and the stored absorption liquid is supplied through a structure through hole formed in the absorption tower upper porous plate;

흡수탑본체의 내부 하부쪽에 설치된 흡수탑 하부다공판에 의해 공간부가 형성되어, 흡수탑 하부다공판에 형성된 구조체 관통구를 통해 유해가스 성분을 흡수한 흡수액이 유입되도록 구성된 하부흡수액 포집조와;A lower absorbent liquid collection tank configured to have a space formed by an absorption tower lower perforated plate installed at an inner lower side of the absorption tower body, and to absorb an absorbent liquid that has absorbed harmful gas components through a structure through hole formed in the lower absorption plate;

상기 흡수탑 상부다공판과 흡수탑 하부다공판의 구조체 관통구간을 연결하여 흡수액이 흐르면서 휘발성 유기화합물이나 이산화탄소 등과 같은 유해가스를 흡수토록 구성한 구조체;를 포함하여 구성된 것을 특징으로 하는 구조체를 따라 흐르는 흡수액이 구비된 스크러버를 제공함으로써 달성된다.Absorbing liquid flowing along the structure comprising a; structure consisting of absorbing harmful gases such as volatile organic compounds and carbon dioxide while absorbing liquid flows by connecting the structure through section of the absorption tower upper porous plate and the absorption tower lower porous plate It is achieved by providing this equipped scrubber.

상기 구조체는 실 형태인 것을 특징으로 한다.The structure is characterized in that the yarn form.

상기 흡수탑 상부 다공판 및 하부 다공판의 내부에 배열되어 천공된 구조체 관통구는 반지름이 r1이고 구조체 관통구와 구조체 관통구 사이의 간격이 s일 때 세 개의 구조체 관통구는 정삼각형 구조로 배치되고, 한 열과 인접한 열 사이의 높이 차이는

Figure 112009069412892-pat00004
되게 형성한 것을 특징으로 한다.The structure through holes arranged and drilled in the upper and lower perforated plates of the absorption tower have a radius r1 and a spacing between the structure through holes and the structure through holes is s, and the three structure through holes are arranged in an equilateral triangle structure. The height difference between adjacent columns
Figure 112009069412892-pat00004
this Characterized in that formed.

상기 흡수탑본체의 일측에 형성된 가스배출구를 통해 배출된 흡수액이 포함된 가스를 청정 가스와 흡수액으로 분리하여 흡수액과 분리된 청정 가스는 최종 가스 배출구으로 배출하고, 분리된 흡수액은 흡수액 회수관 1을 통하여 배출토록 구성된 디미스터 1(demister 1)와;The gas containing the absorbent liquid discharged through the gas discharge port formed at one side of the absorption tower body is separated into a clean gas and an absorbent liquid, and the clean gas separated from the absorbent liquid is discharged to the final gas outlet, and the separated absorbent liquid is absorbed into the absorbent liquid recovery pipe 1. Demister 1 configured to be discharged through;

흡수액 회수관 1을 통해 배출된 흡수액을 회수하여 상부흡수액 공급조의 액위를 일정하게 유지할 수 있도록 흡수액을 보충 공급하는 흡수액 보충 탱크;를 더 포함하여 구성한 것을 특징으로 한다.And an absorbent liquid replenishment tank for replenishing and supplying the absorbent liquid so as to recover the absorbed liquid discharged through the absorbent liquid recovery pipe 1 to maintain a constant level of the upper absorbent liquid supply tank.

상기 하부흡수액 포집조에 저장후 배출되는 하부흡수액 중 고형물을 제거하는 필터와; A filter for removing solids from the lower absorbent liquid stored in the lower absorbent liquid collection tank and discharged;

열매체를 이용하여 필터를 지난 고형물이 제거된 하부흡수에 흡수된 유해가스를 탈거하는 흡수액 탈거탑과;An absorption liquid stripping tower for removing harmful gas absorbed in the lower absorption section through which the solid material passing through the filter is removed using a heat medium;

흡수액 탈거탑에서 유해가스가 탈거된 흡수액을 흡수탑 본체로 재공급 하는 흡수액 순환용 회수 펌프;를 더 포함하여 구성한 것을 특징으로 한다.Characterized in that the configuration further comprises a; absorbing liquid circulation recovery pump for supplying the absorbent liquid from the absorbent liquid stripping tower to remove the harmful liquid removed to the absorber body.

상기 흡수액 탈거탑은 흡수액 탈거과정 중 생성된 탈거가스를 배출하는 탈거가스 배출구와;The absorption liquid stripping tower includes a stripping gas discharge port configured to discharge stripping gas generated during the stripping process of the absorbent liquid;

탈거가스 배출구를 통해 배출된 가스를 기액 분리하여 탈거가스는 배출하여 회수시키고, 분리된 흡수액은 흡수액 회수관 2를 통하여 흡수액 보충 탱크로 회수시키는 디미스터 2(Demister2);를 더 포함하여 구성한 것을 특징으로 한다.Characterized in that it further comprises a demister 2 (Demister 2) for recovering by removing the gas discharged through the stripping gas outlet gas-liquid separation and discharge the stripping gas, the separated absorbent liquid to the absorbent liquid supplement tank through the absorbent liquid recovery pipe 2. It is done.

상기 흡수액 탈거탑은,The absorption liquid stripping column,

상부쪽에서 상부 열매체 다공판에 의해 나뉘어져 형성된 열매체 공급조와;A heat medium supply tank formed by being divided by an upper heat medium porous plate at an upper side thereof;

하부쪽에서 하부 열매체 다공판에 의해 나뉘어져 형성된 열매체 포집조와;A heat medium collecting tank formed by being divided by a lower heat medium porous plate at a lower side thereof;

상부 열매체 다공판 및 탈거탑 상부 다공판에 의해 형성된 탈거될 흡수액 저장조와;An absorbent liquid reservoir to be removed formed by the upper heat medium porous plate and the stripping column upper porous plate;

탈거탑 하부 다공판 및 하부 열매체 다공판에 의해 형성된 탈거된 흡수액 저장조와;A stripped absorbent liquid storage tank formed by the stripping column lower porous plate and the lower heating medium porous plate;

상기 상부 열매체 다공판, 탈거탑 상부 다공판, 탈거탑 하부 다공판 및 하부 열매체 다공판을 관통하는 열매체 흐름관으로 구성된 것을 특징으로 한다.The upper heat medium porous plate, the stripping column upper porous plate, the stripping column lower porous plate and the lower heat medium porous plate is characterized in that consisting of a heat medium flow tube.

