KR100908409B1 - Equipment for manufacturing carbides using sludge - Google Patents

Equipment for manufacturing carbides using sludge Download PDF

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Publication number
KR100908409B1
KR100908409B1 KR1020090016678A KR20090016678A KR100908409B1 KR 100908409 B1 KR100908409 B1 KR 100908409B1 KR 1020090016678 A KR1020090016678 A KR 1020090016678A KR 20090016678 A KR20090016678 A KR 20090016678A KR 100908409 B1 KR100908409 B1 KR 100908409B1
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South Korea
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sludge
exhaust gas
steam
furnace
indirect heating
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KR1020090016678A
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Korean (ko)
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강서희
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(주)랜드브릿지
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Priority to KR1020090016678A priority Critical patent/KR100908409B1/en
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Publication of KR100908409B1 publication Critical patent/KR100908409B1/en
Priority to CN2010800096574A priority patent/CN102333730A/en
Priority to JP2011551979A priority patent/JP2012519064A/en
Priority to PCT/KR2010/001173 priority patent/WO2010098590A2/en

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/001Incinerators or other apparatus for consuming industrial waste, e.g. chemicals for sludges or waste products from water treatment installations
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/10Treatment of sludge; Devices therefor by pyrolysis
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B47/00Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
    • C10B47/02Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion with stationary charge
    • C10B47/16Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion with stationary charge with indirect heating means both inside and outside the retorts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/027Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
    • F23G5/0276Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage using direct heating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/04Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment drying
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/08Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/08Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
    • F23G5/14Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion
    • F23G5/16Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion in a separate combustion chamber
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/44Details; Accessories
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23LSUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L7/00Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
    • F23L7/002Supplying water
    • F23L7/005Evaporated water; Steam
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2201/00Pretreatment
    • F23G2201/10Drying by heat
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2201/00Pretreatment
    • F23G2201/30Pyrolysing
    • F23G2201/304Burning pyrosolids
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/34Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

Abstract

A carbide manufacturing facility using sludge is provided to improve heat recovery efficiency through feedback of latent heat generated in combustion of the sludge in a carbonization furnace. A carbide manufacturing facility using sludge includes an indirect heating vapor drier(212), a molder(213), a carbonization furnace(214), a re-heating furnace(215), a waste heat boiler(216), a condenser(217), white lead reduction air pre-heater(218), and a cleaning-typed dust collector(220). The indirect heating vapor drier discharges moisture included in the sludge by heating the moisture, and uses the sludge by receiving the latent heat collected from the waste heat boiler as dry calories.

Description

슬러지를 이용한 탄화물 제조설비{Equipment for manufacturing carbides using sludge}Equipment for manufacturing carbides using sludge

본 발명은 슬러지를 이용한 탄화물 제조설비에 관한 것으로서, 보다 상세하게는 열회수율이 향상되고 배기가스 처리시스템이 개선된 슬러지를 이용한 탄화물 제조설비에 관한 것이다.The present invention relates to a carbide manufacturing equipment using sludge, and more particularly, to a carbide manufacturing equipment using sludge with improved heat recovery and improved exhaust gas treatment system.

종래에는 하천이나 하수폐기물을 통상적으로 소각 처분시키는게 일반적이었으나, 소각처분 과정에 있어 다이옥신류가 발생하는 문제가 있고, 특히 슬러지등은 다량의 수분이 포함되어 있어 소각처분을 위해 다량의 연료를 필요로하기 때문에 에너지 소비 등의 환경문제를 발생시키게 된다.Conventionally, it has been common to incinerate streams or sewage wastes in general, but there is a problem in that dioxins are generated in the incineration process, and in particular, sludge contains a large amount of water, and thus a large amount of fuel is required for incineration. This causes environmental problems such as energy consumption.

이러한 문제점을 해결하기 위해 근래에 와서는 슬러지등을 건조 탄화시켜 탄화물을 제조하여 자원의 재활용 및 환경문제를 개선시키는 추세에 있다.In order to solve this problem, recently, there is a trend to improve the recycling of resources and environmental problems by manufacturing carbide by dry carbonization of sludge.

일반적으로 슬러지를 이용한 탄화물 제조설비는 도 1에 도시된 바와 같다.In general, the carbide manufacturing equipment using sludge is as shown in FIG.

도 1를 참조하여, 일반적인 슬러지를 이용한 탄화물 제조설비를 살펴본다.Referring to Figure 1, looks at the carbide manufacturing equipment using a general sludge.

도시된 바와 같이, 종래의 슬러지를 이용한 탄화물 제조설비는 슬러지(111)를 공급받아 슬러지(111)에 포함된 수분량을 고온가열하여 감소시키는 직접가열열풍건조기(112)와, 건조된 슬러지분말을 일정한 형태의 패렛 또는 칩형태로 성형하는 성형기(113)와, 고온분위기하에서 슬러지패렛 또는 슬러지칩을 탄화시키는 탄화로(114)와, 탄화로(114)에서 발생한 가스를 연소시키는 재연소로(115)와, 재연소로(115)에서 발생한 연소가스를 고온가스로서 직접가열열풍건조기(112)로 재공급하는 공급로와, 재연소로(115)에서 발생하는 고압가스를 냉각시켜 백연저감공기예열기(118)로 보내는 가스냉각탑(116) 및 연소공기예열기(117)와, 연소공기예열기(117)으로부터 전달된 가스의 백연저감 및 집진시키는 백연저감공기예열기(118), 여과식집진기(119) 및 세정식집진기(120)를 포함하여 이루어진다.As shown, the conventional sludge carbide production equipment is supplied with a sludge 111, the direct heating air dryer (112) for reducing the amount of water contained in the sludge by heating at a high temperature, the dried sludge powder is constant A molding machine 113 for molding into a pellet or chip form, a carbonization furnace 114 for carbonizing sludge pallet or sludge chips under a high temperature atmosphere, a reburn furnace 115 for burning gas generated in the carbonization furnace 114, and In addition, the supply gas for resupplying the combustion gas generated in the reburn furnace 115 as a hot gas to the direct heating air dryer 112, and the high pressure gas generated in the reburn furnace 115 is cooled to the white smoke reduction air preheater 118. Outgoing gas cooling tower 116 and combustion air preheater 117, white smoke reduction air preheater 118, filtration precipitator 119 and cleaning precipitator to reduce and dust-collect the gas delivered from the combustion air preheater 117 ( 120) It achieved by also.

하지만, 이러한 종래의 슬러지를 이용한 탄화물 제조설비에서 재연소로(115)에서의 에너지회수 효율 및 배기가스 처리의 공정상의 문제가 발생된다.However, in the conventional carbide manufacturing equipment using sludge, problems of energy recovery efficiency and exhaust gas treatment in the reburn furnace 115 occur.

종래의 슬러지를 이용한 탄화물 제조설비의 경우 배기가스의 현열을 이용하기 때문에 다량의 배기가스가 필요하고, 배기가스량이 많기 때문에 그대로 재연소로에서 850℃로 연소시키려면 많은 연료가 소모되는 문제가 있다.Carbide manufacturing equipment using conventional sludge uses a large amount of exhaust gas because it uses the sensible heat of the exhaust gas, and there is a problem in that a large amount of fuel is consumed to burn at 850 ° C. in the reburn furnace as it is because the amount of exhaust gas is large.

또한, 종래의 슬러지를 이용한 탄화물 제조설비의 경우 후단에서 가스냉각탑(116), 연소공기예열기(117), 백연저검공기예열기(118), 여과식집진기(119) 및 세정식집진기(120)의 5공정으로 이루어져 처리공정이 복잡하고 더스트(dust)가 퇴적했을 경우의 제거가 어려우며, 배기가스량이 다량으로 발생되는 문제가 있다.In the case of a conventional sludge carbide production equipment, the gas cooling tower 116, the combustion air preheater 117, the low smoke air preheater 118, the filtration precipitator 119, and the cleaning precipitator 120 at the rear stage. It is difficult to remove when dust is accumulated due to a complicated treatment process, and there is a problem that a large amount of exhaust gas is generated.

상술한 종래의 문제점을 해결하기 위한 본 발명의 목적은, 탄화로에서의 슬러지의 탄화에 동반하여 발생되는 가스를 연소시켜, 연소시 발생되는 잠열을 이용하여 건조기로 피드백시켜 열회수효율을 높이는 것과 함께 배기가스 처리 효율을 높일 수 있는 탄화물 제조설비를 제공하는 것에 있다.An object of the present invention for solving the above-mentioned problems is to burn a gas generated in conjunction with carbonization of sludge in a carbonization furnace, and feed back to a dryer by using latent heat generated during combustion to increase heat recovery efficiency. An object of the present invention is to provide a carbide manufacturing apparatus capable of increasing the exhaust gas treatment efficiency.

상술한 과제를 해결하기 위한 본 발명에 따른 슬러지를 이용한 탄화물 제조설비는, 슬러지를 고온증기에 의하여 가열시켜 상기 슬러지에 함유된 수분을 제거하고, 수분이 제거된 건조 슬러지를 컨베이어를 통해 탄화로로 공급하는 간접가열증기건조기와; 상기 건조 슬러지를 고온분위기하에서 탄화시키는 탄화로와; 상기 탄화로에서 발생된 가스를 연소시키는 재연소로와; 상기 재연소로에서 발생한 열을 고온증기로서 상기 간접가열증기건조기로 공급하는 폐열보일러와; 상기 간접가열증기건조기로부터 배출되는 증기를 냉각하여 증발한 증기를 응축하여 상기 재연소로로 공급하는 응축기;를 포함하여 이루어진다. Carbide manufacturing equipment using the sludge according to the present invention for solving the above problems, by heating the sludge by hot steam to remove the water contained in the sludge, the dry sludge from the water is removed through a conveyor into a carbonization furnace An indirect heating steam dryer for supplying; A carbonization furnace for carbonizing the dry sludge under a high temperature atmosphere; A reburn furnace for burning the gas generated in the carbonization furnace; A waste heat boiler for supplying the heat generated from the reburn furnace to the indirect heated steam dryer as high temperature steam; And a condenser for cooling the steam discharged from the indirect heating steam dryer to condense the vaporized vapor and supply it to the reburn furnace.