상기 흡수액 탈거탑은, The absorption liquid stripping column,

열매체 포집조 일측에 형성되어 사용된 열매체를 배출하는 열매체 배출구와;A heat medium discharge port formed on one side of the heat medium collecting tank and discharging the used heat medium;

열매체 배출구로 배출된 열매체를 펌핑하는 열매체 순환용 펌프와;A heat medium circulation pump for pumping the heat medium discharged to the heat medium outlet;

열매체 순환용 펌프로부터 순환 공급되는 열매체를 공급하도록 열매체 공급조 일측에 형성된 열매체 공급구;를 더 포함하여 구성한 것을 특징으로 한다.And a heat medium supply port formed on one side of the heat medium supply tank to supply the heat medium circulated and supplied from the heat medium circulation pump.

상기 탈거탑 상부 다공판및 탈거탑 하부 다공판에는 탈거될 흡수액이 열매체 흐름관 외벽을 타고 흐른 후 탈거탑 하부 다공판에 형성된 흡수액 흐름구를 통해 탈거된 흡수액 저장조에 저장되도록 흡수액 흐름구가 형성된 것을 특징으로 한다.In the stripping column upper porous plate and the stripping column lower porous plate, the absorbent liquid flow port is formed such that the absorbent liquid to be removed flows through the outer wall of the heat medium flow tube and is stored in the stripped absorbent liquid storage tank through the absorbent liquid flow port formed in the stripper lower plate. It features.

또한 본 발명은 휘발성 유기화합물이나 이산화탄소를 포함한 유해가스를 흡수액으로부터 탈거하는 흡수액 탈거처리방법에 있어서, 상기 장치를 구비한 후, 흡수액을 흡수탑 상부다공판 및 흡수탑 하부다공판을 연결하는 실 모양의 구조체를 따라 흡수액이 흐르면서 유해가스를 흡수토록 한 것을 특징으로 하는 구조체를 따라 흐르는 흡수액이 구비된 흡수탑을 이용한 유해가스의 흡수처리방법을 제공함으로써 달성된다.The present invention also provides an absorbent liquid stripping treatment method for removing harmful gases including volatile organic compounds or carbon dioxide from an absorbent liquid, and after the apparatus is provided, a thread shape connecting the absorbent liquid to the upper column of the absorption tower and the lower plate of the absorption tower. It is achieved by providing an absorption treatment method for harmful gases using an absorption tower equipped with an absorption liquid flowing along the structure, characterized in that the absorption liquid flows along the structure of the absorption liquid.

또한 본 발명은 휘발성 유기화합물을 포함한 유해가스 및 흡수액의 탈거처리방법에 있어서, 상기 장치를 구비한 후, 열매체는 다공판을 통해 형성된 열매체 흐름관으로 열매체 공급조에서 포집조로 이동하며, 흡수탑을 거친 탈거될 흡수액은 저장조에서 다공판에 형성된 흡수액 흐름구를 통해 열매체 흐름관 외부를 따라 흐르면서 흡수액을 재생토록 하는 방법을 특징으로 하는 열매체 흐름관을 따라 흐르는 흡수액이 구비된 탈거탑을 이용한 흡수액 탈거처리방법을 제공함으로써 달성된다.In another aspect, the present invention is a method for removing harmful gases and absorbent liquid containing volatile organic compounds, the heating medium is moved to the collection tank from the heating medium supply tank to the heating medium flow pipe formed through the porous plate, the absorption tower The absorbent liquid to be stripped is absorbed liquid stripping treatment using the stripping tower equipped with the absorbent liquid flowing along the heat medium flow tube characterized in that the absorbent liquid flows along the outside of the heat medium flow tube through the absorbent flow hole formed in the porous plate in the reservoir. By providing a method.

또한 본 발명은 휘발성 유기화합물을 포함한 유해가스의 흡수와 탈거 처리방법에 있어서, 상기 장치를 구비한 후, 흡수탑에서 실 모양의 구조체를 따라 흡수액이 흐르면서 유해가스를 흡수하고 동시에 사용된 흡수액을 탈거탑에서 열매체에 의해 탈거하여 재생된 흡수액을 흡수탑으로 재순환시키는 처리방법으로 유해가스 흡수와 탈거를 연속적으로 동시에 처리하는 방법을 특징으로 하는 구조체를 따라 흐르는 흡수액이 구비된 흡수탑과 탈거탑을 이용한 유해가스 흡수와 탈거 처리방법 을 제공함으로써 달성된다.In addition, the present invention is a method for absorbing and removing harmful gases including volatile organic compounds, and after the apparatus is provided, absorbing liquid flows along the thread-shaped structure in the absorption tower to absorb harmful gases and simultaneously remove the used absorbing liquid. A method of recycling the absorbed liquid removed from the tower by the heat medium and recycling it to the absorption tower. The absorption tower and stripping tower equipped with the absorption liquid flowing along the structure are characterized by the method of simultaneously treating the harmful gas absorption and stripping. By providing a method for the absorption and removal of hazardous gases.