여기서, 상기 슬러지를 이용한 탄화물 제조설비에서 발생하는 배기가스의 처리는 백연저감공기예열기, 여과식집진기 및 세정식집진기의 3공정으로 이루어지는 것을 특징으로 하여 이루어진다. Here, the treatment of the exhaust gas generated in the carbide production equipment using the sludge is characterized in that it consists of three processes: a white smoke reduction air preheater, a filter dust collector and a cleaning dust collector.

상술한 본 발명의 구성에 따르면, 탄화로에서의 슬러지의 탄화에 동반하여 발생되는 가스를 연소시켜, 연소시 발생되는 잠열을 이용하여 건조기로 피드백시켜 열회수효율을 높이는 것과 함께 배기가스 처리 효율을 높일 수 있는 탄화물 제조설비를 제공하는 것이 가능하게 된다.According to the configuration of the present invention described above, by burning the gas generated in conjunction with the carbonization of the sludge in the carbonization furnace, feed back to the dryer by using the latent heat generated during combustion to increase the heat recovery efficiency and increase the exhaust gas treatment efficiency It is possible to provide a carbide manufacturing facility which can be used.

이하, 첨부된 도면을 참조하여 본 발명에 따른 슬러지를 이용한 탄화물 제조설비을 설명한다.Hereinafter, a carbide manufacturing apparatus using sludge according to the present invention will be described with reference to the accompanying drawings.

도 2는 본 발명의 슬러지를 이용한 탄화물 제조설비의 블록도를 도시한 것이다. Figure 2 shows a block diagram of the carbide production equipment using the sludge of the present invention.

도시된 바와 같이, 본 발명의 슬러지를 이용한 탄화물 제조설비는 간접가열증기건조기(212), 성형기(213), 탄화로(214), 재연소로(215), 폐열보일러(216), 응축기(217), 백연저감공기예열기(218), 여과식집진기(219) 및 세정식집진기(220)를 포함하여 이루어진다.As shown, the carbide manufacturing equipment using the sludge of the present invention is indirect heating steam dryer 212, molding machine 213, carbonization furnace 214, reburn furnace 215, waste heat boiler 216, condenser 217 , A white smoke reduction air preheater 218, a filter dust collector 219, and a cleaning dust collector 220.

간접가열증기건조기(212)는 슬러지(211)를 공급받아 슬러지(211)에 포함된 수분량을 고온가열하여 감소시켜 배출하며, 폐열보일러(216)로부터 열회수된 잠열 을 피드백받아 슬러지(211)를 건조하는 열량으로 사용한다.The indirect heating steam dryer 212 receives the sludge 211 and discharges it by reducing the amount of moisture contained in the sludge 211 at a high temperature, and drying the sludge 211 by feeding back the latent heat recovered from the waste heat boiler 216. Use in calories to make.

성형기(213)는 간접가열증기건조기(212)로부터 건조된 슬러지의 분말형태를 일정한 형태의 패렛 또는 칩형태로 성형하여 탄화로(214)로 공급한다.The molding machine 213 forms a powder of sludge dried from the indirect heating steam dryer 212 into a pellet or chip of a predetermined shape and supplies it to the carbonization furnace 214.

탄화로(214)는 고온분위기하에서 성형기(213)로부터 공급받은 슬러지패렛 또는 슬러지칩을 탄화시킨다. 탄화로(214)의 구조는 직접가열 회전로상식, 간접가열 회전로상식 및 간접가열 스크류식 등이 있다.The carbonization furnace 214 carbonizes the sludge pallet or sludge chips supplied from the molding machine 213 under a high temperature atmosphere. The structure of the carbonization furnace 214 includes a direct heating rotary type, an indirect heating rotary type, and an indirect heating screw type.

재연소로(215)는 탄화로(214)에서 발생한 가스를 연소시키며, 이때 발생되는 열을 폐열보일러(216)로 보낸다.The reburn furnace 215 combusts the gas generated in the carbonization furnace 214, and sends heat generated at this time to the waste heat boiler 216.

폐열보일러(216)는 재연소로(215)에서 발생한 열을 고온증기로 열회수하여 간접가열증기건조기(212)로 피드백 공급하여 간접가열증기건조기(212)로 하여금 슬러지(211)를 건조하는 열원으로 사용토록 한다.The waste heat boiler 216 heats the heat generated from the reburn furnace 215 to high temperature steam and feeds it back to the indirect heating steam dryer 212 so that the indirect heating steam dryer 212 serves as a heat source for drying the sludge 211. Do it.

응축기(217)는 간접가열증기건조기(212)로부터 배출되는 증기를 냉각하여 증발한 증기를 응축하여 재연소로(215)로 공급한다.The condenser 217 cools the steam discharged from the indirect heating steam dryer 212 and condenses the vaporized vapor to be supplied to the reburn furnace 215.

폐열보일러(216)로부터 발생된 증기의 대부분은 슬러지(211)를 건조하는 간접가열증기건조기(212)로 공급되고 나머지 일부 잔량은 부착된 더스트 제거를 위해 백연저감공기예열기(218)로 보내져 세정식집진기(220)를 거쳐 배기가스에 포함되어 대기로 방출된다.Most of the steam generated from the waste heat boiler 216 is supplied to the indirect heating steam dryer 212 for drying the sludge 211, and the remaining part is sent to the low smoke air preheater 218 to remove the attached dust and washed. It is included in the exhaust gas through the dust collector 220 and is discharged to the atmosphere.

또한, 폐열보일러(216)로부터 발생된 배기가스는 여과식집진기(219) 및 세정식집진기(220)를 거쳐 대기로 방출된다.In addition, the exhaust gas generated from the waste heat boiler 216 is discharged to the atmosphere through the filter dust collector 219 and the cleaning dust collector 220.

이러한 구조의 탄화로 제조설비는 종래의 탄화물 제조설비에 비해 에너지 회수율이 우수하고 배기가스의 처리공정이 단순화되며 배기가스 배출량도 소량이어서 에너지 및 환경친화적 설비를 제공할 수 있게 된다. 좀 더 구체적으로 에너지 회수율 및 배기가스 배출량을 종래의 것과 비교하여 이하에서 설명한다.The carbonization furnace of this structure has better energy recovery than conventional carbide production facilities, simplifies the process of treating exhaust gases, and emits small amounts of exhaust gases, thereby providing energy and environment-friendly facilities. More specifically, the energy recovery rate and the exhaust gas emissions will be described below in comparison with the conventional one.

이하의 내용은 하수슬러지 100톤/일 탄화시 직접가열열풍건조(종래)와 간접가열증기건조(본 발명)의 프로세스 밸런스를 나타내며, 기본적인 비교를 위해 기기의 방열율 이나 리크(leak), 공기양, 탄화 열분해의 비율은 가능한 동일 조건으로 한다. The following shows the process balance of direct heating air drying (conventional) and indirect heating steam drying (invention) for 100 tons of sewage sludge per day, and the heat dissipation rate, leakage and air volume of the device for basic comparison. The rate of pyrolysis of carbonization is to be the same as possible.

[슬러지 건조에 사용하는 열원의 비교 ][Comparison of Heat Sources Used for Sludge Drying]

먼저, 도 1 및 도 2에 도시된 슬러지를 건조하여 성형기(113, 213) 및 탄화로(114, 214) 까지의 공정은 동일하며, 슬러지 건조에 필요한 열량이나 탄화로(114, 214)로부터 배기되는 배기가스의 양도 동일하다.First, the sludge shown in FIGS. 1 and 2 is dried, and the processes up to the molding machines 113 and 213 and the carbonization furnaces 114 and 214 are the same, and the heat from the heat or carbonization furnaces 114 and 214 required for sludge drying is exhausted. The amount of exhaust gas is also the same.

즉, 슬러지에 함유된 수분을 증발시키기 위해 3,056Kg/h(증발시키는 수분)×600 kcal/kg(증발 잠열)=1,833,333 kcal/h가 필요 열량이 된다. That is, 3,056 Kg / h (water evaporating) x 600 kcal / kg (latent heat of evaporation) = 1,833,333 kcal / h is required calorie in order to evaporate the water contained in the sludge.

직접가열열풍 건조(종래)의 경우 배기가스의 현열을 이용하기 때문에, 다량의 배기가스가 필요하며, 반대로 간접가열증기 건조(본 발명)의 경우 증기의 잠열로 가열하기 때문에 소량의 증기로 건조할 수 있다.In the case of the direct heating wind drying (conventional), since the sensible heat of the exhaust gas is used, a large amount of the exhaust gas is required, whereas in the case of the indirect heating steam drying (the present invention), it is heated by the latent heat of the steam. Can be.