본 발명은 휘발성유기화합물 또는 이산화탄소와 같이 제거를 목적으로 하는 성분이 포함된 가스가 하부 또는 측면에서 유입되고 그 반대 방향으로 흡수액이 흐르면서 목표로 하는 성분의 가스를 흡수, 제거하는 세정장치에 관한 것으로서 흡수액이 실과 같은 형태를 가진 구조체를 따라 흐르도록 구성되어 흡수액을 분사시키지 않고 구조체를 타고 흐르도록 유도 하므로서 사용되는 흡수액의 양이 25∼50% 절약되고, 흡수탑 내에서 흡수액의 체류시간이 길어 진다는 장점과, The present invention relates to a cleaning device that absorbs and removes a target component gas while a gas containing a component for removal, such as a volatile organic compound or carbon dioxide, is introduced from the lower side or the side, and the absorbent flows in the opposite direction. The absorbent liquid is configured to flow along the structure having a thread-like structure, leading to flow through the structure without spraying the absorbent liquid, thereby saving 25 to 50% of the absorbent liquid used and increasing the residence time of the absorbent liquid in the absorption tower. With its advantages,

또한 구조체를 따라 흡수액을 흘리면 흡수액을 자유낙하시키거나 혹은 노즐로 분사시킬 때 액적간의 중첩이나 액적이 벽면에 붙어 흘러내리는 단점이 해소되며 흡수액의 사용량이 줄고 흡수액과 반응가스와의 접촉시간이 길어짐으로서 흡수효율을 향상시킬 수 있다는 장점과,In addition, the flow of the absorbent liquid along the structure eliminates the disadvantages of free fall of the absorbent liquid or the overlapping of the droplets and the dropping of the droplets on the wall when sprayed by the nozzle. The amount of the absorbent liquid is reduced and the contact time between the absorbent liquid and the reaction gas is increased The advantage of improving the absorption efficiency,

또한 본 발명은 제거가스가 흡수된 흡수액은 흡수탑 후단에 설치된 탈거탑에서 열매체에 의해 탈거된 후 재생 흡수액이 흡수탑으로 순환 공급되고, 탈거탑은 흡수탑과 같은 원리이나 열매체 공급/포집조가 형성되고, 흡수액이 실 모양의 구조체를 타고 흐르는 대신 열매체 흐름관을 타고 흐르면서 고온에서 고농도의 탈거가스가 배출되므로 탈거가스는 회수가 용이하다는 장점과,In addition, the present invention is the absorption liquid absorbed by the removal gas is removed by the heat medium in the stripping column installed at the rear end of the absorption tower and then the regenerated absorption liquid is circulated and supplied to the absorption tower, the stripping column is the same principle as the absorption tower but the heat medium supply / collection tank is formed And, because the absorbent liquid flows through the heat medium flow pipe instead of flowing through the thread-like structure, high concentration stripping gas is discharged at a high temperature, so stripping gas is easy to recover.

또한 사용된 흡수액은 흡수탑에서 바로 탈거탑으로 들어가 열매체에 의해 탈거된 후 흡수탑으로 재생 공급되므로 흡수반응과 탈거반응이 동시에 일어나 제거가 스의 연속적인 흡수/탈거가 가능하다는 장점을 가진 유용한 발명으로 산업상 그 이용이 크게 기대되는 발명인 것이다.In addition, the used absorbent liquid enters the stripping column directly from the absorption tower and is removed by the heat medium, and then regenerated and supplied to the absorption tower, so that the absorption and stripping reactions occur at the same time, so that the continuous absorption / removal of the removal gas is possible. As such, the invention is an invention that is expected to be greatly used.

이하 본 발명의 실시 예인 구성과 그 작용을 첨부도면에 연계시켜 상세히 설명하면 다음과 같다. 또한 본 발명을 설명함에 있어서, 관련된 공지기능 혹은 구성에 대한 구체적인 설명이 본 발명의 요지를 불필요하게 흐릴 수 있다고 판단되는 경우 그 상세한 설명은 생략한다.Hereinafter, the configuration and the operation of the embodiments of the present invention will be described in detail with reference to the accompanying drawings. In describing the present invention, when it is determined that a detailed description of a related known function or configuration may unnecessarily obscure the subject matter of the present invention, the detailed description thereof will be omitted.

도 1은 본 발명의 바람직한 실시 예를 나타낸 설치상태 구성도이며, 도 2는 본 발명에서 사용하는 실 모양의 구조체를 균일하게 배치한 흡수탑의 상세도이고, 도 3은 흡수된 가스를 탈거하면서 흡수액을 재생하는 탈거탑의 상세도인데, 도시된 바와 같이 본 발명의 구성은 흡수제를 일정한 속도와 간격으로 흐르도록 유도하는 실 모양의 구조체(21)가 내부에 설치된 흡수탑 본체(20)와, 흡수탑 본체(20)에서 사용된 흡수액을 회수하여 재사용하는 과정에서 이물질 등을 처리하는 필터(30)와, 흡수탑에서 흡수액에 흡수된 유해가스를 탈거하여 흡수액을 재생하는 흡수액탈거탑(40)과, 그리고 오염가스를 제거하고 배출되는 청정가스로부터 흡수제를 응축, 회수하는 디미스터(12, 55)로 구성된다. 1 is a configuration diagram showing a preferred embodiment of the present invention, Figure 2 is a detailed view of the absorption tower in which the yarn-like structure used in the present invention is uniformly arranged, Figure 3 while removing the absorbed gas Detailed illustration of the stripping column for regenerating the absorbent liquid, as shown in the configuration of the present invention, the absorption tower body 20 is provided with a thread-like structure 21 to guide the absorbent to flow at a constant speed and interval, and Filter 30 for treating foreign matters in the process of recovering and reusing the absorbent liquid used in the absorption tower body 20, and the absorbent liquid stripping column 40 for removing the harmful gas absorbed in the absorbent liquid from the absorption tower to regenerate the absorbent liquid. And demisters 12 and 55 for removing contaminated gas and condensing and recovering the absorbent from the discharged clean gas.

도 1과 도 2를 참조하여 보다 상세히 설명하면, 본 발명은 분리 제거해야 할 유해 성분이 포함된 가스가 유입되는 가스 유입구(10)가 설치되어 이를 통해 유입된 유해가스가 흡수탑 본체(20)의 하부에서 상부를 거치면서 흡수액과 반응하여 유해 성분이 제거된 후 가스배출구(11)를 통하여 배출된다.Referring to Figures 1 and 2 in more detail, the present invention is installed gas inlet 10 through which gas containing harmful components to be separated and removed is installed harmful gas through the absorption tower body 20 After passing through the upper part from the lower part of the reaction, the harmful components are removed and then discharged through the gas outlet 11.