일반적으로 잠열(latent heat)은 상태의 변화를 수반하는 열량으로, 예를 들면 수분이 액체의 물로부터 수증기로 변화하는 경우 그 온도는 변화하지 않고 약 600 kcal/kg의 열량의 변화만 있다. 이에 비해 현열(sensible heat)은 온도 변화를 수반하므로 상태의 변화가 없는 열량 변화로 비열(kcal/Nm3℃)×온도 변화(℃) 분의 열량 변화밖에 없게 된다. In general, latent heat is a quantity of heat accompanied by a change of state, for example, when moisture changes from liquid water to water vapor, its temperature does not change but only a change in heat of about 600 kcal / kg. In contrast, since sensible heat is accompanied by a change in temperature, there is only a change in calories for a specific heat (kcal / Nm3 ° C.) × change in temperature (° C.) due to a change in heat without a change in state.

현열은 온도 변화를 알 수 있지만, 잠열은 온도 변화를 모르기 때문에, 이러한 단어로 구별되며, 당연히 잠열의 경우는 온도가 변화하지 않아도 상태의 변화 (액체→기체, 기체→액체)로 열량 변화를 알 수 있다.Sensible heat is distinguished by these words because latent heat does not know the change in temperature, and of course, latent heat is known by the change of state (liquid → gas, gas → liquid) even if the temperature does not change. Can be.

직접가열열풍 건조(종래)의 경우, 필요 배기가스량 = 증발에 필요한 열량÷배기가스 평균 비열÷(배기가스 입구 온도-배기가스 출구 온도)가 된다.In the case of direct heating wind drying (conventional), the amount of exhaust gas required = calories required for evaporation ÷ exhaust gas average specific heat ÷ (exhaust gas inlet temperature-exhaust gas outlet temperature).

배기가스의 비열은 대체로 0.35kcal/Nm3℃ 출입구 온도차는 약 500℃ 이므로 단순히 계산하면 1,833,333÷0.35÷500=10,500 Nm3/h의 배기가스가 필요하며, 리크(leak) 공기에 의한 냉각을 고려하면 좀 더 여유를 둔 12,346Nm3/h의 배기가스가 필요하게 된다.Since the specific heat of exhaust gas is about 0.35kcal / Nm 3 ℃ entrance temperature difference is about 500 ℃, simply calculate 1,833,333 ÷ 0.35 ÷ 500 = 10,500 Nm 3 / h exhaust gas and consider cooling by leak air. This would require 12,346 Nm 3 / h of more exhaust gas.

간접가열증기 건조(본 발명)의 경우, 간접적으로 증기가 슬러지를 건조하고 증기가 드레인이 되는 잠열을 이용하기 때문에, 적은 양의 수증기로 건조할 수 있다. 즉, 필요 증기량 = 증발에 필요한 열량÷증기의 잠열이 된다.In the case of indirect heating steam drying (the present invention), since steam uses indirect heat to dry the sludge and steam is a drain, it can be dried with a small amount of steam. That is, the amount of steam required = latent heat of calories ÷ steam necessary for evaporation.

9 kgf/cm2의 증기를 응축시켜 2 kgf/cm2의 열수에서 회수하는 경우 662(9 kgf/cm2에서의 엔탈피)-133(2 kgf/cm2에서의 엔탈피)=529 kcal/kg 수증기이므로, 단순 계산에서 필요 증기량을 구하면 1,833,333÷529=3,465 kg-수증기/h가 되며, 8 kgf/cm2의 증기를 응축시켜 2 kgf/cm2의 열수에서 회수하는 경우는 3,972kg/h 수증기량이 필요하게 된다.When condensing 9 kgf / cm 2 steam and recovering from 2 kgf / cm 2 hot water, 662 (enthalpy at 9 kgf / cm 2 ) -133 (enthalpy at 2 kgf / cm 2 ) = 529 kcal / kg steam From a simple calculation, the required steam volume is 1,833,333 ÷ 529 = 3,465 kg steam / h, and 3,972 kg / h steam volume is required for condensing 8 kgf / cm 2 steam and recovering it from 2 kgf / cm 2 hot water. Done.

[건조기에서의 배기가스량][Exhaust amount in the dryer]

직접가열열풍 건조(종래)의 경우, 직접 슬러지에 접촉하여 수분을 증발시키 기 위해 건조기(112)에서의 배기가스는 입구 배기가스+슬러지의 증발 수분이 되어 18,148 Nm3/h 이고, 간접가열증기 건조의 경우(본 발명)는, 열교환된 증기는 드레인이 되어 회수되기 때문에 건조기(212) 배기가스는 슬러지로부터의 증발 수분+리크(leak) 공기량만이 되어 5,802 Nm3/h 이 된다.In the case of direct heating wind drying (conventional), the exhaust gas from the dryer 112 becomes 18,148 Nm 3 / h as the evaporative water of the inlet exhaust gas + sludge to directly contact the sludge to evaporate the moisture, and the indirect heating steam. In the case of drying (the present invention), since the heat-exchanged steam is recovered as a drain, the exhaust gas of the dryer 212 becomes only 5,802 Nm 3 / h as the amount of evaporated water + leak air from the sludge.