일부 흡수액이 포함되어 흡수탑에서 배출되는 배출가스는 디미스터 1(demister 1)(12)에서는 가스와 흡수액이 분리된다. The exhaust gas discharged from the absorption tower by including some absorbent liquid is separated from the gas and the absorbent liquid in the demister 1 (12).

이후 분리된 흡수액은 흡수액 회수관 1(36)을 통하여 흡수액 보충 탱크(35)로 회수되며 흡수액과 분리된 청정 가스는 최종 가스 배출구(13)으로 배출된다. Thereafter, the separated absorbent liquid is recovered to the absorbent liquid replenishment tank 35 through the absorbent liquid recovery pipe 1 36, and the clean gas separated from the absorbent liquid is discharged to the final gas outlet 13.

흡수액 보충 탱크(35)에서는 상부흡수액 공급조(25)의 액위를 일정하게 유지할 수 있도록 흡수액을 보충 공급하는 역할을 한다. The absorbent liquid replenishment tank 35 serves to replenish the absorbent liquid so that the liquid level of the upper absorbent liquid supply tank 25 can be kept constant.

상부흡수액은 흡수탑 상부다공판(27)을 거쳐 실 형태의 구조체(21) 표면을 따라 흐르면서 유입가스 중의 유해가스 성분을 흡수하고 흡수탑 하부다공판(28)을 지나 하부 흡수액 포집조(26)로 저장된다. The upper absorbent liquid flows along the surface of the structure 21 in the form of a thread through the absorber upper porous plate 27 to absorb harmful gas components in the inflow gas and passes through the absorber lower porous plate 28 to absorb the lower absorbent liquid tank 26. Is stored as.

하부흡수액은 필터(30)를 지나면서 고형물이 제거된 흡수액(31)으로 된 후, 흡수액 탈거탑(40)으로 공급되고 흡수액 탈거탑(40)에서 유해가스가 탈거된 재생 흡수액(32)이 흡수액 순환용 회수 펌프(37)에 의하여 구조체 흡수탑 본체(20)로 재공급 된다. 재공급되는 흡수액(33)은 탈거 후 공급되는 재생 흡수액(32)과 보충 흡수액(34)과 혼합되어 상부흡수액 공급조(25)에 공급된다.The lower absorbent liquid passes through the filter 30 to become the absorbent liquid 31 from which the solids are removed, and then is supplied to the absorbent liquid stripping column 40 and the regenerated absorbent liquid 32 from which the harmful gas is removed from the absorbent liquid stripping column 40 is absorbed. It is supplied back to the structure absorption tower main body 20 by the recovery pump 37 for circulation. The absorbent liquid 33 to be resupplied is mixed with the regenerated absorbent liquid 32 and the supplemental absorbent liquid 34 supplied after being removed and supplied to the upper absorbent liquid supply tank 25.

흡수액 탈거탑(40)에서 흡수액 탈거과정중 생성된 탈거가스는 배출구(54)를 통해 배출되어 디미스터 2(Demister2)(55)에서 기액 분리된 후 회수될 탈거가 스(57)는 다음 회수공정으로 넘어간다. 또한 디미스터 2(Demister2)(55)에서 분리된 흡수액은 흡수액 회수관 2(56)을 통하여 흡수액 보충 탱크(35)로 회수된다.The stripping gas generated during the absorption liquid stripping process in the absorbent liquid stripping column 40 is discharged through the discharge port 54, and the stripping gas 57 to be recovered after gas-liquid separation in the Demister 2 55 is subjected to the next recovery process. To the next. In addition, the absorbent liquid separated from the demister 2 (55) is recovered to the absorbent liquid replenishment tank 35 through the absorbent liquid recovery tube 2 (56).

또한 흡수액 탈거탑(40)에서 사용된 열매체는 열매체 공급조(43)와 열매체 포집조(44)를 연결하는 열매체 흐름관(41) 내부를 흘러 열매체 포집조(44) 일측에 형성된 열매체 배출구(51)를 통해 배출된 후 열매체 순환용 펌프(53)에 의해 상부의 열매체 공급조(43) 일측에 형성된 열매체 공급구(52)를 통해 열매체 공급조(43)로 공급되어 순환 된다.In addition, the heat medium used in the absorbent liquid stripping column 40 flows through the inside of the heat medium flow pipe 41 connecting the heat medium supply tank 43 and the heat medium collecting tank 44, and the heat medium outlet 51 formed on one side of the heat medium collecting tank 44. After being discharged through) through the heat medium supply port 52 formed on one side of the heat medium supply tank 43 by the heat medium circulation pump 53 is supplied to the heat medium supply tank 43 and circulated.

도 2는 흡수탑 본체(2)의 내부에 설치되는 실 모양의 구조체(21)의 설치 형태를 나타낸 것으로, 구조체는 일정한 간격으로 배치되는데, 구조체(21)는 이를 고정 지지하고 있는 흡수탑 상/하부 다공판(27, 28) 및 그 내부에 형성된 구조체 관통구(29)의 배열 형상에 따라 배열되게 구성된다.2 shows an installation form of a thread-shaped structure 21 installed inside the absorption tower body 2, the structures are arranged at regular intervals, the structure 21 is on the absorption tower that is fixedly supported / The lower porous plates 27 and 28 and the structure through-holes 29 formed therein are configured to be arranged.

특히, 흡수탑 상부 다공판(27) 및 흡수탑 하부 다공판(28)의 내부에 배열되어 천공된 구조체 관통구(29)는 반지름이 r1이고 구조체 관통구(29)와 구조체 관통구(29) 사이의 간격이 s일 때 세 개의 구조체 관통구는 정삼각형 구조로 배치되어야 하며 한 열과 인접한 열 사이의 높이 차이는

Figure 112009069412892-pat00005
이어야 한다.In particular, the structure through holes 29 arranged and perforated in the absorption tower upper perforated plate 27 and the absorption tower lower perforated plate 28 have a radius r1 and the structure through holes 29 and the structure through holes 29. When the spacing between them is three, the three through-holes should be arranged in an equilateral triangle structure and the height difference between
Figure 112009069412892-pat00005
Should be

이에 따라 흡수탑 상부 다공판(27) 및 흡수탑 하부 다공판(28)의 구조체 관통구(29)의 크기보다 작게 형성되는 실 모양의 구조체(21)가 흡수탑 본체(20)의 내부에 수직방향으로 배열되어 설치되게 된다. Accordingly, the thread-shaped structure 21 formed smaller than the size of the structure through hole 29 of the absorption tower upper porous plate 27 and the absorption tower lower porous plate 28 is perpendicular to the inside of the absorption tower body 20. It is arranged to be arranged in the direction.