[재연소로로 들어오는 배기가스][Exhaust gas coming into the reburn furnace]

직접가열열풍 건조(종래)의 경우는 배기가스량(14,838Nm3/h, 624℃)이 많기 때문에 그대로 재연소로(115)에서 850℃로 연소시키려면 많은 연료가 필요하기 때문에, 재연소로(115) 출구 배기가스의 일부와 연소공기예열기(117)에서 열교환시켜 배기가스 온도를 올려 연료소모량을 줄일 필요가 있다.In the case of direct heating wind drying (conventional), since the amount of exhaust gas (14,838 Nm 3 / h, 624 ° C.) is large, since a large amount of fuel is required to burn the combustion furnace 115 at 850 ° C., the reburn furnace 115 It is necessary to reduce the fuel consumption by raising the exhaust gas temperature by exchanging a part of the outlet exhaust gas with the combustion air preheater 117.

한편, 간접가열증기 건조(본 발명)의 경우는 배기가스가 응축기(217)에서 냉각하여 증발한 증기를 응축시키는 것으로 재연소로(215)로 전달되는 배기가스량(2,275 Nm3/h, 50 ℃)을 극단적으로 줄일 수 있다.On the other hand, in the case of indirect heating steam drying (invention), the amount of exhaust gas (2,275 Nm 3 / h, 50 ° C.) delivered to the reburn furnace 215 by condensing the vapor evaporated by cooling the exhaust gas in the condenser 217. Can be reduced to an extreme.

즉, 배기가스량이 적기 때문에 연소공기예열기로 열교환할 필요가 없게 되어 연소공기예열기가 필요없는 설비가 가능하다.In other words, since the amount of exhaust gas is small, it is not necessary to heat exchange with the combustion air preheater, and thus an installation without the combustion air preheater is possible.

[재연소로의 연료소모량][Fuel consumption to reburn]

직접가열열풍 건조(종래)의 경우 재연소로(115)에서의 배기가스량(14,838Nm3/h, 624℃)은 매우 많고, 간접가열증기건조(본 발명)의 경우 배기가 스량(2,275 Nm3/h, 50 ℃)은 온도가 낮음에도 불구하고 소량이기 때문에 재연소로에서의 필요 연료소모량은 크게 다르다.In the case of direct heating wind drying (conventional), the amount of exhaust gas in the reburn furnace 115 (14,838 Nm 3 / h, 624 ° C.) is very large, and in the case of indirect heating steam drying (invention), the amount of exhaust gas (2,275 Nm 3 / h, 50 ° C) is small in spite of the low temperature, so the required fuel consumption in the reburn furnace is very different.

즉, 직접가열열풍 건조(종래)의 경우 재연소로(115) 연료소모량 은 159kg/h (중유)이며, 간접가열증기 건조(본 발명)의 경우 재연소로(215) 연료소모량은 40kg/h(중유)만이 필요하여 연료소모량 면에서 약 4배의 에너지가 절감될 수 있다.That is, in the case of direct heating wind drying (conventional), the reburn furnace 115 consumes 159 kg / h (heavy oil), and indirect heating steam drying (invention) reburn furnace 215, consumes 40 kg / h (heavy oil). ), Only about 4 times less energy can be saved in terms of fuel consumption.

[재연소로 배기되는 배기가스량][Exhaust Gas Exhaust by Reburning]

직접가열열풍 건조(종래)의 경우 재연소로(115)로부터 배기되는 배기가스량(23,641 Nm3/h 850 ℃)은 많고, 간접가열증기 건조(본 발명)의 경우 재연소로(215)로부터 배기되는 배기가스량(9,446 Nm3/h 850 ℃)은 매우 적다.In the case of direct heating wind drying (conventional), the amount of exhaust gas exhausted from the reburn furnace 115 (23,641 Nm3 / h 850 ° C.) is large, and in the case of indirect heating steam drying (invention), the amount of exhaust gas exhausted from the reburn furnace 215. (9,446 Nm 3 / h 850 ° C.) is very low.

[배기가스의 배분 필요관계][Required relationship of exhaust gas distribution]

직접가열열풍 건조(종래)의 경우는 일부의 재연소로(115) 배기가스는 850℃에서 슬러지 건조용으로, 나머지는 가스 냉각탑(116)에서 온도를 떨어뜨려 연소공기예열기(117)로 보내진다. 이는 여과식집진기(119) 입구 가스 온도를 170~180℃까지 내릴 필요가 있기 때문이지만, 이 프로세스 온도 조절을 위한 가스 냉각탑(116)에서의 물 분무가 한층 더 배기가스 건조의 경우 배기가스량을 늘리게 된다. 반면에 간접가열증기 건조(본 발명)의 경우는 가스냉각탑이 필요없는 설비구조로 인하여 배기가스량을 적게할 수 있게 된다.In the case of direct heating wind drying (conventional), some of the reburn furnace 115 exhaust gas is sent to the combustion air preheater 117 by dropping the temperature in the gas cooling tower 116 for sludge drying at 850 ℃. This is because the inlet gas temperature of the filter dust collector 119 needs to be reduced to 170 to 180 ° C, but water spraying in the gas cooling tower 116 for controlling the process temperature further increases the amount of exhaust gas in case of exhaust gas drying. do. On the other hand, indirect heating steam drying (the present invention) can reduce the amount of exhaust gas due to the installation structure does not require a gas cooling tower.