도 3은 흡수액 탈거탑(40)을 상세히 나타낸 그림으로 흡수액 탈거탑(40)은 상부쪽에서 상부 열매체 다공판(58)에 의해 나뉘어져 형성된 열매체 공급조(43)와 하부쪽에서 하부 열매체 다공판(59)에 의해 나뉘어져 형성된 열매체 포집조(44)와, 상부 열매체 다공판(58) 및 탈거탑 상부 다공판(47)에 의해 형성된 탈거될 흡수액 저장조(45)와 탈거탑 하부 다공판(48) 및 하부 열매체 다공판(59)에 의해 형성된 탈거된 흡수액 저장조(46) 그리고 상기 상부 열매체 다공판(58), 탈거탑 상부 다공판(47), 탈거탑 하부 다공판(48) 및 하부 열매체 다공판(59)을 관통하는 열매체 흐름관(41)으로 구성되어 있다. 3 is a detailed view of the absorbent liquid stripping column 40. The absorbent liquid stripping column 40 is formed of a heat medium supply tank 43 formed by being divided by an upper heat medium porous plate 58 at an upper side and a lower heat medium porous plate 59 at a lower side. The heat medium collecting tank 44 formed by dividing by the upper portion, the absorbent liquid storage tank 45 to be removed formed by the upper heat medium porous plate 58 and the stripping column upper porous plate 47, and the lower column porous plate 48 and the lower heating medium to be removed. The stripped absorbent liquid storage tank 46 formed by the porous plate 59 and the upper heat medium porous plate 58, the stripping column upper porous plate 47, the stripping column lower porous plate 48, and the lower thermal medium porous plate 59. It consists of the heat medium flow pipe 41 which penetrates.

상부 열매체 다공판(58), 탈거탑 상부 다공판(47), 탈거탑 하부 다공판(48) 및 하부 열매체 다공판(59)는 다수개의 열매체 흐름관(41)이 설치되도록 다수개의 천공구가 배열되어 형성된다. The upper heat medium porous plate 58, the stripping column upper perforated plate 47, the stripping column lower perforated plate 48, and the lower heat medium porous plate 59 are provided with a plurality of drilling tools such that a plurality of heat medium flow tubes 41 are installed. Arranged and formed.

열매체는 열매체 공급조(43)와 열매체 포집조(44)를 연결하는 열매체 흐름관(41) 내부를 흘러 열매체 포집조(44) 일측에 형성된 열매체 배출구(51)를 통해 배출된 후 열매체 순환용 펌프(53)에 의해 상부의 열매체 공급조(43) 일측에 형성된 열매체 공급구(52)를 통해 열매체 공급조(43)로 공급되어 순환 된다. 탈거될 흡수액은 탈거될 흡수액 저장조(45)에서 열매체 흐름관 외부를 타고 흐르면서 탈거과정을 거쳐 탈거된 흡수액 저장조(46)에 포집된 후 흡수탑으로 공급된다.The heat medium flows through the inside of the heat medium flow pipe 41 connecting the heat medium supply tank 43 and the heat medium collecting tank 44, and is discharged through the heat medium outlet 51 formed on one side of the heat medium collecting tank 44, and then the heat medium circulation pump It is supplied to the heat medium supply tank 43 through the heat medium supply port 52 formed at one side of the heat medium supply tank 43 by the upper portion 53 to be circulated. Absorbent liquid to be removed flows through the heat medium flow pipe from the absorbent liquid storage tank 45 to be removed, collected in the stripped absorbent liquid storage tank 46 through the stripping process and then supplied to the absorption tower.

상기 열매체는 열매체 공급조(43)의 하부를 이루는 상부 열매체 다공판(58)에 형성된 열매체 흐름관 입구(49)를 통해 열매체 흐름관(41) 내부를 흐른 후 하부 열매체 다공판(59)에 형성된 열매체 흐름관 입구(도시없음)를 통해 열매체 포집조(44)로 배출되고, 탈거될 흡수액(31)은 탈거될 흡수액 저장조(45)의 탈거탑 상부 다공판(47)에 형성된 흡수액 흐름구(42)를 통해 열매체 흐름관(41) 외벽을 타고 흐른 후 탈거탑 하부 다공판(48)에 형성된 흡수액 흐름구(도시없음)를 통해 탈거된 흡수액 저장조(46)에 저장된다. The heat medium flows into the heat medium flow tube 41 through the heat medium flow tube inlet 49 formed in the upper heat medium porous plate 58 forming the lower part of the heat medium supply tank 43, and then forms the lower heat medium porous plate 59. Absorbent liquid flow port 42 formed in the stripping column upper porous plate 47 of the absorbent liquid storage tank 45 to be discharged to the heat medium collecting tank 44 through the heat medium flow pipe inlet (not shown), to be removed After flowing through the outer wall of the heat medium flow tube 41) is stored in the absorbent liquid storage tank 46 is removed through the absorbent liquid flow port (not shown) formed in the lower porous plate 48 of the stripping column.

흡수액 탈거과정에서 생성된 탈거가스는 배출구(54)를 통해 배출되어 디미스터 2(Demister2)(55)에서 기액 분리된 후 회수될 탈거가스(57)로 배출되어 회수하게 된다.The stripping gas generated in the absorbent liquid stripping process is discharged through the discharge port 54 and separated from the gas liquid in the Demister 2 55 to be discharged and recovered as the stripping gas 57 to be recovered.

본 발명은 상술한 특정의 바람직한 실시 예에 한정되지 아니하며, 청구범위에서 청구하는 본 발명의 요지를 벗어남이 없이 당해 발명이 속하는 기술분야에서 통상의 지식을 가진 자라면 누구든지 다양한 변형실시가 가능한 것은 물론이고, 그와 같은 변경은 청구범위 기재의 범위 내에 있게 된다. The present invention is not limited to the above-described specific preferred embodiments, and various modifications can be made by any person having ordinary skill in the art without departing from the gist of the present invention claimed in the claims. Of course, such changes will fall within the scope of the claims.

도 1은 본 발명의 바람직한 실시예를 나타낸 설치상태의 구성도이고,1 is a configuration diagram of an installation state showing a preferred embodiment of the present invention,

도 2는 본 발명에서 사용하는 흡수탑 본체의 구조체 상세도이고,Figure 2 is a detailed view of the structure of the absorption tower body used in the present invention,

도 3은 본 발명에서 사용하는 흡수액 세정탑의 상세도이다.3 is a detailed view of the absorbent liquid washing column used in the present invention.

<도면의 주요부분에 대한 부호의 설명><Description of the symbols for the main parts of the drawings>

(10) : 가스 유입구 (11) : 가스배출구(10): gas inlet (11): gas outlet

(12) : 디미스터(Demister) 1 (13) : 최종 가스 배출구(12): Demister 1 (13): Final gas outlet

(20) : 흡수탑 본체 (21) : 구조체(string)20: absorption tower body 21: structure (string)

(22) : 구조체 이송 모터 (25) : 상부 흡수액 공급조22: structure transfer motor 25: upper absorbent liquid supply tank

(26) : 하부 흡수액 포집조 (27) : 흡수탑 상부 다공판(26): lower absorbent liquid collection tank (27): absorption tower upper perforated plate

(28) : 흡수탑 하부 다공판 (29) : 구조체 관통구(28): Perforated plate under absorption tower (29): Structure through hole

(30) : 필터(Filter) (31) : 탈거탑으로 유입 흡수액(30): Filter (31): Absorption liquid flowing into the stripping column

(32) : 탈거된 흡수액 (33) : 탈거후 재공급되는 흡수액(32): stripped absorbent liquid (33): stripped absorbent liquid

(34) : 보충 흡수액 (35) : 흡수액 보충 탱크34: replenishment absorbent liquid 35: absorbent liquid replenishment tank

(36) : 흡수액 회수관1 (37) : 흡수액 순환용 회수 펌프(36) Absorbent liquid recovery pipe 1 (37): Absorbent liquid recovery pump

(40) : 흡수액 탈거탑 (41) : 열매체 흐름관(40): Absorbent stripping column (41): Heat medium flow tube

(42) : 흡수액 흐름구 (43) : 열매체 공급조(42) Absorbent liquid flow port 43: Heat medium supply tank

(44) : 열매체 포집조 (45) : 탈거될 흡수액 저장조(44): heat medium collecting tank (45): absorbent liquid storage tank to be removed

(46) : 탈거된 흡수액 저장조 (47) : 탈거탑 상부 다공판(46): stripped absorbent liquid storage tank (47): stripping column upper perforated plate

(48) : 탈거탑 하부 다공판 (49) : 열매체 흐름관 입구(48): perforated plate below the stripping column (49): heat medium flow pipe entrance

(51) : 열매체 배출구 (52) : 열매체 공급구(51): heat medium outlet (52): heat medium supply port

(53) : 열매체 순환용 펌프 (54) : 탈거가스 배출구(53): pump for heat medium circulation (54): stripping gas outlet

(55) : 디미스터(Demister) 2 (56) : 흡수액 회수관2(55): Demister 2 (56): absorbent liquid collection tube 2

(57) : 회수될 탈거가스 (58) : 상부 열매체 다공판(57): stripping gas to be recovered (58): upper heat medium porous plate

(59) : 하부 열매체 다공판(59): lower heating medium porous plate

Claims (12)