가스 냉각탑 분무수량(직접가열열풍건조)은 851 kg/h, 가스 냉각탑 분무수량(간접가열증기건조)의 경우 가스냉각탑이 필요없으며, 여과식집진기 입구 배기 가스(직접가열열풍건조)의 경우 15,749Nm3/h 180 ℃가 배출되고, 여과식집진기 입구 배기가스(간접가열증기건조)의 경우 9,446Nm3/h 175 ℃가 배출된다.Gas cooling tower spray water (direct heating hot air drying) is 851 kg / h, gas cooling tower spray water quantity (indirect heating steam drying) does not require gas cooling tower, and 15,749 Nm for filter dust collector inlet exhaust gas (direct heating hot air drying) 3 / h 180 ℃ is discharged, 9,446 Nm 3 / h 175 ℃ is emitted in the case of the bag filter inlet exhaust gas (indirect heating steam drying).

[백연저감을 포함한 최종 배기가스량][Final exhaust gas including smoke reduction]

직접가열열풍 건조(종래)의 경우, 굴뚝 배출 배기가스는 23,118 Nm3/h 198℃가 배출되며, 간접가열증기건조(본 발명)의 경우, 굴뚝 배출 배기가스는10,093Nm3/h 167℃가 배출된다.In the case of direct heating wind drying (conventional), the chimney exhaust exhaust gas is discharged at 23,118 Nm 3 / h 198 ° C. In the case of indirect heating steam drying (invention), the chimney exhaust exhaust gas is 10,093Nm 3 / h 167 ° C. Discharged.

[배기가스 조성과 백연 방지 범위][Exhaust gas composition and white smoke prevention range]

[표 1]에 따라 직접가열열풍건조의 경우는 배기가스양도 많고 수분 비율도 높은 배기가스가 되며, 간접가열증기건조의 경우는 보일러에서 배기가스를 냉각하는 것에서 수분 비율이 낮은 배기가스가 된다. 그 때문에 다음 페이지에 나타냈듯이 간접가열증기건조의 배기가스가 확연히 백연 방지의 적용 범위가 넓어진다.According to [Table 1], in case of direct heating air drying, the exhaust gas has a large amount of exhaust gas and a high moisture content, and indirect heating steam drying becomes exhaust gas having a low moisture ratio when cooling the exhaust gas in a boiler. Therefore, as shown on the next page, the exhaust gas of indirect heating steam drying significantly extends the application range of the smoke prevention.

Figure 112009012216410-pat00001
Figure 112009012216410-pat00001

이상 첨부된 도면을 참조하여 본 발명의 바람직한 실시예를 설명하였지만, 상술한 본 발명의 기술적 구성은 본 발명이 속하는 기술 분야의 당업자가 본 발명의 그 기술적 사상이나 필수적 특징을 변경하지 않고서 다른 구체적인 형태로 실시될 수 있다는 것을 이해할 수 있을 것이다. 그러므로 이상에서 기술한 실시예들은 모든 면에서 예시적인 것이며 한정적인 것이 아닌 것으로서 이해되어야 하고, 본 발명의 범위는 상기 상세한 설명보다는 후술하는 특허청구범위에 의하여 나타내어지며, 특허청구범위의 의미 및 범위 그리고 그 등가 개념으로부터 도출되는 모든 변경 또는 변형된 형태가 본 발명의 범위에 포함되는 것으로 해석되어야 한다.Although the preferred embodiments of the present invention have been described above with reference to the accompanying drawings, the above-described technical configuration of the present invention may be embodied by those skilled in the art to which the present invention pertains without changing its technical spirit or essential features of the present invention. It will be appreciated that the present invention may be practiced as. Therefore, the above-described embodiments are to be understood as illustrative and not restrictive in all respects, and the scope of the present invention is indicated by the appended claims rather than the detailed description, and the meaning and scope of the claims and All changes or modifications derived from the equivalent concept should be interpreted as being included in the scope of the present invention.

도 1은 종래의 슬러지를 이용한 탄화물 제조설비의 블록도를 도시한 것이다.1 is a block diagram of a carbide manufacturing facility using a conventional sludge.

도 2는 본 발명의 슬러지를 이용한 탄화물 제조설비의 블록도를 도시한 것이다.Figure 2 shows a block diagram of the carbide production equipment using the sludge of the present invention.