흡수탑에 공급되는 흡수액을 사용하여, 유입되는 휘발성 유기화합물이나 이산화탄소 성분을 포함한 유해가스를 흡수처리하는 스크러버에 있어서, In a scrubber for absorbing harmful gases including volatile organic compounds and carbon dioxide components introduced by using the absorbent liquid supplied to the absorption tower, 흡수탑본체(20)의 내부 상부쪽에 설치된 흡수탑 상부다공판(27)에 의해 공간부가 형성되어 흡수액이 저장되고, 저장된 흡수액은 흡수탑 상부다공판(27)에 형성된 구조체 관통구를 통해 공급되도록 구성된 상부흡수액 공급조(25)와;A space is formed by the absorption tower upper perforated plate 27 installed in the upper portion of the absorption tower body 20 so that the absorption liquid is stored, and the stored absorption liquid is supplied through the structure through hole formed in the absorption tower upper porous plate 27. An upper absorption liquid supply tank 25 configured; 흡수탑본체(20)의 내부 하부쪽에 설치된 흡수탑 하부다공판(28)에 의해 공간부가 형성되어, 흡수탑 하부다공판(28)에 형성된 구조체 관통구를 통해 유해가스 성분을 흡수한 흡수액이 유입되도록 구성된 하부흡수액 포집조(26)와;A space portion is formed by the absorption tower lower porous plate 28 installed in the lower portion of the absorption tower body 20, and the absorption liquid absorbing the harmful gas component is introduced through the structure through hole formed in the absorption tower lower porous plate 28. A lower absorbent liquid collection tank 26 configured to be; 상기 흡수탑 상부다공판(27)과 흡수탑 하부다공판(28)의 구조체 관통구간을 연결하여 구조체 표면을 따라 흡수액이 흐르면서 휘발성 유기화합물이나 이산화탄소 성분을 포함한 유해가스를 흡수토록 구성한 구조체(21);를 포함하여 구성된 것을 특징으로 하는 구조체를 따라 흐르는 흡수액이 구비된 스크러버.The structure 21 which connects the structure through section of the absorption tower upper porous plate 27 and the absorption tower lower porous plate 28 to absorb harmful gas including volatile organic compounds or carbon dioxide components while the absorption liquid flows along the structure surface Scrubber provided with an absorption liquid flowing along the structure, characterized in that configured to include. 제 1항에 있어서,The method of claim 1, 상기 구조체(21)는 실 형태인 것을 특징으로 하는 구조체를 따라 흐르는 흡수액이 구비된 스크러버.Scrubber provided with the absorbent liquid flowing along the structure, characterized in that the structure 21 is in the form of a yarn. 제 1항에 있어서,The method of claim 1, 상기 흡수탑 상부다공판(27) 및 흡수탑 하부다공판(28)의 내부에 배열되어 천공된 구조체 관통구는 반지름이 r1이고 구조체 관통구(29)와 구조체 관통구(29) 사이의 간격이 s일 때 세 개의 구조체 관통구는 정삼각형 구조로 배치되고, 한 열과 인접한 열 사이의 높이 차이는
Figure 112009069412892-pat00006
이 되게 형성한 것을 특징으로 하는 구조체를 따라 흐르는 흡수액이 구비된 스크러버.
The through-hole structured and arranged in the absorption tower upper perforated plate 27 and the absorption tower lower perforated plate 28 has a radius r1 and a distance between the structure through-hole 29 and the structure through-hole 29 is s. , The three through-holes are arranged in equilateral triangles, and the height difference between one row
Figure 112009069412892-pat00006
Scrubber provided with an absorbing liquid flowing along the structure, characterized in that formed to be.
제 1항에 있어서,The method of claim 1, 상기 흡수탑본체(20)의 일측에 형성된 가스배출구(11)를 통해 배출된 흡수액이 포함된 가스를 청정 가스와 흡수액으로 분리하여 기액 분리된 청정 가스는 최종 가스 배출구(13)으로 배출하고, 분리된 흡수액은 흡수액 회수관 1(36)을 통하여 배출토록 구성된 디미스터 1(demister 1)(12)와;The gas containing the absorbent liquid discharged through the gas discharge port 11 formed at one side of the absorption tower body 20 is separated into a clean gas and an absorbent liquid, and the gas-separated clean gas is discharged to the final gas discharge port 13. The absorbed liquid is demister 1 (12) configured to be discharged through the absorbent liquid recovery pipe 1 (36); 흡수액 회수관 1(36)을 통해 배출된 흡수액을 회수하여 상부흡수액 공급조(25)의 액위를 일정하게 유지할 수 있도록 흡수액을 보충 공급하는 흡수액 보충 탱크(35);를 더 포함하여 구성한 것을 특징으로 하는 구조체를 따라 흐르는 흡수액이 구비된 스크러버.And an absorbent liquid replenishment tank 35 for replenishing and supplying the absorbent liquid so as to recover the absorbed liquid discharged through the absorbent liquid recovery pipe 1 36 to maintain the level of the upper absorbent liquid supply tank 25 at a constant level. Scrubber provided with an absorption liquid flowing along the structure to be. 제 1항에 있어서,The method of claim 1, 상기 하부흡수액 포집조(26)에 저장후 배출되는 하부흡수액 중 고형물을 제거하는 필터(30)와; A filter 30 for removing solids from the lower absorbent liquid which is stored in the lower absorbent liquid collecting tank 26 and discharged; 열매체를 이용하여 필터(30)를 지난 고형물이 제거된 하부흡수액 중에 흡수된 유해가스를 탈거하는 흡수액 탈거탑(40)과;An absorbent liquid stripping tower 40 for removing the harmful gas absorbed in the lower absorbent liquid from which the solid material passing through the filter 30 is removed using a heat medium; 흡수액 탈거탑(40)에서 탈거된 흡수액을 흡수탑 본체(20)로 재공급 하는 흡수액 순환용 회수 펌프(37);를 더 포함하여 구성한 것을 특징으로 하는 구조체를 따라 흐르는 흡수액이 구비된 스크러버.Absorbent liquid removal from the absorbent liquid stripping tower 40, the absorbent liquid circulation pump for resupply to the absorption tower body 20; 37; scrubber provided with the absorbent liquid flowing along the structure, characterized in that it further comprises. 제 5항에 있어서,The method of claim 5, 상기 흡수액 탈거탑(40)은 흡수액 탈거과정 중 생성된 탈거가스를 배출하는 탈거가스 배출구(54)와;The absorption liquid stripping tower 40 includes a stripping gas discharge port 54 for discharging stripping gas generated during the stripping process of the absorbent liquid; 탈거가스 배출구(54)를 통해 배출된 가스를 기액 분리하여 탈거가스(57)는 배출하여 회수시키고, 분리된 흡수액은 흡수액 회수관 2(56)를 통하여 흡수액 보충 탱크(35)로 회수시키는 디미스터 2(Demister2)(55);를 더 포함하여 구성한 것을 특징으로 하는 구조체를 따라 흐르는 흡수액이 구비된 스크러버.Demister to recover the gas discharged through the stripping gas outlet 54 by gas-liquid separation and the stripping gas 57 to discharge and recover the separated absorbent liquid to the absorbent liquid replenishment tank 35 through the absorbent liquid recovery pipe 2 56. 2 (Demister 2) (55); scrubber provided with an absorbing liquid flowing along the structure, characterized in that it further comprises. 제 5항에 있어서,The method of claim 5, 상기 흡수액 탈거탑(40)은,The absorption liquid stripping column 40, 상부쪽에서 상부 열매체 다공판(58)에 의해 나뉘어져 형성된 열매체 공급조(43)와;A heat medium supply tank 43 formed by being divided by an upper heat medium porous plate 58 at an upper side thereof; 하부쪽에서 하부 열매체 다공판(59)에 의해 나뉘어져 형성된 열매체 포집조(44)와;A heat medium collecting tank 44 formed by being divided by a lower heat medium porous plate 59 at a lower side thereof; 상부 열매체 다공판(58) 및 탈거탑 상부 다공판(47)에 의해 형성된 탈거될 흡수액 저장조(45)와;An absorbent liquid storage tank 45 to be removed formed by the upper heat medium porous plate 58 and the stripping column upper porous plate 47; 탈거탑 하부 다공판(48) 및 하부 열매체 다공판(59)에 의해 형성된 탈거된 흡수액 저장조(46)와;A stripped absorbent liquid storage tank 46 formed by the stripping column lower porous plate 48 and the lower heating medium porous plate 59; 상기 상부 열매체 다공판(58), 탈거탑 상부 다공판(47), 탈거탑 하부 다공판(48) 및 하부 열매체 다공판(59)을 관통하는 열매체 흐름관(41)으로 구성된 것을 특징으로 하는 구조체를 따라 흐르는 흡수액이 구비된 스크러버.A structure comprising a heat medium flow tube 41 passing through the upper heat medium porous plate 58, the stripping column upper porous plate 47, the stripping column lower porous plate 48, and the lower heat medium porous plate 59. Scrubber is provided with an absorbent liquid flowing along. 제 5항에 있어서,The method of claim 5, 상기 흡수액 탈거탑(40)은, The absorption liquid stripping column 40, 열매체 포집조(44) 일측에 형성되어 사용된 열매체를 배출하는 열매체 배출구(51)와;A heat medium discharge port 51 formed on one side of the heat medium collecting tank 44 to discharge the heat medium used; 열매체 배출구(51)로 배출된 열매체를 펌핑하는 열매체 순환용 펌프(53)와;A heat medium circulation pump 53 for pumping the heat medium discharged to the heat medium outlet 51; 열매체 순환용 펌프(53)로부터 순환 공급되는 열매체를 공급하도록 열매체 공급조(43) 일측에 형성된 열매체 공급구(52);를 더 포함하여 구성한 것을 특징으로 하는 구조체를 따라 흐르는 흡수액이 구비된 스크러버.And a heat medium supplying port (52) formed at one side of the heat medium supply tank (43) to supply the heat medium circulated and supplied from the heat medium circulation pump (53). 제 7항에 있어서,The method of claim 7, wherein 상기 탈거탑 상부 다공판(47) 및 탈거탑 하부 다공판(48)에는 탈거될 흡수액(31)이 열매체 흐름관(41) 외벽을 타고 흐른 후 탈거탑 하부 다공판(48)에 형성된 흡수액 흐름구를 통해 탈거된 흡수액 저장조(46)에 저장되도록 흡수액 흐름구가 형성된 것을 특징으로 하는 구조체를 따라 흐르는 흡수액이 구비된 스크러버.In the stripping column upper porous plate 47 and the stripping column lower porous plate 48, the absorbent liquid 31 to be removed flows through the outer wall of the heat medium flow pipe 41, and then the absorbent liquid flow port formed in the stripping column lower porous plate 48. Scrubber provided with the absorbent liquid flowing along the structure, characterized in that the absorbent liquid flow port is formed to be stored in the absorbent liquid storage tank 46 removed through. 휘발성 유기화합물이나 이산화탄소를 포함한 유해가스의 흡수처리방법에 있어서, In the method for absorbing harmful gases including volatile organic compounds and carbon dioxide, 제 1항 내지 9항 중 어느 한항에 따른 장치를 구비한 후, 흡수액을 흡수탑 상부다공판 및 흡수탑 하부다공판을 연결하는 실 모양의 구조체를 따라 흡수액이 흐르면서 유해가스를 흡수토록 한 것을 특징으로 하는 구조체를 따라 흐르는 흡수액이 구비된 스크러버를 이용한 유해가스의 흡수처리방법.After providing the apparatus according to any one of claims 1 to 9, the absorbent liquid is absorbed by the absorbent liquid flows along the thread-shaped structure connecting the upper column and the absorption tower lower perforated plate to absorb the harmful gas. Absorption treatment method for harmful gases using a scrubber provided with an absorbing liquid flowing along the structure. 휘발성 유기화합물이나 이산화탄소를 포함한 유해가스를 흡수액으로부터 탈거하는 흡수액 탈거처리방법에 있어서,In the absorbent liquid stripping method of removing toxic organic compounds including volatile organic compounds and carbon dioxide from the absorbent liquid, 제 1항 내지 9항 중 어느 한항에 따른 장치를 구비한 후, 열매체는 다공판을 통해 형성된 열매체 흐름관으로 열매체 공급조에서 열매체 포집조로 이동하며, 흡수탑을 거친 탈거될 흡수액은 탈거될 흡수액 저장조에서 다공판에 형성된 흡수액 흐름구를 통해 열매체 흐름관 외부를 따라 흐르면서 흡수액을 재생토록 하는 방법을 특징으로 하는 구조체를 따라 흐르는 흡수액이 구비된 스크러버를 이용한 흡수액 탈거처리방법.After providing the apparatus according to any one of claims 1 to 9, the heat medium is a heat medium flow tube formed through the porous plate to move from the heat medium supply tank to the heat medium collecting tank, the absorbent liquid to be removed through the absorption tower is to be removed absorbent storage tank Absorbing liquid stripping treatment method using a scrubber provided with the absorbent liquid flowing along the structure, characterized in that to flow along the outside of the heat medium flow pipe through the absorbent liquid flow port formed in the porous plate. 휘발성 유기화합물을 포함한 유해가스의 흡수와 탈거 처리방법에 있어서, In the method of absorbing and removing hazardous gases containing volatile organic compounds, 제 1항 내지 9항 중 어느 한항에 따른 장치를 구비한 후, After providing the device according to any one of claims 1 to 9, 흡수탑에서 실 모양의 구조체를 따라 흡수액이 흐르면서 유해가스를 흡수하고 동시에 사용된 흡수액을 탈거탑에서 열매체에 의해 탈거하여 재생된 흡수액을 흡수탑으로 재순환시키는 처리방법으로 유해가스 흡수와 탈거를 연속적으로 동시에 처리하는 방법을 특징으로 하는 구조체를 따라 흐르는 흡수액이 구비된 스크러버를 이용한 유해가스 흡수와 탈거 처리방법.Absorption liquid flows along the thread-shaped structure in the absorption tower to absorb harmful gas and at the same time remove the used absorption liquid by heat medium from the stripping column and recycle the regenerated absorbent liquid to the absorption tower. A method for absorbing and removing harmful gases using a scrubber having an absorbent liquid flowing along a structure, characterized in that the treatment is performed at the same time.
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