Claims (2)

슬러지를 폐열보일러로부터 피드백되어 공급된 고온증기에 의하여 가열시켜 상기 슬러지에 함유된 수분을 제거하고, 수분이 제거된 건조 슬러지를 컨베이어를 통해 탄화로로 공급하는 간접가열증기건조기와;An indirect heating steam dryer for heating the sludge by hot steam fed back from the waste heat boiler to remove water contained in the sludge, and supplying the dried sludge to the carbonization furnace through the conveyor; 상기 건조 슬러지를 고온분위기하에서 탄화시키는 탄화로와;A carbonization furnace for carbonizing the dry sludge under a high temperature atmosphere; 상기 탄화로에서 발생된 가스를 연소시키는 재연소로와;A reburn furnace for burning the gas generated in the carbonization furnace; 상기 재연소로에서 발생한 열을 고온증기로서 상기 간접가열증기건조기로 공급하고 배기가스는 배출하는 폐열보일러와;A waste heat boiler for supplying heat generated from the reburn furnace to the indirect heating steam dryer as high temperature steam and discharging the exhaust gas; 상기 간접가열증기건조기로부터 배출되는 증기를 응축하여 응축수는 배출하고, 수증기는 상기 재연소로로 공급하는 응축기;를, 포함하는 슬러지를 이용한 탄화물 제조설비.And a condenser for condensing the steam discharged from the indirect heated steam dryer and discharging condensed water and supplying the steam to the reburn furnace. 제1항에 있어서,The method of claim 1, 상기 슬러지를 이용한 탄화물 제조설비에서 발생하는 배기가스의 처리는 백연저감공기예열기, 여과식집진기 및 세정식집진기의 3공정으로 이루어지는, 슬러지를 이용한 탄화물 제조설비.The treatment of the exhaust gas generated from the carbide production equipment using the sludge is a sludge carbide production equipment consisting of three processes: a low smoke air preheater, a filter dust collector and a cleaning dust collector.
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JP2011551979A JP2012519064A (en) 2009-02-27 2010-02-25 Carbide manufacturing equipment using sludge
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103225810A (en) * 2012-01-31 2013-07-31 月岛机械株式会社 A pressurized fluidized furnace
CN111533128A (en) * 2020-05-15 2020-08-14 中天超容科技有限公司 Preparation device and preparation method of activated carbon for supercapacitor

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019142387A1 (en) * 2018-01-18 2019-07-25 川崎重工業株式会社 Method for treating sludge and cement manufacturing system
CN110748899A (en) * 2019-11-27 2020-02-04 中国华能集团清洁能源技术研究院有限公司 Coal-fired coupled sludge drying incineration system and method considering waste heat utilization
CN114163099A (en) * 2021-11-29 2022-03-11 上海发电设备成套设计研究院有限责任公司 Manifold type sludge drying system

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR200218031Y1 (en) * 2000-10-13 2001-03-15 주식회사대한건설엔지니어링 Multipurpose Refuse Ram Feed Incinerator
KR20010038613A (en) * 1999-10-26 2001-05-15 박경만 The drying system and method for fuelizing of wet sludge
KR20080110969A (en) * 2008-11-28 2008-12-22 (주)한국환경기술 Sludge drying and carbonization apparatus

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000084597A (en) * 1998-09-11 2000-03-28 Toshiba Plant Kensetsu Co Ltd Sludge drying apparatus
JP2000317258A (en) * 1999-05-06 2000-11-21 Ishikawajima Harima Heavy Ind Co Ltd Flue gas desulfurization equipment
KR100482187B1 (en) * 2001-09-20 2005-04-13 니폰 조키 세야쿠 가부시키가이샤 Method and apparatus for carbonization treatment of organic waste
KR100643183B1 (en) * 2003-06-27 2006-11-10 한국하이테크 주식회사 apparatus for manufacturing a charcoal used a sludge
JP2006207960A (en) * 2005-01-31 2006-08-10 Ishikawajima Harima Heavy Ind Co Ltd Highly wet object treating device and method
JP2008201964A (en) * 2007-02-21 2008-09-04 Mitsubishi Heavy Ind Ltd Process and system for producing solid fuel

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010038613A (en) * 1999-10-26 2001-05-15 박경만 The drying system and method for fuelizing of wet sludge
KR200218031Y1 (en) * 2000-10-13 2001-03-15 주식회사대한건설엔지니어링 Multipurpose Refuse Ram Feed Incinerator
KR20080110969A (en) * 2008-11-28 2008-12-22 (주)한국환경기술 Sludge drying and carbonization apparatus

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103225810A (en) * 2012-01-31 2013-07-31 月岛机械株式会社 A pressurized fluidized furnace
CN103225810B (en) * 2012-01-31 2017-05-24 月岛机械株式会社 A pressurized fluidized furnace
CN111533128A (en) * 2020-05-15 2020-08-14 中天超容科技有限公司 Preparation device and preparation method of activated carbon for supercapacitor

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